Introduction

Due to the increase in adverse chemical reactions in the environment, research activities focus to swap synthetic fibers and its composites with natural or bio-based fibers and its composite. Synthetic fibers such as carbon, glass. nylon and kevlar have been widely used for making polymer composites for more than three decades. Increasing the demand of natural biodegradable fiber in the industries and the global market, it should need to find new natural fiber1,2. Main purpose of this study investigates the mechanical, chemical, thermal and properties of novel natural fibers pull out from the skin of BA trees. Albizia is a tree of fabaceae family. It grows prominently in South and East Africa, Sudan and Ethiopia. It is also found in India and other countries like Sri Lanka, Bangladesh, etc. Performing the required analysis on integrated properties ensures the suitability of various natural fibers and it is very significant to have basic information for making composites. Therefore, studying the characteristics of such fibers through research plays an important role in introducing new natural fibers to the engineering and technology field. A standardized testing process for performing structural analysis of natural fibers was followed by many researchers3. The advantage of natural fibers is high compared with synthetic fibers like carbon, glass and kevlar, including lower production costs, reduced environmental impact, lighter weight, greater accessibility, and resistance to corrosion4.

Many engineering industries, including construction, automotive, aerospace, electrical, marine, and home utilities the natural fiber reinforced polymer composites in a broader extent5,6. Natural fibers’ mechanical qualities were determined solely by their chemical make-up, growth region, source, age, and extraction technique7,8. Many researches that the microfibrils are oriented spirally in the fiber axis, it exhibits rigid behaviour. The efficiency of reinforcing the natural fibers increase with increase in the length-to-diameter ratio (i.e. aspect ratio) of natural fiber over the critical ratio at which applied load or stress transfer between matrix and natural fiber occurs completely before the failure of composite samples. However, higher aspect ratio leads more fiber entanglement during the composite manufacturing processing and occurred poor dispersion9. In this way, many researchers have extracted new biofibers such as Pandanus Tectorius8, Acacia leucophloea10, Sansevieria Ehrenberg11, Prosopis juliflora12 and Agave gigantea13, using qualitative procedure. FTIR spectroscopy, XRD, TGA10 and Single fiber testing was adopted to characterize the fibers. These fibers are used to develop the fiber reinforced polymer matrix composites. In many cases, the natural plant fibers like cotton, sisal, hemp, and jute are also used as reinforcements to produce a hybrid composite1,2.

Plants that create such natural fibers, on the other hand grows exclusively in certain places based on natural circumstances. It is important to test new fiber with advisable properties that may guarantee the development of green composites. It is expected that the future requirements for unique natural fibers will expand as new products development and technologies. The requirement and demand of natural fiber are continuously increased in the world market. Compensating the demand of natural fiber in the work marked, the new plant fiber should be identified and characterized before being used in composite developments. A new plant fiber is identified from a plant of Bitter Albizia tress. The current study investigates the physical, thermal, tensile, and chemical properties of unique BA bark fiber, which has not been reported in the literature. BA fibers extracted manually from plant stalks and are subjected to mechanical property testing like tensile behaviour. Alongside, TGA, DSC, XRD, and FTIR, and morphology of fiber surface using Scanning Electron Microscopy are investigated in the present study. The BA tree was collected from agricultural land as per the Tamilnadu agricultural institution guidelines, Tamilnadu, India.

Materials and methods

Bitter Albizia plant and its fiber extraction

Bitter Albiza tree (Fig. 1A) belongs to Fabaceae family. It is abundantly available in South and East Africa. The Bitter Albizia tree was cultivated and harvested as per the guideline stated in Institute of Forest Genetics and Tree Breeding by Indian Council of Forestry Research and Education, Coimbatore, Tamilnadu, India. The trees are collected from an agricultural land in Perundurai, Erode district, Tamilnadu, India. The GPS locations of the collected BA tree skin are in East of 77° 35′ 26.1492″, North of 11° 16′ 5.0664″, Latitude of 11.268074 and longitude of 77.590597. The prior permission was approved by concern authority for collecting this tree. Its leaves are in small size ranging between 2 and 8 mm (Fig. 1B). Figure 1C shows the hard outer skin of BA tree and it peeled off manually (Fig. 1D) for fiber extraction. Figure 1E shows the collected skin fiber extraction. Figure 1F shows the extracted fibers for characterization. Restoration processes are adopted to remove plant fibers (Table 1). Bitter Albizia (BA) plant bark is waterlogged in stored water for three weeks to discrete the fibers using water soaking process11. The extracted skins fiber is dried at room temperature for three more days and prepared to use for the future study.

Figure 1
figure 1

(A) Bitter Albizia (BA) Tree, (B) Leaf Twig of BA, (C) Bark in BA tree (hard skin), (D) Peeling of BA skin, (E) BA skins and (F) BA skin fibers (BAFs).

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Table 1 Natural fibers extraction methods.
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Chemical analysis of BAFs

Standard test procedures were adopted to calculate the various chemical components or properties of BAFs, including wax, hemi-cellulose, pectin, cellulose moisture, and ash content7. BAF density is obtained using the meltbertoledoxsz05 balances method of (Machine maker and mode: Mettler Toledo and xsz05) testing. The moisture level of BAF was examined using the electrical humidity analysis, and the ash component was quantified according to ASTM E1755-01 standard using Cubis® II (Sartorious, model MA45). The wax mixture is calculated in the Conrad method. Pectin is analyzed in the form of ammonium oxalate KOH(Potassium hydroxide) amalgamation method.

Moisture

Moisture analysis is performed to see the humidity in the inner and outer fiber surface which can affects the mechanical behaviour of natural plant fibers, particularly in the fiber-matrix connection. The test was performed by measuring approximately 5 g of sample in a towel-filled petrol container. It is also stored in a dry place in an air oven of 100 ± 20 °C. Then, the samples were cooled in automatic desiccator for period of 25 min and their weight of the sample was calculated. Again, the BA fibers were dried for 30 min, cooled in a autmomatic desiccator for 25 min and again their weight was calculated. This process was continuously repeated until a saturated value of weight was obtained during two consecutive trials. The moisture lavel in the fiber is calculated by using Eq. (1).

$${\text{Moisture}}\,\,(\% \,\,{\text{by}}\,\,{\text{weight}})\, = \,\frac{{{\text{W}}_{1} - {\text{W}}_{2} }}{{{\text{W}}_{1} - {\text{W}}}} \times 100\,,$$
(1)

where W is dish weight in grams, W1 is dish weight in grams + weight before dying in grams, W2 is dish weight + weight after dying in grams.

Ash

Ash test is done to calculate the total content of the ash filled inside the BA fiber. The test was performed using a 5 g of sample in a towel container. The inside temperature of the container was maintained as 550 °C. Heating rate in the oven was maintained as 10 °C/min, so that the formed ashes are carbon-free. Weight of the fibers were then recorded using standard measuring practices. The Ash content is calculated by Eq. (2):

$${\text{Total}}\,{\text{ash}}\,\,{ = }\,\frac{{{\text{(W}}_{2} - {\text{W}}_{1} ) \times 100 \times 100}}{{{\text{(W}}_{{1}} - {\text{W)(100}} - {\text{m)}}}}\,,$$
(2)

W1 = crucible + sample weight (g), W2 = crucible weight + ash content (g), W = the empty crucible weight (g), m = moisture % of the sample.

Pectin

A beaker of 1000 ml capacity have mixed 50 g of BAFs and 400 ml of 0.005 N HCl. The beaker was heated upto 90 °C for 2 h and boiled with water of 400 ml. This was cooled and transfered to a volumetric flask of 500 ml. Here, add 200 ml of distiller water and 10 ml of NaOH in the beaker, it allows overnight. Finally add acetic acid and calcium chloride of 50 ml and 25 ml in the beaker, it is boiled for 3 min and filtred. The filtered residual was used to calculate the pectin content of BAFs.

Cellulose

Cellulose is a structural polysaccharide present in plants. Initially the samples were appropriately scissored. They were then freezed by keeping in a liquid nitrogen bath and converted into fine powder. This samples were weighed approximately ranging between 0.5 and 1.5 g of samples and they were transferred to tubes of 50 ml capacity. Then the BAF samples were heated in a hot water at 100 ºC for 100 min before taking them out. Following the heating, a 10 ml of hydrogen peroxide solution (5%) was added into the tube. Again, the BA fibers were placed in hot water bath at 75 °C for 40 min and the samples were cooled in the room temperature for 60 minuts. The samples were then packed with filter paper and they were dried in an incubator at 65 °C temperature until reaching the constant weight. The weight of the dried insoluable samples were weighed which showed the present of cellulose content and preserved in the centrifugal tubes.

Hemi-cellulose

They are a combination of plant polysaccharides and lower molecular weight than cellulose and soluble in diluted alkali. They are employed in the making paper and ethanol. In an acetate buffer solution, the pulp was dipped in a dry solid to liquid ratio content of 1/60 (g/ml). Following the process, the holocellulose substance was rinsed and filtered with distilled water, and followed to dried in an hot air oven for 20 h at 40 °C. Sodium sulphite and Neutral detergent solution were used wet the cellulose for a period of three days. Three volumes of ethanol were used to precipitate hemicellulose, which was then filtered, freezeed and dried.

Lignin

Lignin is an important organic polymer found in the walls of various types of cells. It includes biological tasks such as mechanical support, water transport, and stress resistance. For the lignin test, a variety of chemicals were utilised, including acid, peroxide, caustic soda, and water. A small amount of pulp was removed and placed in a conical flask. The 85% of organic acid (formic and acetic acid mixture of 70 and 30 by volume) was added to the flask at a fiber to liquid ratio of 1:8 and left to boil for two hours on a hot plate. The flask and its substances were cooled to room temperature after 2 h. The fibers were filtered through a Buckner funnel and then washed in 80% acid before being rinsed in hot H2O. The delignified fibers were then bleached for two hours in an extremely precarious bath at 8 °C using a 14 ml of 35% H2O2 solution. Following the pulping and delignification process, the wasted liquor was heated to 105 °C. The H2O was used to precipitate lignin that had been dissolved in acid.

Physical analysis of BAF’s—density

A single long fiber was sliced into short length and kept on a microscope sliding table. It was projected to a screen using a microscope. The dimensions were measured in millimetre using a ruler. By measuring the weights and dimensions of the object, the linear density was computed. A total of 100 fibers were examined in order to estimate the average BA fiber diameter and 10 fibers were tested in order to calcalted the average linear density. Using Eq. (3), the volume density of the natural fiber was calculated using the average linear density and average diameter of fibers27.

$${\rho }_{f=}\frac{M}{\frac{\pi {d}^{2}}{4}l},$$
(3)

where M = mass of a natural BA fiber (grams), d = average diameter of the BA fiber (m), and l = BA fiber length (m).

FESEM

The surface morphology of BAFs was analyzed through FESEM (Field emission scanning electron icroscopy) with high resolution (Model: Thermo Scientific Apreo S). The BA fiber surface was coated with gold of thin layer before imaging. The gun voltage of 30 kV was used to capture the image of the BAFs surface.

FTIR

The Shimadzu spectrometer was used to record the FTIR (Fourier transform infrared spectroscopy) spectrum of BAF’s. The BAF samples were milled using a ball milling machine until they were reduced to a powder. This BA fiber powder and bromide of potassium crystals was mixed thoroughly and then the mixture was compacted into a pellet. FTIR data were collected using the attenuated total reflectance mode, and the scan rate was kept at 32 scans per minute while the resolution remained at 2 cm–114 over the frequency range of 4100 to 500 cm–1.

XRD

The X-ray diffraction (XRD) method has been commonly used to know the composition and structure of crystalline materials. The XRD of BAFs was explored (powder XRD) with help of X’Pert-Pro diffractometer1.

$${CI}_{1/4}= \frac{{H}_{002}- {H}_{am}}{{H}_{002}},$$
(4)

where H21.72 and H15.81 are the higher peaks at 2θ = 21.72° and 15.81°, respectively. CS (i.e. Crystallite size) is calculated using the deflection pattern of the cellulose’s 200 lattice planes. Using Scherrer’s formula, the CS was computed as follows in Eq. (5).

$${CS}_{1/4}=\frac{K\lambda }{\mathrm{B*cos}\theta },$$
(5)

where K is Scherrer’s constant (0.89), β = half width of the radian, λ(delta) = the wavelength of radiation (0.15406 Å), and θ (Theta) = Bragg angle in radian.

TGA (thermogravimetric analysis) and DTG (derivative thermogravimetry)

TGA/DTG are done to find the substance weight and its rate of change of phase in term of curve was recored when the BA fiber sample is heated in a controlled nitrogen atmosphere contition. The various stage of BAF degradation were calculated using Jupiter thermogravimetric analysis spectrometer (Makea and Model: STA449F3-NETZSCH, Country: Germany). This device contains a heating furnace and sample of BA fibers placed on a idle crucible attached to an accurate balance. The sample of BA fiber was heated between 36 °C and 650 °C by 10 °C/min heating rate14. To prevent the effects of oxidation or burning, the fiber sample was burnt in a nitrogen gas environment with 20 ml/min gas flow rate delivered to the furnace. The activation capabilities of BAFs were tested utilising the Broido firm expression (Eq. 6) to determine their thermal stability.

$$In\left[In\left(\frac{1}{y}\right)\right]= -\left(\frac{{E}_{a}}{R}\right)\left[\left(\frac{1}{T}\right)+k\right],$$
(6)

where R and T are Universal gas constnat of 8.32 J/mol K and Temperature in Kelvin, , k and y are constant and the proportion of initial molecules which is not decomposed (wt/wo), where wt = sample weight at any time t and wo = Fiber sample’s beginning weight.

DTA (differential thermal analysis)

The BA fiber sample is heated at a controlled place with an inert reference material in the DTA testing. The reference material and sample temperature was risesed by heating. If the sample undergoes a phase transition, the power is absorbed or extracted, and differerence in referenced and sample temperature (T) is determined. A DTA curve shows the temperature difference as afunction of time.

Single fiber test

The tensile characteristics of the BAFs were tested by cutting them into 100 lengths. The fiber gauge length is 50 mm and a total of 20 samples of single fibers were evaluated. Individual fibers were gripped using a pneumatic gripper during testing, with the testing cross head speed of 0.1 mm/min11,15. The force vs. elongation curve of fiber at various gauge lengths was measured using a 1.3 kN load cell, and the data were plotted. The average tensile strain, Youngs modulus, tensile strength, and elongation values were calculated. The tensile sudy was conducted in a laboratory with the room temperature at 25 °C, and the relative humidity (RH) was set at 72%. Finally, the recorded data were analysed to determine the fiber's tensile characteristics. Equation (7) is used to calculate the total cross head travel (displacement (δt)) during fiber testing:

$$\frac{\delta t}{F}=\left[\frac{1}{EA}\right]L+C,$$
(7)

where F = applied load (Newton), L = gage length (mm), E = Young’s modulus, A = Fiber Cross sectional area, and c = machine compliance.

Results and discussion

SEM analysis of BAF

High-precision SEM analysis of natural fiber’s surface morphology revealed microscopic fissures on the BA fiber's surface, roughly halfway along the fiber’s length (Fig. 2a)14. The exterior of the BA fiber surface was showed rough (Fig. 2b) in nature. This can increase the area of contact with resin during composite preparation which increase the mechanical properteis of the composites. The presence of white substance in the BA fiber zone (Fig. 2c) shows the existence of amorphous cellulose, lignin and hemicellulose, content28. The cellulode sturcture layer are tighly packed. This increase the stiffness of fiber. The higher stiffness of the fiber might make it easier to better adhere to the fiber-matrix by physical contact between them. The gummy polysaccharides and impurities are presented in between the openings of filaments in the fiber surfance. The scanning images demonstrated the avaliblility of sticky polysaccharides in addition to other contaminants between the spaces occupied by the filaments. (Fig. 2d) that are filtered when the fiber is chemically treated and a strong fiber structure formed thereby enhances the BA fiber and matrix inerfacial adhesion during making of the polymer composites. The BPF diameter was taken using FESEM for various phase lengths varying from 17.5 to 68 μm.

Figure 2
figure 2

SEM image of Bitter Albizia fiber.

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BAFs chemical analysis

Table 2 lists the chemical characteristics of BAFs and numerous other plant fibers. Natural fibers functional properties are largely determined by their cellular and lignin content value. Plant natural fibers with a higher lignocellulose concentration have a high traction strength and tensile modulus, whereas the fiber with a more lignin content have long life11. The precentage volume of cellulose (74.89 wt. percent) present in BAFs has relatively high compared to that found in compositions such as Kenaf of 53.14 wt. percent, Palm oil of 65 wt. percent, coir of 37 wt. percent, Jute of 72 wt. percent20,28 and hemp fibers of 74 wt18 percent. The presence of higher cellulose content is increased the BA fiber tensile properties. The present of lignin content in BAFs was calculatedd to be 12.80 wt. percent, which is greater than sida rhombifolia fiber of 7.48 wt percent7, Hibiscus vitifolius Plant Stalk of 8.18 wt.percent14 hemp fiber of 4 wt. percent18 and flax fiber of 3 wt. percent29. The lignin content shows medium in BA fiber This can increased the single fiber tensile strength. The increased presence of wax has a negative impact on fiber/matrix interfacial bonding in all natural fiber. BAFs have a medium wax content of 0.31 wt. percent compared to other natural fibers such as Agave gigantea (0.26 wt. percent)8, flax fibers (1.7 wt. percent)29 and Jute (0.51 wt. percent)20. The BA fiber showed less wax content. This will increased the better bonding between fiber-matrix.

Table 2 Comparison of chemical compositions of raw BAFs with various natural fibers.
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FTIR spectrum

FTIR spectrum is used to identify the main active groups existing in BAFs over the wavelength (The specrum range between 500 to 4000 cm−1) as showed in Fig. 3. Showing a sharp peak of waveform at 3697 cm−1 depicts the free hydroxyl groups with OH expansion, and cellulose hydrogen is represented by the minimum exposure at points of 3880 cm–1 and 3414 cm–111,33. The expanding C-H bond was shown by a narrow band of 2985 cm–111,34. A band visible at 2387 cm–1 could be mostly due to lignin ion bonds11,35. The tiny peak of 2005 cm–1 reflects the presence of CH233. It showed the presence of higher crystalline cellulose. In lignin (guaicycl) cellulose, a sharp height of 1658 cm–1 correlates to the respiratory guaiacyl ring with a significant C–O stretch36. The sharp peak values was very low. This shows the less lignin content in the BA fiber. C–O–C in the from of cellulose is shown by a strong peak at 1072 cm−1 and a peak value of 908 cm−1 showed β links of BA fiber cellulose11,37. OH group bending outside the plane is absorped as high peakc at 561 cm−135.

Figure 3
figure 3

BAFs FTIR spectrum.

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XRD spectrum

Figure 4 presence the XRD pattern of BAFs. The Two peaks with angles (2θ = 15.81° and 21.72°) were detected in the diffractogram structure, generally indicating the existence of monoclinic Cellulose-I crystals10,11. In all natural plant fibers, crystalline cellulose helps higher tensile stress and also the stability of fiber structure, and this is usually indicated by the CI (crystallinity index)38. The BAFs, CI value was found to be 57.20% when tested using the Segal equation mentioned in the scale (Eq. 5) and this number is relatively less compared to that of fibers such as Acacia leucophloea (42%)10, Prosopis juliflora (46%)12. Furcraea Foetida (42.7%)28, Ferula communis (48%)39 and Borrassus (38.4%)40 fibers. The Scherrer formula10,11 was used to calculate the crystallite size BAFs, which was found to be 1.68 nm. Table 3 shows the CI and CS values of BAFs and other fibers in Fig. 4. The BA fiber has higher CI and CS values. This leads to more fiber stiffness.

Figure 4
figure 4

XRT of BAFs.

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Table 3 Physico-mechanical properties of BAFs and other natural fibers.
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TGA and DTG analysis

The TGA and DTG curves were used to analyze the thermal stability and behavior of BAFs (Fig. 5). The early thermal disintegration fiber samples occurred at 68.57 °C, owing to fibers moisture loss due to evaporation10,38. Second phase was occurred from 100 °C to 150 °C with a high temperature of 138.05 °C. Due to a drop in cellulose content, a sudden increase of temperature to 334.73 °C resulted in a large weight loss of roughly 59.76%. Similar peaks at 331.1 °C, 350 °C 328.2 °C, and 346.8 °C have been observed with Sida rhombifolia7, Acacia leucophloea10 Prosopis juliflora12 and Shwetark fibers36. Fragrant lignin’s molecular structure makes it more steady in thermally than other natural fiber components11,16,44. The residual mass percentage of the fiber at 548 °C was found to be 23.35%. The broido equation (Eq. 6) is used to calculate the activation energy that is associated with thermal degradation of BAFs at temperatures ranging from 80 °C to 360 °C (4). From the structure ln(1/y) compared to T–1 shown in Fig. 6, total BAFs regenerative power was showed to be 55.295 kJ/mol. The activation energy is relating to bonding of chemical composition in the natural fiber. The higher value shows higher bonding which could increase the thermal stability like shifting the degradation temperature of composition towards higher level in the TGA curve. The BA fiber have moderate values which shows better thermal stability.

Figure 5
figure 5

TGA and DTG curves of BAFs.

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Figure 6
figure 6

Broido’s plot of BAFs.

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In the DTA curve of TDF given in Fig. 4b four endothermic peaks at 242.03 °C, 364.86 °C, 522.48 °C and 663.77 °C were observed. The first major endotherm ranging between 171.03 °C and 364.86 °C corresponds to thermal depolymerization of hemicellulose and the second major endotherm existing within 333.62 °C and 476.33 °C attributed to the thermal degradation of cellulose. The minor endotherm which ranges between 476.33 °C and 616.20 °C corresponds to the thermal degradation of lignin and the peak at 663.77 °C indicates the temperature at which thermal degradation of wax and other impurities occurs.

The range of temperature over which the thermal decomposition of each chemical constituent occurs is analyzed quantitatively through differential thermal analysis (DTA).

DTA analysis

Figure 7 shows the DTA curve of BAFs. The thermal decomposition of chemical composition in BA fiber is investigated quantitatively through DTA as shown in Fig. 7. The DTA with temperature in (°C) shows the complex peak arises at 69.3 °C and the complex onset arises at 68. 4 °C. The area is shown as 7.085 J/g45. The two endothermic peaks at 69.3 °C and 68. 4 °C were observed. The first peak at 68. 4 °C showed thermal depolymerization of hemicellulose and lignin, the second peak at 69.3 °C showed thermal degradation of cellulose.

Figure 7
figure 7

Derivative thermogravimetry analysis of BAFs.

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Mechanical properties of BAF’s

Figure 8 presence the BA fiber tensile stress versus strain plots. The tensile propertes of the BAFs was calculated by indirectly from the tensile stress values which was found between 513 and 1226 MPa. The strenght of BAFs was higher than some natual fibers such as palm of 377 MPa, petiole bark of 185.52 MPa, kenaf bast of 427–519, bamboo of 503 and banana of 600 MPa21,34. The strain to failure of BAFs was estimated to be 0.8–1.37%, the Youngs modulus of BFAs was estimated from the slope of the tensile stress plots which is 6.9–9.6 GPA. Therefore, the Table 3 shows that it can be concluded that BAFs have a natural fiber that is rather strong. The existence of a high cellulose content in BAFs is responsible for their great potency. The cellulose microfibrils are lodged in the lignin matrix at an angle, known as the microfibrillar angle (α), is another key factor that determines the mechanical characteristics of natural plant fibers25. Low microfibrillar angle in natural fiber shows high tensile strength and durability as well as fibers with a higher micro fibrillar angle indicate improved fiber ductility17. The BAF has hgiher microfibrillar angle of 11.32° which influences the hgiher mechanical stregnth of fiber and fiber-matrix composites. Plant fiber density, in addition to mechanical qualities, has an essential function in lowering weight and the pace at which it is used in green composites. The physical density of BAFs was discovered as 1285 kg/m3. This showed lower value compared to other natural fiber. This BA fiber can used to make light weight composites.

Figure 8
figure 8

The stress and strain relations for five of BAFs.

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Conclusion

Physical, mechanical, thermal, morphological, and chemical tests were conducted on biocellulosic fibers from the Bitter Albizia tree for use in composite. The results of these testing was confirmed BAF's ability to strengthen the polymer matrix. The presence of more cellulose content (74.89 wt.%), moisture content (11.71 wt.%), and low wax content of 0.31 wt.% enhances BAF strength and enhances the fiber matrix interfacial bonding. The values of microfibrillar angle (α) of BAFs was showed as 11.32° (α) and plant fibers with α greater than 10° tend to show higher ductility with increasing load. In comparison to most natural fibers, BAFs has a high crystallinity index (57.20%) and a small crystallite size (1.68 nm). This will ideal for the fabrication of polymer composites and increaed the mechanical proeprties. Thermal stability (up to 360 °C) and kinetic activation energy (55.295 kJ / mol) were discovered in BAF by TGA, which are important requirements for compounding. This showed that the BFAs has higher thermal stablity. With this research, it is concluded that a sustainable polymer matrix compoistes can be developed with BAFss that will be useds polymer composite materials in different applications such as car parts, wall panels, sports equipment and building partition boards.