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| Open AccessRole of domain walls in the abnormal photovoltaic effect in BiFeO3
The origin of the abnormal photovoltaic effect in bismuth ferrite thin films, which causes voltages larger than the band gap, is poorly understood. Bhatnagar et al.show that this effect can be attributed to a bulk photovoltaic effect and that it can be enhanced by controlling domain wall conductivity.
- Akash Bhatnagar
- , Ayan Roy Chaudhuri
- & Marin Alexe
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Ferroelectric polymer networks with high energy density and improved discharged efficiency for dielectric energy storage
Ferroelectric polymers are attractive candidates as dielectric materials for electrical energy storage applications, but suffer from large dielectric loss. Here, the authors report a method for creating ferroelectric polymer networks with reduced dielectric loss and large charge–discharge efficiencies.
- Paisan Khanchaitit
- , Kuo Han
- & Qing Wang
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Atomic-scale mechanisms of ferroelastic domain-wall-mediated ferroelectric switching
In ferroelectric thin films, ferroelastic domains affect the features of polarization switching. Gao et al.perform real-time transmission electron microscopy measurements and show that ferroelastic domains can hinder the switching via formation of a transient interface layer with a dipole glass structure.
- Peng Gao
- , Jason Britson
- & Xiaoqing Pan
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| Open AccessUltrafast modulation of polarization amplitude by terahertz fields in electronic-type organic ferroelectrics
Controlling ferroelectric polarization on a terahertz timescale is a challenge, because typically the domain-wall motion occurs on much longer time scales. Here, the authors achieve control over the electronic ferroelectricity in an organic material using a terahertz pump–probe technique.
- Tatsuya Miyamoto
- , Hiroyuki Yada
- & Hiroshi Okamoto
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Room-temperature spin-spiral multiferroicity in high-pressure cupric oxide
As ferroelectric and magnetic ordering coexist in multiferroic materials, they might be used for memory applications, but only if the multiferroic phase is stable at room temperature. Here, the authors find such a phase in cupric oxide, whose spin-spiral multiferroicity is stabilized by pressure.
- Xavier Rocquefelte
- , Karlheinz Schwarz
- & Jeroen van den Brink
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Microwave magnetoelectric effect via skyrmion resonance modes in a helimagnetic multiferroic
Magnetic skyrmions are topologically stable swirls in a spin structure. Here, the authors demonstrate new ways of controlling them by showing that the absorption of an electromagnetic wave by a skyrmion depends on the direction of incidence and that the resonance modes respond to a magnetic field.
- Y. Okamura
- , F. Kagawa
- & Y. Tokura
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| Open AccessElectric in-plane polarization in multiferroic CoFe2O4/BaTiO3 nanocomposite tuned by magnetic fields
Multiferroics, materials that exhibit two or more ferroic orders, are potentially useful for data storage if the coupling between these orders can be exploited. Here the authors elucidate how the magnetism in ferrimagnetic nanopillars can control the electric polarization of a surrounding matrix.
- Carolin Schmitz-Antoniak
- , Detlef Schmitz
- & Heiko Wende
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| Open AccessNon-volatile memory based on the ferroelectric photovoltaic effect
Ferroelectric RAM is considered a promising candidate on the quest for a universal memory, but the concept is still problem prone. Here, the authors use the ferroelectric photovoltaic effect as a non-destructive read-out method for a new prototype memory, which shows good data retention and fatigue resistance.
- Rui Guo
- , Lu You
- & Junling Wang
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| Open AccessFree-electron gas at charged domain walls in insulating BaTiO3
Although ferroelectrics are generally insulating, their domain walls can show electrical conductivity. Here Sluka et al. observe a highly conducting free-electron gas at charged domain walls in ferroelectric BaTiO3.
- Tomas Sluka
- , Alexander K. Tagantsev
- & Nava Setter
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A strong electro-optically active lead-free ferroelectric integrated on silicon
The strong electro-optical response of BaTiO3 could be useful for making high-speed switches for optical telecommunications. Abel et al. demonstrate the ability to maintain this response in BaTiO3films grown directly onto silicon, extending its potential to the development of silicon photonics.
- Stefan Abel
- , Thilo Stöferle
- & Jean Fompeyrine
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| Open AccessMagnetic switching of ferroelectric domains at room temperature in multiferroic PZTFT
Multiferroic materials that exhibit coupled ferromagnetic and ferroelectric characteristics could be useful in the development of non-volatile digital storage. Evans et al. report a single-phase multiferroic material whose room-temperature magnetoelectric coupling appears to be unusually strong.
- D.M. Evans
- , A. Schilling
- & J.F. Scott
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Structural domain walls in polar hexagonal manganites
Domain walls in multiferroic materials exhibit novel properties that are not present in the bulk. This work reports first-principle calculations that relate the structure of the domain-wall to its electronic properties in multiferroic hexagonal manganites.
- Yu Kumagai
- & Nicola A. Spaldin
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| Open AccessAbove-room-temperature ferroelectricity and antiferroelectricity in benzimidazoles
There are only a few known organic ferroelectrics, particularly ones that operate at high temperatures. Here the discovery of ferroelectricity above room temperature in members of an ubiquitous family of organic molecules reveals the possibility of novel low-cost electronic applications.
- Sachio Horiuchi
- , Fumitaka Kagawa
- & Yoshinori Tokura
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Magneto-orbital helices as a route to coupling magnetism and ferroelectricity in multiferroic CaMn7O12
The coupling of magnetism and ferroelectricity is of relevance for applications such as sensing, but occurs only rarely in bulk materials. The large magnetically induced ferroelectric polarization observed here in CaMn7O12establishes a new approach to achieve a strong magnetoelectric coupling.
- N.J. Perks
- , R.D. Johnson
- & P.G. Radaelli
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Tunable ferroelectricity in artificial tri-layer superlattices comprised of non-ferroic components
Ferroelectric materials are appealing for use in a range of technological applications. This study demonstrates the onset of ferroelectric behaviour in a superlattice structure that consists of three non-ferroelectric layers, suggesting ferroelectricity can also be induced by interface effects.
- K. Rogdakis
- , J.W. Seo
- & C. Panagopoulos
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Atomic-scale evolution of modulated phases at the ferroelectric–antiferroelectric morphotropic phase boundary controlled by flexoelectric interaction
Morphotropic phase boundaries—regions of abrupt structural change and enhanced material response—are of practical importance and are a challenge for the fundamental theory of phase transitions. Here, the ferroelectric–antiferroelectric boundary is studied using atomically resolved mapping in BiFeO3.
- A.Y. Borisevich
- , E.A. Eliseev
- & S.V. Kalinin
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| Open AccessEnhanced electromechanical response of ferroelectrics due to charged domain walls
The piezoelectric materials most commonly used for technological applications contain lead, a toxic element. Slukaet al. identify a mechanism that leads to an enhancement of the dielectric and piezoelectric properties of non-toxic ferroelectrics, due to the presence of charged domain walls.
- Tomas Sluka
- , Alexander K. Tagantsev
- & Nava Setter
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Wide bandgap tunability in complex transition metal oxides by site-specific substitution
Tuning the bandgap of complex transition metal oxides in a manner that preserves their intrinsic properties has so far remained elusive. Choiet al. demonstrate that the bandgap of bismuth titanate can be varied by substitutional alloying with lanthanum cobaltate, without altering its ferroelectric properties.
- Woo Seok Choi
- , Matthew F. Chisholm
- & Ho Nyung Lee
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Revealing the role of defects in ferroelectric switching with atomic resolution
Ferroelectric materials are characterized by a spontaneous polarization, which in practical applications is manipulated by an electric field. This study examines how defects affect the switching with atomic resolution, by usingin situaberration-corrected transmission electron microscopy.
- Peng Gao
- , Christopher T. Nelson
- & Xiaoqing Pan
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Concurrent transition of ferroelectric and magnetic ordering near room temperature
Magnetoelectric materials combine ferroelectric and magnetic properties through a coupling of the spin and lattice degrees of freedom. Here, magnetoelectric bismuth ferrite is found to simultaneously undergo both a magnetic and a ferroelectric transition at the same temperature.
- Kyung-Tae Ko
- , Min Hwa Jung
- & Chan-Ho Yang
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| Open AccessMesoscale flux-closure domain formation in single-crystal BaTiO3
Flux-closure patterns are rarely observed in ferroelectric materials and almost exclusively form at the nanoscale. McQuaidet al. report mesoscopic dipole closure patterns formed in free-standing single-crystal lamellae of BaTiO3, thought to result from an unusual set of experimental conditions.
- R.G.P. McQuaid
- , L.J. McGilly
- & J.M. Gregg
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Tip-enhanced photovoltaic effects in bismuth ferrite
Bismuth ferrite has photoelectric properties that make it an attractive alternative for use in photovoltaic devices. Here, using photoelectric atomic force microscopy, the authors show that photogenerated carriers can be collected by the tip and suggest that this can be used in photoelectric applications.
- Marin Alexe
- & Dietrich Hesse
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Electrically controllable spontaneous magnetism in nanoscale mixed phase multiferroics
Complex oxide interfaces are important for electronic and spintronic applications. In this study, the authors show the emergence of spontaneous magnetism at one such interface between two phases of BiFeO3due to strain effects and piezoelectric coupling.
- Q. He
- , Y. -H. Chu
- & R. Ramesh