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| Open AccessExcitonic linewidth and coherence lifetime in monolayer transition metal dichalcogenides
The interplay between dark and bright excitons has a significant impact on the optical properties of semiconducting transition metal dichalcogenides. Here, the authors perform computational and experimental studies which unveil the microscopic origin of the excitonic coherence lifetime in WS2 and MoSe2.
- Malte Selig
- , Gunnar Berghäuser
- & Andreas Knorr
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| Open AccessTime-resolved single dopant charge dynamics in silicon
Probing individual impurities will become increasingly important as devices shrink towards the nanoscale. Here Rashidi et al., introduce a method based on time-resolved scanning tunnelling spectroscopy of surface dangling bonds to investigate the dynamics of individual dopants in silicon.
- Mohammad Rashidi
- , Jacob A. J. Burgess
- & Robert A. Wolkow
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| Open AccessStretching magnetism with an electric field in a nitride semiconductor
The wurtzite crystal structure of nitride semiconductors results in strong piezoelectricity. Here, the authors also achieve electric-field control of the magnetization of gallium manganese nitride, thus showing that piezoelectric and magnetoelectric effects can be combined in the same material.
- D. Sztenkiel
- , M. Foltyn
- & T. Dietl
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| Open AccessIn-depth analysis of chloride treatments for thin-film CdTe solar cells
High performance CdTe thin film solar cells typically require a chloride activation treatment. Here, Majoret al. show that the main effect of the most effective chloride-based treatments is chloride accumulation at grain boundaries and that it results in improved open circuit voltages.
- J. D. Major
- , M. Al Turkestani
- & K. Durose
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| Open AccessPhoto-excited charge carriers suppress sub-terahertz phonon mode in silicon at room temperature
Direct measurement of electron-phonon interactions at the single-mode level has been a challenge. Here, Liaoet al. use a three-pulse photoacoustic spectroscopy technique to investigate the damping of a single sub-terahertz coherent phonon mode by photo-excited free charge carriers in silicon at room temperature.
- Bolin Liao
- , A. A. Maznev
- & Gang Chen
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| Open AccessTheory of highly efficient multiexciton generation in type-II nanorods
Multiple exciton generation could help limit thermalization losses in solar cells, but the efficiency of the process is still limited. Here, the authors show by atomistic calculations that type-II interfaces in nanostructures along with a change in exciton cooling rate favour multiple exciton generation.
- Hagai Eshet
- , Roi Baer
- & Eran Rabani
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| Open AccessQuantum decoherence dynamics of divacancy spins in silicon carbide
The length of time a qubit can store information is linked to its coherence time. Here, the authors demonstrate that industrially important crystals comprising more than one species can host qubits with unexpectedly long coherence times.
- Hosung Seo
- , Abram L. Falk
- & David D. Awschalom
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| Open AccessEven–odd layer-dependent magnetotransport of high-mobility Q-valley electrons in transition metal disulfides
Few-layer transition metal dichalcogenides exhibit strong spin-valley entanglement and unconventional quantum Hall states, however their study has been limited by electron mobility. Here, the authors explore how quantum transport varies between even- and odd-layered systems of high mobility.
- Zefei Wu
- , Shuigang Xu
- & Ning Wang
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| Open AccessQuantum dot spin coherence governed by a strained nuclear environment
Spins confined to quantum dots are a possible qubit, but the mechanism that limits their coherence is unclear. Here, the authors use an all-optical Hahn-echo technique to determine the intrinsic coherence time of such spins set by its interaction with the inhomogeneously strained nuclear bath.
- R. Stockill
- , C. Le Gall
- & M. Atatüre
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| Open AccessColossal Seebeck effect enhanced by quasi-ballistic phonons dragging massive electrons in FeSb2
Thermoelectric performances depend on phonon and electron transport. Here, Takahashi et al. show that the large Seebeck coefficient observed in high-purity single-crystal FeSb2 is due to the phonon-drag effect and to the high effective mass of delectrons interacting with quasi-ballistic phonons.
- H. Takahashi
- , R. Okazaki
- & I. Terasaki
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| Open AccessDimensional crossover in semiconductor nanostructures
Nanostructured materials offer a route to tuning the bandgap of a semiconductor. Here, the authors use single particle absorption spectroscopy to investigate bandgap evolution between cadmium selenide nanowires and quantum dots and identify the length at which a nanorod becomes zero-dimensional.
- Matthew P. McDonald
- , Rusha Chatterjee
- & Masaru Kuno
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Article
| Open AccessObservation of an anisotropic Dirac cone reshaping and ferrimagnetic spin polarization in an organic conductor
Strong electronic correlations are expected to generate novel behaviour in materials possessing exotic massless electrons with a relativistic nature. Here, the authors demonstrate the reshaping of tilted Dirac cones and ferrimagnetism associated with Coulombic interactions in a layered organic compound.
- Michihiro Hirata
- , Kyohei Ishikawa
- & Kazushi Kanoda
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Article
| Open AccessOptical patterning of trapped charge in nitrogen-doped diamond
Manipulating nitrogen vacancies in nitrogen-doped diamond is important for quantum information processing. Here the authors use a two-colour excitation to redistribute the localized trapping charges in type-1b diamonds.
- Harishankar Jayakumar
- , Jacob Henshaw
- & Carlos A. Meriles
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Article
| Open AccessStructural and compositional dependence of the CdTexSe1−x alloy layer photoactivity in CdTe-based solar cells
Using a CdTexSe1−x alloy in CdTe solar cells leads to better performances. Here, Poplawsky et al. show that the photoactive properties of the alloy depend on its chemical composition and structural properties, and derive a phase diagram to further optimize alloy growth for photovoltaic devices.
- Jonathan D. Poplawsky
- , Wei Guo
- & Yanfa Yan
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| Open AccessSudden restoration of the band ordering associated with the ferromagnetic phase transition in a semiconductor
As semiconductors are doped with impurities, their useful electrical transport properties are degraded as their band structures are increasingly modified. Here, the authors demonstrate that the band ordering is restored in Mn-doped GaAs above a ferromagnetic transition at a critical concentration.
- Iriya Muneta
- , Shinobu Ohya
- & Masaaki Tanaka
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| Open AccessSlower carriers limit charge generation in organic semiconductor light-harvesting systems
In organic solar cells, the photogeneration of free charge carriers is limited by the dissociation of interfacial charge transfer states. Here, the authors study the impact of charge carrier mobilities in operational devices and show that the slowest charge carriers limit the dissociation of charge transfer states.
- Martin Stolterfoht
- , Ardalan Armin
- & Paul Meredith
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| Open AccessDiscovery of earth-abundant nitride semiconductors by computational screening and high-pressure synthesis
Nitride semiconductors are attractive for various applications. Here a computational screening study identifies a number of possible ternary nitrides as promising candidates, including a phase that the authors synthesize for the first time via a high-pressure route.
- Yoyo Hinuma
- , Taisuke Hatakeyama
- & Fumiyasu Oba
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| Open AccessDoping-enhanced radiative efficiency enables lasing in unpassivated GaAs nanowires
Until now, efforts to enhance the performance of nanolasers have focused on reducing the rate of non-radiative recombination. Here, Burgess et al.employ controlled impurity doping to increase the rate of radiative recombination.
- Tim Burgess
- , Dhruv Saxena
- & Chennupati Jagadish
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| Open AccessNanodiamond-based nanostructures for coupling nitrogen-vacancy centres to metal nanoparticles and semiconductor quantum dots
The coupling of nitrogen-vacancy centres with plasmonic and photonic nanostructures is usually studied by top-down preparation. Here, Gong et al. use a bottom-up approach to grow metallic and semiconducting nanoparticles on nanodiamonds, controlling the nanoparticle coverage, size and composition.
- Jianxiao Gong
- , Nat Steinsultz
- & Min Ouyang
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| Open AccessObservation of the quantum Hall effect in δ-doped SrTiO3
Observation of quantum phenomena in correlated electron systems is challenging due to low mobility and high concentration of carriers. Here, Matsubara et al. report a two-dimensional electron system with high mobility-low carrier density in δ-doped SrTiO3, demonstrating quantum Hall effect in d-electron systems.
- Y. Matsubara
- , K. S. Takahashi
- & M. Kawasaki
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| Open AccessSpin-texture inversion in the giant Rashba semiconductor BiTeI
In semiconductors containing heavy elements, the Rashba spin-orbit interaction can couple the momentum and spin of electrons, yielding spintronic functionality. Here, the authors image band- and orbital-dependent spin-textures in the layered polar semiconductor BiTeI, demonstrating behaviour beyond the standard Rashba model.
- Henriette Maaß
- , Hendrik Bentmann
- & Friedrich Reinert
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| Open AccessQuadrupolar and anisotropy effects on dephasing in two-electron spin qubits in GaAs
Electron spins in semiconductors form a potential basis for quantum information technology however they are strongly affected by interactions with nuclear spins. Here, the authors show how quadrupolar interactions, although suppressing nuclear dynamics, can result in an anisotropic enhancement of electronic decoherence.
- Tim Botzem
- , Robert P. G. McNeil
- & Hendrik Bluhm
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| Open AccessGate-controlled electromechanical backaction induced by a quantum dot
Coupling between quantum structures and mechanical resonators remains a challenge. Here, the authors couple a quantum dot and a piezoelectric microresonator and show that gate-induced single electron transport in the quantum dot enables control of the amplitude of the mechanical response.
- Yuma Okazaki
- , Imran Mahboob
- & Hiroshi Yamaguchi
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Article
| Open AccessQuantized conductance coincides with state instability and excess noise in tantalum oxide memristors
Oxide memristors exhibit noise in excess of 2–4 orders of magnitude above the baseline at quantized conductance states. Here, the authors measure anomalous electrical noise at these states in tantalum oxide memristors and relate it to thermally-activated atomic fluctuations by numerical simulations.
- Wei Yi
- , Sergey E. Savel'ev
- & R. Stanley Williams
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| Open AccessSuppressing molecular vibrations in organic semiconductors by inducing strain
The mobility of organic semiconductors can be tuned by modifying their chemical composition or crystalline properties. Here, the authors show that bending organic single crystals increases their field effect transistor mobility due to restrained molecular vibrations and subsequently reduced dynamic disorder.
- Takayoshi Kubo
- , Roger Häusermann
- & Jun Takeya
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| Open AccessSignature of coexistence of superconductivity and ferromagnetism in two-dimensional NbSe2 triggered by surface molecular adsorption
Ferromagnetism and superconductivity possess inherently incompatible electronic spin ordering, and their coexistence requires elaborate engineering of material components. Here, the authors induce ferromagnetism in a two-dimensional superconducting crystal by the adsorption of hydrazine molecules.
- Xiaojiao Zhu
- , Yuqiao Guo
- & Yi Xie
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Article
| Open AccessGrowth of semiconducting single-wall carbon nanotubes with a narrow band-gap distribution
Growth of high-quality semiconducting single-wall carbon nanotubes is crucial for high-performance devices. Here, the authors report a partially carbon-coated cobalt nanoparticle catalyst which catalyzes growth of predominantly semiconducting single-wall carbon nanotubes with a narrow band-gap distribution.
- Feng Zhang
- , Peng-Xiang Hou
- & Hui-Ming Cheng
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| Open AccessObservation of Weyl nodes and Fermi arcs in tantalum phosphide
Weyl semimetals exhibit exotic properties owing to the presence of Weyl fermions. Here, Xu et al. show that tantalum phosphide is an ideal platform for studying the transport properties of these particles because its low-energy properties are dominated by a single type of Weyl fermion.
- N. Xu
- , H. M. Weng
- & M. Shi
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Article
| Open AccessDrift transport of helical spin coherence with tailored spin–orbit interactions
Spin-orbit effects in non-magnetic semiconductors allow for the manipulation of electronic spins in the absence of an applied magnetic field. Here, the authors exploit a persistent spin helix state in single quantum wells to enhance the coherence length of electronic drift transport.
- Y. Kunihashi
- , H. Sanada
- & T. Sogawa
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| Open AccessTemperature mapping of operating nanoscale devices by scanning probe thermometry
Thermometry using scanning probe techniques allows for the thermal imaging and characterization of devices with nanoscale resolution, however can be hindered by contact-related artefacts. Here, the authors demonstrate a thermal scanning probe approach which eliminates contact-resistance effects.
- Fabian Menges
- , Philipp Mensch
- & Bernd Gotsmann
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| Open AccessOptically controlled electroresistance and electrically controlled photovoltage in ferroelectric tunnel junctions
Tunnelling electroresistance is the variation of resistance of a thin-film junction with the polarization state of its ferroelectric tunnel barrier. Here the authors demonstrate a large light-modulated tunnelling electroresistance and a hysteretic photovoltaic effect in a complex oxide heterostructure.
- Wei Jin Hu
- , Zhihong Wang
- & Tom Wu
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| Open AccessDirectional charge separation in isolated organic semiconductor crystalline nanowires
Photo-induced charge separation in organic semiconductors usually occurs at interfaces between electron donors and acceptors. Here, the authors show using photoluminescence measurements that charge separation is intrinsic and directional in organic crystalline nanowires made of stacked monomers.
- J. A. Labastide
- , H. B. Thompson
- & M. D. Barnes
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| Open Access1s-intraexcitonic dynamics in monolayer MoS2 probed by ultrafast mid-infrared spectroscopy
Excitons—bound electron-hole pairs—in two-dimensional transition-metal dichalcogenides can exhibit a rich spectrum of excited states. Here, the authors use ultrafast mid-infrared spectroscopy to explore the dynamics of these so-called 1s-intraexcitonic transitions in monolayer molybdenum disulphide.
- Soonyoung Cha
- , Ji Ho Sung
- & Hyunyong Choi
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| Open AccessFerroelasticity and domain physics in two-dimensional transition metal dichalcogenide monolayers
The atoms in two-dimensional transition-metal dichalcogenides can arrange into a number of different structures, or polymorphs. Here, the authors use first-principles calculations to show that one such polymorph, 1T', can exhibit a large mechanical response to external applied strain.
- Wenbin Li
- & Ju Li
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| Open AccessReducing dynamic disorder in small-molecule organic semiconductors by suppressing large-amplitude thermal motions
Thermal vibration is harmful to charge transport in molecular semiconductors, which hinders the use of these materials in flexible electronics. Here, Illig et al.show that the vibration is suppressed when molecular side chains are attached to the long axis of conjugated cores.
- Steffen Illig
- , Alexander S. Eggeman
- & Henning Sirringhaus
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| Open AccessArbitrary cross-section SEM-cathodoluminescence imaging of growth sectors and local carrier concentrations within micro-sampled semiconductor nanorods
Semiconductor nanocrystals are potential nanoelectronic materials but often display nonuniform electric properties due to their anisotropic growths. Here, the authors report cross-sectional cathodoluminescence imaging of a single-crystalline ZnO nanowire to resolve its growth sectors with different carrier concentrations.
- Kentaro Watanabe
- , Takahiro Nagata
- & Yoshiaki Nakamura
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| Open AccessStructural semiconductor-to-semimetal phase transition in two-dimensional materials induced by electrostatic gating
Control of conductivity and optical properties via atomic structure changes is of technological importance in information storage. Here, Li et al.show that electrostatic gating has the potential to drive structural semiconductor-to-semimetal phase transitions in some monolayer transition metal dichalcogenides.
- Yao Li
- , Karel-Alexander N. Duerloo
- & Evan J. Reed
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| Open AccessExciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla
The spin and valley degrees of freedom are coupled in two-dimensional transition-metal dichalcogenides. Here, the authors use high magnetic fields to optically measure the valley Zeeman effect and diamagnetic exciton shift in tungsten disulphide and molybdenum disulphide, and determine the exciton binding energies.
- Andreas V. Stier
- , Kathleen M. McCreary
- & Scott A. Crooker
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| Open AccessSustained hole inversion layer in a wide-bandgap metal-oxide semiconductor with enhanced tunnel current
Wide-bandgap, metal-oxide thin-film transistors are limited in their application by the lack of available p-type material. Here, the authors demonstrate a wide-bandgap metal-oxide n-type semiconductor that sustains a strong p-type inversion layer using a barrier dielectric with a high-dielectric constant.
- Gem Shoute
- , Amir Afshar
- & Douglas Barlage
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Article
| Open AccessStrain effects on the work function of an organic semiconductor
The understanding of strain effect on electronic properties of organic semiconductors is crucial for the designs of flexible electronics. Here, Wu et al.characterize the tensile and compressive strain effects on the work function of rubrene single crystals as a benchmark system.
- Yanfei Wu
- , Annabel R. Chew
- & C. Daniel Frisbie
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Article
| Open AccessMagnetic ground state of an individual Fe2+ ion in strained semiconductor nanostructure
Iron Fe2+ions embedded in semiconductor matrix usually have zero magnetic moment in the ground state. Here, the authors show theoretically and experimentally that a nearly doubly degenerate magnetic ground state is produced when iron ions are subjected to strain in epitaxial quantum dots, suggesting they could be used in spintronics and solotronics.
- T. Smoleński
- , T. Kazimierczuk
- & W. Pacuski
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Article
| Open AccessDirect growth of single-crystalline III–V semiconductors on amorphous substrates
Growth of high-quality III–V semiconductors for electronics and optoelectronics usually requires an atomic-lattice matched substrate. Here, the authors use templated liquid-phase crystal growth to create single-crystalline III–V material up to ten micrometres across on an amorphous substrate.
- Kevin Chen
- , Rehan Kapadia
- & Ali Javey
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Article
| Open AccessWavelength-tunable sources of entangled photons interfaced with atomic vapours
Quantum dots can produce entangled photons, but careful control over photon wavelength is required for real-life applications. Here, the authors use three-directional strain engineering to overcome this problem and to interface entangled photons from quantum dots with a cloud of natural atoms.
- Rinaldo Trotta
- , Javier Martín-Sánchez
- & Armando Rastelli
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Article
| Open AccessDynamic detection of electron spin accumulation in ferromagnet–semiconductor devices by ferromagnetic resonance
In semiconductor spintronic devices, Hanle precession allows for electrical detection of spin accumulation however it is inhibited at room temperature in GaAs by magnetic-field effects. Here, the authors present an alternative method for detecting spin accumulation based on ferromagnetic resonance.
- Changjiang Liu
- , Sahil J. Patel
- & Paul A. Crowell
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Article
| Open AccessTellurium as a high-performance elemental thermoelectric
Good thermoelectric materials are often complex compounds. Here, the authors reveal that elemental tellurium has a high thermoelectric figure of merit between 300 and 700 K when doped with As, with the potential advantages of easy preparation and relative isotropy.
- Siqi Lin
- , Wen Li
- & Yanzhong Pei
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Article
| Open AccessBio-recognitive photonics of a DNA-guided organic semiconductor
BioLEDs is an emerging group of light-emitting diodes that use duplex-strand DNA to enhance luminescence intensity. Here, Back et al.show that only the specific binding between a pair of single-strand DNA can trigger the enhancement, which potentially makes BioLEDs an easy platform for DNA recognition.
- Seung Hyuk Back
- , Jin Hyuk Park
- & Dong June Ahn
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Article
| Open AccessQuasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires
Polymerization on surfaces is an emerging approach for producing graphene nanoribbons with a tunable bandgap, a promising material for carbon-based electronics. Here, Vasseur et al.show quasi-one-dimensional band structure of a model semiconducting polymer synthesized directly on a supporting surface.
- Guillaume Vasseur
- , Yannick Fagot-Revurat
- & Dmitrii F. Perepichka
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| Open AccessGiant negative magnetoresistance induced by the chiral anomaly in individual Cd3As2 nanowires
Dirac semimetals possess an electronic dispersion relation which is linear in three dimensions, making them three-dimensional analogues of graphene. Here, the authors report large negative magnetoresistance in single-crystal Cd3As2nanowires, evidencing a sought-after chiral anomaly effect.
- Cai-Zhen Li
- , Li-Xian Wang
- & Da-Peng Yu
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| Open AccessHigh mobility emissive organic semiconductor
Organic semiconductors with high mobility and strong fluorescence are necessary for optoelectronic devices. Here, Liu et al. show an organic semiconductor, 2,6-diphenylanthracene, satisfying both requirements with mobility of 34 cm2 V−1 s−1 and emission of 6,627 cd m−2at a turn-on voltage of 2.8 V.
- Jie Liu
- , Hantang Zhang
- & Alan J. Heeger