News & Views |
Featured
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In Your Element |
Rhodium roles
Lars Öhrström relates the various roles played by rhodium in our daily lives, ranging from car components to drugs.
- Lars Öhrström
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News & Views |
Packing heat
Nanoscopic templates functionalized with light-reactive chromophores could ultimately be used to store solar energy and later release it as heat. Now, it has been shown that packing the chromophores together increases both storage capacity and lifetime.
- Nathan R. Neale
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Article |
Charging a Li–O2 battery using a redox mediator
Recharging Li–O2 batteries requires oxidation of the discharge product solid Li2O2. Now a redox-mediating molecule is shown to assist this process by transferring electron–holes between solid Li2O2 and the positive electrode in a non-aqueous Li–O2 cell. This allows the cell to be charged at rates that are otherwise impossible.
- Yuhui Chen
- , Stefan A. Freunberger
- & Peter G. Bruce
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Article |
Shape-selective sieving layers on an oxide catalyst surface
Templated atomic layer deposition (ALD) is used to create oxide ‘nanocavities’ on the surface of catalyst particles. Subnanometre-nm films containing nanocavities act as sieves for the underlying catalyst, resulting in high selectivities for the smaller of two reactants in competitive oxidations or reductions.
- Christian P. Canlas
- , Junling Lu
- & Justin M. Notestein
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Article |
Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host
Porous solids are well suited to the capture of environmentally harmful gases, but further understanding of the solid–gas interactions involved is required. Combining dynamic and static characterization with modelling, researchers have now described how a metal–organic framework binds CO2 and SO2 selectively through hydroxyl groups — rather than amine ones as typically featured.
- Sihai Yang
- , Junliang Sun
- & Martin Schröder
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News & Views |
Feeling the strain
Characterizing electrochemical behaviour on the nanometre scale is fundamental to gaining complete insight into the working mechanisms of fuel cells. The application of a new scanning probe microscopy technique can now relate local surface structure to electrochemical activity at a resolution below 10 nm.
- Johannes A. A. W. Elemans
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Article |
High-efficiency dye-sensitized solar cells with ferrocene-based electrolytes
Dye-sensitized solar cells combining electrolytes based on the ferrocene/ferrocenium redox couple with a metal-free organic donor–acceptor sensitizer are reported to achieve a record 7.5% energy conversion efficiency, revealing the great potential of ferrocene-based electrolytes for future dye-sensitized solar cell applications.
- Torben Daeneke
- , Tae-Hyuk Kwon
- & Leone Spiccia
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Research Highlights |
Checking out curves
The complex pore structures of mesoporous crystals can be elucidated by assessing the curvature of their boundary surface.
- Neil Withers
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Perspective |
Porous organic molecules
When it comes to porosity, the materials that spring to mind are typically one-, two- or three-dimensional extended networks. In this Perspective, discrete organic molecules are discussed that form porous solids — either owing to hollow molecular structures or simply through inefficient packing — with different properties from those of extended networks.
- James R. Holst
- , Abbie Trewin
- & Andrew I. Cooper
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Article |
Enhanced electrocatalysis of the oxygen reduction reaction based on patterning of platinum surfaces with cyanide
The phosphoric acid fuel cell is limited by its slow rate of oxygen reduction at the cathode, but now an approach to the rational design of improved catalysts for this process has been developed. Molecular patterning of platinum surfaces with cyanide adsorbates is used to block the adsorption of spectator anions without hindering oxygen reduction, thus improving catalytic activity.
- Dusan Strmcnik
- , María Escudero-Escribano
- & Nenad M. Marković
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Article |
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte
Aqueous lithium-ion batteries have great potential as stationary power sources, but they have had problems with poor stability. A significant improvement in their cycling stability has been achieved by eliminating oxygen, adjusting the electrolyte pH values, and using a carbon-coated electrode material.
- Jia-Yan Luo
- , Wang-Jun Cui
- & Yong-Yao Xia
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Article |
An organic redox electrolyte to rival triiodide/iodide in dye-sensitized solar cells
Although the triiodide/iodide redox couple works efficiently in dye-sensitized solar cells it restricts functionality by absorbing visible light. Now, a disulfide/thiolate redox couple that has negligible absorption in the visible spectral range is presented, which in conjunction with a sensitized heterojunction, displays an efficiency of 6.4% under standard illumination test conditions.
- Mingkui Wang
- , Nathalie Chamberland
- & Michael Grätzel