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| Open AccessDeposition and drying dynamics of liquid crystal droplets
When particle-laden drops evaporate, coffee ring patterns form which can affect particle deposition. Here Davidsonet al. show that unlike previously investigated drops, the flows in drying drops of liquid crystals are driven by an increase in surface tension due to liquid crystal concentration.
- Zoey S. Davidson
- , Yongyang Huang
- & A. G. Yodh
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| Open AccessA light-driven artificial flytrap
Stimuli-responsive materials are commonly used in autonomous systems, whilst it is challenging to power them in a programmable manner. Here, Waniet al. use an optical fibre to control the shape of light-responsive liquid-crystal elastomers, which allow the device to detect and trap targeted objects.
- Owies M. Wani
- , Hao Zeng
- & Arri Priimagi
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| Open AccessActively addressed single pixel full-colour plasmonic display
Tuning of plasmonic nanostructures has yet to cover a full colour basis set with a single nanostructure. Franklinet al. demonstrate a liquid crystal-plasmonic system that covers the full red-green-blue colour basis set as a function of voltage and which can be actively addressed with thin-film-transistor technology.
- Daniel Franklin
- , Russell Frank
- & Debashis Chanda
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| Open AccessSegregation of liquid crystal mixtures in topological defects
Liquid crystal mixtures are used in commercial applications and their composition affects their properties. Here Rahimiet al. use atomistic simulations to show that defects influence the molecular arrangement of the mixture components leading to a deviation of the local order from that of the bulk.
- Mohammad Rahimi
- , Hadi Ramezani-Dakhel
- & Juan J. de Pablo
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| Open AccessFine structure of the topological defect cores studied for disclinations in lyotropic chromonic liquid crystals
Topological defects play important roles in determining material properties, whilst their core regions remain unexplored due to strongly distorted structures. Zhouet al. take advantage of extended core regions in a chromonic liquid crystal and show both a radial and azimuthal dependent director and scalar order parameter.
- Shuang Zhou
- , Sergij V. Shiyanovskii
- & Oleg D. Lavrentovich
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| Open AccessHidden topological constellations and polyvalent charges in chiral nematic droplets
Once a purely mathematical discipline, topology has become an essential tool to investigate physical phenomena such as topological states in liquid crystals. Posnjaket al. observe the existence of 3D point defects of higher than unit topological charge in thermally quenched chiral nematic droplets.
- Gregor Posnjak
- , Simon Čopar
- & Igor Muševič
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| Open AccessMagnetic routing of light-induced waveguides
Nematic liquid crystals are frequently used as a reconfigurable material to control light propagation and as a nonlinear medium supporting solitons. Here, the authors demonstrate steering of such solitons in bulk nematic liquid crystals without lateral anchoring by external magnetic fields.
- Yana Izdebskaya
- , Vladlen Shvedov
- & Wieslaw Krolikowski
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| Open AccessFractal nematic colloids
Topological defects in nematic liquid crystals can be controlled upon external stimuli for designing novel photonic materials. Here, Hashemiet al. show geometry-induced formation of fractal defects in nematic fluids with the fractal self-similarity more than 90% from micrometers to nanometres.
- S. M. Hashemi
- , U. Jagodič
- & M. Ravnik
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| Open AccessA plant tendril mimic soft actuator with phototunable bending and chiral twisting motion modes
Plant tendrils are able to undergo both bending and chiral twisting motions but unfortunately synthetic mimics are unable to do this. Here the authors show a dual-layer polysiloxane-based liquid crystal soft actuator capable of two different 3D reversible transformations via light stimuli.
- Meng Wang
- , Bao-Ping Lin
- & Hong Yang
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| Open AccessPhotomotility of polymers
The demand for soft robots urges the development of new light-responsive materials for remotely powered actuation. Here, Wie et al. show directional motion over centimeter scales using azobenzene-functionalized liquid crystalline polymer films upon continuous radiation from ultraviolet to visible light.
- Jeong Jae Wie
- , M. Ravi Shankar
- & Timothy J. White
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| Open AccessLarge-scale self-organization of reconfigurable topological defect networks in nematic liquid crystals
Patterning liquid crystals is essential for their applications in photonics, which is commonly achieved by top-down lithographic approaches. Here, Sasaki et al. show a template-free approach that enables fabricating a large number of ordered square microarrays with tunable lattice on millimetre scale.
- Yuji Sasaki
- , V.S.R. Jampani
- & Hiroshi Orihara
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Article
| Open AccessTowards first-principles molecular design of liquid crystal-based chemoresponsive systems
Nematic liquid crystals have potential as sensors for various molecules. Here, the authors present a computational chemistry model for describing the detection of a warfare agent by liquid crystals, opening the door for the atomic-scale design of sensitive and selective chemoresponsive systems.
- Luke T. Roling
- , Jessica Scaranto
- & Manos Mavrikakis
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Article
| Open AccessPhoton upconversion with directed emission
Photon upconversion can be used to harvest low energy photons, which are otherwise lost in solar cells. Here, Börjesson et al. use a well-oriented liquid crystal matrix to host the upconversion system in order to emit upconverted photons in a preferential direction, where the solar cells would be located.
- K. Börjesson
- , P. Rudquist
- & K. Moth-Poulsen
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Article
| Open AccessColloidal cholesteric liquid crystal in spherical confinement
Confinement-induced organization of nanoparticles is utilized to generate new structures with novel optical or magnetic properties. Here, Li et al.show that colloidal liquid crystals formed by rod-like nanoparticles self-assemble into various geometries depending on the degree of spherical confinement in droplets.
- Yunfeng Li
- , Jeffrey Jun-Yan Suen
- & Eugenia Kumacheva
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| Open AccessAtomically resolved three-dimensional structures of electrolyte aqueous solutions near a solid surface
Liquids near a solid surface form an interfacial layer where the molecular structure is different from the bulk. Here the authors report atomic resolution three-dimensional images of electrolyte solutions that demonstrate the existence of three types of interfacial structures as a function of concentration.
- Daniel Martin-Jimenez
- , Enrique Chacon
- & Ricardo Garcia
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| Open AccessLight-melt adhesive based on dynamic carbon frameworks in a columnar liquid-crystal phase
Liquid crystals are used in many applications, such as removable adhesives, but this requires both good bonding strength, and its rapid disappearance under an external stimulus. Here, Saito and others report a dynamic liquid crystal material that loses is bonding strength under photo irradiation.
- Shohei Saito
- , Shunpei Nobusue
- & Shigehiro Yamaguchi
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| Open AccessFinite particle size drives defect-mediated domain structures in strongly confined colloidal liquid crystals
Liquid crystals confined to micrometre-sized geometries can be well described by a continuum theory, where the size effect of constituent mesogens is negligible. Here, the authors show how the continuum theory breaks down in colloidal liquid crystal, leading to the formation of defect-mediated domains.
- Ioana C. Gârlea
- , Pieter Mulder
- & Bela M. Mulder
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| Open AccessSpontaneous helix formation in non-chiral bent-core liquid crystals with fast linear electro-optic effect
Liquid crystals that consist of rod-like molecules currently dominate the materials used in industry for display and photonic applications. Here, the authors demonstrate electro-optic grey-scale switching based on the spontaneous formation of a short-pitch helix in a tilted smectic phase of achiral bent-core molecules.
- Sithara P. Sreenilayam
- , Yuri P. Panarin
- & Carsten Tschierske
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| Open AccessControlling the volatility of the written optical state in electrochromic DNA liquid crystals
Electrochromism, the dependence of light absorption upon electronic control, finds a wide range of applications in smart materials. Here, Liu et al. show an electrochromic DNA–surfactant liquid crystal system that exhibits electrically tunable optical absorption and thermally tunable memory.
- Kai Liu
- , Justin Varghese
- & Andreas Herrmann
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| Open AccessEntropy-driven formation of chiral nematic phases by computer simulations
The entropy-driven formation of cholesteric liquid crystal, one of the widely used liquid crystal phase, has not yet been addressed in simulations due to large unit cells. Here, Dussi and Dijkstra overcome this problem by introducing a hard-particle model and show that shape alone can stabilize a chiral nematic phase.
- Simone Dussi
- & Marjolein Dijkstra
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| Open AccessLarge-area graphene-based nanofiltration membranes by shear alignment of discotic nematic liquid crystals of graphene oxide
Membranes made from graphene have ultra-fast water transport and precise molecular sieving properties. Here, the authors show how large-area membranes can be manufactured by a rapid and scalable process based on shear alignment of graphene-oxide liquid crystals for unlocking industrial applications.
- Abozar Akbari
- , Phillip Sheath
- & Mainak Majumder
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| Open AccessSpontaneous liquid crystal and ferromagnetic ordering of colloidal magnetic nanoplates
Ferromagnetism has been known as a material property of solids since the time of the ancient Greeks. Here, Shuai et al. report that magnetic nanoplates suspended in a simple solvent can spontaneously align to form a ferromagnetic liquid, capable of both producing and sensing magnetic fields.
- M. Shuai
- , A. Klittnick
- & N. A. Clark
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| Open AccessA liquid-crystalline hexagonal columnar phase in highly-dilute suspensions of imogolite nanotubes
Liquid crystals are grouped into four main classes—nematic, lamellar, cubic and columnar—depending on their symmetries. Here, the authors show for the first time that a columnar phase can form in suspensions of imogolite nanotubes at very low concentrations.
- Erwan Paineau
- , Marie-Eve M. Krapf
- & Patrick Davidson
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| Open AccessControlling Gaussian and mean curvatures at microscale by sublimation and condensation of smectic liquid crystals
The self-assembly of soft matter is sensitive to their morphology, which is changeable. Here, Kim et al.show how evaporation and condensation at high temperature modify the surface of a smectic liquid crystal film in a way controlled by the local Gaussian and mean curvature of its layered structure.
- Dae Seok Kim
- , Yun Jeong Cha
- & Dong Ki Yoon
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| Open AccessGraphene liquid crystal retarded percolation for new high-k materials
It is commonly believed that graphene flakes form electrical percolation networks at low concentration, and thus can be used as conductive materials. Here, Yuan et al. show in graphene polymer composites that the transition to liquid crystals hinders the formation of percolated networks, resulting in high-kmaterials.
- Jinkai Yuan
- , Alan Luna
- & Philippe Poulin
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| Open AccessZeolite-like liquid crystals
Zeolites with regular porous structures are widely used as gas adsorbents and scaffolding for catalysts. Poppe et al. report a liquid crystal with zeolite-like structure by self-assembly of polyphilic molecules with π-conjugated rod-like cores into a honeycomb formed by pentagonal/octagonal channels.
- Silvio Poppe
- , Anne Lehmann
- & Carsten Tschierske
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| Open AccessMacroscopic ordering of helical pores for arraying guest molecules noncentrosymmetrically
Helical nanostructures often exhibit intriguing physical phenomena. Here, the authors fabricate a helical porous material exhibiting both controlled handedness and macroscopic orientation, which promises applications in a wide array of disciplines.
- Chunji Li
- , Joonil Cho
- & Yasuhiro Ishida
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| Open AccessNew insights into photoactivated volume generation boost surface morphing in liquid crystal coatings
The photomechanical surface modulation of liquid crystal polymer networks can be amplified with a small amount of azobenzene, but its mechanism is not yet fully understood. Here, Liu and Broer propose that the continuously oscillating trans-to-cisisomerization of azobenzene plays the dominating role.
- Danqing Liu
- & Dirk J. Broer
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| Open AccessSpontaneous emergence of chirality in achiral lyotropic chromonic liquid crystals confined to cylinders
Chirality in molecular materials is commonly used to manipulate the polarization of light. Here, Nayani et al. observe the formation of doubly twisted structure in achiral chromonic liquid crystals when confined to a cylindrical capillary, which leads to spontaneous chiral breaking.
- Karthik Nayani
- , Rui Chang
- & Mohan Srinivasarao
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Diastereomeric liquid crystal domains at the mesoscale
Helical nanofilaments—composed of achiral, bent core molecules—have been shown to assemble into left- and right-handed structures. Here, the authors show diastereomeric interactions on the mesocale between chiral liquid crystal guest compounds and helical nanofilament-based pores.
- Dong Chen
- , Michael R. Tuchband
- & Noel A. Clark
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| Open AccessDielectrophoretic manipulation of the mixture of isotropic and nematic liquid
Nematic and isotropic liquid phases can coexist within a narrow temperature window. Here, Kim et al. show how to control this mixed phase via thermal and dielectrophoretic manipulations, based on which nematic microfilaments in an isotropic medium, or vice versa, are demonstrated.
- Soo-Dong Kim
- , Bomi Lee
- & Jang-Kun Song
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| Open AccessCreation and manipulation of topological states in chiral nematic microspheres
Controlling the topology of matter offers an alternative way to make functional materials, among which liquid crystals hold promise due to their spontaneously occurring defects. Here Orlova et al. demonstrate the formation and remote control of topological structures in frustrated cholesteric droplets.
- Tetiana Orlova
- , Sarah Jane Aßhoff
- & Etienne Brasselet
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Three-dimensional patterning of solid microstructures through laser reduction of colloidal graphene oxide in liquid-crystalline dispersions
Existing lithographic methods for the micropatterning of reduced graphene oxide (rGO) are limited by mask production. Here, the authors fabricate fully 3D rGO microstructures in an aqueous nematic liquid crystal of two-dimensional GO flakes via a scalable, mask-free pulsed near-infrared laser approach.
- Bohdan Senyuk
- , Natnael Behabtu
- & Ivan I. Smalyukh
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| Open AccessThree-dimensional positioning and control of colloidal objects utilizing engineered liquid crystalline defect networks
Topological defects can be used not only to modify the properties of liquid crystals but also as scaffolds to build new structures by trapping particles. Here, Yoshida et al. construct three-dimensional colloidal superstructures in a nematic host, which are reconfigurable in an electric field.
- H. Yoshida
- , K. Asakura
- & M. Ozaki
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| Open AccessLiquid crystals for organic thin-film transistors
Polycrystalline thin films of small molecules hold promise for organic thin-film transistors because of their large charge mobility, but are currently limited by poor film homogeneity and thermal durability. Here, Iino et al. design an ordered liquid crystal phase to overcome these two problems.
- Hiroaki Iino
- , Takayuki Usui
- & Jun-ichi Hanna
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| Open AccessSelf-assembly and electrostriction of arrays and chains of hopfion particles in chiral liquid crystals
Topological defects can be spontaneously generated to thermodynamically stabilize a variety of peculiar condensed matter phases for technological applications. Here, Ackerman et al. show electrically controllable self-assembly of knotted defects into periodic arrays in chiral liquid crystals.
- Paul J. Ackerman
- , Jao van de Lagemaat
- & Ivan I. Smalyukh
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| Open AccessA molecular nematic liquid crystalline material for high-performance organic photovoltaics
There is a trade-off between increasing thickness of active layers in organic photovoltaic cells to be compatible with modern printing techniques and decreasing it to improve the device performance. Sun et al.report a nematic liquid crystalline molecular electron donor material used in thick layers.
- Kuan Sun
- , Zeyun Xiao
- & David J. Jones
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Power-controlled transition from standard to negative refraction in reorientational soft matter
Anisotropic media have interesting effects, particularly at interfaces. Piccardi et al.show that optical refraction in nonlinear nematic liquid crystals can be tuned from positive to negative by acting on beam power, altering the distribution of the optic axis and the energy flux.
- Armando Piccardi
- , Alessandro Alberucci
- & Gaetano Assanto
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| Open AccessLiquid crystal-enabled electro-osmosis through spatial charge separation in distorted regions as a novel mechanism of electrokinetics
Electro-osmosis is the control of fluid motion through application of an electrical field. Here, the authors present a new method of electro-osmosis using electrically conductive liquid crystals, and show tunable electro-osmotic flow using director liquid-crystal patterns.
- Israel Lazo
- , Chenhui Peng
- & Oleg D. Lavrentovich
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| Open AccessA liquid crystalline chirality balance for vapours
Chiral determination of vapours is possible in biological systems as an important part of the olfactory system. Here, the authors describe a system that is capable of visually detecting and distinguishing the chirality of vapour-phase molecules by structural changes in a liquid crystal confined in open microchannels.
- Takuya Ohzono
- , Takahiro Yamamoto
- & Jun-ichi Fukuda
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Large-scale self-assembled zirconium phosphate smectic layers via a simple spray-coating process
The large-scale assembly of asymmetric colloidal particles is used in creating high-performance fibres and two-dimensional materials. Here, the authors present a spray-coating process for the fabrication of thin, flexible nanoplatelet/epoxy films and study their gas barrier properties.
- Minhao Wong
- , Ryohei Ishige
- & Hung-Jue Sue
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Detection of graphene domains and defects using liquid crystals
Determining graphene domain size and distribution is important for realizing functional electronic devices. Here, the authors use liquid crystals to study graphene surfaces, via the liquid crystal molecules aligning with the domains, and use nematic to smectic transitions to study defects.
- Jong-Ho Son
- , Seung-Jae Baeck
- & Jong-Hyun Ahn
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Helical nanofilaments of bent-core liquid crystals with a second twist
Banana-shaped liquid crystals attract people’s attention nowadays because of their peculiar optical properties associated with a helical nanofilament phase. Here Zhang et al. report a doubly twisted packing of this phase, which is different from the parallel packing observed in the past.
- C. Zhang
- , N. Diorio
- & A Jákli
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| Open AccessFree-surface molecular command systems for photoalignment of liquid crystalline materials
Molecular alignment in liquid crystals is conventionally achieved by surface mediation from the substrate side. Fukuhara et al.develop a method to photocontrol the orientation of liquid crystalline polymer films from the air side, which is guided by a photoresponsive skin layer.
- Kei Fukuhara
- , Shusaku Nagano
- & Takahiro Seki
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Ultrafast observation of critical nematic fluctuations and giant magnetoelastic coupling in iron pnictides
Anisotropy in the normal-state properties of the iron pnictides could be important to their exotic behaviour, but its cause is unclear. Femtosecond spectrometry of an iron-pnictide superconductor performed by Patz et al.reveals critical nematic fluctuations and unexpectedly large magnetoelastic coupling.
- Aaron Patz
- , Tianqi Li
- & Jigang Wang
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Electrofluorochromism in π-conjugated ionic liquid crystals
The ability to easily modulate a material’s photoluminescent properties in response to stimuli is difficult to achieve in liquid crystals. Here the authors report ionic liquid crystals exhibiting high fluorescent quantum yields with redox-dependent photoluminescence.
- Amerigo Beneduci
- , Sante Cospito
- & Giuseppe Chidichimo
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Topological zoo of free-standing knots in confined chiral nematic fluids
Knotted structures can be stabilized in nematic liquid crystals using colloidal particles. Here the authors demonstrate theoretically and numerically that metastable free-standing knots can also be realized in cholesteric droplets, and their topology is determined by chirality and confinement conditions.
- David Seč
- , Simon Čopar
- & Slobodan Žumer
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| Open AccessTopological structure dynamics revealing collective evolution in active nematics
Topological defects are observed in a range of active systems, but their dynamical properties are largely unknown. Here, the authors use a simulation of self-propelled hard-rods to generate topological defects in active nematics, finding that their anomalous dynamics may lead to large-scale collective motions.
- Xia-qing Shi
- & Yu-qiang Ma
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| Open AccessNematic twist-bend phase with nanoscale modulation of molecular orientation
Theories predict the existence of a nematic liquid crystal phase with a local twist-bend structure, but no experimental proof is available over the past 40 years. Borshch et al.identify this phase for the first time in two different materials containing dimeric molecules.
- V. Borshch
- , Y.-K. Kim
- & O. D. Lavrentovich