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| Open AccessRe-order parameter of interacting thermodynamic magnets
Phase diagrams of materials are typically based on a static order parameter, but it faces challenges when distinguishing subtle phase changes, such as re-ordering. Here the authors introduce a dynamic re-order parameter, in particular magnons, and illustrate it in a material with complex magnetic phases.
- Byung Cheol Park
- , Howon Lee
- & Taewoo Ha
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Article
| Open AccessFerrielectricity controlled widely-tunable magnetoelectric coupling in van der Waals multiferroics
Two-dimensional multiferroics with effective magnetoelectric coupling has not been realized. Here, the authors find a magnetoelectric coupling mechanism in two-dimensional CuCrP2S6 interlocked with heterogeneous ferrielectric state.
- Qifeng Hu
- , Yuqiang Huang
- & Yi Zheng
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Article
| Open AccessSwitching the spin cycloid in BiFeO3 with an electric field
Previous understanding of the coupling between ferroelectric structure and magnetic texture in BiFeO3 has relied on mesoscale measurements. Here, the authors image coupling directly, showing a complex spin cycloid controlled with electric field.
- Peter Meisenheimer
- , Guy Moore
- & Ramamoorthy Ramesh
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Article
| Open AccessEnhanced polarization switching characteristics of HfO2 ultrathin films via acceptor-donor co-doping
Ferroelectric HfO2 is faced with an oxygen vacancy dilemma, which favors the polar phase but harm to switching behaviors. Here, the authors propose a donor-acceptor co-doping method to enhance polarization switching characteristics of the HfO2 films.
- Chao Zhou
- , Liyang Ma
- & Zuhuang Chen
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Article
| Open AccessRealization of sextuple polarization states and interstate switching in antiferroelectric CuInP2S6
Materials with higher-order multistates are desired for non-Boolean high-density storage. Here the authors realized sextuple intrinsic polarization states in vdW CuInP2S6, and reversible transformation among sextuple-, quadruple-, and double-polarization orders.
- Tao Li
- , Yongyi Wu
- & Tai Min
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Article
| Open AccessVoltage-based magnetization switching and reading in magnetoelectric spin-orbit nanodevices
The authors realize voltage-based magnetization switching and reading in nanodevices at room temperature, through exchange coupling between multiferroic BiFeO3 and ferromagnetic CoFe, for writing, and spin-to-charge current conversion between CoFe and Pt, for reading.
- Diogo C. Vaz
- , Chia-Ching Lin
- & Fèlix Casanova
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Article
| Open AccessNon-volatile electrical polarization switching via domain wall release in 3R-MoS2 bilayer
Sliding ferroelectricity occurs in stacks of van der Waals materials. Depending on the particular stacking, the system can host a spontaneous polarization, and under an applied electric field, polarization domain walls will propagate transverse to the electric field. Here, Yang et al use an optical approach to directly observe this sliding of domain walls in bilayer MoS2.
- Dongyang Yang
- , Jing Liang
- & Ziliang Ye
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Article
| Open AccessHigh-throughput computational stacking reveals emergent properties in natural van der Waals bilayers
2D bilayers have recently attracted significant attention due to fundamental properties like interlayer excitons and interfacial ferroelectricity. Here, the authors report a density functional theory approach to identify 2586 stable homobilayer systems and calculate their stacking-dependent electronic, magnetic and vibrational properties.
- Sahar Pakdel
- , Asbjørn Rasmussen
- & Kristian S. Thygesen
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Article
| Open AccessDesigning transparent piezoelectric metasurfaces for adaptive optics
Most multi-degrees-of-freedom systems are composed of several piezoelectric stacks, leading to cumbersome and complicated structures. Here, the authors propose a piezo metasurface to achieve various types of high strains in a wide frequency range.
- Liao Qiao
- , Xiangyu Gao
- & Fei Li
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Article
| Open AccessRobust multiferroic in interfacial modulation synthesized wafer-scale one-unit-cell of chromium sulfide
2D multiferroic materials have garnered broad interests due to their magnetoelectric properties and multifunctional applications. Here, the authors discover a multiferroic feature in interfacial modulation synthesized wafer-scale one-unit-cell Cr2S3.
- Luying Song
- , Ying Zhao
- & Jun He
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Article
| Open AccessAtomic-scale manipulation of polar domain boundaries in monolayer ferroelectric In2Se3
Here, the authors realize controllable manipulation of polar domain boundaries in a two-dimensional ferroelectric material In2Se3. It reveals the origin of distinct behaviors for different domain boundaries in combination with density functional theory calculations.
- Fan Zhang
- , Zhe Wang
- & Chenggang Tao
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Article
| Open AccessLow-k nano-dielectrics facilitate electric-field induced phase transition in high-k ferroelectric polymers for sustainable electrocaloric refrigeration
Low-k nanodiamonds are discovered to possess the ability to concurrently enhance the electrocaloric effect, thermal conductivity, and electrical stability of polymeric nanocomposites, providing support for electrocaloric refrigeration.
- Qiang Li
- , Luqi Wei
- & Xiaoshi Qian
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Article
| Open AccessA ferroelectric fin diode for robust non-volatile memory
Designing efficient high-density crossbar arrays are nowadays highly demanded for many artificial intelligence applications. Here, the authors propose a two-terminal ferroelectric fin diode non-volatile memory in which a ferroelectric capacitor and a fin-like semiconductor channel are combined to share both top and bottom electrodes with high performance and easy fabrication process
- Guangdi Feng
- , Qiuxiang Zhu
- & Chungang Duan
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Article
| Open AccessLow-temperature grapho-epitaxial La-substituted BiFeO3 on metallic perovskite
In the field of multiferroic thin films, attaining low-temperature epitaxy has been a long-standing problem. In this work, authors propose a pathway to significantly reduce the BiFeO3 thin film growth temperature using the BaBiPbO3 template.
- Sajid Husain
- , Isaac Harris
- & Ramamoorthy Ramesh
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Article
| Open AccessSwitchable tribology of ferroelectrics
The interaction of flexoelectric polarization arising from strain gradients with ferroelectricity impacts tribological properties and facilitates fine physical lithography without masks or chemicals, with potential applications in various fields.
- Seongwoo Cho
- , Iaroslav Gaponenko
- & Seungbum Hong
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Article
| Open AccessTunable and parabolic piezoelectricity in hafnia under epitaxial strain
The sign of longitudinal piezoelectric coefficients is typically positive. Here, the authors tune the sign of the linear piezoelectric coefficient of HfO2 from positive to negative via epitaxial strain, finding nonlinear and parabolic piezoelectric behaviors at tensile epitaxial strain.
- Hao Cheng
- , Peijie Jiao
- & Yurong Yang
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Article
| Open AccessMotion and teleportation of polar bubbles in low-dimensional ferroelectrics
Nanoscale ferroelectric domains called electric bubbles are shown to behave as dynamical particles. Using atomistic simulations and experiments, the authors reveal a bubble liquid phase and demonstrate teleportation-like displacements of single bubbles.
- S. Prokhorenko
- , Y. Nahas
- & L. Bellaiche
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Article
| Open AccessElectrically and mechanically driven rotation of polar spirals in a relaxor ferroelectric polymer
Polar spirals induced in a relaxor ferroelectric can be quasi-continuously rotated by applying electric/mechanical fields, due to an asymmetric Coulomb interaction. The rotations are non-volatile with robust retention, and can be optically read out.
- Mengfan Guo
- , Erxiang Xu
- & Yang Shen
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Article
| Open AccessMultiresistance states in ferro- and antiferroelectric trilayer boron nitride
Here, the authors use three-layer boron nitride to construct interfacial ferro- and antiferroelectric tunnel junctions and find that the polarization is flipped in a layer-by-layer way, resulting in multiresistance states.
- Ming Lv
- , Jiulong Wang
- & Jiamin Xue
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Article
| Open AccessFractional quantum ferroelectricity
A concept of fractional quantum ferroelectricity is proposed, where the direction of ferroelectric polarization difference no longer subjects to the symmetry restrictions of Neumann’s principle. It indicates that ferroelectricity can exist in nonpolar systems, which may lead to discovery of many overlooked ferroelectrics.
- Junyi Ji
- , Guoliang Yu
- & H. J. Xiang
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| Open AccessRecord high room temperature resistance switching in ferroelectric-gated Mott transistors unlocked by interfacial charge engineering
Ferroelectric transistors are promising building blocks for developing energy-efficient memory and logic applications. Here, the authors report a record high 300 K resistance on-off ratio achieved in ferroelectric-gated Mott transistors by exploiting a charge transfer layer to tailor the channel carrier density and mitigate the ferroelectric depolarization effect.
- Yifei Hao
- , Xuegang Chen
- & Xia Hong
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Article
| Open AccessUnconventional polarization fatigue in van der Waals layered ferroelectric ionic conductor CuInP2S6
The authors find unconventional fatigue characteristics, involving dramatic morphological changes and anomalous polarization enhancement in van der Waals layered ferroelectric CuInP2S6, due to a synergic effect of ionic conduction and surface oxidation.
- Ziwen Zhou
- , Shun Wang
- & Lu You
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Article
| Open AccessThe anti-symmetric and anisotropic symmetric exchange interactions between electric dipoles in hafnia
Materials exhibiting anti-symmetric exchange interactions between electric dipoles are rare and the existence of the symmetric exchange interactions remains ambiguous. Here, authors identify hafnia as a candidate hosting such interactions by symmetry analysis and first-principles calculations.
- Longju Yu
- , Hong Jian Zhao
- & Yanming Ma
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Article
| Open AccessLarge off-diagonal magnetoelectricity in a triangular Co2+-based collinear antiferromagnet
Magnetoelectric coupling, where magnetic and electronic order is linked, allows for the control of magnetism via an electric field and vice versa, potentially offering new approaches to data storage, sensors, actuators and wealth of other devices. Here, using a diverse array of experimental probes, Xu et al show the emergence of both diagonal and off-diagonal magnetoelectric coupling in CoTe6O13.
- Xianghan Xu
- , Yiqing Hao
- & R. J. Cava
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Article
| Open AccessElectrical detection and modulation of magnetism in a Dy-based ferroelectric single-molecule magnet
The significant magnetoelectric effects in a Dy-based ferroelectric single molecule magnet enable electrical manipulation and detection of resonant quantum tunneling of magnetization.
- Yu-Xia Wang
- , Dan Su
- & Peng Cheng
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| Open AccessHigh-performance van der Waals antiferroelectric CuCrP2S6-based memristors
Layered thio- and seleno-phosphate ferroelectrics show promise for next-generation memory but have thermal stability issues. Using the electric field-driven phase transition in antiferroelectric CuCrP2S6, the authors introduce a robust memristor, emphasizing the potential of van der Waals antiferroelectrics in advanced neuromorphic computing.
- Yinchang Ma
- , Yuan Yan
- & Xixiang Zhang
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Article
| Open AccessQuantum criticality at cryogenic melting of polar bubble lattices
Quantum effects due to zero-point phonon vibrations are well-explored in bulk ferroelectrics, but little is known about them in ultra-thin films. Luo et al. report atomistic simulations of ultra-thin ferroelectrics, showing that, unlike in bulk, quantum fluctuations stabilize topological structures.
- Wei Luo
- , Alireza Akbarzadeh
- & Laurent Bellaiche
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Article
| Open AccessProgrammable catalysis by support polarization: elucidating and breaking scaling relations
Can support polarisation introduce an extra degree of freedom in catalyst scaling relations? This research considers a computational approach for studying catalysts on polar supports and identifies the origin of broken scaling relations.
- Seongjoo Jung
- , Cristina Pizzolitto
- & Turan Birol
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Article
| Open AccessNon-equilibrium dynamics of spin-lattice coupling
Experimental approaches that can directly measure spin-lattice coupling are rare. Here, authors report direct observation of the coupling of the phonon and magnon dynamics of a coherently driven electromagnon in a multiferroic hexaferrite using time-resolved X-ray diffraction. (277 characters in total).
- Hiroki Ueda
- , Roman Mankowsky
- & Urs Staub
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Article
| Open AccessDomain-dependent strain and stacking in two-dimensional van der Waals ferroelectrics
Van der Waals ferroelectrics hold promising potential as electronic materials. Here, the authors have pioneered an electron microscopy technique to unveil both in-plane and out-of-plane structures critical to their switching behavior, providing valuable insights into potential device applications. (298 in total)
- Chuqiao Shi
- , Nannan Mao
- & Yimo Han
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| Open AccessVisualizing moiré ferroelectricity via plasmons and nano-photocurrent in graphene/twisted-WSe2 structures
Recent experiments have shown the formation of ferroelectric domains in twisted van der Waals bilayers. Here, the authors report near-field infrared nano-imaging and nano-photocurrent measurements to investigate ferroelectricity in minimally twisted WSe2 by visualizing the plasmonic and photo-thermoelectric response of an adjacent graphene monolayer.
- Shuai Zhang
- , Yang Liu
- & D. N. Basov
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Article
| Open AccessEfficient magnetic switching in a correlated spin glass
GeTe is a ferroelectric semiconductor with broken inversion symmetry, which leads to a large spin-orbit interaction. When doped with small amounts of manganese, it becomes magnetoelectric. Here, Krempasky et al show that the ferrimagnetic ordering of Mn-doped GeTe can be switched with unusually small currents under specific resonant conditions, orders of magnitude smaller than typical for spin-orbit torque based switching.
- Juraj Krempaský
- , Gunther Springholz
- & J. Hugo Dil
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Article
| Open AccessManipulation of nonlinear optical responses in layered ferroelectric niobium oxide dihalides
This paper reports the intralayer ferroelectric-to-antiferroelectric and ferroelectric-toparaelectric phase transitions in layered NbOCl2 and NbOI2 under a small pressure, respectively, along with the strong manipulations of nonlinear optics.
- Liangting Ye
- , Wenju Zhou
- & Bing Huang
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Article
| Open AccessOrganic radical ferroelectric crystals with martensitic phase transition
Organic martensitic compounds are emerging smart materials with intriguing physical properties. Here authors show that upon H/F substitution a series of 1,4,5,8-naphthalenediimide derivatives exhibit reversible ferroelectric and martensitic transitions with a large thermal hysteresis.
- Nan Zhang
- , Wencong Sun
- & Han-Yue Zhang
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Article
| Open AccessA molecular pyroelectric enabling broadband photo-pyroelectric effect towards self-driven wide spectral photodetection
Broadband spectral photoresponse has potential for optoelectronic devices, but obtaining high photoactivity beyond the material bandgap is challenging. Here, the authors report the development of a molecular pyroelectric material with broadband photopyroelectric effects.
- Xi Zeng
- , Yi Liu
- & Zhihua Sun
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| Open AccessBroad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics
One of the key challenges in dielectric ceramics for energy storage lies in the comprehensive optimization of their properties. Here, the authors establish an equitable system considering performance and structure evolution in a lead-free ceramic capacitor, achieving a broad-high temperature performance.
- Weichen Zhao
- , Diming Xu
- & Di Zhou
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Article
| Open AccessMagnetization reversal through an antiferromagnetic state
Magnetization reversal is a well-studied non-equilibrium process by which a ferromagnet or ferrimagnet reverses its magnetization direction under an applied magnetic field larger than the coercive field. Here, Ghara et al find a new pathway by which this process can occur, showing that in the polar honeycomb magnet (Fe,Zn)2Mo3O8, magnetization reversal involves the emergence of an intermediate antiferromagnetic state.
- Somnath Ghara
- , Evgenii Barts
- & Joachim Deisenhofer
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Article
| Open AccessProton-controlled molecular ionic ferroelectrics
Molecular ferroelectrics contain stimuli-responsive structure and ionic building blocks, promising for ionically tailored multifunctionality. Here, the authors report molecular ionic ferroelectrics exhibiting the coexistence of room-temperature ionic conductivity and ferroelectricity.
- Yulong Huang
- , Jennifer L. Gottfried
- & Shenqiang Ren
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Article
| Open AccessEmergent layer stacking arrangements in c-axis confined MoTe2
The layer stacking order in 2D materials can be used to control functional properties. Here, the authors find a thickness effect, where thin flakes of MoTe2 display stacking arrangements different from bulk crystals.
- James L. Hart
- , Lopa Bhatt
- & Judy J. Cha
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Article
| Open AccessThe emergence of three-dimensional chiral domain walls in polar vortices
The authors investigate how the disorder and the interplay of lateral and axial polarization of the polar vortex topology in SrTiO3/PbTiO3 superlattices can lead to the formation of the chiral and achiral domain walls, and subsequently the triple point topologies.
- Sandhya Susarla
- , Shanglin Hsu
- & Colin Ophus
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Article
| Open AccessAnomalous polarization enhancement in a van der Waals ferroelectric material under pressure
Here, the authors report a hydrostatic-pressure-driven anomalous enhancement of the spontaneous polarization of CuInP2S6 at room temperature, in contrast to the standard pressure-induced suppression of ferroelectricity. The polarization enhancement stems from the spatial instability of the Cu cations and increase of Cu occupancy at the interlayer site.
- Xiaodong Yao
- , Yinxin Bai
- & Jinlong Zhu
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Article
| Open AccessFerroelectric solitons crafted in epitaxial bismuth ferrite superlattices
Topological structures could spark promising functionalities in next generation nanoelectronics. Here, the authors report the realization of complex topological polar textures in epitaxial multiferroic BiFeO3 –SrTiO3 superlattices induced by competing electrical and mechanical boundary conditions.
- Vivasha Govinden
- , Peiran Tong
- & Daniel Sando
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Article
| Open AccessPolar Solomon rings in ferroelectric nanocrystals
Polar Solomon rings in a ferroelectric nanocrystal have been observed and electrically manipulated, which consist of two intertwined vortices and are mathematically equivalent to a \({4}_{1}^{2}\) link in topology based on knots and links theory.
- Jing Wang
- , Deshan Liang
- & Ce-Wen Nan
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Article
| Open AccessEmergent and robust ferromagnetic-insulating state in highly strained ferroelastic LaCoO3 thin films
Transition metal oxides are a promising class of materials to engineer multiferroic properties for next-generation spintronic devices. Here, the authors demonstrate an emergent and robust ferromagnetic-insulating state in ferroelastic LaCoO3 epitaxial films by strain-defect-microstructure manipulated electronic and magnetic states.
- Dong Li
- , Hongguang Wang
- & Weiwei Li
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Article
| Open AccessAll-ferroelectric implementation of reservoir computing
While reservoir computing can process temporal information efficiently, its hardware implementation remains a challenge due to the lack of robust and energy efficient hardware. Here, the authors develop an all-ferroelectric reservoir computing system, showing high accuracies and low power consumptions in various tasks like the time-series prediction.
- Zhiwei Chen
- , Wenjie Li
- & Jun-Ming Liu
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Article
| Open AccessExperimental demonstration of a skyrmion-enhanced strain-mediated physical reservoir computing system
An energy-efficient physical reservoir is crucial for reservoir computing (RC). Here the authors demonstrate an all-electric skyrmion-enhanced strain-mediated physical RC system and achieve a benchmark chaotic time series prediction.
- Yiming Sun
- , Tao Lin
- & Weisheng Zhao
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Article
| Open AccessTuning magnetoelectricity in a mixed-anisotropy antiferromagnet
In magnetoelectric materials, the magnetization can be controlled by the application of an electric field, making it comparatively easy to switch magnetization, which is attractive for data storage and other proposed devices. Unfortunately, the effect in single-phase materials is typically fairly weak. Here Fogh et al. demonstrate a two orders of magnitude enhancement of the magnetoelectric coupling in LiNi0.8Fe0.2PO4 compared to the parent compounds.
- Ellen Fogh
- , Bastian Klemke
- & Rasmus Toft-Petersen
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Article
| Open AccessAbsence of critical thickness for polar skyrmions with breaking the Kittel’s law
Here, the authors find that ferroelectric skyrmions can be sustained in [(PbTiO3)2/(SrTiO3)2]m ultrathin superlattices. The period-thickness relationship of skyrmions in the ultrathin PbTiO3 layers breaks Kittel’s law.
- Feng-Hui Gong
- , Yun-Long Tang
- & Xiu-Liang Ma
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Article
| Open AccessSuperior ferroelectricity and nonlinear optical response in a hybrid germanium iodide hexagonal perovskite
The authors report on a quasi-one-dimensional organic-inorganic hybrid perovskite, DMAGeI3 (DMA = Dimethylamine), with notable ferroelectric attributes at room temperature including large spontaneous polarisation, low coercive field, and strong second harmonic generation response.
- Kun Ding
- , Haoshen Ye
- & Da-Wei Fu