Abstract
Beyond its economic value, copper (Cu) serves as a valuable tracer of deep magmatic processes due to its close relationship with magmatic sulfide evolution and sensitivity to oxygen fugacity (fO2). However, determining Cu’s oxidation state (+ 1 or + 2) in silicate melts, crucial for interpreting its behavior and reconstructing fO2 in the Earth’s interior, has long been a challenge. This study utilizes X-ray Absorption Near Edge Structure spectroscopy to investigate the Cu oxidation state in hydrous mafic silicate melts equilibrated under diverse fO2 (− 1.8 to 3.1 log units relative to the Fayalite–Magnetite–Quartz buffer), temperature (1150–1300 °C), and pressure (1.0–2.5 GPa) conditions. Our results reveal that Cu predominantly exists as Cu+ across all fO2 conditions, with a minor Cu2+ component. This dominance of Cu+ persists even in relatively oxidized melts, highlighting its limited sensitivity to fO2 under upper mantle conditions. This significantly constrains the utility of Cu as an oxybarometer in hydrous silicate melts in the deep Earth. However, our findings suggest that Cu isotopes primarily reflect the interplay of sulfide segregation/accumulation during magmatic differentiation, shedding light on these fundamental processes in Earth’s interior.
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Introduction
Copper, beyond its critical role as a mineral resource, serves as a sensitive tracer for unraveling deep magmatic processes1,2,3,4,5,6,7,8. Its geochemical behavior is inextricably linked to the fate of magmatic sulfide, as Cu exhibits pronounced incompatibility within silicate minerals7,9,10. This intimate relationship makes Cu a valuable proxy for tracking sulfide evolution, which is highly sensitive to changes in oxygen fugacity (fO2) within the magma reservoir. Furthermore, Cu isotopes can undergo significant fractionation during magmatic differentiation involving sulfides, further amplifying its potential as a geochemical recorder1,4. Consequently, the combined analysis of Cu content and isotope variations in igneous rocks offers invaluable insights into magma evolution and the fO2 conditions in the deep Earth.
The multivalent nature of Cu allows it to exist as Cu+ and Cu2+ in silicate melts and fluids7,11,12,13. Its valence state profoundly impacts its diffusion, partitioning behavior, and Cu isotope fractionation during magmatic evolution1,4,10,14,15. Cu+ exhibits significantly higher diffusivity than Cu2+, likely due to its smaller ionic radius and weaker interaction with the melt structure15,16. This order-of-magnitude difference in mobility compared to sulfur and chlorine suggests that the Cu+/Cu2+ ratio could influence Cu’s partitioning behavior, particularly during disequilibrium magmatic and hydrothermal processes. Previous studies indicate the average Cu valence state in silicate melts under upper mantle conditions ranges from + 1 to + 2, increasing with elevated fO27. Wood and Kiseeva17 further suggest that the Cu+/Cu2+ ratio, alongside FeO content, significantly affects Cu partitioning between sulfide and silicate melts. Given the dominance of Cu+ in magmatic sulfides, the equilibrium Cu isotope fractionation factor between sulfide and silicate melts can be substantial, reaching values up to ~ 2‰ (e.g., Liu et al.1). Similarly, the oxidation state of Cu in aqueous fluids is predominantly Cu+ at high temperatures11,18, potentially explaining Cu isotope fractionation between fluids and silicate melts19. This dependence on fO2 raises the intriguing possibility of using the Cu+/Cu2+ ratio in silicate melts as a novel oxybarometer (a tool for inferring fO2).
Previously, determining the valence state of Cu in silicate melts relied on analyzing the slope of its solubility data plotted against fO2. This approach relied on the relationship: Cumetal + n/2 O2 = CuOnmelt, where logCu solubility (ppm) = n/2 log fO2 + C. A slope of 0.5 indicated Cu2+ dominance (n = 1), while 0.25 suggested Cu+ (n = 0.5). However, this method faced limitations. Melt composition and temperature significantly influenced the slope, introducing ambiguities and inaccuracies in valence state determination. XANES (X-ray Absorption Near Edge Structure) emerges as a powerful tool that overcomes these limitations. By analyzing the Cu K-edge spectrum, it provides direct and quantitative measurements of Cu’s oxidation state, surpassing the indirect and often ambiguous inferences drawn from the slope method. This precision allows researchers to not only confirm the dominant valence state but also identify subtle variations and even the coexistence of multiple oxidation states within a single melt, shedding light on a previously hidden dimension of Cu behavior in silicate melts. The application of XANES for determining Cu oxidation state in silicate melts is a recent development, exemplified by the work of Miller et al.20. Their research demonstrated that Cu predominantly exists as Cu+ in silicate melts under terrestrial conditions, focusing on anhydrous melts (mostly Fe-free) at ambient pressure and pressures up to 2.5 GPa, as well as the examination of hydrous haplogranitic melts under 1.0 GPa.
Hydrous basalts, which form in the mantle wedge at subduction zones, are critical for studying magmatic processes and tracing fO2 using Cu. However, the oxidation state of Cu in these silicate melts, particularly in the presence of iron and under high pressures, remains poorly understood. To address this gap, we employ XANES spectroscopy to determine the Cu+/ΣCu ratio (where ΣCu = Cu+ + Cu2+) for silicate glasses quenched from both Fe-bearing and Fe-free hydrous basaltic melts. These melts were equilibrated under diverse fO2 conditions (− 1.8 to 3.1 log units relative to the fayalite–magnetite–quartz buffer, FMQ), at temperatures ranging from 1150 to 1300 °C, and under pressures from 1.0 to 2.5 GPa. By elucidating the oxidation state of Cu in these melts under upper mantle conditions, this study holds the potential to refine our understanding of magmatic processes and fO2 variations within the Earth’s interior.
Results and discussion
Run products
Seven piston cylinder experiments (detailed in Table 1) employed three synthetic silicate glasses (Table S1) as starting materials: four MORB-like, two Di70An30, and one komatiitic. Despite mineral crystallization occurring in five runs (20–33 wt%), segregation of silicate melt pools at the capsule top facilitated XANES analysis (Fig. S1). This favorable distribution, combined with low Cu partition coefficients between mafic melts and minerals (D < 0.2)7, minimized the influence of mineral-hosted Cu on XANES spectra.
Compositions of the quenched glasses are presented in Table 2; refer to Liu et al.7 for detailed mineral compositions. These hydrous melts exhibit basaltic characteristics, although some minor compositional deviations from the starting materials may arise due to olivine and pyroxene crystallization. Estimated H2O contents, derived from the difference between EMP analytical totals (which exclude volatiles) and 100%, range from 5.7 to 11.5 wt%. These values often exceed those expected from the H2O contents added to the starting materials, likely due to H2 diffusion from the buffer materials and mineral crystallization7.
Cu contents in melts and fO2 estimation
Utilizing Pt95Cu05 alloy capsules, the measured Cu contents in the silicate melts represent their apparent solubilities. Previous studies have established that the solubility of Cu in mafic melts rises with temperature and fO2, with minimal pressure dependence at upper mantle conditions7,10,12,13,21,22. Notably, Cu solubility exhibits minimal variation among basaltic, andesitic, and dacitic melts at comparable temperatures and fO221. In this study, Cu contents in silicate melts were measured using LA-ICP-MS and EPMA, ranging from 281 to 6320 ppm (Tables 1 and 2).
Accurate fO2 values were determinable for runs Cu-8, MORB-L2, and Cu-50, where fO2 buffer control was successfully established. Methods outlined by Xu et al.23 and Burnham24 estimated fO2 in these runs, yielding a range from ΔFMQ − 1.8 to ΔFMQ + 3.1. Subsequently, the fO2 conditions in unbuffered runs were estimated based on their respective melt Cu contents, as observed variations in Cu content primarily arise from differences in temperature and fO2. The higher Cu contents observed in the 1150 °C runs (Cu-6, 8, 45) compared to those in the 1230–1300 °C runs provide evidence of their elevated fO2 conditions, supporting the fO2 estimations obtained for the successfully buffered runs (Table 1). This trend is further validated by comparing the Cu contents across these runs: 6320 ± 320 ppm (ΔFMQ + 3.1) in Cu-8, 420 ± 9 ppm (ΔFMQ − 0.6) in MORB-L2, and 281 ± 8 ppm (ΔFMQ − 1.8) in Cu-50. Therefore, the melt Cu content can serve as a proxy indicator of fO2 conditions in the unbuffered runs.
In the subset of 1150 °C runs utilizing MORB as starting material, Cu-6 (4885 ± 76 ppm Cu) and Cu-45 (5848 ± 284 ppm Cu) likely have slightly lower fO2 than Cu-8 (6320 ± 320 ppm Cu at ΔFMQ + 3.1), as evidenced by their slightly lower, yet comparable, Cu contents. Similarly, Cu-52 (4777 ± 228 ppm Cu) at 1230 °C is expected to have a lower fO2 than Cu-6 (1150 °C) but significantly higher than MORB-L2 (ΔFMQ − 0.6) due to their comparable Cu contents. Additionally, Cu-47 exhibits a slightly higher fO2 than MORB-L2. Consequently, the estimated relative fO2 sequence for the unbuffered runs is as follows: Cu-8 (ΔFMQ + 3.1) > Cu-45 > Cu-6 > Cu-52 > Cu-47 > MORB-L2 (ΔFMQ − 0.6) > Cu-50 (ΔFMQ − 1.8).
Capsule influence minimized on Cu K-edge XANES
This study utilized Pt95Cu05 alloy capsules in piston cylinder experiments to serve as Cu source and prevent Cu loss7. However, their significantly higher Cu content (~ 5 wt%) compared to the silicate melts (200–6000 ppm) posed a potential challenge: misleading Cu K-edge XANES spectra due to unwanted contributions from the capsule walls. To address this concern, we implemented a focused beam strategy using a slit collimation system. This strategy confined the synchrotron X-ray beam to a diameter less than 1 mm during non-focusing mode, selectively probing the central region of the glass sample and minimizing the influence of Cu from the surrounding capsule wall.
The effectiveness of this approach is evident in both the minimal Pt fluorescence intensity and the dominant Cu fluorescence intensity observed in the X-ray spectrum (Fig. 1). While the Pt:Cu ratio in the capsule is 19:1, the Cu fluorescence intensity (200–300 counts) far exceeds the expected contribution from the capsule material. This confirms that the focused beam successfully targeted the glass sample, minimizing contributions from the Cu-rich capsule wall. Furthermore, we obtained the XANES spectra of both the capsule wall and quenched silicate glasses in Cu-47 for comparison (Fig. 2). The results reveal distinct spectra for the capsule and glasses, indicating that the influence of the capsule wall on XANES can be readily discerned. Consequently, the prominent Cu peak clearly originates from the glass sample itself, providing reliable data for investigating its Cu valence states and coordination.
Assessment of beam damage
Beam damage in XANES can alter oxidation states through thermal effects and photo-induced oxidation/reduction. Previous studies observed oxidation of Cu in most samples and reduction of highly oxidized ones (ΔFMQ > 7.4) due to this phenomenon20. To evaluate potential beam damage in this study, we employed time-dependent monitoring and spectral comparisons at the XANES beamline. We acquired XANES spectra at the same glass location in run Cu-47 three times to monitor for potential changes during analysis. The spectra retained the same overall features throughout, although minor fluctuations, particularly in the pre-edge peak intensity, were observed (Fig. 2). Comparing spectra collected at different times and locations on the same sample further supported these observations, suggesting minimal impact of beam damage on Cu oxidation state in the silicate melts. Notably, we observed no significant oxidation or reduction attributable to beam damage in our samples. This minimal beam damage effect confirms the reliability of our XANES results in accurately reflecting the Cu oxidation state within the silicate melts. This supports the conclusions drawn from our analysis regarding Cu behavior at upper mantle conditions.
Oxidation state of Cu in silicate melts
Figure 3 exhibits the normalized Cu K-edge XANES spectra of reference standards and quenched glass samples, revealing the dominance of Cu+ in these hydrous basaltic melts. Key to this determination is the first peak of the derivative spectrum: 8979.4 eV for Cu0, 8980.9 eV for Cu+2O, and 8984.0 eV for Cu2+O (Fig. 3b). Notably, Fig. 3a shows a characteristic pre-edge peak centered around 8983.4 eV in all melt glasses, confirming Cu+ presence due to the 1s → 4p electron excitation11,20,25. This peak weakens with increasing coordination number, reflecting orbital interactions with surrounding ligands20. While Cu+ in silicate melts and Cu+ in the Cu2O standard share the same oxidation state, their specific XANES features differ due to distinct chemical environments and coordination geometries. Conversely, Cu2+ exhibits a weak peak around 8979 eV due to the dipole-forbidden 1s → 3d transition, absent in Cu+ due to filled 3d orbitals20,25. Remarkably, even across a wide range of fO2 conditions (ΔFMQ − 1.8 to ΔFMQ + 3.1), no systematic correlations between Cu oxidation state and fO2 were observed in our study. Figure 3 clearly illustrates this lack of dependence, and the unexpectedly weak intensity in run Cu-52 (with conditions similar to the higher-intensity run Cu-47 but under a much more reduced condition) further reinforces this finding. This finding deviates from Miller et al.20, who observed increasing pre-edge intensity with decreasing fO2.
While Miller et al.20 observed features indicating Cu2+ in oxidized samples (ΔFMQ > 5.1), our spectra lack the prominent 1s → 3d transition peak at 8979 eV and the shoulder attributed to Cu2+O. However, faint echoes of these features appear in the most oxidized runs (Cu-8, 45, 6, and 52) as weak flat peaks near ~ 8991 eV in the derivative spectra, potentially corresponding to the α and β peaks observed by Miller et al.20 at ~ 8984.1 eV and ~ 8991.4 eV, respectively. These peaks, attributed to Cu2+O in an octahedral coordination environment, are significantly less pronounced in our samples compared to the CuO standard, suggesting a very minor contribution of Cu2+O alongside the overwhelming dominance of Cu+.
The peak at 8978.8 eV, associated with Cu0, only appears in the derivative spectra of the alloy capsule in run Cu-47 (Fig. 2b), along with the standard (Fig. 3). These results collectively indicate Cu+ as the dominant valence state in the silicate melts, accompanied by a minor Cu2+ component. This aligns with the estimation using the empirical equation from Miller et al.20, yielding Cu+/ΣCu values of 0.903 in Cu-8 (ΔFMQ + 3.1), 0.983 in MORB-L2 (ΔFMQ − 0.6) and 0.993 in Cu-50 (ΔFMQ − 1.8).
As shown in Fig. 4, temperature, pressure, and melt composition appear to exert minimal influence on Cu’s oxidation state within our experimental range, echoing recent findings that Cu+/ΣCu weakly depends on composition, with a slight preference for Cu2+ in more mafic melts20. They also found that increasing temperature stabilizes Cu+, while increasing pressure had little effect on Cu+/ΣCu in mafic melts but preferentially stabilized Cu2+O in granite melts. Importantly, arc basalts that form at subduction zones are predominantly produced through fluid-induced melting of the mantle wedge. The quenched glasses in this study, which mimic natural hydrous basaltic magmas under sub-arc mantle conditions, provide a more direct relevance to the interpretation of natural samples. By emphasizing the dominance of Cu+ in hydrous arc basalts under these conditions, our work not only corroborates established findings but also contributes valuable insights into the behavior of Cu in such geological settings.
Geological implications
Our XANES analysis, in agreement with recent studies20, reveals Cu+ as the dominant oxidation state in hydrous mafic melts under upper mantle conditions, exceeding 90% in most cases even under relatively oxidized conditions. This prevailing dominance of Cu+ across a broad spectrum of fO2 values significantly diminishes the sensitivity of the Cu+/Cu2+ ratio as an indicator for terrestrial fO2. As a result, the effectiveness of the Cu+/ΣCu ratio as an oxybarometer to monitor the genesis and evolution of hydrous basaltic magmas within subduction zones is compromised, as the Cu+/ΣCu ratio only fluctuates from approximately 90% to 98%. However, it unlocks new avenues for understanding magmatic processes through Cu isotopes. Previous studies have demonstrated that Cu isotope fractionation can occur during: (a) sulfide-silicate melt partitioning, where Cu preferentially concentrates in sulfide, leading to isotopically heavier equilibrium silicate melts1,4; (b) fluid-silicate melt partitioning, where exsolved chlorine-bearing fluids have higher δ65Cu than the residual magmas19; and (c) electron-exchange-driven fractionation, where changes in Cu oxidation state, such as Cu+ to Cu2+, can result in isotopic fractionation26. Crucially, our finding of Cu+’s dominance under diverse fO2 conditions suggests that Cu oxidation state changes are unlikely to be the primary driver of Cu isotope variations in natural samples. Instead, the observed isotopic signatures likely reflect the interplay of sulfide segregation/accumulation or fluid exsolution during magmatic differentiation. For example, given the affinity of Cu+ for sulfide phases, its geochemical behavior is closely linked to the evolution of sulfur during magma generation, ascent, and cooling1. Under upper mantle conditions, Cu is primarily hosted in Cu-poor monosulfide solid solutions or sulfide melts, with minimal partitioning into other phases1,2,7. This accounts for the limited isotopic fractionation observed during partial melting of the mantle, even in the presence of sulfide residues1. However, as magmas evolve and cool at lower crustal levels, the formation of Cu-rich sulfides leads to substantial isotopic fractionation, with isotopically heavier Cu preferentially incorporated into these sulfide phases. Additionally, chlorine-rich fluid saturation at depth can also lead to lighter δ65Cu in residual phases. By decoupling redox variations from isotopic signatures, we can gain clearer insights into the evolution of sulfur within magmatic systems, which is not solely related to redox changes23. This newfound understanding can illuminate critical aspects of magmatic differentiation, including the formation of ore deposits and the behavior of volatile elements.
Methods
Starting materials
This study examined the valence state of Cu in different silicate melts using three mafic compositions—komatiite, mid-ocean ridge basalt (MORB), and Fe-free Di70An30 (diopside-anorthite) (Table S1). Reagent-grade oxides (SiO2, Al2O3, Fe2O3, MgO, TiO2, MnO, NiO, P2O5 and Cr2O3) and carbonates (CaCO3, Na2CO3, and K2CO3) were mixed, ground under acetone, and successively sintered at 1000 °C for ten hours and fused at 1500 °C for two hours in platinum crucibles to remove CO2 and ensure chemical homogeneity. Subsequently, the crucibles were rapidly cooled by immersion in purified water, and the quenched glass was finely ground to yield homogeneous glass powder. Two rounds of this fusion-grinding process were employed to achieve complete decarbonation and enhance melt consistency. For more details, refer to Liu et al.7, where a portion of the Cu solubility results were previously reported.
Sample capsules and fO2 control
We employed the same experimental setup as described in Liu et al.7, utilizing Pt95Cu05 alloy capsules in two sizes: a smaller sample container (ID: 2.7 mm, OD: 3.0 mm) and a larger capsule for sample and oxygen fugacity solid buffer (ID: 4.7 mm, OD: 5.0 mm). Each capsule, except for Cu-50 with 1 wt% H2O, received approximately 15 mg of initial silicate powder and 5–6 wt% H2O before welding. The added H2O facilitates equilibration and promotes the formation of crystal-free basaltic glasses during the experiments. Notably, in Cu-50, the sample capsule was loaded into a graphite capsule within a larger alloy capsule, with one end welded and the other crimped for communication with the graphite. Following welding, all capsules underwent drying to confirm no leaks. The alloy capsule also serves as the source of Cu. With a high mass ratio of the capsule (12–16 times the silicate charge), the alloy capsule acts as a buffer, maintaining a constant Cu activity or concentration in each phase of the silicate charge under specific P–T-fO2 conditions. This approach guarantees Cu homogeneity within the melts and circumvents the disequilibrium issues commonly associated with the “Cu-loss problem”.
Oxygen fugacity of primitive arc basalts spans a wide range, typically extending from ΔFMQ-2.0 to ΔFMQ + 3.5, with most clustering between FMQ and ΔFMQ + 2.03,27. To replicate this diversity in the study, a conventional double-capsule technique utilizing Fayalite–Magnetite–Quartz (FMQ), Ni-NiO (NNO), and MnO-Mn3O4 (MnMnO) buffers was employed to control the experimental fO2, following the methodology outlined in Liu et al.7. In this configuration, a sealed sample capsule containing the silicate powder is welded into an outer alloy capsule. The space between the capsules is then filled with the specific buffer material and H2O. It’s important to note that the actual fO2 should be slightly lower than the imposed buffer due to the H2O activity in the silicate melt being less than unity23. On the other hand, three unbuffered experiments were conducted using a single sample capsule placed inside an MgO tube with crushable spacers and MgO powder filling the remaining space. In these runs, the fO2 is believed to be primarily imposed by the starting material and the cell assembly.
Piston cylinder experiments
Primitive arc basalts form under a range of temperature and pressure conditions, typically spanning 1150–1350 °C and 0.8–2.1 GPa, respectively27. To simulate these conditions and investigate Cu behavior in arc basalts, our experiments employed high pressures (1.0–2.5 GPa) and temperatures (1150–1300 °C) with durations of 27–74 h using end-loaded piston-cylinder apparatuses (details in Table 1). Six experiments at 1.0 GPa were conducted in a 3/4 inch pressure vessel at the Guangzhou Institute of Geochemistry, while one experiment at 2.5 GPa (run MORB-L2) used a 1/2 inch vessel at the Bayerisches Geoinstitut. Each assembly consisted of an outer NaCl/talc + Pyrex sleeve and a tapered graphite heater (NaCl used in Guangzhou, talc in Bayreuth). The sample capsule, housed in a pyrophyllite or MgO sleeve, was positioned at the center of the heater within Al2O3 spacers. The hot piston-in method applied pressure, automatically regulated throughout the experiment. Pressure values were further corrected for friction based on the specific assembly used (3% for NaCl + Pyrex, 18% for talc + Pyrex). Temperature control was achieved using Pt/Pt90Rh10 thermocouples and a Eurotherm controller, maintaining a deviation of ± 2 °C from the nominal temperature during the experiment. An estimated uncertainty of ± 15 °C was considered due to the temperature gradient within the capsule. Quenching was achieved by rapid cooling upon switching off the power. Each capsule was then carefully extracted from the assembly, mounted in epoxy, and polished for subsequent optical and chemical analyses.
EPMA and LA-ICP-MS
Major element and CuO concentrations in both minerals and quenched glasses were determined using electron probe microanalysis (EPMA) on two JEOL JXA microprobes: the JXA-8100 at the Guangzhou Institute of Geochemistry and the JXA-8200 at the Bayerisches Geoinstitut. The analysis employed a focused beam for minerals and a 20 µm beam for quenched glasses. The accelerating voltage was set at 15 kV for all elements in minerals and 20 nA for Cu, while other elements in quenched glasses were analyzed at 10 nA. Counting times were set at 20 s for all elements, except Na, K, and Cu, where 10 s on the peaks for Na and K, and 40 s on the peak for Cu were used. The detection limit for Cu was approximately 350 ppm. Wavelength-dispersive spectrometry (WDS) was employed for analysis, and the PAP matrix correction was applied to raw data. Standards used included andradite (Si), MnTiO3 (Ti), spinel (Al), metal Fe (Fe), MnTiO3 (Mn), forsterite (Mg), wollastonite (Ca), albite (Na), orthoclase (K), gallium phosphite (P), metal Ni (Ni), metal Cr (Cr), and metal Cu (Cu). Excellent agreement between measurements (major elements and CuO) obtained from both instruments in Guangzhou and Bayreuth was achieved7.
Cu concentrations in quenched glasses were determined using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) at either the Bayerisches Geoinstitut (run MORB-L2) or the Guangzhou Institute of Geochemistry (run Cu-6, -45, -52, -47, and Cu-50). Both utilized 193 nm ArF excimer lasers coupled to ICP-MS systems: a Geolas M with an Elan DRC-e at Bayreuth and a Resonetic with an Agilent 7500a at Guangzhou. Laser operation parameters ranged from 5 to 10 Hz repetition rate, 80 mJ energy, and 20–80 µm spot size (typically 30 µm). The sample chamber was flushed with He at 0.4 L/min, with 5 ml/min of H2 added to the carrier gas to enhance Cu sensitivity. We achieved a detection limit of 0.1 ppm for Cu. NIST SRM 610 glass served as the external standard, while Si content determined by electron microprobe analysis provided the internal standard. The measured Cu concentration in the SRM 610 standard exhibited a reproducibility (1σ) of < 10%. For further details on the LA-ICP-MS methodology, please refer to Liu et al.7.
XANES
The oxidation state of Cu in quenched glasses from piston cylinder experiments was investigated using Cu K-edge XANES (X-ray Absorption Near Edge Structure) spectra at the Shanghai Synchrotron Radiation Facility (BL14W1 beamline station). Measurements were conducted under well-defined beam conditions, with a stored ring electron energy of 3.5 GeV and a beam current ranging from 150 to 210 mA. The ionization chamber was filled with N2 to reduce attenuation and scatter. Two sets of analyses with fluorescence mode were conducted: (a) non-focusing mode: utilized a double-crystal Si (311) monochromator with a spot size of 800 × 400 µm and a 32-element high-purity Ge solid-state detector for X-ray absorption spectra collection; and (b) focusing mode: employed a Si (111) monochromator with a spot size of 200 × 200 µm and a Lytle fluorescence ionization chamber for signal collection. Both approaches effectively measured the Cu K-edge absorption edge for samples with Cu content exceeding 100 ppm.
For accurate energy calibration, the first derivative peak in the Cu foil XANES spectrum (transmission mode) was aligned to 8978.9 eV before sample measurements. The scanning range spanned 180 eV pre-edge to 200 eV post-edge, optimizing extended edge analysis for Cu coordination, particularly oxidation state. CuO2 and CuO standards were finely powdered and tape-mounted for transmission measurement. Spectra were recorded from 8778.9 to 9175.2 eV with a step size of 5 eV up to 8959 eV, 0.3 eV between 8959 and 9030 eV, 1 eV between 9030 and 9079 eV, and 2 eV above 9079 eV. The count time was 2 s per point. Signals from the 32-element detector were averaged, and resulting spectra were normalized using ATHENA. A total of seven samples underwent analysis through Cu K-edge XANES spectra. The first set of samples, analyzed using the non-focusing mode, comprised runs Cu-47, Cu-8, MORB-L2, Cu-6, and Cu-52. In contrast, the second set, which employed the focusing mode, included samples Cu-45, Cu-50, and Cu-52. To ensure the reliability of the results, each sample underwent multiple measurements, minimizing potential interference in the analysis process.
Data availability
The datasets used and/or analyzed during the current study available from the corresponding author on reasonable request.
References
Liu, S.-A. et al. Copper isotope evidence for sulfide fractionation and lower crustal foundering in making continental crust. Sci. Adv. 9, eadg6995 (2023).
Li, Y., Li, Y.-X. & Xu, Z. The partitioning of Cu and Ag between minerals and silicate melts during partial melting of planetary silicate mantles. Geochim. Cosmochim. Acta 324, 280–311 (2022).
Zhao, S.-Y., Yang, A. Y., Langmuir, C. H. & Zhao, T.-P. Oxidized primary arc magmas: Constraints from Cu/Zr systematics in global arc volcanics. Sci. Adv. 8, eabk0718 (2022).
Wang, Z. et al. Copper recycling and redox evolution through progressive stages of oceanic subduction: Insights from the Izu–Bonin–Mariana forearc. Earth Planet. Sci. Lett. 574, 117178 (2021).
Liu, X. & Xiong, X. Copper. In Encyclopedia of Geochemistry: A Comprehensive Reference Source on the Chemistry of the Earth (ed. White, W. M.) 303–305 (Springer International Publishing, 2018).
Jenner, F. E. et al. The competing effects of sulfide saturation versus degassing on the behavior of the chalcophile elements during the differentiation of hydrous melts. Geochem. Geophys. Geosyst. 16, 1490–1507 (2015).
Liu, X. et al. Partitioning of copper between olivine, orthopyroxene, clinopyroxene, spinel, garnet and silicate melts at upper mantle conditions. Geochim. Cosmochim. Acta 125, 1–22 (2014).
Lee, C.-T.A. et al. Copper systematics in arc magmas and implications for crust-mantle differentiation. Science 336, 64–68 (2012).
Sun, Z. et al. Sulfur abundance and heterogeneity in the MORB mantle estimated by copper partitioning and sulfur solubility modelling. Earth Planet. Sci. Lett. 538, 116169 (2020).
Liu, X., Xiong, X., Audétat, A. & Li, Y. Partitioning of Cu between mafic minerals, Fe–Ti oxides and intermediate to felsic melts. Geochim. Cosmochim. Acta 151, 86–102 (2015).
Berry, A. J., Hack, A. C., Mavrogenes, J. A., Newville, M. & Sutton, S. R. A XANES study of Cu speciation in high-temperature brines using synthetic fluid inclusions. Am. Mineral. 91, 1773–1782 (2006).
Holzheid, A. & Lodders, K. Solubility of copper in silicate melts as function of oxygen and sulfur fugacities, temperature, and silicate composition. Geochim. Cosmochim. Acta 65, 1933–1951 (2001).
Ripley, E. M. & Brophy, J. G. Solubility of copper in a sulfur-free mafic melt. Geochim. Cosmochim. Acta 59, 5027–5030 (1995).
Zhang, L., Wang, F. & Ni, H. Anisotropic copper diffusion in olivine: Implications for Cu preservation in olivine and olivine-hosted melt inclusions. Geochim. Cosmochim. Acta 347, 116–124 (2023).
Ni, H. et al. Cu diffusivity in granitic melts with application to the formation of porphyry Cu deposits. Contrib. Mineral. Petrol. 173, 50 (2018).
Ni, P. & Zhang, Y. Cu diffusion in a basaltic melt. Am. Mineral. 101, 1474–1482 (2016).
Wood, B. J. & Kiseeva, E. S. Trace element partitioning into sulfide: How lithophile elements become chalcophile and vice versa. Am. Mineral. 100, 2371–2379 (2015).
Berry, A. J., Harris, A. C., Kamenetsky, V. S., Newville, M. & Sutton, S. R. The speciation of copper in natural fluid inclusions at temperatures up to 700 °C. Chem. Geol. 259, 2–7 (2009).
Guo, H., Xia, Y., Bai, R., Zhang, X. & Huang, F. Experiments on Cu-isotope fractionation between chlorine-bearing fluid and silicate magma: implications for fluid exsolution and porphyry Cu deposits. Natl. Sci. Rev. 7, 1319–1330 (2020).
Miller, L. A. et al. The effect of composition, temperature and pressure on the oxidation state and coordination environment of copper in silicate melts. Geochim. Cosmochim. Acta 364, 129–147 (2024).
Liu, X. et al. An experimental study of the solubility of copper in hydrous silicate melts. Geotecton. Metallog. 46, 803–813 (2022).
Ripley, E. M., Brophy, J. G. & Li, C. Copper solubility in a basaltic melt and sulfide liquid/silicate melt partition coefficients of Cu and Fe. Geochim. Cosmochim. Acta 66, 2791–2800 (2002).
Xu, T., Liu, X., Xiong, X. & Wang, J. Sulfur dissolution capacity of highly hydrated and fluid-saturated dacitic magmas at the lower crust and implications for porphyry deposit formation. Geochim. Cosmochim. Acta 333, 107–123 (2022).
Burnham, C. W. The importance of volatile constituents. In Evolution of the Igneous Rocks (ed. Yoder, Jr., H. S.) 439–482 (Princeton University Press, 1979).
Kau, L. S., Spira-Solomon, D. J., Penner-Hahn, J. E., Hodgson, K. O. & Solomon, E. I. X-ray absorption edge determination of the oxidation state and coordination number of copper. Application to the type 3 site in Rhus vernicifera laccase and its reaction with oxygen. J. Am. Chem. Soc. 109, 6433–6442 (1987).
Fernandez, A. & Borrok, D. M. Fractionation of Cu, Fe, and Zn isotopes during the oxidative weathering of sulfide-rich rocks. Chem. Geol. 264, 1–12 (2009).
Wang, J. et al. Oxidation state of arc mantle revealed by partitioning of V, Sc, and Ti between mantle minerals and basaltic melts. J. Geophys. Res. Solid Earth 124, 4617–4638 (2019).
Acknowledgements
We thank Andreas Audétat for help with the LA-ICP-MS analysis. This study was supported by NSFC (No. 42250202, 42073057, 41921003, 92062222, 42250710679) and GIG, CAS (E2510317). We are grateful for the constructive review provided by the anonymous reviewer and for the efficient handling of this manuscript by Anatoly Belonoshko.
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X.L. and X.X. conceived the project. X.L. performed the piston cylinder experiments, EPMA and LA-ICP-MS. X.L., S.Z. and L.L. performed the XANES analyses. All authors contributed to the extensive discussion and interpretation on the data and wrote the manuscript.
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Liu, X., Zhang, L., Zhu, S. et al. Oxidation state of Cu in silicate melts at upper mantle conditions. Sci Rep 14, 5802 (2024). https://doi.org/10.1038/s41598-024-56538-9
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DOI: https://doi.org/10.1038/s41598-024-56538-9
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