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Carbon allotropes

On the road to carbyne

Chemists have now prepared the longest known stable subunit of the elusive all-carbon polymer — carbyne. Their results suggest that carbyne itself would have a polyyne-like rather than a cumulene structure.

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Figure 1: Carbyne and oligomeric substructures.

References

  1. Kroto, H. W., Heath, J. R., O'Brien, S. C., Curl, R. F. & Smalley, R. E. Nature 318, 162–163 (1985).

    Article  CAS  Google Scholar 

  2. Falcao, E. H. L. & Wudl, F. J. Chem. Technol. Biotechnol. 82, 524–531 (2007).

    Article  CAS  Google Scholar 

  3. Pierson, H. O. Handbook of Carbon, Graphite, Diamond and Fullerenes — Properties, Processing and Applications (William Andrew/Noyes, 1993).

    Google Scholar 

  4. Rice, M. J., Phillpot, S. R., Bishop, A. R. & Campbell, D. K. Phys. Rev. B 34, 4139–4149 (1986).

    Article  CAS  Google Scholar 

  5. Heimann, R. B., Kleiman, J. & Salansky, N. M. Nature 306, 164–167 (1983).

    Article  CAS  Google Scholar 

  6. Chalifoux, W. A. & Tykwinski, R. R. Nature Chem. 2, 967–971 10.1038/nchem.828 (2010).

    Article  CAS  Google Scholar 

  7. Szafert, S. & Gladysz, J. A. Chem. Rev. 106, PR1–PR33 (2006).

    Article  CAS  Google Scholar 

  8. Chalifoux, W. A., McDonald, R., Ferguson, M. J. & Tykwinski, R. R. Angew. Chem. Int. Ed. 48, 7915–7919 (2009).

    Article  CAS  Google Scholar 

  9. Hopf, H. Classics in Hydrocarbon Chemistry 178–182 (Wiley-VCH, 2000).

    Google Scholar 

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Haley, M. On the road to carbyne. Nature Chem 2, 912–913 (2010). https://doi.org/10.1038/nchem.884

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