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| Open AccessGross violation of the Wiedemann–Franz law in a quasi-one-dimensional conductor
Interacting electrons in one dimension are predicted to have independent spin and charge excitations. Wakehamet al. show evidence of this behaviour in a bulk conductor by measuring a ratio of thermal to electrical conductivity orders of magnitude larger than in conventional three-dimensional metals.
- Nicholas Wakeham
- , Alimamy F. Bangura
- & Nigel E. Hussey
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Article
| Open AccessFractional quantum Hall effect in the absence of Landau levels
The fractional quantum Hall effect occurs when electrons move in Landau levels. In this study, using a theoretical flat-band lattice model, the fractional quantum Hall effect is observed in the presence of repulsive interactions when the band is one third full and in the absence of Landau levels.
- D.N. Sheng
- , Zheng-Cheng Gu
- & L. Sheng
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Confined propagation of covalent chemical reactions on single-walled carbon nanotubes
Covalent reactions on carbon nanotube surfaces typically occur at random positions on the hexagonal lattice. Denget al. show that Billups–Birch reductive alkylation takes place at, and propagates from, sp3defect sites, leading to confinement of the reaction fronts in the tubular direction.
- Shunliu Deng
- , Yin Zhang
- & YuHuang Wang
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Fermi surface dichotomy of the superconducting gap and pseudogap in underdoped pnictides
Iron pnictide compounds have recently been shown to have superconducting properties. Xuet al. show that the superconducting gap of underdoped pnictides scales linearly with the transition temperature, and that a pseudogap develops with underdoping.
- Y.-M. Xu
- , P. Richard
- & H. Ding
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Article
| Open AccessOptical switching of nuclear spin–spin couplings in semiconductors
Two-qubit operation is an essential part of quantum computation, but implementation has been difficult. Gotoet al.introduce optically controllable internuclear coupling in semiconductors providing a simple way of switching inter-qubit couplings in semiconductor-based quantum computers.
- Atsushi Goto
- , Shinobu Ohki
- & Tadashi Shimizu
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Using disorder to detect locally ordered electron nematics via hysteresis
Interactions between charge, orbital and lattice degrees of freedom in correlated electron systems have resulted in predictions of new electronic phases of matter. Carlson and Dahmen propose two protocols for detecting disordered electron nematics in condensed matter systems using non-equilibrium methods.
- E.W. Carlson
- & K.A. Dahmen
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Article
| Open AccessMediatorless high-power glucose biofuel cells based on compressed carbon nanotube-enzyme electrodes
Glucose biofuel cells can be used to produce clean energy from renewable sources, but their use is limited by poor stability and low power output. In this study, bioelectrodes are fabricated using carbon nanotubes and the resulting biofuel cells have improved stability and power.
- Abdelkader Zebda
- , Chantal Gondran
- & Serge Cosnier
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Imaging local electronic corrugations and doped regions in graphene
The unoccupied electronic levels of graphene are modified by corrugation, doping and presence of impurities. Here, the authors map discrete electronic domains within a single graphene sheet using scanning transmission X-ray microscopy and provide insight into the modification of unoccupied levels.
- Brian J. Schultz
- , Christopher J. Patridge
- & Sarbajit Banerjee
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Article
| Open AccessSize limits the formation of liquid jets during bubble bursting
A bubble at an air–liquid interface can form a liquid jet upon bursting, spraying aerosol droplets into the air. Leeet al. show that jetting is analogous to pinching-off in liquid coalescence, which may be useful in applications that prevent jet formation and in the improved incorporation of aerosols in climate models.
- Ji San Lee
- , Byung Mook Weon
- & Wah-Keat Lee
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Biologically inspired achromatic waveplates for visible light
Waveplates are used in optoelectronics to alter the polarization of light, but they do not typically perform achromatically, which is important for applications such as three-dimensional displays. Here, biologically inspired periodically multilayered structures are produced, which function as achromatic visible-light waveplates.
- Yi-Jun Jen
- , Akhlesh Lakhtakia
- & Jyun-Rong Lai
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Observing chaos for quantum-dot microlasers with external feedback
Optoelectronic devices such as conventional semiconductor lasers are used to study the chaotic behaviour of nonlinear systems. Here chaos is observed for quantum-dot microlasers operating close to the quantum limit with potential for new directions in the study of chaos in quantum systems.
- Ferdinand Albert
- , Caspar Hopfmann
- & Ido Kanter
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| Open AccessPromotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells
Anodes composed of nickel/yttria-stabilized zirconia in solid oxide fuel cells are known to suffer from coking, which reduces their performance. Here, Yang and colleagues report a new barium oxide/nickel anode, which efficiently oxidizes fuel with minimum carbon buildup.
- Lei Yang
- , YongMan Choi
- & Meilin Liu
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Collective fluorescence enhancement in nanoparticle clusters
Single nanoparticles are known to emit light intermittently, or 'blink', but the mechanisms describing this phenomenon are not fully understood. This study demonstrates that, for small clusters of blinking nanoparticles, the number of particles within a cluster dramatically influences blinking time.
- Siying Wang
- , Claudia Querner
- & Marija Drndic
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Helium penetrates into silica glass and reduces its compressibility
SiO2 glass and helium are important in various fields of science and engineering. Sato et al. show SiO2glass to be less compressible in helium under high pressure, which may be relevant for the interpretation of high-pressure experiments and in the design of new materials.
- Tomoko Sato
- , Nobumasa Funamori
- & Takehiko Yagi
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| Open AccessColossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
Negative thermal expansion—contraction upon heating—is an unusual process that may be exploited to produce materials with zero or other controlled thermal expansion values. Azumaet al. observe negative thermal expansion in BiNiO3which is a result of Bi/Ni charge-transfer transitions.
- Masaki Azuma
- , Wei-tin Chen
- & J. Paul Attfield
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Article
| Open AccessRevealing the high-energy electronic excitations underlying the onset of high-temperature superconductivity in cuprates
Understanding how the high-energy physics of Mott-like excitations affects condensate formation is a key challenge in high-temperature superconductivity. Giannettiet al. clarify the relationship of many-body CuO2excitations and the onset of superconductivity using a new optical pump supercontinuum-probe technique.
- Claudio Giannetti
- , Federico Cilento
- & Fulvio Parmigiani
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Flexible concentrator photovoltaics based on microscale silicon solar cells embedded in luminescent waveguides
Photovoltaic systems comprising monocrystalline silicon have many applications in solar power generation. Yoonet al. describe a composite luminescent concentrator photovoltaic system containing arrays of microscale silicon solar cells, which can be implemented in ultrathin, mechanically bendable formats.
- Jongseung Yoon
- , Lanfang Li
- & John A. Rogers
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Origami-like unfolding of hydro-actuated ice plant seed capsules
Hydro-responsive plant movements have provided inspiration for the design of adaptive materials. Harringtonet al. investigate the hydration-dependent unfolding of ice plant seed capsules and find an origami-like folding pattern, which could aid the development of biomimetic folding structures.
- Matthew J. Harrington
- , Khashayar Razghandi
- & Ingo Burgert
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Article
| Open AccessDetermination of nanoparticle size distribution together with density or molecular weight by 2D analytical ultracentrifugation
Nanoparticles continue to find research and industrial applications, but no single technique exists to characterise their physical properties. Now, an analytical ultracentrifugation method is described which allows the simulataneous determination of nanoparticle size, density and molecular weight distribution.
- Randy P. Carney
- , Jin Young Kim
- & Osman M. Bakr
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Stabilizing lithium–sulphur cathodes using polysulphide reservoirs
Lithium–sulphur batteries may achieve higher energy densities than conventional lithium-ion cells, but the dissolution of sulphur intermediates is a continuing challenge. Here this problem is overcome using a cathode with a mesoporous structure that is able to accommodate intermediate polysulphide anions.
- Xiulei Ji
- , Scott Evers
- & Linda F. Nazar
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Article
| Open AccessActive microrheology and simultaneous visualization of sheared phospholipid monolayers
Two-dimensional fluid interfaces are ubiquitous, but studying their surface dynamic properties is difficult because of coupling between the film and bulk fluid. Choiet al.combine active microrheology with fluorescence microscopy to image fluid interfaces under applied stress.
- S.Q. Choi
- , S. Steltenkamp
- & T.M. Squires
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Cooperative material transport during the early stage of sintering
Sintering is the basis for the production of many metallic and composite materials. Gruppet al. use a new technique to measure the rotation of microscopic copper particles during sintering and find intrinsic rotations to be the dominant movement.
- R. Grupp
- , M. Nöthe
- & J. Banhart
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Synthesis of hexagonal close-packed gold nanostructures
Solid gold is most stable as a face-centred cubic structure, and stable colloidal gold with hexagonal close packing has not been produced. Huanget al.prepare square gold sheets with hexagonal close packing that are stable under ambient conditions.
- Xiao Huang
- , Shaozhou Li
- & Hua Zhang
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Article
| Open AccessReversible temperature regulation of electrical and thermal conductivity using liquid–solid phase transitions
Temperature-controlled regulation of thermal conductivity is difficult to achieve because thermal properties do not change significantly through solid-state phase transitions. Here temperature control of thermal conductivities is demonstrated using liquid–solid phase transitions in a nanoparticle suspension.
- Ruiting Zheng
- , Jinwei Gao
- & Gang Chen
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Size and mechanics effects in surface-induced melting of nanoparticles
Melting-related phenomena are of fundamental and applied interest, but the melting theory is poorly understood. Levitas and Samani develop an advanced phase-field theory of melting coupled to mechanics that resolves existing contradictions and reveals the features of melting phenomena.
- Valery I Levitas
- & Kamran Samani
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A monolithically integrated plasmonic infrared quantum dot camera
Infrared cameras are used for night vision and in medical diagnostics, but currently only present monochrome images. Krishnaet al. demonstrate a monolithically intergrated plasmonic infrared quantum dot camera as a step towards coloured infrared imaging.
- Sang Jun Lee
- , Zahyun Ku
- & Sam Kyu Noh
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Article
| Open AccessNano-engineered electron–hole exchange interaction controls exciton dynamics in core–shell semiconductor nanocrystals
Electron–hole exchange interaction is an intrinsic property of semiconductors, which affects their fine structure. Brovelliet al. demonstrate a nanoengineering-based approach that provides control over the exchange interaction energy at nearly constant emission energy, which cannot be carried out using core-only nanocrystals.
- S. Brovelli
- , R.D. Schaller
- & V.I. Klimov
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Article
| Open AccessPatterns and flow in frictional fluid dynamics
Pattern-forming processes in simple fluids and suspensions are well understood, but displacement morphologies in frictional fluids and granular mixtures have not been studied extensively. Sandneset al. consider the effects of Coulomb friction and compressibility on the fluid dynamics of granular mixtures.
- B. Sandnes
- , E.G. Flekkøy
- & H. See
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Molecular dynamics of single-particle impacts predicts phase diagrams for large scale pattern formation
Energetic particle irradiation can lead to surface smoothing, pattern formation or degradation of the structural integrity of nuclear reactor components. Here, molecular dynamics simulations are used to study the mechanisms that determine the transitions between these disparate processes.
- Scott A. Norris
- , Juha Samela
- & Michael J. Aziz
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Article
| Open AccessMagnetic vortex core reversal by excitation of spin waves
Micron and submicron-sized magnetic platelets in a vortex configuration may be useful in micromagnetics and spintronics applications. Kammereret al. show that a fast unidirectional vortex core reversal process occurs when azimuthal spin wave modes are excited at GHz frequency.
- Matthias Kammerer
- , Markus Weigand
- & Gisela Schuetz
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Article
| Open AccessGapless spin liquid of an organic triangular compound evidenced by thermodynamic measurements
Frustrated magnetic systems can form an exotic quantum spin-liquid ground state, in which strongly correlated spins fluctuate in the spin lattices. Here, the low-temperature electronic state of a charge-transfer compound is found to form a gapless spin liquid.
- Satoshi Yamashita
- , Takashi Yamamoto
- & Reizo Kato
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Article
| Open AccessThe Meissner effect in a strongly underdoped cuprate above its critical temperature
In the pseudogap state of cuprates, although diamagnetic signals have been detected, a Meissner effect has never been observed. Morenzoni and colleagues probe the local diamagnetic response in the normal state of an underdoped layer showing that a 'barrier' layer exhibits a Meissner effect.
- Elvezio Morenzoni
- , Bastian M. Wojek
- & Ivan Božović
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Tip-enhanced photovoltaic effects in bismuth ferrite
Bismuth ferrite has photoelectric properties that make it an attractive alternative for use in photovoltaic devices. Here, using photoelectric atomic force microscopy, the authors show that photogenerated carriers can be collected by the tip and suggest that this can be used in photoelectric applications.
- Marin Alexe
- & Dietrich Hesse
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Article
| Open AccessDevelopment of a universal stress sensor for graphene and carbon fibres
Embedding carbon fibres in polymer matrices provides significant gains in strength and stiffness. Here, the Raman G peak of carbon fibre is studied in relation to applied strain and referenced to graphene; the work could facilitate stress measurements of carbon fibre polymer composites.
- Otakar Frank
- , Georgia Tsoukleri
- & Costas Galiotis
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The lifetime of the deviations from bulk behaviour in polymers confined at the nanoscale
Monitoring the impact of annealing on nanometre-thick polymer layers provides new insight into the changes in the performance of macromolecular materials. Here, the authors present results showing a correlation between the deviations from bulk behaviour and the growth of an irreversibly adsorbed layer.
- Simone Napolitano
- & Michael Wübbenhorst
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Quasi-two-dimensional Skyrmion lattices in a chiral nematic liquid crystal
Skyrmions are particle-like topological entities in a continuous field that have a role in various condensed matter systems. Here, numerical methods are used to show that a chiral nematic liquid crystal could be used as a model system to facilitate direct structural investigation of Skyrmions.
- Jun-ichi Fukuda
- & Slobodan Žumer
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Electrical injection and detection of spin accumulation in silicon at 500 K with magnetic metal/silicon dioxide contacts
Harnessing spin angular momentum could allow the development of electronic devices that are not limited by Moore's law. Here, electrical injection and detection of spin accumulation is achieved at temperatures that are practical for device operation.
- C.H. Li
- , O.M.J. van 't Erve
- & B.T. Jonker
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Review Article |
Trends in the development of environmentally friendly fouling-resistant marine coatings
Biofouling, or the unwanted growth of biological organisms, is a particular problem in marine environments. This review considers recent advances in the development of environmentally friendly coatings to combat biofouling of submerged surfaces.
- James A. Callow
- & Maureen E. Callow
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Article
| Open AccessNear-field examination of perovskite-based superlenses and superlens-enhanced probe-object coupling
A superlens with a negative index of refraction creates a perfect image because propagating waves focus and evanescent waves reconstruct in the image plane. Here, a perovskite-based superlens is demonstrated for electric evanescent fields, which has potential thermal sensor applications.
- S.C. Kehr
- , Y.M. Liu
- & R. Ramesh
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Article |
Coherent electron–phonon coupling in tailored quantum systems
Graphene and InAs nanowires are both promising materials for coherent spin manipulation, but coupling between a quantum system and its environment leads to decoherence. Here, the contribution of electron–phonon coupling to decoherence in graphene and InAs nanowire is studied.
- P. Roulleau
- , S. Baer
- & T. Ihn
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Article
| Open AccessA new method to position and functionalize metal-organic framework crystals
Metal-organic frameworks (MOFs) have potential catalysis, filtration and sensing applications, but device fabrication will require controlled MOF growth. Here, α-hopeite microparticles are used to achieve spatial control of MOF nucleation, and accelerate MOF growth.
- Paolo Falcaro
- , Anita J. Hill
- & Dario Buso
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Article |
Electrically controllable spontaneous magnetism in nanoscale mixed phase multiferroics
Complex oxide interfaces are important for electronic and spintronic applications. In this study, the authors show the emergence of spontaneous magnetism at one such interface between two phases of BiFeO3due to strain effects and piezoelectric coupling.
- Q. He
- , Y. -H. Chu
- & R. Ramesh
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Article
| Open AccessPhonon-tunnelling dissipation in mechanical resonators
The performance of micromechanical and nanomechanical resonators is often hampered by mechanical damping. In this study, the authors demonstrate a numerical solver for the prediction of support-induced losses in these structures and verify experimentally the fidelity of this method.
- Garrett D. Cole
- , Ignacio Wilson-Rae
- & Markus Aspelmeyer
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Article
| Open AccessFirst direct observation of the Van Hove singularity in the tunnelling spectra of cuprates
In two-dimensional lattices the electronic levels are unevenly spaced and the density of states exhibits a divergence known as the Van Hove singularity. In this study, the Van Hove singularity is observed for the first time in a cuprate using scanning tunnelling microscopy.
- A. Piriou
- , N. Jenkins
- & Ø. Fischer
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Article |
Identification of active atomic defects in a monolayered tungsten disulphide nanoribbon
The physical and chemical properties of low-dimensional materials, such as nanoribbons, are affected by edge structures and atomic defects. Here, single-atom defects in a monolayered tungsten disulphide nanoribbon are discriminated and the motions of atomic defects are visualized.
- Zheng Liu
- , Kazu Suenaga
- & Sumio Iijima
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Article |
Imaging oxygen defects and their motion at a manganite surface
Oxygen diffusion processes are critical for the catalytic action of manganites but a full understanding of these processes is elusive. The authors perform atomic resolution scanning tunnelling microscopy imaging of layered manganites and show oxygen and defect dynamics on these surfaces.
- B. Bryant
- , Ch. Renner
- & G. Aeppli
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Article
| Open AccessSuperconductivity-induced optical anomaly in an iron arsenide
Electronic excitations with energies near the superconducting energy gap are strongly affected by superconducting transitions. The authors show, with a comprehensive optical investigation, that excitations with energies up to two orders of magnitude greater are also affected by the transition.
- A. Charnukha
- , P. Popovich
- & A. V. Boris
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Porous organic molecular solids by dynamic covalent scrambling
The construction of porous solids from discrete organic molecules usually involves the formation of regular porous crystals. In this study, a covalent scrambling reaction gives molecules with a range of shapes that do not pack effectively — manipulation of the reagent ratio allows fine control of porosity.
- Shan Jiang
- , James T. A. Jones
- & Andrew I. Cooper
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Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene
Separation of acetylene and ethylene is an important industrial challenge, which may be aided by selectively adsorbant materials. In this study, a metal-organic framework material is reported, which allows highly selective separation of acetylene and ethylene.
- Sheng-Chang Xiang
- , Zhangjing Zhang
- & Banglin Chen