Abstract
Ultrathin transition metal dichalcogenide (TMD) films show great promise as absorber materials in high-specific-power (i.e., high-power-per-weight) solar cells, due to their high optical absorption, desirable band gaps, and self-passivated surfaces. However, the ultimate performance limits of TMD solar cells remain unknown today. Here, we establish the efficiency limits of multilayer (≥5 nm-thick) MoS2, MoSe2, WS2, and WSe2 solar cells under AM 1.5 G illumination as a function of TMD film thickness and material quality. We use an extended version of the detailed balance method which includes Auger and defect-assisted Shockley-Read-Hall recombination mechanisms in addition to radiative losses, calculated from measured optical absorption spectra. We demonstrate that single-junction solar cells with TMD films as thin as 50 nm could in practice achieve up to 25% power conversion efficiency with the currently available material quality, making them an excellent choice for high-specific-power photovoltaics.
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Introduction
Transition metal dichalcogenides (TMDs) have recently received growing interest in high-specific-power (i.e., high-power-per-weight) photovoltaics where light weight and high power conversion efficiency (PCE) are strongly desired1,2,3,4. TMD materials such as MoS2 and WSe2 have high optical absorption coefficients, desirable band gaps for use in single-junction and tandem solar cells (~1.0–2.5 eV), and self-passivated surfaces free of dangling bonds, enabling high performance even for ultrathin absorber layers on the order of 100 nm2,4,5,6. Recently, ultrathin TMD solar cells reached high specific power of 4.4 W g−1, on par with established thin-film solar technologies cadmium telluride (CdTe), copper indium gallium selenide (CIGS), amorphous silicon and III-Vs, with the potential to achieve 10× higher specific power upon optimization4.
Moreover, adopting ultrathin TMD absorber layers minimizes material utilization, therefore helping with sustainable material use and cost reduction. In addition, the chemical and mechanical stability of TMDs7 promises reliable and long-lasting performance similar to silicon solar panels, while their biocompatibility8 allows usage in wearable and implantable electronics in contact with the human body. At the same time, rapid developments in the nanoelectronics industry related to TMD growth and device fabrication9,10,11,12 pave the way for low-cost mass production of TMD solar cells, similar to how silicon solar cells benefited in their early days from developments made in the microelectronics industry. It is therefore timely to determine the ultimate performance limits of TMD solar cells, illustrating their potential for next-generation solar cell technology which could be realized after sufficient optimization.
In this work, we establish the fundamental performance limits of single-junction solar cells made of multilayer (bulk, ≥5 nm-thick) MoS2, MoSe2, WS2, and WSe2 absorber films with a realistic analysis based on the Tiedje-Yablonovitch model originally developed for silicon solar cells13. This detailed balance model uses material-specific optical absorption data and includes radiative and Auger recombination as well as free carrier absorption, providing material-specific, thickness-dependent performance limits, as opposed to Shockley-Queisser models2,14, which assume that absorptance steps from zero to unity at the band gap energy. We also improve our predictions beyond the Tiedje-Yablonovitch model by incorporating defect-assisted Shockley-Read-Hall (SRH) recombination, providing thickness-dependent efficiency limits for various material quality levels. As a consequence, we find that up to 25% power conversion efficiency is achievable in ultrathin (~50 nm) single-junction TMD solar cells even with existing material quality, corresponding to ~10× higher power per weight than commercialized solar cell technologies4. This already renders TMD photovoltaics an excellent choice for high-specific-power applications such as autonomous drones, electric vehicles, Internet-of-Things devices, and wearable electronics, which are rapidly growing and soon becoming an integral part of our daily life.
Results and discussion
Modeling setup
The extended detailed balance method developed by Tiedje et al. (known as the Tiedje-Yablonovitch model) is used as the basis for this study13. The model was originally developed for silicon solar cells to provide an accurate estimate of their efficiency limits by incorporating the optical absorption characteristics of silicon, radiative and Auger recombination, and free carrier absorption. In this study, we go beyond the Tiedje-Yablonovitch model and investigate the effect of material quality on solar cell performance by including defect-assisted SRH recombination, as detailed in Supplementary Note 1. This comprehensive model provides efficiency limits of single-junction, multilayer (≥5 nm-thick) TMD (MoS2, MoSe2, WS2, and WSe2) solar cells as a function of TMD film thickness and quality.
To mimic optimal light trapping, a rectangular slab of multilayer MoS2, MoSe2, WS2, and WSe2 with a perfect anti-reflection coating on the front surface (zero reflection) and a perfect back-reflector (unity reflection) is considered (Fig. 1). The illumination (AM 1.5 G spectrum with one-sun intensity) includes both direct and diffuse sunlight over a full 2π-steradian acceptance angle, appropriate for a non-tracking flat solar panel. In the Tiedje-Yablonovitch model13, the surfaces are assumed to be textured non-specular (Lambertian), e.g., created by etching, leading to randomized light and angle-independent absorption. For absorber layers that are many wavelengths thick (L >> λ, where λ is the wavelength), as in the case of thick (~100 µm) silicon solar cells in the original Tiedje-Yablonovitch study13, this gives a mean path length of 4n2L (absorption enhancement factor of 4n2) for light rays in the semiconductor13,15, calculated using the conventional ray optics model, where L is the film thickness and n is the semiconductor refractive index.
For nanoscale films with thicknesses comparable to or smaller than the wavelength scale (e.g., the 5 nm–1 µm TMD films studied here), some of the basic assumptions of the conventional theory are no longer applicable13,16. To address this, Yu et al.16 developed a statistical coupled-mode theory that describes light trapping in general from a rigorous electromagnetic perspective, showing that the absorption enhancement factor in nanoscale films can go far beyond the 4n2 bulk limit with proper design. As an example, the authors numerically demonstrated a light-trapping scheme for a 5 nm film leading to an absorption enhancement factor of 12 × 4n2 over a virtually unlimited spectral bandwidth and with near-isotropic angular response. We can therefore conclude that 4n2 is a conservative upper limit for absorption enhancement in the nanoscale films considered here. Nevertheless, given the dependence of absorption enhancement in nanoscale films on the chosen light trapping scheme (e.g., mirrors, periodic structures, scattering or cladding layers, etc.)16, in this study we use 4n2 enhancement factor as a baseline for optimal light trapping, which can be achieved in practice with proper design. Because n is relatively constant across all wavelengths of interest17, we use the n value at the band gap energy. The operating temperature is assumed to be 300 K.
Radiative, Auger, and SRH recombination mechanisms are all considered (Fig. 1), as described in Supplementary Note 1. Measured optical absorption coefficient spectra of bulk TMDs17 (Supplementary Fig. 1) are used to accurately calculate both absorptance and the radiative losses, and to extract the optical band gap of TMD films using the Tauc method18 (Supplementary Fig. 2). SRH lifetime (τSRH) is varied from 1 ns to infinity (the case in the Tiedje-Yablonovitch model) to determine efficiency limits at various material quality levels. Auger coefficients are extrapolated from Auger coefficient–band gap charts in the literature19. Intrinsic or lightly doped TMDs are considered such that hole and electron densities are equal under illumination. At low doping densities, free carrier absorption is negligible in ultrathin absorbers20. We therefore exclude free carrier absorption from our analysis. A summary of modeling parameters is listed in Table 1. The model outputs the performance limits of the solar cell, particularly the power conversion efficiency, as a function of TMD film thickness and material quality.
Another important loss mechanism in solar cells is surface recombination, which could be eliminated by suitable passivation treatments13. TMDs have the unique advantage of dangling-bond-free, self-passivated surfaces thanks to their van der Waals, layered structure. In the absence of defects at the TMD interfaces with other materials (e.g., the contacts), these surfaces can guarantee near-zero surface recombination. In the presence of defects, conventional passivation techniques such as the use of oxides, are shown5,21 to effectively passivate surface defects in TMDs and achieve near-zero surface recombination. We therefore assume zero surface recombination in optimally-designed TMD solar cells reaching the efficiency limits, and exclude surface recombination from our analysis. Nevertheless, the results are valid even in the presence of surface recombination. This is because the SRH lifetime in our model could be considered an effective recombination lifetime representing both bulk SRH and surface recombination. This particularly reflects the SRH lifetime measurements in thin absorber films, where the results are influenced by surface recombination and hence represent the effective lifetime rather than the SRH lifetime22.
We note that excitons play a key role in the optoelectronic characteristics of TMDs, particularly in the monolayer limit. Due to quantum confinement effects and reduced Coulomb screening, monolayer TMDs exhibit23 large exciton binding energies >0.5 eV. These binding energies are one order of magnitude larger than the room-temperature thermal energy, limiting thermal or spontaneous dissociation even at elevated temperatures and exciton densities. It is therefore essential to include the dynamics of exciton dissociation in power conversion efficiency models for monolayer TMDs24,25,26,27,28.
On the other hand, multilayer or bulk TMDs (≥5 nm-thick) which are the focus of our study, show29,30 significantly smaller exciton binding energies around 0.05 eV, comparable to the room-temperature thermal energy, leading to rapid dissociation upon generation31,32. Femtosecond pump–probe spectroscopy measurements on few-layer WS2 show31 efficient exciton dissociation with a characteristic time of 1.3 ps. The presence of a weak-to-moderate electric field, as guaranteed in a well-designed solar cell reaching the efficiency limits, results in even faster exciton dissociation. Pedersen et al. showed32 that in-plane or out-of-plane electric fields as low as 10 mV/nm yield dissociation rates as high as 1013 s−1 in bulk WSe2, WS2, MoSe2, and MoS2. These exciton dissociation rates are 3–4 orders of magnitude faster than exciton recombination rates in multilayer TMDs33,34,35,36. We therefore assume here that photogenerated excitons are instantly dissociated into free electrons and holes before recombination, similar to 3D semiconductor solar cells such as Si and GaAs.
Spectral absorptance
To highlight the unusually high light absorption in thin TMD films, we calculate the spectral absorptance of multilayer MoS2, MoSe2, WS2, and WSe2 films with an absorption enhancement factor of 4n2 (as achieved by the setup shown in Fig. 1) at 5, 10, 20, 50, 100, and 1000 nm film thickness (Fig. 2) using their measured optical absorption coefficient spectra17 (Supplementary Fig. 1). Due to their large absorption coefficients and refractive indices, all these TMDs exhibit significant light absorptance even in ultrathin films of 5 nm thickness (Fig. 2), four orders of magnitude thinner than conventional silicon solar cell absorber layers (~200 μm). As the thickness approaches 1000 nm, the absorptance approaches the simplified step-function assumption in the Shockley-Queisser model14, with exponential Urbach tails37 arising from exciton-phonon and exciton-defect interactions in TMDs38. The absorptance peaks are mainly attributed to the A and B excitons in these materials39 (Supplementary Fig. 1).
The relative absorptance of the four TMDs can be explained by their respective absorption coefficient spectra (Supplementary Fig. 1), particularly in the 1–2.5 eV range, and by their refractive indices (Table 1). Selenides (MoSe2 and WSe2) have larger absorption coefficients than the sulfides (MoS2 and WS2), leading to steeper and higher absorptance in the 1–2.5 eV regime, beyond which near-unity absorptance is reached in all four TMDs, even in ultrathin films of only 5 nm thickness. WSe2 has a larger refractive index, and thus longer optical path length (4n2L) compared to MoSe2, leading to the highest absorptance among the four TMDs. On the other hand, WS2 has the smallest absorption coefficient in the 1–2.5 eV range, with a refractive index comparable to MoS2, therefore making it the least light-absorptive of the four TMDs.
Short-circuit current density
Figure 3 shows the calculated short-circuit current density (JSC) of TMD solar cells as a function of the TMD (absorber) film thickness. As expected from their exceptional light absorption characteristics, all TMDs can achieve high JSC even at small thicknesses. Absorptance and therefore JSC increase with increasing TMD film thickness. Radiative, Auger, and SRH recombination do not affect the JSC limits within the thickness and SRH lifetime ranges modeled here, particularly due to the low carrier density at zero bias in the intrinsic or lightly-doped TMDs assumed (see Supplementary Note 1 for more details). In the simple detailed balance Shockley-Queisser model, semiconductors with smaller band gap exhibit higher JSC, because they absorb a larger portion of the AM 1.5 G spectrum, with photon energies above their band gap. However, as evident in Fig. 3, this is not necessarily true with the extended Tiedje-Yablonovitch method, where absorptance is determined by optical absorption coefficient and refractive index. We observe that JSC follows the same trend as absorptance, with WSe2 and WS2 showing the highest and lowest JSC, respectively, and MoSe2 and MoS2 in between.
We also note a change in slope of the JSC trends in Fig. 3, where JSC increases more strongly at smaller thicknesses, but then rises at a lower rate in thicker films. The initial steeper JSC increase with thickness can be explained by the noticeable absorptance enhancement (Fig. 2) in the ~1.5–2.5 eV regime as the TMD film thickness approaches ~20 nm (MoSe2 and WSe2) to ~50 nm (MoS2 and WS2). Beyond these thicknesses, the absorptance improvement in the ~1.5–2.5 eV region is less prominent. Note that the absorption threshold shifts by approximately 0.2 eV to lower energies as the film thickness increases from 5 nm to 1000 nm (see Fig. 2). This shift is the main driver for the continued, yet gentler JSC increase beyond ~20 nm (~50 nm) in MoSe2 and WSe2 (MoS2 and WS2). The absorption threshold shift is more pronounced in MoSe2 (Fig. 2), enabling it to achieve larger JSC than MoS2 and WSe2 at large thicknesses beyond ~600 nm.
Luminescent emission rates
Examining the radiative losses, Fig. 4 shows the spectral dependence of the luminescent emission rates for 100 nm-thick TMD films in thermal equilibrium at 300 K, as described in Supplementary Note 2. One can observe that reabsorption is almost equally probable as external emission in MoS2. Moreover, the radiative loss is primarily from the low-energy (long-wavelength) photons, which have higher absorption depth and therefore lower probability of being reabsorbed into the TMD film. Similar behavior is observed in MoSe2, WS2, and WSe2, with external emission occurring at lower photon energies (longer wavelengths) and reabsorption taking place at higher photon energies (shorter wavelengths). The magnitude of emission rates varies among the four TMDs due to the difference in their absorption coefficients and refractive indices. As detailed in Supplementary Note 2, at equilibrium, the internal emission rate is proportional to the absorption coefficient and the square of the refractive index. For example, MoSe2 has a noticeably higher absorption coefficient than other TMDs in the 1–1.3 eV range due to its smaller band gap (1.16 eV), leading to the highest internal emission rates. The opposite holds true for WS2, which has the largest band gap (1.36 eV) and smallest absorption coefficient in the entire 1–1.6 eV range (Supplementary Fig. 1). The reabsorption rate is equal to the product of the internal emission rate and the absorptance (Fig. 2). Finally, the external emission rate, in the absence of free carrier absorption, is the difference between the rates of internal emission and reabsorption.
Open-circuit voltage
The calculated open-circuit voltage (VOC) of TMD solar cells as a function of TMD film thickness and material quality (SRH lifetime, τSRH) is shown in Fig. 5, along with the estimate from the Shockley-Queisser model. Infinite SRH lifetime corresponds to the Tiedje-Yablonovitch model where defect-assisted SRH recombination is excluded. The Shockley-Queisser results were generated from the Tiedje-Yablonovitch model by setting a step-function absorptance (from zero to unity at the band gap) and excluding Auger recombination. The results (shown in Supplementary Table 1) perfectly match with previous Shockley-Queisser reports40, confirming the accuracy of our Tiedje-Yablonovitch model and code.
We observe that radiative and Auger losses have comparable contributions (Supplementary Fig. 3), similar to the case of Si in the original Tiedje-Yablonovitch study13, with radiative loss showing a relatively higher contribution due to the higher absorption coefficient in TMDs. Radiative and Auger mechanisms both have recombination lifetimes >10 µs in the multilayer TMDs studied here (Supplementary Fig. 3), which are 2–4 orders of magnitude larger than in direct band gap monolayer TMDs41,42. These results agree well with previous reports of photoluminescence quantum yield (PLQY) in monolayer and multilayer TMDs2,41. PLQY, the ratio of radiative recombination over total recombination43, approaches near unity in monolayer TMDs thanks to their direct band gaps, but is only 10−4 to 10−2 in multilayer TMDs, which have dominant non-radiative recombination due to their indirect band gaps2,41. The measured SRH lifetimes3,44 of ~20–600 ns and PLQY values2 of 10−4 to 10−2 verify the 10–100 µs radiative lifetime values calculated here. In Fig. 5, we demonstrate the noticeable effect of material quality on VOC for τSRH smaller than 10 μs where SRH recombination starts to dominate the VOC loss. Among these four TMDs, we note that WS2 has the largest VOC for any given τSRH, due to its largest band gap among the TMDs investigated here. Incidentally, an SRH lifetime up to ~611 ns has also been reported3 for multilayer WS2, although lifetimes for this and other TMDs are all expected to increase as the material quality improves. Applied to the materials studied here, such an SRH lifetime would lead to a VOC limit between 0.8 to 1.0 V in 100 nm-thick TMD solar cells.
The largest VOC reported to date in single-junction multilayer TMD solar cells under AM 1.5 G illumination is 0.7 V, demonstrated in p–n junction WS2 and locally-gated MoSe2 solar cells5,45, the latter approaching the VOC limit predicted by our model. Given the ~7-nm MoSe2 film thickness in the study45 and the measured SRH lifetimes of ~20–600 ns reported in the literature for bulk TMDs3,44, our model predicts a VOC limit of ~0.7–0.9 V (Fig. 5b). The small discrepancy between the predicted VOC limit and the experimentally demonstrated VOC could be due to various sources including the suboptimal choice of contact metals (Ti/Au for both n- and p-contacts), surface recombination, and incomplete exciton dissociation which is not included in our model. Svatek et al. have demonstrated46 VOC of 1.02 V in a 120 nm-thick p–n junction MoS2 solar cell under broadband illumination with 4 W cm−2 power intensity (equivalent to 40-sun intensity). Given the logarithmic dependence of VOC on light intensity, this corresponds to a VOC of ~0.9 V under 1-sun illumination, which is on par with the VOC limit predicted by our model for a τSRH of 611 ns (Fig. 5a), demonstrating the feasibility of achieving the performance limits predicted in this study by an optimized design.
We note that for thin TMD films, our model estimates a larger VOC limit than the simpler Shockley-Queisser model for τSRH larger than 1 μs. This is due to our inclusion of measured optical absorption spectra. As can be seen in Fig. 2, the absorption threshold depends on the thickness and occurs at higher photon energies in thinner TMD films, yielding an effectively larger band gap than the simple Shockley-Queisser model, a discrepancy that becomes greater for thinner films. This highlights the inadequacy of the step-function absorption assumption in the Shockley-Queisser model, where only one threshold (band gap) energy is used for all film thicknesses. This negative shift in absorption threshold with increasing thickness also explains why VOC decreases as the thickness increases.
Fill factor
We also investigate the effect of TMD film thickness and material quality on the fill factor of the four types of TMD solar cells in Fig. 6. It is well-known that the larger the VOC, the higher the fill factor of the solar cell47. Therefore, WS2, having the largest band gap and VOC, shows the highest fill factor, and MoSe2, which has the smallest band gap and VOC, exhibits the lowest fill factor among the four TMDs. The fill factor dependence on VOC also explains why fill factor decreases with increasing thickness (due to the negative shift in absorption threshold) and decreasing material quality—following the same trend as VOC (Fig. 5). Studies also show that the closer the solar cell (diode) ideality factor to unity, the higher the fill factor47, which explains the higher fill factor in the absence of SRH recombination (τSRH → ∞) compared to the case where τSRH = 100 μs even though the two have essentially the same VOC. Dominant SRH recombination (i.e., τSRH < 10 μs) leads to an ideality factor of 2 at high-level injection48,49, which is the case here since the semiconductor is assumed intrinsic or lightly-doped, whereas dominant Auger recombination gives an ideality factor of 2/348,49, leading to higher fill factor.
Power conversion efficiency
Most importantly, Fig. 7 shows the power conversion efficiency of MoS2, MoSe2, WS2, and WSe2 solar cells as a function of TMD film thickness and material quality (i.e., SRH lifetime, τSRH). The Shockley-Queisser efficiency limits are included for comparison. Given that efficiency is equal to the product of JSC, VOC, and fill factor, the efficiency trends observed in Fig. 7 can be easily explained by JSC, VOC, and fill factor trends in Figs. 3, 5, and 6, respectively. As the TMD film thickness increases, absorptance and therefore JSC improve (Fig. 3), whereas both VOC (Fig. 5) and fill factor (Fig. 6) degrade due to the negative shift in absorption threshold. This competition causes the inverted U-shaped curves in Fig. 7, where efficiency initially increases with thickness and then decreases after a certain point. With the Tiedje-Yablonovitch model (τSRH → ∞), the maximum efficiency occurs for thicknesses over 1000 nm, therefore we only observe an increasing trend within the range of thicknesses considered here. At 100 nm absorber layer thickness, TMD solar cells achieve up to ~31% Tiedje-Yablonovitch efficiency (Supplementary Table 2), which is ~5% higher than the Tiedje-Yablonovitch efficiency limit of silicon solar cells (29.8%) with 1000 times thicker absorber layers (100 µm). This highlights the considerable potential of TMD solar cells for ultrathin photovoltaics with high power per weight.
Going beyond the Tiedje-Yablonovitch model, we introduce non-negligible SRH recombination (i.e., reduced τSRH, corresponding to reduced material quality), observing how the efficiency drops in Fig. 7, as a consequence of VOC and fill factor degradation (Figs. 5 and 6). Moreover, we note that for smaller τSRH the maximum efficiency in Fig. 7 occurs at smaller thicknesses since stronger SRH recombination leads to steeper degradation in VOC and fill factor with increasing film thickness. In other words, although the peak efficiency is reduced, one benefit of “more defective” TMD materials is that their efficiency is maximized in a thinner material, which could potentially have higher specific power and lower cost.
Another way to visualize the effect of material quality (τSRH) on the solar cell performance is to look at current density–voltage (J–V) characteristics for a fixed thickness, for example, 100 nm (Supplementary Fig. 4). As noted previously, within the thickness and τSRH ranges considered here, SRH recombination does not influence JSC due to the low carrier density at zero bias in the intrinsic or lightly-doped TMDs assumed, but it impacts both VOC and fill factor, therefore power conversion efficiency. We also examine the effect of Auger recombination on power conversion efficiency, varying the Auger coefficients of TMDs in the absence of SRH recombination by four orders of magnitude (Supplementary Fig. 5), two orders of magnitude below and above the primary Auger coefficients used in this study, which were extrapolated from Auger coefficient–band gap charts in the literature19. We observe that such a large variation in Auger coefficients leads to a mere 1–2% change in power conversion efficiency, demonstrating the robustness of the efficiency limits modeled in this study despite the uncertainty over the exact Auger coefficient values.
The relative efficiencies of the four TMDs can be explained by their relative JSC, VOC, and fill factors. In the 100 ns–1 µs SRH lifetime regime, WSe2 solar cells demonstrate the highest efficiency, followed by MoS2, WS2, and MoSe2 solar cells. Our WS2 results agree with previous simulation studies on multilayer WS2 solar cells having a particular design structure (i.e., with back-reflector, transparent conductive oxide contacts, and a front glass shield), which achieve ~15% efficiency with a ~500 nm-thick WS2 absorber layer having 10–100 ns charge carrier lifetime26. To date, SRH lifetimes up to 611 ns are reported in the literature for multilayer TMDs3, corresponding to ~20–25% power conversion efficiency for the TMD solar cells examined here with ultrathin films of 20–100 nm thickness (Fig. 7). Such power conversion efficiency can be practically achieved by optimizing the optical and electrical design of the ultrathin TMD solar cells, yielding 57–71 W g−1 specific power in a packaged cell (Supplementary Fig. 6), ~10× higher than established solar cell technologies such as III–Vs, CdTe and CIGS4. Packaged TMD solar cells could be used in low-power, size-constrained applications like Internet of Things (IoT) and wearable electronics. High-power applications, however, such as drones, low-earth-orbit satellites, and electric vehicles require large solar modules consisting of numerous solar cells, which exhibit noticeably higher areal densities due to the inclusion of thick module encapsulation layers as well as interconnects1. 20–25% efficient TMD solar cells can achieve 2.6–3.3 W g−1 specific power in a fully packaged module (Supplementary Fig. 6), which is approximately 5× higher than high-specific-power solar modules currently on the market1. Such lightweight TMD solar cells and modules could create unprecedented opportunities across various industries from aerospace to wearable electronics.
Loss mechanisms at play
Finally, Fig. 8 summarizes the relative magnitudes of various loss mechanisms in optimized 100 nm-thick TMD solar cells at the maximum power point (MPP), as detailed in Supplementary Note 1. τSRH of 100 μs is considered, where SRH recombination has comparable carrier lifetime and therefore magnitude with Auger and radiative losses (Supplementary Table 3). At shorter τSRH, SRH recombination dominates and accounts for nearly all the recombination loss, as can be seen in Figs. 5–7. At a fixed τSRH, the relative magnitudes of SRH recombination in various TMDs depend on their carrier densities (Supplementary Note 1). At their maximum power point, 100 nm-thick MoS2 and WS2 have the highest and lowest carrier densities (Supplementary Table 3), and therefore the largest and smallest current loss due to the SRH recombination.
Internal emission scales exponentially with the output voltage (Supplementary Note 1). As a result, MoSe2 which has the smallest band gap and therefore VMPP (Supplementary Table 3), shows the smallest internal emission despite its relatively higher absorption coefficient. For each TMD, the relative magnitudes of reabsorption and external emission are the same as in Fig. 4. Auger loss is proportional to Auger coefficient and the cube of carrier density at the maximum power point (Supplementary Note 1), therefore smallest for WS2 and WSe2 (see Table 1 and Supplementary Table 3). As discussed previously, free carrier absorption is negligible due to the low doping density and small thickness of the TMDs assumed here20. The relative magnitudes of SRH, Auger and radiative recombination in each TMD can be explained by their relative carrier lifetimes, given the inverse proportionality between the recombination rate and the carrier lifetime (Supplementary Note 1). For example, WS2, with radiative and Auger lifetimes of ~50 µs and ~2 ms, respectively (Supplementary Table 3), exhibits ~2× larger radiative emission than SRH recombination, and negligible Auger loss.
Conclusions
We have examined the efficiency limits of multilayer TMD solar cells (MoS2, MoSe2, WS2, and WSe2) as a function of TMD film thickness and material quality, going beyond the Tiedje-Yablonovitch and Shockley-Queisser models by including experimental optical absorption spectra, as well as radiative, Auger and SRH recombination. We find that ultrathin TMD solar cells (as thin as 50 nm) can realistically achieve up to 25% power conversion efficiency even with today’s material quality. This makes them an excellent choice for high-specific-power photovoltaics (i.e., with high power per weight), achieving up to 10× higher specific power than existing technologies. Such ultralight solar cells could transform energy harvesting across various industries including autonomous drones, electric vehicles, wearable electronics, and the Internet of Things. Future efforts must be dedicated to optimizing the electronic and optical TMD solar cell designs, to unlock their potential for high power conversion efficiency and specific power at large, industrial scale.
Methods
The detailed balance equation governing the current density–voltage characteristics of the solar cell and the method to extract the performance metrics, i.e., short-circuit current density, open-circuit voltage, fill factor, and power conversion efficiency, is explained in detail in Supplementary Note 1. The code developed to solve the detailed balance equation is provided in the Code availability section.
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Code availability
Code to replicate the main findings of this study can be found at https://doi.org/10.5281/zenodo.10291294.
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Acknowledgements
The authors acknowledge partial support from Stanford Precourt Institute for Energy and the member companies of the SystemX Alliance at Stanford.
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K.N. and F.U.N. contributed equally. K.N. conceived the project. K.N. and F.U.N. developed the extended detailed balance model. F.U.N. implemented the model on TMDs, assisted by K.N. All authors, i.e., K.N., F.U.N., A.D., K.C.S, and E.P., contributed to the data interpretation, presentation, and writing of the manuscript. E.P. supervised the work.
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Nassiri Nazif, K., Nitta, F.U., Daus, A. et al. Efficiency limit of transition metal dichalcogenide solar cells. Commun Phys 6, 367 (2023). https://doi.org/10.1038/s42005-023-01447-y
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DOI: https://doi.org/10.1038/s42005-023-01447-y
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