Thirty years ago the assembly of molecular ‘tectons’ into organic networks with large chambers using directional non-covalent interactions — hydrogen bonds — provided a blueprint for the synthesis of porous functional materials through crystal engineering.
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Cooper, A.I. Tectonic shifts in framework chemistry. Nat. Chem. 13, 620–621 (2021). https://doi.org/10.1038/s41557-021-00741-y
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DOI: https://doi.org/10.1038/s41557-021-00741-y
