BY analogy with the excitation and ionisation of atoms by light, one might expect that any complex nucleus should be excited or ‘ionised’, that is, disintegrated, by γ-rays of suitable energy. Disintegration would be much easier to detect than excitation. The necessary condition to make disintegration possible is that the energy of the γ-ray must be greater than the binding energy of the emitted particle. The γ-rays of thorium C″ of hv = 2.62 × 106 electron volts are the most energetic which are available in sufficient intensity, and therefore one might expect to produce disintegration with emission of a heavy particle, such as a neutron, proton, etc., only of those nuclei which have a small or negative mass defect; for example, D2, Be9, and the radioactive nuclei which emit a-particles. The emission of a positive or negative electron from a nucleus under the influence of γ-rays would be difficult to detect unless the resulting nucleus were radioactive.