Batteries articles within Nature

Featured

  • Article |

    The introduction of chemical short-range disorder substantially affects the crystal structure of layered lithium oxide cathodes, leading to improved charge transfer and structural stability.

    • Qidi Wang
    • , Zhenpeng Yao
    •  & Chenglong Zhao
  • Article |

    A conductive, low-melting-point and healable sulfur iodide material aids the practical realization of solid-state Li–S batteries, which have high theoretical energy densities and show potential in next-generation battery chemistry.

    • Jianbin Zhou
    • , Manas Likhit Holekevi Chandrappa
    •  & Ping Liu
  • Article |

    An electrolyte design using small-sized fluoroacetonitrile solvents to form a ligand channel produces lithium-ion batteries simultaneously achieving high energy density, fast charging and wide operating temperature range, desirable features for batteries working in extreme conditions.

    • Di Lu
    • , Ruhong Li
    •  & Xiulin Fan
  • Article |

    Calendar ageing of lithium metal batteries in the discharged state improves capacity retention through isolated lithium recovery, which is in contrast with the capacity degradation observed during charged state calendar ageing.

    • Wenbo Zhang
    • , Philaphon Sayavong
    •  & Yi Cui
  • Article |

    We investigate the mechanism underlying the sulfur reduction reaction that plays a central role in high-capacity lithium sulfur batteries, highlighting the electrocatalytic approach as a promising strategy for tackling the fundamental challenges associated with these batteries.

    • Rongli Liu
    • , Ziyang Wei
    •  & Xiangfeng Duan
  • Article
    | Open Access

    Single-cycle terahertz pumps are used to impulsively trigger ionic hopping in battery solid electrolytes, probing ion transport at its fastest limit and demonstrating the connection between activated transport and the thermodynamics of information.

    • Andrey D. Poletayev
    • , Matthias C. Hoffmann
    •  & Aaron M. Lindenberg
  • Article |

    The inclusion of a Mg–Bi-based interlayer between the lithium metal and solid electrolyte and a F-rich interlayer on the cathode improves the stability and performance of solid-state lithium-metal batteries.

    • Hongli Wan
    • , Zeyi Wang
    •  & Chunsheng Wang
  • Article |

    In situ liquid-cell electrochemical transmission electron microscopy allows the direct visualization of the transformation of lithium polysulfides over electrode surfaces at the atomic scale, leading to a new energy-storage mechanism in lithium–sulfur batteries.

    • Shiyuan Zhou
    • , Jie Shi
    •  & Hong-Gang Liao
  • Article |

    Analysis of dendrite initiation, owing to filling of pores with lithium by means of microcracks, and propagation, caused by wedge opening, shows that there are two separate processes during dendrite failure of lithium metal solid-state batteries.

    • Ziyang Ning
    • , Guanchen Li
    •  & Peter G. Bruce
  • Article |

    The state of charge, mechanical strain and temperature within lithium-ion 18650 cells operated at high rates are characterized and operando temperature rise is observed to be due to heat accumulation, strongly influenced by cell design and charging protocol.

    • T. M. M. Heenan
    • , I. Mombrini
    •  & P. R. Shearing
  • Article |

    A LaCl3-based lithium superionic conductor is developed that has excellent interfacial compatibility with lithium metal electrodes, with its optimized Li0.388Ta0.238La0.475Cl3 electrolyte exhibiting good Li+ conductivity and low activation energy.

    • Yi-Chen Yin
    • , Jing-Tian Yang
    •  & Hong-Bin Yao
  • Article |

    A new approach to charging energy-dense electric vehicle batteries, using temperature modulation with a dual-salt electrolyte, promises a range in excess of 500,000 miles using only rapid (under 12 minute) charges.

    • Chao-Yang Wang
    • , Teng Liu
    •  & Brian D. McCarthy
  • Perspective |

    The economic, technical, environmental and safety requirements of battery-powered aircraft are considered, and promising technologies and future prospects for battery innovation are discussed.

    • Venkatasubramanian Viswanathan
    • , Alan H. Epstein
    •  & Michael Winter
  • Article |

    By coordinating copper ions with the oxygen-containing groups of cellulose nanofibrils, the molecular spacing in the nanofibrils is increased, allowing fast transport of lithium ions and offering hopes for solid-state batteries.

    • Chunpeng Yang
    • , Qisheng Wu
    •  & Liangbing Hu
  • Article |

    Rechargeable Na/Cl2 and Li/Cl2 batteries are produced with a microporous carbon positive electrode, aluminium chloride in thionyl chloride as the electrolyte, and either sodium or lithium as the negative electrode.

    • Guanzhou Zhu
    • , Xin Tian
    •  & Hongjie Dai
  • Article |

    The dynamics of ions within a working lithium-ion battery are examined using optical interferometric scattering microscopy, which allows ion transport to be related to phase transitions and microstructural features.

    • Alice J. Merryweather
    • , Christoph Schnedermann
    •  & Akshay Rao
  • Article |

    An environmentally friendly, all-organic radical battery is demonstrated, in which redox-active polypeptides perform as both cathode and anode materials, with a metal-free organic electrolyte.

    • Tan P. Nguyen
    • , Alexandra D. Easley
    •  & Karen L. Wooley
  • Article |

    A diversity-oriented synthesis approach that yields a library of architecturally broad microporous polymers is used to develop structurally diverse polymer membranes with ion specificity and to screen their properties.

    • Miranda J. Baran
    • , Mark E. Carrington
    •  & Brett A. Helms
  • Article |

    Real-time nuclear magnetic resonance studies of electrolyte decomposition and self-discharge in redox flow batteries provide insights into the underlying mechanisms of the reactions, such as radical formation and electron transfer.

    • Evan Wenbo Zhao
    • , Tao Liu
    •  & Clare P. Grey
  • Letter |

    Titration gas chromatography is developed as an analytical method of distinguishing between lithium metal and lithium compounds within a cycled battery and assessing the amount of unreacted metallic lithium available.

    • Chengcheng Fang
    • , Jinxing Li
    •  & Ying Shirley Meng
  • Article |

    An energy-dense hydraulic fluid is used to construct a synthetic circulatory system in a lionfish-like soft robot, enabling untethered movement for up to 36 hours.

    • Cameron A. Aubin
    • , Snehashis Choudhury
    •  & Robert F. Shepherd
  • Article |

    Lithium-rich cathode materials in which manganese undergoes double redox could point the way for lithium-ion batteries to meet the capacity and energy density needs of portable electronics and electric vehicles.

    • Jinhyuk Lee
    • , Daniil A. Kitchaev
    •  & Gerbrand Ceder
  • Letter |

    A lithium–oxygen battery, comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/dimethyl sulfoxide electrolyte, operates in a simulated air atmosphere with a long cycle life of up to 700 cycles.

    • Mohammad Asadi
    • , Baharak Sayahpour
    •  & Amin Salehi-Khojin
  • Letter |

    Here we report a lithium-ion all-climate battery that very efficiently heats itself up in extremely cold environments by diverting current through a strip of metal foil to generate heat of resistance and then reverts to normal high-power operation.

    • Chao-Yang Wang
    • , Guangsheng Zhang
    •  & Yongjun Leng
  • Letter |

    Lithium–oxygen batteries allow oxygen to be reduced at the battery’s cathode when a current is drawn; in present-day batteries, this results in formation of Li2O2, but it is now shown that another high energy density material, namely LiO2, with better electronic conduction can be used instead as the discharge product, if the electrode is decorated with iridium nanoparticles.

    • Jun Lu
    • , Yun Jung Lee
    •  & Khalil Amine
  • Letter |

    An aluminium-ion battery is reported that can charge within one minute, and offers improved cycle life compared to previous devices; it operates through the electrochemical deposition and dissolution of aluminium at the anode, and the intercalation/de-intercalation of chloroaluminate anions into a novel graphitic-foam cathode.

    • Meng-Chang Lin
    • , Ming Gong
    •  & Hongjie Dai
  • Letter |

    Two-dimensional titanium carbide has been produced by etching out aluminium in a lithium fluoride and hydrochloric acid mixture; it is hydrophilic and mouldable like clay and has excellent volumetric capacitance and cyclability, properties that are desirable for portable electronics.

    • Michael Ghidiu
    • , Maria R. Lukatskaya
    •  & Michel W. Barsoum
  • Letter |

    All-liquid batteries comprising a lithium negative electrode and an antimony–lead positive electrode have a higher current density and a longer cycle life than conventional batteries, can be more easily used to make large-scale storage systems, and so potentially present a low-cost means of grid-level energy storage.

    • Kangli Wang
    • , Kai Jiang
    •  & Donald R. Sadoway