Featured
-
-
Article
| Open AccessSocial and environmental analysis of food waste abatement via the peer-to-peer sharing economy
Reducing food waste is important. Here the authors investigate whether digitally enabled social networks can efficiently reduce food waste and find that in 19 months, around 91t of food waste were collected by secondary consumers and diverted from disposal.
- Tamar Makov
- , Alon Shepon
- & Marian Chertow
-
Article
| Open AccessComparative performance of rural water supplies during drought
The authors compared the performance of a range of rural water supply types during drought in Ethiopia. They show that prioritising access to groundwater via multiple improved water sources and technologies, such as hand-pumped and motorised boreholes, supported by monitoring and proactive operation and maintenance increases rural water supply resilience.
- D. J. MacAllister
- , A. M. MacDonald
- & R. Calow
-
Article
| Open AccessSilica accelerates the selective hydrogenation of CO2 to methanol on cobalt catalysts
The hydrogenation of CO2 into valuable chemicals is greatly demanded, but suffers from complex product distribution. Here, the authors reported that, as a support and ligand, silica boosts cobalt catalysts to selectively hydrogenate CO2 into the desired methanol product.
- Lingxiang Wang
- , Erjia Guan
- & Feng-Shou Xiao
-
Article
| Open AccessSingle-pass transformation of syngas into ethanol with high selectivity by triple tandem catalysis
Direct synthesis of ethanol from non-petroleum carbon resources via syngas (CO/H2) is a highly attractive but challenging target. Here, the authors report a triple tandem catalytic system for single-pass conversion of syngas into ethanol with selectivity as high as 90%.
- Jincan Kang
- , Shun He
- & Ye Wang
-
Comment
| Open AccessIs electrosynthesis always green and advantageous compared to traditional methods?
While electrosynthesis represents a green and advantageous alternative to traditional synthetic methods, electrochemical reactions still suffer from some drawbacks that require further efforts in order to fully express the potential of electricity-driven transformations. In this Comment, we will briefly discuss both the advantages and limitations of electrosynthesis, especially when compared with the other traditional synthetic organic methods, and share some forward-looking thoughts on the future developments of electrochemical reactions.
- Yong Yuan
- & Aiwen Lei
-
Article
| Open AccessPollution exacerbates China’s water scarcity and its regional inequality
The impact on inadequate water quality on water scarcity is unclear. Here the authors quantify China’s present-day water scarcity and show that inadequate water quality exacerbates China’s water scarcity, which is unevenly distributed across the country.
- Ting Ma
- , Siao Sun
- & Chenghu Zhou
-
Article
| Open AccessNanocomposite electrodes for high current density over 3 A cm−2 in solid oxide electrolysis cells
High-temperature solid oxide electrolysis cells are a promising technology for energy conversion, but higher current density is needed to increase efficiency. Here the authors design nanocomposite electrodes to improve electronic and ionic conductivity to achieve a high current density.
- Hiroyuki Shimada
- , Toshiaki Yamaguchi
- & Yoshinobu Fujishiro
-
Article
| Open AccessImpact of transport electrification on critical metal sustainability with a focus on the heavy-duty segment
Resource impacts from the electrification of transport sector in terms of heavy-duty vehicles are understudied. Here the authors find that a mass deployment of plug-in electric vehicles in the heavy-duty segment at the global level can substantially increase the lithium demand.
- Han Hao
- , Yong Geng
- & Fuquan Zhao
-
Article
| Open AccessChemo-enzymatic cascades to produce cycloalkenes from bio-based resources
Cycloalkenes are bulk petrochemicals that are currently obtained from fossil fuels. Here, the authors developed multi enzyme pathways in combination with a Ru-catalyzed metathesis reaction for the one-pot production of cyclopentene, cyclohexene, and cycloheptene from olive oil-derived intermediates.
- Shuke Wu
- , Yi Zhou
- & Thomas R. Ward
-
Article
| Open AccessGreen oxidation of indoles using halide catalysis
Indole oxidation represents a fundamental organic transformation delivering valuable nitrogen compounds. Here, the authors report a general halide catalysis protocol applied to three classes of oxidation reactions of indoles with oxone as a sustainable terminal oxidant.
- Jun Xu
- , Lixin Liang
- & Rongbiao Tong
-
Comment
| Open AccessMotivating actions to mitigate plastic pollution
Plastic pollution is a purely anthropogenic problem and cannot be solved without large-scale human action. Motivating mitigation actions requires more realistic assumptions about human decision-making based on empirical evidence from the behavioural sciences enabling the design of more effective interventions.
- Lili Jia
- , Steve Evans
- & Sander van der Linden
-
Article
| Open AccessThe role of irrigation in changing wheat yields and heat sensitivity in India
Irrigation buffers crop yields from extreme weather, but comes at environmental costs. Here the authors show that in India irrigation has improved wheat yield and reduced its sensitivity to heat, yet further increases are unlikely to offset the impact of warming.
- Esha Zaveri
- & David B. Lobell
-
Comment
| Open AccessTowards Urbanome the genome of the city to enhance the form and function of future cities
The health of the city depends on how well all the elements of this system are interconnected and operating in harmony. Here the authors introduced the concept of urbanome which is analogous to the human genome that can be used to characterise the form and functioning of cities.
- Lidia Morawska
- , Wendy Miller
- & Marie Thynell
-
Article
| Open AccessHighly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination
Hydrogen peroxide can be produced alternatively using green inputs such as air, water, and sunlight but this requires a selective catalyst. Here the authors report an iron single atom catalyst that can convert oxygen into hydrogen peroxide with a selectivity of above 95% in both alkaline and neutral pH.
- Kun Jiang
- , Seoin Back
- & Haotian Wang
-
Article
| Open AccessCatalytic amidation of natural and synthetic polyol esters with sulfonamides
Triacylglycerides are naturally abundant and renewable feedstock, but their chemical transformation is hindered by their stability. Here, under Lewis acid catalysis, the authors report the selective alkyl C–O bond conversion of triglycerides into C–N bonds and even apply this efficient method to PET depolymerization.
- Hua Liu
- , Yi-Ling Zhu
- & Zhi Li
-
Article
| Open AccessCarbon dioxide electroreduction to C2 products over copper-cuprous oxide derived from electrosynthesized copper complex
Electrocatalytic reduction of carbon dioxide is attractive for obtaining multicarbon products, but conversion efficiency is low. Here the authors use copper complex materials for electrochemical reduction of carbon dioxide to ethanol and acetic acid with high efficiencies and activities.
- Qinggong Zhu
- , Xiaofu Sun
- & Buxing Han
-
Article
| Open AccessDisturbance modifies payoffs in the explore-exploit trade-off
The empirical consequences of human explorative strategies are not fully understood. Here the authors find that during undisturbed conditions, more-explorative vessels gained no performance advantage while during a major disturbance event, explorers benefited significantly from less-impacted revenues and were also more likely to continue fishing.
- Shay O’Farrell
- , James N. Sanchirico
- & Andrew Strelcheck
-
Article
| Open AccessDirect electrochemical oxidation of alcohols with hydrogen evolution in continuous-flow reactor
Alcohol oxidation to carbonyl compounds is a very useful functional group transformation in organic synthesis. Here, the authors perform the direct electrochemical oxidation of various alcohols to the corresponding ketones in a continuous-flow reactor without external oxidants, base or mediators.
- Dan Wang
- , Pan Wang
- & Aiwen Lei
-
Article
| Open AccessImpact hotspots of reduced nutrient discharge shift across the globe with population and dietary changes
The environmental impacts of increasing wastewater management are poorly understood. Here, the authors simulate impacts for 173 countries between 1990 and 2050; despite the development of wastewater infrastructure, they identify hotspots of unexpected detrimental effects which are shifting from Asia to Africa.
- Xu Wang
- , Glen Daigger
- & David Butler
-
Article
| Open AccessActive catalyst construction for CO2 recycling via catalytic synthesis of N-doped carbon on supported Cu
Bridging homogeneous and heterogeneous catalysis is a long-term pursuit in the field of catalysis. Here, the authors present results on integration of nano- and molecular catalysis via catalytic synthesis of nitrogen doped carbon layers on AlOx supported nano-Cu which can finely tune the catalytic performance of the supported copper catalyst.
- Yajuan Wu
- , Tao Wang
- & Feng Shi
-
Article
| Open AccessSwitching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.
- Xiuquan Jia
- , Jiping Ma
- & Jie Xu
-
Article
| Open AccessArtisanal fish fences pose broad and unexpected threats to the tropical coastal seascape
Artisanal fish fences are used for fishing along many tropical coastlines. Here, Exton et al. examine the impact footprint of artisanal fish fences, showing that they are highly non-selective, cause direct harm across the tropical seascape, disrupt ecological connectivity and create social conflict.
- Dan A. Exton
- , Gabby N. Ahmadia
- & David J. Smith
-
Article
| Open AccessBridging the gap between transition metal- and bio-catalysis via aqueous micellar catalysis
Chemo-enzymatic tandem processes allow access to more complex non-racemic products. Here, the authors show that non-ionic surfactants, especially the tailor-made surfactant TPGS-750-M, enhance the activity of alcohol dehydrogenase to afford stereopure products in a 1-pot reaction.
- Margery Cortes-Clerget
- , Nnamdi Akporji
- & Bruce H. Lipshutz
-
Article
| Open AccessSynthesis of an aromatic N-heterocycle derived from biomass and its use as a polymer feedstock
Aromatic N-heterocyclic compounds are important chemicals, but produced from petroleum. Here the authors show a pyridazine-based compound 6-(4-hydroxy-3-methoxyphenyl)pyridazin-3(2H)-one, used as polymer feedstocks, can be synthesized by a Friedel-Crafts reaction from biomass starting materials.
- Yu Qi
- , Jinyan Wang
- & Xigao Jian
-
Article
| Open AccessSocial-ecological alignment and ecological conditions in coral reefs
The relationships between people can have important consequences for the systems they depend on. Here the authors show that when coral reef fishers face commons dilemmas, the formation of cooperative communication with competitors can lead to positive gains in reef fish biomass and functional richness.
- Michele L. Barnes
- , Örjan Bodin
- & Nicholas A. J. Graham
-
Article
| Open AccessThe future of Southeast Asia’s forests
Southeast Asia’s forests play important roles in the society, but the region is a deforestation hotspot. Here, the authors examined the future changes in the region’s forests under different scenarios and found that by 2050 under a regional rivalry/rocky road scenario, the region’s forests would shrink by 5.2 million ha.
- Ronald C. Estoque
- , Makoto Ooba
- & Yuji Murayama
-
Article
| Open AccessOrganopolymer with dual chromophores and fast charge-transfer properties for sustainable photocatalysis
While photoredox catalysis offers a new dimension to chemical synthesis, there are few heterogeneous organocatalysts for metal-free transformations. Here, authors prepare and perform in-depth studies on polymeric photocatalyst scaffolds for organic chemistry transformations.
- Justin D. Smith
- , Abdelqader M. Jamhawi
- & Sachin Handa
-
Article
| Open AccessOptimizing the conservation of migratory species over their full annual cycle
Conservation decisions to protect land used by migratory birds rely on understanding species’ dynamic habitat associations. Here the authors identify conservation scenarios needed to maintain >30% of the abundances of 117 migratory birds across the Americas, considering spatial and temporal patterns of species abundance.
- Richard Schuster
- , Scott Wilson
- & Joseph. R. Bennett
-
Article
| Open AccessOver-exploitation of natural resources is followed by inevitable declines in economic growth and discount rate
The exploitation of ecosystems has long-lasting consequences for the future provision of natural resources and ecosystem services. Here the author showed that the transition to sustainable harvest after a period of over-harvesting leads to a decline in welfare, economic growth, and in the discount rate.
- Adam Lampert
-
Article
| Open AccessCopper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay
The synthesis of high value heterocycles from cheap starting materials remains challenging. Here, the authors develop a new strategy to realize practical and modular synthesis of N-H indoles and analogs from toluene and nitrile derivatives using naturally abundant copper salt as catalyst.
- Xiang-Huan Shan
- , Hong-Xing Zheng
- & Yan-Biao Kang
-
Article
| Open AccessStereoselective synthesis of sulfur-containing β-enaminonitrile derivatives through electrochemical Csp3–H bond oxidative functionalization of acetonitrile
Direct α-functionalization of acetonitrile, a bulk chemical, is usually limited to its enolate chemistry. Here, the authors show an electro-oxidative C(sp3)–H bond functionalization of acetonitrile with thiols to afford tetrasubstituted olefins with high stereoselectivity.
- Tian-Jun He
- , Zongren Ye
- & Jing-Mei Huang
-
Article
| Open AccessDirect dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
Heck coupling of alkenes with organic halides, arenes or organometallics poses sustainability issues due to hazardous waste formation and use of oxidants. Here, the authors show an oxidant-free alkyl Heck-coupling of vinylarenes with umpolung aldehydes, liberating H2, N2 and H2O as sole side products.
- Leiyang Lv
- , Dianhu Zhu
- & Chao-Jun Li
-
Article
| Open AccessN-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks
Processes for efficient production of primary, secondary or ternary aminated compounds are constant challenges for chemical and pharmaceutical industries. Here, the authors develop selective and sustainable amination chemistry widely applicable to chemical substrates via formic acid.
- Hu Li
- , Haixin Guo
- & Richard Lee Smith Jr.
-
Article
| Open AccessOil palm expansion and deforestation in Southwest Cameroon associated with proliferation of informal mills
Deforestation for palm oil production is often attributed to large-scale, agro-industrial expansion. Here, Ordway et al. show that much recent expansion in Southwest Cameroon can be attributed to an informal sector of non-industrial producers establishing near informal, non-industrial palm oil mills.
- Elsa M. Ordway
- , Rosamond L. Naylor
- & Eric F. Lambin
-
Article
| Open AccessOlefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
Cross-coupling reactions have been achieved in solution, yet tend to be inefficient in a solid state. Here, the authors report a solid-state palladium-catalyzed Buchwald-Hartwig cross-coupling using olefins as molecular dispersants, enabling reduction of solvent waste.
- Koji Kubota
- , Tamae Seo
- & Hajime Ito
-
Article
| Open AccessAir quality co-benefits for human health and agriculture counterbalance costs to meet Paris Agreement pledges
Local air quality co-benefits can provide convincing support for climate action. Here the authors revisited air quality co-benefits of climate action in the context of NDCs and found that 71–99 thousand premature deaths can be avoided each year by 2030, offsetting the climate mitigation costs on a global level.
- Toon Vandyck
- , Kimon Keramidas
- & Bert Saveyn
-
Article
| Open AccessWater assisted biomimetic synergistic process and its application in water-jet rewritable paper
Water based inks used for water-jet rewritable paper (WJRP) are an environmental friendly alternative to conventional printing, but black colour in WJRP could not be realized so far. Here the authors demonstrate black as well as other colour WJRP based on binary systems containing less-sensitive acidochromic dyes and mild proton donors.
- Guan Xi
- , Lan Sheng
- & Sean Xiao-An Zhang
-
Article
| Open AccessN2H4 as traceless mediator for homo- and cross- aryl coupling
Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products.
- Leiyang Lv
- , Zihang Qiu
- & Chao-Jun Li
-
Article
| Open AccessModern slavery and the race to fish
There have been growing concerns about the exploitation of workers in the fisheries sectors. Here, Tickler et al. use a country-level metric of slavery to determine the risk of fisheries-level slavery across 20 countries, and find it rises as unreported catch increases and mean value of catch decreases.
- David Tickler
- , Jessica J. Meeuwig
- & Dirk Zeller
-
Article
| Open AccessManganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
Catalytic reduction of CO2 and biomass derivatives is of great current interest from a sustainable chemistry perspective. Here, the authors report a manganese pincer complex able to reduce under mild conditions carboxylic acids, carbonates and even carbon dioxide using pinacolborane as reducing agent.
- Christina Erken
- , Akash Kaithal
- & Walter Leitner
-
Article
| Open AccessGlobal state and potential scope of investments in watershed services for large cities
Investment in watershed services programs is growing, however the factors that contribute to sustainability of such programs are unclear. Here the authors use a large database of cities around the world to show that payment schemes are more likely to be present in watersheds with more agricultural land and less protected areas.
- Chelsie L. Romulo
- , Stephen Posner
- & Robert I. McDonald
-
Article
| Open AccessSimple ruthenium-catalyzed reductive amination enables the synthesis of a broad range of primary amines
Synthesis of primary amines via operationally simple, inexpensive and environmentally friendly methodologies has high impact in industrial settings. Here, the authors show a reductive amination process involving a ruthenium catalyst, aldehydes/ketones, ammonia, and hydrogen that displays a remarkable scope of primary amine products.
- Thirusangumurugan Senthamarai
- , Kathiravan Murugesan
- & Rajenahally V. Jagadeesh
-
Article
| Open AccessA global strategy to mitigate the environmental impact of China’s ruminant consumption boom
Rising demand for ruminant meat and dairy products in developing nations drives increasing GHG and ammonia emissions from livestock. Authors show here that only long-term adoption of global best-practice in sustainable intensification buffered by a short-term coping strategy of green-source trading can offer a way forward.
- Yuanyuan Du
- , Ying Ge
- & Raphael K. Didham
-
Article
| Open AccessSustainable scalable synthesis of sulfide nanocrystals at low cost with an ionic liquid sulfur precursor
Developing sustainable and scalable nanocrystal syntheses is challenging but necessary for future technologies and the environment. Here, the authors show that using an ionic liquid to stabilize a highly reactive precursor can fulfill the major aims of sustainable nanocrystal synthesis, including high yields, energy efficiency, atom economy, and recyclability.
- Bin Yuan
- , Timothy Karl Egner
- & Ludovico Cademartiri
-
Article
| Open AccessA flow platform for degradation-free CuAAC bioconjugation
Cu-catalyzed azide-alkyne cycloaddition (CuAAC) reaction is a common bioconjugation technique; however oxidative degradation and residual copper may limit its use. Here, the authors show that ppm levels of Cu, generated in situ by solvent-mediated pipe erosion in flow, catalyze the CuAAC reaction with no product degradation.
- Marine Z. C. Hatit
- , Linus F. Reichenbach
- & Allan J. B. Watson
-
Article
| Open AccessPastoralism may have delayed the end of the green Sahara
Climate deterioration towards desertification in North Africa following the African Humid Period has previously been associated with the emergence of pastoralism. Here, using a climate-vegetation model, the authors show that pastoralism in fact likely slowed the deterioration of orbitally-driven climate change.
- Chris Brierley
- , Katie Manning
- & Mark Maslin
-
Article
| Open AccessDeveloping China’s Ecological Redline Policy using ecosystem services assessments for land use planning
Ecosystem services, though a prominent ecological concept, have yet to be considered in major land use policy changes. Here, the authors demonstrate how the Ecological Redline Policy implemented in Shanghai utilized ecosystem services science and stakeholder engagement.
- Yang Bai
- , Christina P. Wong
- & Qing Wang
-
Article
| Open AccessBottle-grade polyethylene furanoate from ring-opening polymerisation of cyclic oligomers
The synthesis of polyethylene furanoate, a promising renewable resource-based bioplastic, still has challenges. Here the authors show that bottle-grade polyethylene furanoate can be obtained within minutes from ring-opening polymerisation of its cyclic oligomers, thereby avoiding degradation and discolouration.
- Jan-Georg Rosenboom
- , Diana Kay Hohl
- & Massimo Morbidelli
-
Article
| Open AccessUnraveling substituent effects on the glass transition temperatures of biorenewable polyesters
Biorenewable feedstocks allow the design of polymers with targeted properties and functionalities. Here the authors report a series of high glass transition temperature sugar-based polyesters and investigate how substituents affect their thermal properties.
- Xiaopeng Yu
- , Junteng Jia
- & Robert A. DiStasio Jr.