A deeper understanding of reaction mechanisms should lead to improvements in the selectivity of organic electrosynthesis methods. This approach has now been used to explain the role of magnesium diacetate in the Ag-electrocatalysed reductive coupling of sp3 organic chlorides with aldehydes or ketones with increased selectivity for the desired alcohol product.
This is a preview of subscription content, access via your institution
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Faraday, M. Pogg. Ann. 33, 433–451 (1834).
Kolbe, H. Justus Liebigs Ann. Chem. 69, 257–294 (1849).
Yoshida, J. I., Kataoka, K., Horcajada, R. & Nagaki, A. Chem. Rev. 108, 2265–2299 (2008).
Waldvogel, S. R. & Janza, B. Angew. Chem. Int. Edn 53, 7122–7123 (2014).
Novaes, L. F. T. et al. Chem. Soc. Rev. 50, 7941–8002 (2021).
Vijh, A. K. & Conway, B. E. Chem. Rev. 67, 623–664 (1967).
Chen, Q.-C., Kress, S., Molinelli, R. & Wuttig, A. Nat. Catal. https://doi.org/10.1038/s41929-023-01073-5 (2024).
Isse, A. A., Gottardello, S., Durante, C. & Gennaro, A. Phys. Chem. Chem. Phys. 10, 2409–2416 (2008).
Chaussard, J. et al. Synthesis 1990, 369–381 (1990).
Klein, M. & Waldvogel, S. R. Angew. Chem. Int. Edn 61, e202204140 (2022).
Osawa, M. Bull. Chem. Soc. Jpn 70, 2861–2880 (1997).
Osawa, M., Ataka, K.-I., Yoshii, K. & Nishikawa, Y. Appl. Spectrosc. 47, 1497–1502 (1993).
Cuesta, A. in Vibrational Spectroscopy at Electrified Interfaces (eds Wieckowski, A. et al.) Ch. 8, 266–306 (John Wiley & Sons, 2013).
Bewick, A., Mellor, J. M. & Pons, B. S. Electrochim. Acta 25, 931–941 (1980).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Rights and permissions
About this article
Cite this article
Cuesta, A. Understanding organic electrosynthesis. Nat Catal 7, 115–116 (2024). https://doi.org/10.1038/s41929-023-01101-4
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41929-023-01101-4