Perovskite solar cells must overcome the long-term stability problem in order to be put into practical use. Materials science, through the development of synthetic chemistry, materials characterization and device engineering can contribute to improvements in stability and scalability towards enabling large scale production. This Collection presents recent research efforts in stabilizing perovskite solar cells with three interconnected themes: characterizing instability, synthesizing stable perovskites and curing the interfaces.
Currently, one of the most fascinating areas of energy materials and optoelectronic devices research is perovskite solar cells. They are not only found to be one of the most efficient types of solar cells, but also constitute one of the fastest growing fields in materials science. Yet, with all the momentum in the field, perovskite solar cells are not ready to be commercialized, mainly due to the long-term instability problems1,2,3,4,5,6. These problems have their atomistic origin; the materials are mixed covalent and ionic and they have soft and dynamic lattices. Such characteristics have direct consequences for the long-term stability of the solar cells, including relatively fast degradation of perovskite absorbers1,7,8,9,10, their interfaces with charge transport layers under thermal stress2,5,6, photoexcitation and electrical bias, and the hysteresis of current–voltage (J–V) curves3,4. This Collection includes recent research efforts in stabilizing perovskite solar cells with three interconnected themes: (1) characterization methods for studying the instability problems from atomistic to device level1,2,3,4, (2) strategies to improve the stability and cure the interfaces problems at the perovskite/charge transport layers5,6 in the devices (3) materials engineering strategies to synthesize and fabricate stable perovskites in the lab7,8,10 and industrial scale9.
Characterizing instability
To stabilize perovskite solar cells, fundamental research focusing on understanding the origin of instability through different characterizations is essential. Several articles focus on the ion migration-induced effect on perovskite absorbers, on the aging at electrode/charge transport layer/perovskite interfaces, and hysteresis behavior in the devices. For instance, Cuzzupè et al.1 employed a physical contact annealing approach to probe the A-site cation diffusion between MAPbI3 and FAPbI3 films and find a mutual cation migration. The authors highlight that the migration is helpful to convert the unwanted yellow phase of FAPbI3 to the black phase and heals MAPbI3 by removing pinholes. Yet, similar phenomena can be detrimental to device application when other stress factors, such as hysteresis in J–V under the operation of the solar cells3,4,5,6 are present. In this regard, Minbashi et al.3 studied such an effect by using a drift–diffusion solver with an ion migration model incorporated. They found that the scan rate and charge-carrier mobility have a significant effect on the severity of the hysteresis. Furthermore, Huang et al.4 argue that the dielectric constant of the charge transport layers and the total ion density, relevant to the quality of the perovskite crystal and the degree of degradation of the interfaces, are also important factors. These factors contribute to the strength of the built-in electric field across the perovskite and its interfaces with contact layers, which in turn affect the degradation speed of the perovskites and interfaces.
Growing stable perovskites
Obtaining high-quality perovskite films with fewer defects has recently attracted extensive attention as a way to improve the stability of corresponding solar cells. Four articles in the Collection focus on this theme7,8,9,10. Two articles are dedicated to the use of additives to control crystallization and nucleation7,8. Where Eze et al.7 employ AgI as a nucleation promotor in the fabrication of CsPbIBr2 perovskites with increased grain size and reduced defects, Koech et al.8 improve the film morphology and the interfacial energy alignment by incorporating a small amount of polyethylene oxide in the hybrid FAPbI3 perovskite. In addition, efforts have also been devoted to the optimization of fabrication methods to suit industrial-scale production. For instance, Rezaee et al.9 developed perovskite precursor inks that are compatible with a scalable slot-die coating method at room temperature. They demonstrated the importance of the solvents, annealing temperature, air or inert gas blowing on the nucleation and growth mechanisms. On the other hand, a sequential spray deposition technique has been used to fabricate stacked triple cation perovskites with graded Cs content, enabling a wide absorption range and broadband photodetector applications10. Although this work does not focus directly on solar cells, it demonstrates that the careful control of the deposition process of perovskites opens up novel applications in other optoelectronic devices.
Curing the interfaces
The degradation of the interface of the perovskite-charge transport layer is another very challenging issue for the stability. In particular, the high efficiency cells often employ organic materials, Spiro-MeOTAD and PEDOT:PSS as charge transport layers5,6, which degrade severely and cause the J–V hysteresis and thus leads to rapid decrease of the efficiency of the solar cells. Two articles in this Collection propose to either replace the organic hole transport layer with an inorganic one (ZnCo2O4 nanoparticles), by Jheng et al.5 or to use an inert interlayer (polymer polyaniline) in between perovskite and electron transport layer, by Kim et al.6. Both approaches resulted in improved stability. It should be noted that the addition of a new layer or replacing an existing layer introduces more complexity to the device and may come at a cost of other desired properties. Further fundamental understanding of the functions and the impact of these new layers and adjustment of other adjacent layers may be required.
The field of perovskite solar cells has revolutionized the paths for development of energy materials. The simultaneous push for high-efficiency and quest into fundamental materials chemistry and physics results in an exciting and fast-developing field. It is our opinion that commercial perovskite solar cells can be seen in the near future only if improved performance can be translated to large area devices with greater stability, and this requires sound knowledge at the fundamental level of materials science. This research not only provides insights on which knobs to turn in the design of stable and efficient solar cells but also demonstrates the power of materials science to develop renewable energy technologies.
We thank all the authors for their contributions and hope that researchers working on perovskite solar cells and other photovoltaic technologies will enjoy reading this Collection. We also thank the editorial staff of Scientific Reports for their kind support.
References:
Cuzzupè, D. T. et al. Thermally-induced drift of A-site cations at solid–solid interface in physically paired lead halide perovskites. Sci. Rep. 12, 10241 (2022).
Ahmad, Z. et al. Consequence of aging at Au/HTM/perovskite interface in triple cation 3D and 2D/3D hybrid perovskite solar cells. Sci. Rep. 11, 33 (2021).
Minbashi, M. & Yazdani, E. Comprehensive study of anomalous hysteresis behavior in perovskite-based solar cells. Sci. Rep. 12, 14916 (2022).
Huang, J. Y. et al. Influences of dielectric constant and scan rate on hysteresis effect in perovskite solar cell with simulation and experimental analyses. Sci. Rep. 12, 7927 (2022).
Jheng, B. R. et al. Using ZnCo2O4 nanoparticles as the hole transport layer to improve long term stability of perovskite solar cells. Sci. Rep. 12, 2921 (2022).
Kim, D. I. et al. A high-efficiency and stable perovskite solar cell fabricated in ambient air using a polyaniline passivation layer. Sci. Rep. 12, 697 (2022).
Eze, V. O. et al. Inorganic cesium lead mixed halide based perovskite solar materials modified with functional silver iodide. Sci. Rep. 12, 7794 (2022).
Koech, R. K. et al. Effects of polyethylene oxide particles on the photo-physical properties and stability of FA-rich perovskite solar cells. Sci. Rep. 12, 12860 (2022).
Rezaee, E. et al. A route towards the fabrication of large-scale and high-quality perovskite films for optoelectronic devices. Sci. Rep. 12, 7411 (2022).
Amratisha, K. et al. Graded multilayer triple cation perovskites for high speed and detectivity self-powered photodetector via scalable spray coating process. Sci. Rep. 12, 11058 (2022).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher's note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Tao, S., Polavarapu, L. & Vivo, P. Perovskite photovoltaics: stability and scalability. Sci Rep 13, 4370 (2023). https://doi.org/10.1038/s41598-023-31512-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-023-31512-z