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News & Views |
Hot holes break the speed limit
Charge transfer through DNA has been well studied over recent decades from both a biological and electronics perspective. It has now been shown that charge transfer can be accelerated one hundredfold by using highly energetic 'hot holes', revealing a new mechanism that could help to create useful electronic biomaterials.
- D. N. Beratan
- & D. H. Waldeck
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Article |
Mechanically controlled quantum interference in individual π-stacked dimers
Single-molecule junctions provide a unique platform to understand how molecular structure affects electronic transport. Now it has been shown that electronic transport through a π-stacked dimer can be precisely controlled when pulling it apart. This behaviour is caused by quantum interference effects that are turned ON or OFF depending on dimer conformation.
- Riccardo Frisenda
- , Vera A. E. C. Janssen
- & Nicolas Renaud
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News & Views |
Seeing both sides
To improve organic electronic devices, the principles underlying organic-film/metal-electrode interfaces must be understood. A comprehensive study of the organic electron acceptor TCNQ on a copper surface reveals a structural rearrangement of both the organic molecule and the metal surface atoms after charge transfer across the interface.
- Clara Santato
- & Federico Rosei
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Article |
Exploring local currents in molecular junctions
A methodology for describing local electronic transmission through bridging molecules between metallic electrodes is presented. Its application to simple alkane, phenyl and cross-conjugated systems highlights an unexpected number of cases whereby ‘through space’, rather than ‘through bond’ terms dominate and that interference effects coincide with the reversal of ring currents.
- Gemma C. Solomon
- , Carmen Herrmann
- & Mark A. Ratner