Using anion-binding interactions to tackle challenging polymerizations is an ambitious goal and in its infancy. Seleno-cyclodiphosph(v)azanes are demonstrated to exert anion-binding interactions to precisely control the equilibrium between a dormant covalent precursor and active cationic species under mild conditions, thus enabling living cationic polymerization.
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References
Aoshima, S. & Kanaoka, S. A renaissance in living cationic polymerization. Chem. Rev. 109, 5245–5287 (2009). A review article that presents the advances in living cationic polymerization initiators.
Zhang, Z. & Schreiner, P. R. (Thio)urea organocatalysis—What can be learnt from anion recognition? Chem. Soc. Rev. 38, 1187–1198 (2009). A review article that offers an overview of anion-binding catalysis in organic synthesis.
Brak, K. & Jacobsen, E. N. Asymmetric ion-pairing catalysis. Angew. Chem. Int. Ed. 52, 534–561 (2013). A review article that presents an overview of asymmetric ion-pairing catalysis.
Macheño, O. G. (ed.) Anion-Binding Catalysis (Wiley, 2022). A book that introduces the use of anion-binding processes in catalytic chemical activation.
Plajer, A. J. et al. Tailoring the binding properties of phosphazane anion receptors and transporters. J. Am. Chem. Soc. 141, 8807–8815 (2019). This paper reports the first use of seleno-cyclodiphosph(v)azanes as anion receptors and transporters.
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This is a summary of: Li, M. et al. Anion-binding catalysis enables living cationic polymerization. Nat. Synth. https://doi.org/10.1038/ss44160-022-00142-0 (2022).
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Living cationic polymerization driven by anion-binding interactions. Nat. Synth 1, 761–762 (2022). https://doi.org/10.1038/s44160-022-00143-z
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DOI: https://doi.org/10.1038/s44160-022-00143-z
