Table of contents


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Editorial

Let the Sun shine p825

doi:10.1038/nmat2303

There is more than enough power available from the Sun to satisfy the world's needs, so why are we not rushing to exploit it?


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Commentaries

Two million hours of science pp827 - 830

G. N. Greaves, C. R. A. Catlow, G. E. Derbyshire, M. I. McMahon, R. J. Nelmes & G. van der Laan

doi:10.1038/nmat2305

After over a quarter of a century, the doors of the world's first synchrotron radiation source have closed. Its contribution to materials science in the past and the future should not be underestimated.


In search of a theory of supercooled liquids pp831 - 833

Steven A. Kivelson & Gilles Tarjus

doi:10.1038/nmat2304

Despite the absence of consensus on a theory of the transition from supercooled liquids to glasses, the experimental observations suggest that a detail-independent theory should exist.


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Research Highlights

Sensitive, switchable, productive... p834

doi:10.1038/nmat2306


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News and Views

Photovoltaics: Solar cells on curtains pp835 - 836

Zhiyong Fan & Ali Javey

doi:10.1038/nmat2312

Crystalline silicon solar cell arrays on flexible, transparent substrates may lead to unconventional new applications.


Drug delivery: The heart of the matter pp836 - 837

David Putnam

doi:10.1038/nmat2309

A polymeric delivery vehicle, with neutral degradation products, keeps inflammation at bay during sustained drug release following myocardial infarction.


Material witness: A twisted tale p837

Philip Ball

doi:10.1038/nmat2307


Ionic conductors: Feel the strain pp838 - 839

John A. Kilner

doi:10.1038/nmat2314

The high temperatures required for oxygen ion conductivity have hampered the development of practical applications of ionic conductors. Now superlattices made of yttria-stabilized zirconia and strontium titanate show promise for room-temperature devices.


Dielectric materials: Gels excel pp839 - 840

Antonio Facchetti

doi:10.1038/nmat2310

Printing electronic circuits will usher in a new era in electronics. With ion gel dielectrics, unprecedented transistor performance and speeds at low voltage can be demonstrated.


Carbon nanotubes: Doped defects tracked down pp840 - 841

Marcus Freitag

doi:10.1038/nmat2308

Single doped defects in carbon nanotubes locally modify the energies of charge carriers and lattice vibrations. They can now be detected by inelastic light-scattering experiments.


Glasses: When disorder helps pp842 - 843

Giancarlo Ruocco

doi:10.1038/nmat2311

Amorphous solids show intriguing universal behaviour whose origins often remain poorly understood. One of these features, the boson peak, is now shown to be directly linked to transverse vibrations.


Ceramic materials: Levitating liquids pp843 - 844

Paul F. McMillan

doi:10.1038/nmat2313

Refractory ceramic liquids studied by containerless levitation and synchrotron X-ray scattering reveal an unusual density-driven liquid–liquid phase transition.


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Review

Materials for electrochemical capacitors pp845 - 854

Patrice Simon & Yury Gogotsi

doi:10.1038/nmat2297


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Letters

Electric-field-induced superconductivity in an insulator pp855 - 858

K. Ueno, S. Nakamura, H. Shimotani, A. Ohtomo, N. Kimura, T. Nojima, H. Aoki, Y. Iwasa & M. Kawasaki

doi:10.1038/nmat2298

Increasing the carrier density of a material to the limit at which superconductivity can be induced has been a long-standing challenge. This is now realized in an insulator by using an electric-double-layer gate in an organic electrolyte.

Subject Categories: Electronic materials | Optical, photonic and optoelectronic materials | Nanoscale materials


Electron-trapping polycrystalline materials with negative electron affinity pp859 - 862

Keith P. McKenna & Alexander L. Shluger

doi:10.1038/nmat2289

The trapping of electrons by grain boundaries in semiconducting and insulating materials is important for a wide range of devices such as sensors, and solar and fuel cells. First-principles calculations on MgO, LiF and NaCl reveal a novel type of electron trapping at grain boundaries associated with the negative electron affinity of these materials.

Subject Categories: Ceramics | Computation, modelling and theory


Sustained release of a p38 inhibitor from non-inflammatory microspheres inhibits cardiac dysfunction pp863 - 868

Jay C. Sy, Gokulakrishnan Seshadri, Stephen C. Yang, Milton Brown, Teresa Oh, Sergey Dikalov, Niren Murthy & Michael E. Davis

doi:10.1038/nmat2299

A new polymer is investigated as a drug-delivery vehicle for the treatment of inflammatory diseases, such as cardiac dysfunction. The biocompatibility, neutral degradation products and controlled-release properties of the polyketal microparticles indicate the material's promising future in inflammation inhibition.

Subject Categories: Polymers | Biomedical materials

See also: News and Views by Putnam


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Articles

Universal link between the boson peak and transverse phonons in glass pp870 - 877

Hiroshi Shintani & Hajime Tanaka

doi:10.1038/nmat2293

A universal feature of disordered glasses is the appearance of the so-called boson peak in neutron-scattering experiments. A universal link between this boson peak and transverse phonons has now been discovered, and linked to locally favoured structures in the glass.

Subject Categories: Glasses | Colloids | Computation, modelling and theory

See also: News and Views by Ruocco


Electron and phonon renormalization near charged defects in carbon nanotubes pp878 - 883

Indhira O. Maciel, Neil Anderson, Marcos A. Pimenta, Achim Hartschuh, Huihong Qian, Mauricio Terrones, Humberto Terrones, Jessica Campos-Delgado, Apparao M. Rao, Lukas Novotny & Ado Jorio

doi:10.1038/nmat2296

Defects can significantly alter the physical properties of materials. A detailed experimental analysis of defects in carbon nanotubes enables the relationship between the atomic response and the broadly available macrosopic behaviour to be captured.

Subject Categories: Electronic materials | Optical, photonic and optoelectronic materials | Nanoscale materials

See also: News and Views by Freitag


Tunnelling spectra of individual magnetic endofullerene molecules pp884 - 889

Jacob E. Grose, Eugenia S. Tam, Carsten Timm, Michael Scheloske, Burak Ulgut, Joshua J. Parks, Héctor D. Abruña, Wolfgang Harneit & Daniel C. Ralph

doi:10.1038/nmat2300

To enable the development of devices based on the electrical manipulation of magnetic molecules, their magnetic state needs to be conserved when electrical contacts are applied. N@C60 molecules have now been integrated as part of single-molecule transistors, and their spin states retained. This achievement may lead towards their use in high-density information storage and quantum-state control.

Subject Categories: Electronic materials | Nanoscale materials


Pressure-dependent structures of amorphous red phosphorus and the origin of the first sharp diffraction peaks pp890 - 899

Joseph M. Zaug, Alan K. Soper & Simon M. Clark

doi:10.1038/nmat2290

Characterizing medium-range order in disordered solids and liquids is crucial for elucidating their structure and transport properties, but it has so far proved difficult. Using a combination of X-ray diffraction and Raman scattering, the pressure-dependent and atomic-void structure of amorphous red phosphorous is determined.

Subject Categories: Design synthesis and processing | Characterisation and analytical techniques


Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic pp900 - 906

Jeong Ho Cho, Jiyoul Lee, Yu Xia, BongSoo Kim, Yiyong He, Michael J. Renn, Timothy P. Lodge & C. Daniel Frisbie

doi:10.1038/nmat2291

Flexible electronics require that all parts can be printed on plastic substrates, but finding materials that can act as high-capacitance dielectrics is a priority. An emerging class of polymer electrolytes, ion gels, can do the job—with high capacitance and at low voltage.

Subject Category: Electronic materials

See also: News and Views by Facchetti


Ultrathin silicon solar microcells for semitransparent, mechanically flexible and microconcentrator module designs pp907 - 915

Jongseung Yoon, Alfred J. Baca, Sang-Il Park, Paulius Elvikis, Joseph B. Geddes, III, Lanfang Li, Rak Hwan Kim, Jianliang Xiao, Shuodao Wang, Tae-Ho Kim, Michael J. Motala, Bok Yeop Ahn, Eric B. Duoss, Jennifer A. Lewis, Ralph G. Nuzzo, Placid M. Ferreira, Yonggang Huang, Angus Rockett & John A. Rogers

doi:10.1038/nmat2287

In a device design that brings mechanical flexibility to silicon photovoltaics, Jongseung Yoon, Alfred J. Baca and colleagues demonstrate how transfer-printing of ultrathin silicon films onto flexible substrates leads to semitransparent and large-scale arrays of integrated solar microcells with high solar-energy conversion efficiencies of 6–8%.

Subject Categories: Optical, photonic and optoelectronic materials | Materials for energy

See also: News and Views by Fan & Javey


Metal hydrides for lithium-ion batteries pp916 - 921

Y. Oumellal, A. Rougier, G. A. Nazri, J-M. Tarascon & L. Aymard

doi:10.1038/nmat2288

Conversion electrodes for lithium-ion batteries are capable of high capacity but low energy efficiency and low voltages are problematic. The electrochemical reactivity of MgH2 with Li shows promise in using metal-hydride electrodes for both lithium-ion-battery and hydrogen storage applications.

Subject Categories: Materials for energy | Nanoscale materials


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Corrigendum

Ferroelectricity near room temperature in co-crystals of nonpolar organic molecules p922

Sachio Horiuchi, Fumiyuki Ishii, Reiji Kumai, Yoichi Okimoto, Hiroaki Tachibana, Naoto Nagaosa & Yoshinori Tokura

doi:10.1038/nmat2294


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