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Main group chemistry

A heavier-element ketone at last

The first heavier main-group-14-element analogue of a ketone, which contains a three-coordinate germanium atom multiply bonded to oxygen, has been prepared and characterized.

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Figure 1: A crowding ligand can stabilize a heavier-element ketone.

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Correspondence to Philip P. Power.

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Power, P. A heavier-element ketone at last. Nature Chem 4, 343–344 (2012). https://doi.org/10.1038/nchem.1309

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