Abstract
Drop rebound after collision with a very hot substrate is usually attributed to the Leidenfrost effect, characterized by intensive film boiling in a thin vapour gap between the liquid and substrate. Similarly, drop impact onto a cold superhydrophobic substrate leads to a complete drop rebound, despite partial wetting of the substrate. Here we study the repellent properties of hot smooth hydrophilic substrates in the nucleate boiling, non-Leidenfrost regime and discover that the thermally induced repellency is associated with vapour percolation on the substrate. The wetting structure in the presence of the percolating vapour rivulets is analogous to the Cassie-Baxter wetting mode, which is a necessary condition for the repellency in the isothermal case. The theoretical predictions for the threshold temperature for vapour percolation agree well with the experimental data for drop rebound and correspond to the minimum heat flux when spray cooling.
Similar content being viewed by others
Introduction
In describing drop interaction with solid surfaces, researchers have reverted (unknowingly) to endowing drops and surfaces with the ability to empathize—drops spread with love on friendly hydrophilic substrates (the word hydrophilic is formed from the ancient Greek words ὕδωρ and φιλία for water and love.). In contrast, drops impacting onto a fearful hydrophobic (from the Greek ὕδρόφοβος, terrified by water) or even superhydrophobic surfaces can often lead to rebound. What then does a drop “feel” when impacting onto an extremely hot substrate? Thermally induced drop rebound is one of the numerous observed impact outcomes1,2,3, which also include deposition, evaporation, breakup and atomization. These phenomena are substantially more complex and have to be described combining the hydrodynamic and thermodynamic aspects of the drop boiling on a hot substrate.
Drop spreading after impact onto a solid dry substrate is governed by the impact Reynolds number (\({{{{{{{\rm{Re}}}}}}}}\equiv \rho {d}_{0}{U}_{0}/\mu\)) and the Weber number (\({{{{{{{\rm{We}}}}}}}}\equiv \rho {d}_{0}{U}_{0}^{2}/\sigma\)), where ρ, μ, and σ are the density, viscosity, and surface tension of the liquid, d0 is the initial drop diameter and U0 is the impact velocity. Drop collision in the absence of thermal effects leads to the generation of a thin radially spreading lamella, bounded by a rim, formed by surface tension and the forces associated with the substrate wetting properties4,5.
Immediately after impact, an expanding viscous boundary layer of thickness \(\sim\! \sqrt{\nu t}\) is formed in the vicinity of the wall, where ν is the kinematic viscosity of the liquid and t the time after impact. At some instant the thickness of the viscous boundary layer is equal to the lamella thickness. At subsequent times the flow in the lamella is quickly damped by the viscosity. The theoretically predicted residual lamella thickness and the characteristic time of spreading governed by viscosity are obtained in the form6
For lower Weber number the effect of surface tension becomes dominant and the rim can start to recede before the cessation of the flow in the lamella. In many cases, for example in the film boiling regime7, in the case of drop impact onto a superhydrophobic substrate8,9,10,11, or binary drop collisions12, the spreading time is scaled very well with the typical time of drop natural oscillations
The viscous spreading regime corresponds to the case tν ≪ tσ, namely when \({{{{{{{\rm{We}}}}}}}}\gg {{{{{{{{\rm{Re}}}}}}}}}^{2/5}\).
In the case of drop impact onto a hot substrate, two thermal boundary layers, in the solid substrate and in the liquid flow, start to expand in the vicinity of the liquid/solid interface13. If the substrate initial temperature Twall is well above the saturation point Tsat, the flow is accompanied by the heterogeneous nucleation of the vapor bubbles14,15. In this regime the wall temperature near the evaporating contact line of each bubble approaches Tsat. The heat flux \(\dot{q}\) in the nucleate boiling regime is then estimated16 from the well-known solution of the conduction problem in the wall
The total evaporation time of the deposited drop can now be estimated using Eq. (3) from the balance of the total heat required for the complete drop evaporation and the heat transferred from the substrate16
in which kw is a dimensionless empirical constant of the order of unity, associated with the surface wettability, ew is the thermal effusivity of the substrate and L* = L + ΔH0 is the sum of the latent heat of evaporation L and the enthalpy difference ΔH0 between the initial drop and saturated liquid.
In this experimental and theoretical study, we demonstrate that the relations of the main time scales (the capillary time, the viscous time and the typical time for drop evaporation) determine the observed outcome of drop impact onto a hot substrate. Moreover, we demonstrate that the drop rebound is not necessarily associated with the film boiling regime and the threshold temperature of the drop rebound is therefore not always equal to the Leidenfrost point.
Results and discussion
Observed phenomena
Typical phenomena of drop impact onto a substrate at various initial temperatures, captured using a high-speed video system, are shown in Fig. 1a–c. The contact residence time tr of an impacting drop is determined either by the instant of drop rebound or by the duration of complete evaporation of a deposited drop and is shown in Fig. 1d as a function of the initial substrate overheat Twall − Tsat. Three main outcomes of drop impact accompanied by boiling include drop deposition with complete evaporation (one example is shown in Fig. 1a), complete or in some cases partial rebound after a certain delay due to a short period of sticking to the substrate (illustrated by the example in Fig. 1b), and non-sticking rebound (Fig. 1c). These results are similar to the recently published observations of drop impact17. The observations of the drop impact outcome cannot always unequivocally indicate a certain microscopic thermodynamic phenomenon at the substrate: nucleate, transitional or film boiling.
As shown in the graph in Fig. 1d, the contact residence time tr of the deposited drop for ΔTwall < 50 ∘C marked by the yellow color, agrees well with the theoretical predictions in Eq. (4) developed for nucleate boiling. In the range of highest wall temperatures (ΔTw > 100 ∘C, pink region in Fig. 1) the residence time is very close to the drop capillary time tσ defined in Eq. (2) due to the non-sticking drop rebound. In this temperature range the drop is still in contact with the substrate as shown in literature17. However, in the intermediate range of the temperatures (50 ∘C < ΔTw < 100 ∘C) the residence time tr deviates significantly from both tϵdrop and tσ. The delay of the drop rebound in this regime is caused by the bonding of the drop at residual wetted spots of the target, as in the 10 ms frame in Fig. 1b.
In Fig. 2 the results of the measurements of tr on the steel target are also shown in comparison with the theoretically predicted times tϵdrop and tσ. While in Fig. 2a the residence time for a certain set of impact parameters are shown, in Fig. 2b the value of tr is shown averaged over a substrate temperature class. For the steel target the regime of the good agreement of the residual time with tϵdrop is observed in the range ΔTwall < 100 ∘C, which is significantly wider than the range observed for aluminum targets (see Fig. 1). Therefore, the residence time is significantly influenced by the thermal properties of the substrate, its initial temperature as well as by the impact parameters.
Let us denote T* as the lowest wall temperature at which the drop does not stick to the substrate. This point corresponds to the local minimum in the total heat, \(Q=\int\nolimits_{0}^{{t}_{{{{{{{{\rm{r}}}}}}}}}}A(t)\dot{q}(t){{{{{{{\rm{d}}}}}}}}t\) transferred from the substrate during drop impact, since the heat increases with the residence time and with the wall temperature. Here A(t) is the wetted area of the substrate. We can thus expect that the heat flux during spray cooling at the threshold point T* will also be minimal.
In Fig. 3a, the evolution of the heat flux \(\dot{q}\) and the interface temperature Ti of a thick stainless steel target continuously cooled by spray impact are shown. The target is initially heated uniformly up to Tw ≈ 450∘C. The high-speed observations of spray impact, shown in the inserts in Fig. 3a, demonstrate that the threshold temperature T* associated with the minimum of the heat flux curve indeed determines the deposition/rebound limit for the impacting drops.
The value of the threshold temperature T* depends neither on the drop diameter in the spray nor on the impact velocity, but on the target material, as is demonstrated in Fig. 3b, c. Moreover, no dependence of the temperature T* on the mass flux of the impacting spray or other impact properties has been identified.
Drop boiling on a hot substrate
In Fig. 4 details are shown of the development of the vapor phase in the advanced nucleate boiling regime, which allow us to better understand the mechanisms of a single drop rebound. Figure 4a clearly shows the vapor bubbles on the aluminum substrate at Twall = 170 ∘C and in b the formation of elongated vapor rivulets at higher temperatures, Twall = 200 ∘C, at which drops rebound without delay. The impact parameters in Fig. 4a, b are the same as in Fig. 1. Figure 4c is the map of the heat flux distribution at the surface of a transparent sapphire target at Twall = 378 ∘C during drop spreading (see Table 1). The wall temperature is well above the threshold temperature T*. The red spots, corresponding to high local heat flux, indicate wetting of the substrate. The green or blue regions of low heat flux indicate the percolated vapor rivulets, similar to those observed in Fig. 4b. The same phenomena of vapor rivulets and cluster have been observed during drop impacts of ethanol drops onto sapphire substrate with TIR measurements in the same drop impact regime17.
The randomly distributed disks on a plane in Fig. 4d is an exemplary illustration of the irregular nucleation of bubbles on a solid surface. The spatial distribution of disks is characterized by the cumulative relative area λ of the disks, scaled by the total area of the domain. Some of the discs intersect and thus form clusters of discs. The distribution of the cluster sizes is studied in the framework of the percolation theory. The percolation threshold in this two-dimensional problem18 is λc = 1.128. At this point an infinite cluster of the intersecting disks first appears, as shown in Fig. 4d. The formation of the wrapping cluster of the disks at the percolation threshold can explain the percolation of the vapor bubbles and formation of the vapor rivulets. At the percolation threshold the liquid area of drop/substrate contacts are isolated spots. This situation is analogous to the Cassie-Baxter wetting of heterogeneous substrates, associated with the superhydrophobicity and superrepellency19 in conventional, isothermal cases.
The computed value λc = 1.128 is only a very rough approximation for the percolation threshold for the vapor bubbles, since the model does not consider bubble coalescence or shear driven motion of the bubbles in the liquid flow.
The relative wetted surface area (not belonging to the surface covered by the bubbles) is, ϵ, derived using the Poisson distribution for the expected number of bubbles covering a given point of the surface20, assuming a random spatial distribution of bubble centers. At the percolation threshold it yields
Heat transfer in the wall during nucleate boiling of a drop
The flow in the drop for values of relative volume of the liquid phase ϵ < ϵc is completely different since the liquid contacts the substrate only at isolated wetted spots, which cannot prevent drop rebound, as in Fig. 1c. Let us roughly estimate the wall temperature corresponding to the emergence of the percolating vapor channels during the spreading time tσ.
Consider the liquid lamella of the thickness \({h}_{{{{{{{{\rm{res}}}}}}}}}\) defined in Eq. (1). It can be estimated from the one-dimensional energy balance accounting for the creation of the vapor phase, expressed as
where ϵ is the relative volume of the liquid phase in the lamella. The heat flux \(\dot{q}\) at the wall surface, determined in Eq. (3), is governed by the heat conduction in the thermal boundary layer in the wall. This expression allows to predict very well the heat flux during spray cooling in the nucleate boiling regime in a wide range of spray parameters and wall temperatures21. Therefore, the presence of bubbles does not influence the value of \(\dot{q}\) significantly. In a steady heat conduction in the wall, the presence of bubbles leads to local disturbances of the temperature field, but the total heat flux at the interface remains the same due to the energy balance. The heat flux can only be changed if transient effects, associated with bubble growth are significant22. The size of the wall region, disturbed by the presence of a bubble is comparable with the bubble radius. Therefore, the contribution of the bubbles presence at the substrate surface is small if the bubble size is much smaller than the thickness of the thermal boundary layer in the wall. This condition is satisfied in our experiments.
The solution of the ordinary differential equation in Eq. (6) is
With the help of Eqs. (2), (3), and (5) the condition ϵ = ϵc at the instant t = tσ yields the following expression for the threshold overheat ΔT in the surface tension driven spreading regime
where b = 0.48 and ΔTσ is a typical scale for the threshold overheat in the surface tension dominated drop impact regime.
It should be noted that the coefficient b can be influenced by the reduction of the wetted area of the drop due to the appearance of dry spots, due to the liquid flow in the lamella, drop atomization and other factors. Therefore, the solution Eq. (8) is not exact. However, in this study it is important that the factor b in Eq. (8) has to be comparable with unity if the major physical factors are taken into account correctly.
For very high Weber numbers the duration of drop spreading is scaled by the viscous time scale tν, defined in Eq. (1). The percolation condition ϵ = ϵc at the instant t = tν yields another expression for the threshold wall overheat ΔTν in the viscous spreading regime
In our estimation of heat transfer Eq. (6) the relative wetted surface area ϵ is approximated by the liquid volume fraction and the residual thickness \({h}_{{{{{{{{\rm{res}}}}}}}}}\) is assumed to be constant. This assumption cannot be very precise if the height of the vapor bubbles/channels changes in time, for example due to the evaporation of the drop lamella. Our analysis is therefore valid for the cases when the tσ ≪ tϵdrop. This condition is satisfied for drop impacts at the threshold temperature, as shown in Fig. 1. The recent direct observations of the relative liquid contact area17 can potentially help to determine the relation to the volume fraction. These data could be a topic of interesting future investigations.
The expression for ΔTν does not depend on the drop diameter or impact velocity. This is not surprising, since the time tν and the lamella thickness \({h}_{{{{{{{{\rm{res}}}}}}}}}\) correspond to the one-dimensional growth of the viscous boundary layer in the lamella.
In Fig. 5, the theoretically predicted scales for the threshold temperature ΔTσ and ΔTν are compared with the experimental data. The data for low-speed impacts with \({{{{{{{\rm{We}}}}}}}} \, < \, 2.5\ {{{{{{{{\rm{Re}}}}}}}}}^{2/5}\), governed by surface tension, are shown in Fig. 5a as a function of ΔTσ. The factor 2.5 is empirical, determined from numerous experiments. The agreement is good, considering that the target materials and the impact velocities have been widely varied in the experiments.
The slope for spray impact is, however, larger than for a single drop, since the thermodynamic processes in the spreading drop are influenced significantly by the flow, although the expressions for the viscous length scale and for the time scale of capillary oscillations remain the same. In the case of spray cooling, shown in Fig. 5b, the values for ΔT* are determined from the condition of the minimum of the heat flux. Note also that in the spray case the surface temperature is not uniform and is not continuous since it is influenced by single drop impacts. Each drop impact leads to a significant local cooling of a substrate. The subsequent drop with some probability, depending on the spray flux, could impact onto this relatively cold spot and thus initiate a wetted boiling region. This phenomenon has been recently identified using the high-speed video observations of spray impact onto very hot substrates21. The nucleate boiling in these wetted regions contribute significantly to the heat flux. The only average in time and space surface temperature has been determined in the spray cooling experiments, shown in Fig. 5b.
Moreover, the threshold temperature during spray cooling can also be influenced by the thermal atomization phenomenon associated with the drop levitation when the thermal boundary layer reaches the free surface of the drop spreading lamella23. It can be shown with the help of Eq. (1) that the residence time tθ of the thermal atomization regime is
where Pr is the Prandtl number characterizing the drop liquid. Some influence of the Prandtl number on the slope of the linear the dependence of ΔT* on ΔTν can thus be expected in the cases when the effect of thermal atomization is significant. Such an effect can only be identified in experiments of spray cooling with different liquids.
Several hypotheses have been put forward in the literature to explain the mechanism of film boiling. Some theoretical models have been developed based on the hydrodynamic stability analysis of the vapor/liquid interface24,25 or thermocapillary stability26. Other authors assume that the Leidenfrost temperature is determined by the foam limit27,28 or by the limiting minimum vapor thickness29 comparable with the surface roughness. In this study, we have demonstrated that the transition to the film boiling regime is initiated at the threshold point for vapor percolation. Further drop evaporation is governed by the presence of the vapor rivulets and is characterized by the disappearance of the isolated wetted spots. The film boiling regime corresponds to a complete vanishing of the wetted spots.
Methods
Two main experimental setups are used to observe single drop impact and to characterize spray cooling of hot substrates. They are shown schematically in Fig. 6.
Observations of single-drop impact onto a hot substrate
Two configurations of the experimental setup for a single drop impact are used in this study. One is to study the outcome of drop impact onto metal targets (Fig. 6a) and the other is for the high-speed thermographic visualization of the substrate interface exposed to the collision of a drop (Fig. 6b).
In both setups single drops of double-distilled water with a diameter of d0 = 2.3 mm are generated by a drop generator (as shown in Fig. 6a). A Bartels micro pump mp6 feeds an hydrophobic G27 blunt needle. The drop is released when the gravitational force exceeds the force due to the surface tension of the liquid. This principle leads to very constant drop diameters. The needle of the drop generator is cooled to maintain the liquid temperature constant at 20 °C. By changing the height of the needle above the substrate, the impact velocity can be changed in the range of U0 = 0.4 to 2 m s−1. Various target materials are used to identify the influence of the material properties on the drop impact outcome: aluminum (EN AW 7075), copper (CW004A) or stainless steel (1.4841). The surface of all impact targets are mirror polished (surface roughness Sa = 0.0108 µm). The replaceable impact substrates are heated by a custom heating device with a total heating power of 400 W. The surface temperature is measured with a type J thermocouple (class 1) 1 mm below the surface. The drop impact is observed using a high-speed video system, consisting of a CMOS camera (Phantom V12.1) with a telecentric lens (Opto engineering TC16M036) and background illumination (Opto engineering LTCLHP036-G).
The setup for the visualization of the micro-scale thermodynamic effects at the drop-substrate interface and for the measurements of the temperature distribution is shown in Fig. 6b. A 3 mm thick, infrared (IR) transparent sapphire target which is coated on top with a 600 nm thick highly infrared emissive CrN PVD layer is used as an impact target. The IR radiation of the coating is captured through the transparent substrate with a mid-wave infrared camera (FLIR x6901sc) during the drop impact experiments.
An in-situ calibration is performed to convert the captured IR radiation into the surface temperature. During the calibration a copper block is placed at the coated surface and both, the copper block as well as the heating structure are heated to the same temperature to provide a homogeneous temperature at the impact surface. A type J thermocouple (class 1) is placed 0.5 mm above the copper/sapphire interface inside the copper block. For the calibration it is assumed that the surface temperature of the sapphire window is the same as measured in the copper block. The calibration is repeated for the surface temperatures from 80 °C up to 380 °C in steps of 10 °C for each camera setting. The recorded radiance show a perfect agreement with the Stefan–Boltzmann law.
The heat flux at the substrate interface is then obtained by a numerical solution of the heat conduction problem in the sapphire substrate, satisfying the boundary conditions for the evolution of the temperature distribution obtained from the thermographic measurements.
Spray cooling setup
The experimental setup, as shown in Fig. 6c, consists of a heated target, a spraying system, a high-speed visual observation system and a spray characterization system. The target is heated in the beginning of the experiments with a custom cartridge heater to a surface temperature of 450 °C. After the temperature field inside the target was in steady state, the heater was switched off and a spray was applied to the target surface, until the surface temperature was cooled down to 100 °C. The temperature distribution in the target is measured by a set of 15 thermocouples type K, (class 1), thickness 0.5 mm, placed in two rows at 0.5 mm and 20 mm below the surface. These temperatures are used for computation of the local heat flux and instantaneous surface temperature by solution of the inverse heat conduction problem30. A Phantom v2012 high-speed camera equipped with a long distance microscope (Questar QM-100) allows observation of the hydrodynamic phenomena at the target surface during spray impact. The results of an exemplary experiment is shown in Fig. 3.
Different standard pressure driven full-cone nozzles have been used to vary and identify the effect of the main spray parameters on the cooling rate. The average drop diameter, average velocity and the mass flux density of the spray have been varied in the experiments and accurately characterized using a Dantec phase Doppler system and a custom built patternator, as schematically shown in Fig. 6d. The phase Doppler measurements were performed without the target, but at positions corresponding to specific locations immediately above the target; hence the spray parameters were local values.
To determine the effect of the wall thermal properties on the threshold temperature T*, two targets of different materials, stainless steel (1.4841) and nickel (2.4068) have been used. The surface roughness is in the same order of magnitude as in the single drop experiments with a polished surface (surface roughness Sa = 0.0092 µm).
The substrate materials and their thermal properties
The experimental data from the literature, the substrate materials and their thermal properties are summarized in Table 1. The thermal properties of the designated substrate materials are taken from general literature and handbooks. Since these properties are temperature dependent, they have been calculated at the corresponding threshold temperature. In all cited studies the surfaces are polished.
For the threshold temperature T* during spray cooling the point corresponding to the minimum heat flux is taken.
Data availability
The data sets for the residence time of the single drop, threshold temperature for low-speed drop impact and spray cooling, presented in this manuscript, are available online in TUdatalib (https://doi.org/10.48328/tudatalib-530)31.
References
Bertola, V. An impact regime map for water drops impacting on heated surfaces. Int. J. Heat Mass Transf. 85, 430–437 (2015).
Liang, G. & Mudawar, I. Review of spray cooling – Part 2: H- igh temperature boiling regimes and quenching applications. Int. J. Heat Mass Transf. 115, 1206–1222 (2017).
Breitenbach, J., Roisman, I. V. & Tropea, C. From drop impact physics to spray cooling models: a critical review. Exp. Fluids 59, 55 (2018).
Roisman, I. V., Rioboo, R. & Tropea, C. Normal impact of a liquid drop on a dry surface: model for spreading and receding. Proc. R. Soc. London Ser. A-Math. Phys. Eng. Sci. 458, 1411–1430 (2002).
Yarin, A. L., Roisman, I. V. & Tropea, C. Collision Phenomena in Liquids and Solids (Cambridge University Press, 2017).
Roisman, I. V. Inertia dominated drop collisions. II. An analytical solution of the Navier–Stokes equations for a spreading viscous film. Phys. Fluids 21, 052104 (2009).
Senoner, J.-M., Castanet, G., Caballina, O. & Villedieu, P. Modeling of water drop impactions in the Leidenfrost regime. Atom. Sprays 26, 853–888 (2016).
Renardy, Y. et al. Pyramidal and toroidal water drops after impact on a solid surface. J. Fluid Mech. 484, 69–83 (2003).
Bird, J. C., Dhiman, R., Kwon, H.-M. & Varanasi, K. K. Reducing the contact time of a bouncing drop. Nature 503, 385–388 (2013).
Liu, Y. et al. Pancake bouncing on superhydrophobic surfaces. Nat. Phys. 10, 515–519 (2014).
Richard, D., Clanet, C. & Quéré, D. Contact time of a bouncing drop. Nature 417, 811–811 (2002).
Willis, K. & Orme, M. Binary droplet collisions in a vacuum environment: an experimental investigation of the role of viscosity. Exp. Fluids 34, 28–41 (2003).
Roisman, I. V. Fast forced liquid film spreading on a substrate: flow, heat transfer and phase transition. J. Fluid Mech. 656, 189–204 (2010).
Itaru, M. & Kunihide, M. Heat transfer characteristics of evaporation of a liquid droplet on heated surfaces. Int. J. Heat Mass Transf. 21, 605–613 (1978).
Abu-Zaid, M. An experimental study of the evaporation characteristics of emulsified liquid droplets. Heat Mass Transf. 40, 737–741 (2004).
Breitenbach, J., Roisman, I. V. & Tropea, C. Drop collision with a hot, dry solid substrate: heat transfer during nucleate boiling. Phys. Rev. Fluids 2, 074301 (2017).
Lee, S.-H. et al. Drop impact on hot plates: contact times, lift-off and the lamella rupture. Soft Matter 16, 7935–7949 (2020).
Mertens, S. & Moore, C. Continuum percolation thresholds in two dimensions. Phys. Rev. E 86, 061109 (2012).
Quéré, D. Non-sticking drops. Rep. Prog. Phys. 68, 2495–2532 (2005).
Feller, W. An Introduction to Probability Theory and its Applications, Vol 2 (John Wiley & Sons, 2008).
Tenzer, F. M., Roisman, I. V. & Tropea, C. Fast transient spray cooling of a hot thick target. J. Fluid Mech. 881, 84–103 (2019).
Staszel, C. & Yarin, A. L. Exponential vaporization fronts and critical heat flux in pool boiling. Int. Commun. Heat Mass Transf. 98, 171–176 (2018).
Roisman, I. V., Breitenbach, J. & Tropea, C. Thermal atomisation of a liquid drop after impact onto a hot substrate. J. Fluid Mech. 842, 87 (2018).
Zuber, N. On the stability of boiling heat transfer. Trans. Am. Soc. Mech. Engrs. 80, 711–720 (1958).
Kakac, S. & Bon, B. A review of two-phase flow dynamic instabilities in tube boiling systems. Int. J. Heat Mass Transf. 51, 399–433 (2008).
Aursand, E., Davis, S. H. & Ytrehus, T. Thermocapillary instability as a mechanism for film boiling collapse. J. Fluid Mech. 852, 283–312 (2018).
Spiegler, P., Hopenfeld, J., Silberberg, M., Bumpus, C. F. & Norman, A. Onset of stable film boiling and the foam limit. Int. J. Heat Mass Transf. 6, 987–989 (1963).
Wang, Z., Qu, W., Xiong, J., Zhong, M. & Yang, Y. Investigation on effect of surface properties on droplet impact cooling of cladding surfaces. Nucl. Eng. Technol. 52, 508–519 (2020).
Cai, C., Mudawar, I., Liu, H. & Si, C. Theoretical Leidenfrost point (LFP) model for sessile droplet. Int. J. Heat Mass Transf. 146, 118802 (2020).
Woodfield, P. L., Monde, M. & Mitsutake, Y. Improved analytical solution for inverse heat conduction problems on thermally thick and semi-infinite solids. Int. J. Heat Mass Transf. 49, 2864–2876 (2006).
Schmidt, J. B. et al. Dataset: Thermosuperrepellency of a hot substrate caused by vapour percolation, https://doi.org/10.48328/tudatalib-530 (2020).
Hoogendoorn, C. J. & Den Hond, R. Leidenfrost temperature and heat-transfer coefficients for water sprays impinging on a hot surface. In IFTH International Heat Transfer Conference, Vol. 4, 135–138 (Begel House Inc., 1974).
Shoji, M., Wakunaga, T. & Kodama, K. Heat transfer from a heated surface to impinging subcooled droplets : heat transfer characteristics in non-wetting region. Heat Tran. Jpn. Res. 50, 716–723 (1984).
Ito, T., Takata, Y., Mousa, M. M. M. & Yoshikai, H. Studies on the water cooling of hot surfaces (experiment of spray cooling). Memoirs Faculty Eng. Kyushu Univ. 51, 119–144 (1991).
Yao, S. C. & Choit, K. J. Heat transfer experiments of mono-dispersed vertically impacting sprays. Int. J. Multiphase Flow 13, 639–648 (1987).
Choi, K. J. & Yao, S. C. Mechanisms of film boiling heat transfer of normally impacting spray. Int. J. Heat Mass Transf. 30, 311–318 (1987).
Yao, S. C. & Cox, T. L. A general heat transfer correlation for impacting water sprays on high-temperature surfaces. Exp. Heat Transfer 15, 207–219 (2002).
Bernardin, J. D., Stebbins, C. J. & Mudawar, I. Mapping of impact and heat transfer regimes of water drops impinging on a polished surface. Int. J. Heat Mass Transf. 40, 247–267 (1997).
Tran, T., Staat, H. J. J., Prosperetti, A., Sun, C. & Lohse, D. Drop impact on superheated surfaces. Phys. Rev. Lett. 108, 036101 (2012).
Acknowledgements
The authors gratefully acknowledge the Deutsche Forschungsgemeinschaft for its financial support in the framework of the project SFB-TRR 75, project number 84292822, and the Industrieverband Massivumformung e.V.
Funding
Open Access funding enabled and organized by Projekt DEAL.
Author information
Authors and Affiliations
Contributions
C.T. and I.V.R. conceived the project. J.B.S. and J.B. performed the single drop experiments. J.H. and F.M.T. performed the spray cooling experiments. C.T. was responsible for the scientific coordination of the project. I.V.R. developed theoretical description of the problem. All authors performed the data analysis and participated in writing the manuscript.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Peer review information Communications Physics thanks the anonymous reviewers for their contribution to the peer review of this work.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Schmidt, J.B., Hofmann, J., Tenzer, F.M. et al. Thermosuperrepellency of a hot substrate caused by vapour percolation. Commun Phys 4, 181 (2021). https://doi.org/10.1038/s42005-021-00680-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s42005-021-00680-7
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.