Electronic devices articles within Nature Chemistry

Featured

  • Article |

    The phase in which a crystal exists can have a direct influence over its properties; however, it is usually difficult to control during synthesis. Now it has been shown that micrometre-sized metallic 1T′-MoS2- and 1T′-MoSe2-layered crystals can be prepared in high phase purity on a large scale, and that they display promising electrocatalytic activity towards the hydrogen evolution reaction.

    • Yifu Yu
    • , Gwang-Hyeon Nam
    •  & Hua Zhang
  • News & Views |

    Charge transfer through DNA has been well studied over recent decades from both a biological and electronics perspective. It has now been shown that charge transfer can be accelerated one hundredfold by using highly energetic 'hot holes', revealing a new mechanism that could help to create useful electronic biomaterials.

    • D. N. Beratan
    •  & D. H. Waldeck
  • Article |

    Single-molecule junctions provide a unique platform to understand how molecular structure affects electronic transport. Now it has been shown that electronic transport through a π-stacked dimer can be precisely controlled when pulling it apart. This behaviour is caused by quantum interference effects that are turned ON or OFF depending on dimer conformation.

    • Riccardo Frisenda
    • , Vera A. E. C. Janssen
    •  & Nicolas Renaud
  • News & Views |

    To improve organic electronic devices, the principles underlying organic-film/metal-electrode interfaces must be understood. A comprehensive study of the organic electron acceptor TCNQ on a copper surface reveals a structural rearrangement of both the organic molecule and the metal surface atoms after charge transfer across the interface.

    • Clara Santato
    •  & Federico Rosei
  • Article |

    A methodology for describing local electronic transmission through bridging molecules between metallic electrodes is presented. Its application to simple alkane, phenyl and cross-conjugated systems highlights an unexpected number of cases whereby ‘through space’, rather than ‘through bond’ terms dominate and that interference effects coincide with the reversal of ring currents.

    • Gemma C. Solomon
    • , Carmen Herrmann
    •  & Mark A. Ratner