Metalloclusters play important roles in biology, materials and catalysis; however, their synthesis is not straightforward. Now, a strategy is reported where a controlled level of substitution based on incoming ligand steric properties is achieved, creating interesting metallocluster compositions.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Cesari, C., Shon, J.-H., Zacchini, S. & Berben, L. A. Chem. Soc. Rev. 50, 9503–9539 (2021).
Muetterties, E. L. Bull. Soc. Chim. Belg. 84, 959–986 (1975).
Bostelaar, T. M., Brown, A. C., Sridharan, A. & Suess, D. L. M. Nat. Synth. https://doi.org/10.1038/s44160-023-00286-7 (2023).
Huang, J., Schanz, H.-J., Stevens, E. D. & Nolan, S. P. Organometallics 18, 2370–2375 (1999).
Arduengo, A. J. III, Harlow, R. L. & Kline, M. J. Am. Chem. Soc. 113, 361–363 (1991).
Huang, J. & Nolan, S. P. J. Am. Chem. Soc. 121, 9889–9890 (1999).
Weskamp, T., Schattenmann, W. C., Spiegler, M. & Herrmann, W. A. Angew. Chem. Int. Ed. 37, 2490–2493 (1998).
Huang, J., Stevens, E. D., Nolan, S. P. & Petersen, J. L. J. Am. Chem. Soc. 121, 2674–2678 (1999).
Fortman, G. C. & Nolan, S. P. Chem. Soc. Rev. 40, 5151–5169 (2011).
Crudden, C. M. et al. Nat. Chem. 6, 409–414 (2014).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Rights and permissions
About this article
Cite this article
Nolan, S.P. Controlled cluster compositions. Nat. Synth 2, 701–702 (2023). https://doi.org/10.1038/s44160-023-00282-x
Published:
Issue Date:
DOI: https://doi.org/10.1038/s44160-023-00282-x
