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Na3SbSe4−xS x as Sodium Superionic Conductors


Na based all-solid-state batteries are a promising technology for large-scale energy storage applications owing to good safety properties and low cost. High performance solid electrolyte materials with high room temperature ionic conductivity, good electrochemical stability and facile synthesis are highly desired for the commercialization of this technology. In this work, we report the synthesis and characterization of a novel fast Na-ion conductor, cubic Na3SbSe4, with an excellent ionic conductivity of 0.85 mS cm–1 at room temperature, and a group of S doped variants. Na3SbSe4 exhibits good compatibility with metallic Na and good stability in a wide voltage range. The application of this compound as solid electrolyte is demonstrated in all-solid-state Na-ion cells cycled at room temperature.


With the rapid global growth of electricity generation from renewable and clean energy sources such as solar and wind, the demand for stable, safe and low-cost energy storage solutions to flatten and level the fluctuations and intermittence in the electrical grid are becoming critical. Lithium-ion batteries (LIBs) are expensive for grid level storage due to the use of precious Li, Ni and Co metals. Sodium based electrochemical storage, such as Na-ion batteries (NIBs), are considered as a promising technology for grid storage owing to the high natural abundance and availability of sodium1,2,3,4,5,6,7. Sodium ion batteries with inorganic solid electrolyte, i.e. all-solid-state NIBs are particularly attractive in terms of safety, as no flammable organic liquid is used in the cell.

As the key component of all-solid-state NIBs, solid state Na-ion conductors with comparable room temperature conductivity as organic liquid electrolytes and good stability are very much desired. Yet in the past some super Na-ion conductors have been discovered, including β-alumina8 and NASICON type oxides9. However, the high grain boundary resistance in these materials commonly requires sintering at very high temperature, and high conductivity at room temperature is not easy to achieve. Recently the fast progress on chalcogenide-based alkali-metal-ion conductors have attracted a great deal of attention10,11,12. The promise has been well demonstrated first in Li-ion conductors. High ionic conductivities of 1–10 mS cm−1 at room temperature have been achieved in sulfides such as Li10GeP2S1213, Li7P3S1114, and Li9.54Si1.74P1.44S11.7Cl0.315, which have enabled a number of well performing all-solid-state LIBs. Promise has also been achieved in chalcogenide sodium-ion conductors. High conductivity was computationally predicted and then experimentally achieved in Na10MP2S12 (M = Si, Ge, and Sn)16,17. A cubic Na3PS4 phase with Na+ ion conductivity greater than 0.1 mS cm−1 at 25 °C was reported by Tatsumisago et al.18. The conductivity of Na3PS4 was further improved by introducing Si on P sites19 and by Cl doping on S sites20. High conductivities of \(\sim 1\,{{\rm{mScm}}}^{-1}\) were also reported in other compounds with similar structures, such as Na3PSe421,22, Na3SbS423,24 and Na3P1−xAs x S425. The high conductivity in these body-centered-cubic (bcc) based structures was proposed by Ceder et al.26 due to the existence of low barrier diffusion pathways alternatively connecting the tetrahedral and octahedral sites. It is interesting and important to explore if the diffusion barrier can be further lowered in this bcc structure by tuning other critical factors, such as the size of the tetrahedral and octahedral sites and the electronegativity and polarizability of the anions.

For this reason, Na3SbSe4 was chosen for our investigation. The crystal structure of Na3SbSe4 has been identified previously27 and it has the same space group \((I\bar{4}3m)\) as cubic Na3PS418. Compared with Na3PS4, the replacement of Se at S sites and Sb at P sites may effectively enlarge the unit cell, so as to have larger size of the intermediate sites connecting the octahedral sites, which may be beneficial for the diffusion of Na ions. In addition, bigger ionic radius and higher polarizability of Se2− and Sb5+ are also considered to be beneficial for the diffusion of alkaline ions, as demonstrated in Na3PSe422 and Na3SbS423. Although selenides are more expensive than sulfides and oxides, it is worth to explore their ionic conduction properties in the context of understanding the conductivity of this group of Na-ion conductors with cubic structures. In this work, cubic Na3SbSe4 was synthesized, characterized, and electrochemically tested. A group of Na3SbSe4−xS x samples were also synthesized and tested. An all-solid-state sodium-ion battery using Na3SbSe4 as the electrolyte was demonstrated for the first time with reasonably well performances at room temperature. The details of the experimental results are elaborated and discussed as follows.

Results and Discussion

Synthesis and structural characterizations of Na3SbSe4−xS x

Na3SbSe4 was successfully synthesized through calcination of the mixture of Na and Sb metals and Se powder in a sealed quartz tube at 650 °C for 18 hours. The crystal structure of Na3SbSe4 was characterized with X-ray diffraction (XRD). Figure 1a shows the synchrotron XRD pattern of as-synthesized Na3SbSe4 along with the Rietveld refinement results, which confirmed the formation of cubic Na3SbSe4 with trace amount of unknown secondary phase. A crystal structure model with space group \(I\bar{4}3m\) was used for the refinement. The refined cell parameters are listed in Table 1. The unit cell has a lattice parameter of a = b = c = 7.501(2) Å, which is larger than that of the isostructural compounds such as Na3PS428 (a = 6.9781 Å) and Na3PSe421 (a = 7.3094 Å). These results are also consistent with the parameters reported by Eisenmann et al.27.

Figure 1

(a) XRD pattern of Na3SbSe4 and the Rietveld refinement. (b) XRD patterns of Na3SbSe4−xS x . (Minor impurities of NaSbSe2 in S1 are labeled with arrows). (c) Cell volume variation with respect to S concentration in Na3SbSe4−xS x . (d) SEM images of as-synthesized Na3SbSe4 and corresponding EDX mapping of Na3SbSe4.

Table 1 Full pattern fitting refinement results for synchrotron X-ray diffraction patterns of Na3SbSe4−xS x compounds.

To further investigate the impact of unit cell size and anion polarizability on Na ion diffusion in this cubic structure, Na3SbSe4−xS x samples with substitution of the smaller S2− anion at the Se2− sites were also attempted and successfully obtained using the same synthesis method. Na3SbSe4−xS x samples with x = 1, 2, 3 and 4 are hereafter noted as S1, S2, S3 and S4, together with S0 noting Na3SbSe4 with no S doping. Figure 1b shows the synchrotron XRD patterns of S0 to S4. Peaks of minor impurities are observed in S1 at 2θ = 4.7° and 6.6°, which are from intermediate product NaSbSe2 and possibly due to the loss of S and Se during the heating process. With the increased S content from S0 to S4, all reflections shift toward higher two-theta angles, as more clearly defmonstrated in the zoomed area. This peak shifting indicates a gradual shrinkage of the unit cell volume, which is consistent with the substitution of Se2− by the smaller S2−. Obvious peak splitting such as at 2θ = 3.82°, 4.66°, 5.44°, 6.08°, etc. is observed in S4, which indicates Na3SbS4 has a tetragonal unit cell, while others in the series are all cubic. Details of refinement results for S1, S2, S3 and S4 are also listed in Table 1. The refinement results confirmed that S1, S2 and S3 also have \(I\bar{4}3m\) space group with a = 7.420(5) Å, 7.346(4) Å and 7.271(7) Å, respectively, while S4 was refined with a tetragonal space group \(P\bar{4}{2}_{1}c\) with a slightly elongated c-axis (a = 7.163(3) Å, c = 7.295(3) Å and c/a = 1.018). The cell volume of the Na3SbSe4−xS x phases is shown in Fig. 1c and a linear decrease as the function of S concentration is observed.

Scanning electron microscope (SEM) was used to investigate the morphology of Na3SbSe4−xS x samples. Figure 1d shows the scanning electron microscope (SEM) images for the synthesized Na3SbSe4 and the elemental mapping with energy dispersive X-ray (EDX) spectroscopy. SEM images and elemental mapping for S1–S4 were shown in Figure S1 in the supplementary information. For all the compounds in this solid solution series, the particles show irregular shapes and a relatively wide distribution of particle sizes. This inhomogeneity in particle size and morphology is plausibly due to the melting-quenching process in synthesis. The distribution of Na, Sb and Se elements in the EDX mapping on the other hand confirms the uniform formation of Na3SbSe4 with no evident element or phase segregations. The elemental mappings for S1–S4 samples also show uniform distribution throughout the selected areas, indicating a series of solid-solution compounds in the designed system have been successfully obtained.

Ionic conductivity of cubic Na3SbSe4 and Na3SbSe4−xS x system

Powder of the samples was pressed into pellets and analyzed with electrochemical impedance spectroscopy (EIS). The Nyquist plots of the impedance for Na3SbSe4 at different temperatures are shown in Figure S2. The impedance spectra in the high-frequency region show a small semicircle, suggesting that the grain boundary resistance is low and the overall resistance is dominated by the bulk conductivity. This feature is similar to previously reported sulfide conductors, which typically have lower grain boundary resistance than oxides18,21. Based on the total resistance of Na3SbSe4 including the bulk and grain boundary resistances and the dimensions of the pellet, Na+ conductivity (σ) of the synthesized Na3SbSe4 was calculated to be 0.85 mS cm−1 at room temperature, which is higher than those of cubic-Na3PS418, Si-doped19, Sn-doped16,28, and Se-doped22 cubic Na3PS4 phases. This conductivity is also comparable to those of recently reported sulfides such as Na3SbS423 and Na3P0.62As0.38S425. This high ionic conductivity can be explained by the large unit cell of Na3SbSe4 and the high polarizability of Se2−, which lowers the electrostatic binding energy and weakens the attraction between Na+ and the tetrahedron of [SbSe43−]29,30.

S0–S4 samples with different S content and therefore different unit cell sizes were all tested for ionic conductivity at variable temperatures from 30 °C to 100 °C. Arrhenius plots of the samples are shown in Fig. 2a. The log(σ) versus 1/T curves of all samples show good linearity, indicating no phase transition or ordering change in this temperature range. Based on the slope of the linear fitting curve, the diffusion activation energy of Na3SbSe4 is calculated to be 0.193 eV using the equation σ = Aexp(−E a /k b T), where A is the pre-exponential parameter, E a is the activation energy and k b is the Boltzmann constant. This activation energy is lower than most of those previously reported for sulfide-based Na ionic conductors20,21,22,23,24,25, which ranges from 0.20–0.26 eV. With a lower activation energy, this solid-state electrolyte can maintain a relatively high conductivity at low temperature, which is significantly advantageous over organic liquid electrolytes and benefits applications in low temperature environments.

Figure 2

(a) Arrhenius conductivity plots of the Na3SbSe4−xS x . (b) the activation energies calculated from the slopes.

The linear fitting of conductivities of S1–S4 are also shown in Fig. 2a and the calculated activation energies are shown in Fig. 2b. With the increased S concentration in the solid solution phases, a gradual increase of activation energy can be observed for Na+ migration. This trend is similar to what was observed in other Se-S solid solution ionic conductors30,31, resulted from a softer lattice with more polarizable Se2−. The values of activation energies are listed in the Table S1 in supplementary information, together with the ionic conductivities of the compounds at room temperature.

Comparing the conductivities of S0–S4 samples in the variable temperature tests, it can be seen that with increased concentration of S in the solid solution, the conductivity first decreases from S0 to S2, and then increases from S2 to S4, with the two end members showing the highest conductivity. Since the sizes of the unit cell from S0 to S4 linearly increases, as shown in Fig. 1c, it is clear that the diffusivity is not solely controlled by the averaged size of the diffusion channels. The non-monotonic trend of conductivity was also reported by Yu et al. in the solid solution series of Na3P1−xAs x S4. The highest conductivity of this series of compounds was obtained in an intermediate composition of Na3P0.62As0.38S425. This effect was explained by Yu et al. that the dual effects of lattice expansion and a shorter Na-S bond length caused by the increased As concentration together resulted in the lowest diffusion barrier in this tetrahedral structure at the composition of As = 0.38. However, in the case of Na3SbSe4−xS x series, the two end members are not in exactly the same structure. Na3SbSe4 is in cubic with an \(I\bar{4}3m\) space group while Na3SbS4 is tetragonal \(P\bar{4}{2}_{1}c\). The larger unit cell in Na3SbSe4 can have symmetric low barrier diffusion pathways along all three directions among Na ions sitting at 6b sites. On the other hand, although the unit cell size of Na3SbS4 is smaller, the tetragonal distortion plausibly provides similarly low barrier pathways along ab planes in the price of having higher barriers along c-axis32. Despite the lower symmetry of the tetragonal structure of S4, it shows high conductivity comparable to S0, likely due to the shorter Sb-S bonds compared with Sb-S/Se bonds in mixed anion compounds, which result in weaker Li-(S/Se) interactions and therefore facilitate faster Li diffusion. Ionic conductivity is influenced by many factors, such as structure symmetry, lattice softness, sizes of diffusion channels, bond lengths, defects, etc. At this point, it is difficult to differentiate what is the predominate factor that increases the conductivity of S4. It may be ascribed to the change of the bond length and size of the diffusion channels caused by the tetragonal distortion. As for S1–S3 samples with intermediate S concentrations and cubic structure, their smaller unit cell size than that of Na3SbSe4 and their lack of tetragonal distortion as in Na3SbS4, are likely to be the reasons for their lower conductivities than both end members.

It should also be noted that the room temperature conductivity of S4 (Na3SbS4) in this work is lower than the values reported in the recent works by Wang et al.23 and Zhang et al.33. This may be due to the different starting materials and synthesis procedures, which may introduce slight variations in amorphous phase composition, particle size, local ordering and grain boundary conditions that can have non-negligible impacts on the conductivity measurement. An additional ball-milling step prior to the impedance measurements was used in Zhang’s work to increase the conductivity of the pressed pellet. However, in our tests the ball-milled samples showed lower conductivity than as-synthesized product. This again indicates that the conductivity measurement is sensitive to many factors other than bulk phase composition and that there may still be room to further optimize and explore this series of Na3SbSe4−xS x compounds for even higher conductivities. Another important issue that was not explored in current work is the local ordering of Se and S. In our model, a random mixing of Se and S at 8c site was assumed and it agrees very well with the refinement. However, due to the insensitivity of XRD for local structure, local ordering of Se and S cannot be excluded at this point. The local ordering may create higher (or lower) hopping barriers therefore to impact the overall conductivity. To address these issues, further investigation with other techniques, such as neutron diffraction, are undergoing in our group to reveal more information of the local ordering.

Electrochemical properties and performance in all-solid-state batteries

The electrochemical stability of Na3SbSe4 was evaluated with cyclic voltammetry (CV) of a Na | SE | Sn cell at room temperature, with as-synthesized Na3SbSe4 as the solid electrolyte (SE), metallic Na as the reference and counter electrode, and Sn as the working electrode. In the scan from −0.5 V to 5 V at a rate of 5 mV/s, as shown in Fig. 3a, no significant current due to electrolyte decomposition is detected at high voltage. Cathodic and anodic currents are only observed near 0 V, corresponding to sodium plating and stripping. XRD patterns of Na3SbSe4 before and after CV tests are shown in Figure S3 in the supplementary information. No extra peak other than from residue Sn is observed after the CV cycles, suggesting good compatibility with metallic Na and good electrochemical stability in a wide voltage window for this material.

Figure 3

(a) Cyclic voltammetry curves of Na3SbSe4. (b) Charge–discharge curves of all-solid-state Na-Sn| Na3SbSe4| TiS2 cell cycled at room temperature.

All-solid-state Na-ion battery Na-Sn|SE|TiS2 was fabricated by using synthesized Na3SbSe4 as solid electrolyte (SE), TiS2-SE mixed powder as cathode and Sn-Na alloy as anode. The cell was cycled at room temperature under a current density of 0.01 mA cm−2 (0.015 C based on theoretical capacity of 239 mAh/g for TiS2) within the voltage range from 0.9 V to 2.6 V. The charge–discharge curves were shown in Fig. 3b. The cell exhibits discharge and charge capacities of 90 mAh g−1 and 64 mAh g−1, respectively, in the first cycle. It is worth noting that the voltage profiles in solid state batteries are commonly more sloping and featureless than those in liquid electrolyte cells, due to the lower conductivity of the solid electrolyte itself and the sluggish ionic transport at the solid-solid interfaces. Similar sloping voltage curves of TiS2was also reported by other attempts of all solid state Na-ion batteries, such as work by Ong et al.20. The cycling curves and reasonable capacities demonstrated that Na3SbSe4 can enable all-solid-state Na-ion batteries at room temperature and the promise of the selenide-based solid electrolytes. The subsequent cycling of the cell showed relatively fast decay in capacity as the cell was far from optimized in pressure, ratio of materials and interface treatment. Although no visible degradation phases were detected by XRD, interface reactions did take place, indicated by the significantly increased impedance and a fast decay of the capacity. The interface degradation and the compatibility and stability between the electrolyte and the electrode will need further investigation. Further improvement calls for not only the optimization of the cell fabrication and test conditions, but also more fundamental understanding on the mechanical and chemical degradation of solid state batteries.


In this work, a new Na ion conductor, cubic Na3SbSe4 and a group of S doped solid solution phases have been synthesized and demonstrated with high conductivities up to 0.85 mS cm−1 at room temperature, which is among the highest conductivities reported in chalcogenide-based Na-ion conductors. Structure characterizations reveal that the large unit cell size may be the key factor for higher conductivity than cubic Na3PS4. Na3SbSe4 also showed excellent electrochemical stability and enabled the cycling of an all-solid-state Na-ion battery at room temperature. This work will open opportunities in designing new chalcogenide ionic conductor and developing new Na-based all-solid-state batteries.


Synthesis of Na3SbSe4−xS x

Na3SbSe4 compounds were synthesized by solid-state reaction. Starting materials including Na metal (99.8%, Sigma Aldrich), Sb (99.5%, Alfa Aesar) and Se (99.99%, Sigma Aldrich) were weighed and mixed with stoichiometric ratio. Se was used with 10% excess to compensate the loss during heating. The mixture was loaded into a quartz tube in an Ar-filled glove box, and then the tube was sealed under vacuum. The tube has an inner diameter of 14 mm and a length of 8 inches. Typically, each tube contained 1 g of mixed starting materials per batch. The tube was then heated to 650 °C with a 3 °C/min ramp in a box furnace, dwelling for 18 h, and quenched on a copper plate in the ambient atmosphere. Then the tube was moved into the glove box and the product powder was obtained through hand grinding with mortar and pestle after breaking the tube. Na3SbSe4−xS x (x = 1, 2, 3, 4) samples were synthesized with the same protocol by replacing stoichiometric amount of Se by S (99.5%, Alfa Aesar) in the starting materials, also with 10% excess.


Crystal structures of the obtained samples were analyzed first by X-ray diffraction (XRD) with a D8 Advance X-ray Diffractometer (Bruker) equipped with a strip detector and a Molybdenum tube [λ K α1 = 0.7093 Å]. The powder samples were scanned in an air-tight sample container covered with a Kapton tape to avoid exposure to air and moisture. The samples were also investigated in sealed capillaries with synchrotron X-ray diffraction at beam line 17-BM at the Advanced Photon Source (APS) at the Argonne National Laboratory (ANL) and at 28-ID-2 at the National Synchrotron Light Source II at Brookhaven National Laboratory. Rietveld refinement was performed using the synchrotron XRD data with the EXPGUI suite of GSAS code34. Hitachi SU8230 Scanning Electron Microscope (SEM) was used to characterize the morphology and elementary distribution of the as-synthesized samples. Energy-dispersive X-ray spectroscopy (EDX) was conducted to analyze the element distribution using Oxford EDS detector with 10 kV accelerating voltage, high probe current, and 30 μA emission current.

Electrochemical Tests

AC impedance measurements were conducted using a Bio-Logic VMP3 impedance analyzer in the frequency range from 1 MHz to 0.5 Hz with a voltage amplitude of 100 mV. The pellets for the measurements were cold-pressed from as-synthesized powders at 100 MPa pressure in an acrylic tube with an inner diameter of 0.5 inch. Two stainless-steel rods were used as blocking electrodes. Temperature-dependent conductivity measurements were performed from room temperature to 100 °C with two stainless-steel rods as electrodes and a heatable pressing die with a temperature controller. Cyclic voltammetry of Na|Na3SbSe4|Sn cell was measured with Sn as the work electrode and Na metal as the counter and reference electrode.

All-solid-state Na-ion battery was fabricated using TiS2 (99.9%, Sigma-Aldrich) as the cathode material, Na3SbSe4 as the solid electrolyte (SE), and a Na-Sn alloy as the anode. The composite cathode consists of TiS2 active material and the synthesized SE powder in a weight ratio of 2:3. They were well-mixed with hand milling in an agate mortar. About 10 mg of mixed cathode powder was pressed on one side of the SE pellet (200 mg) by applying a pressure of 50 MPa in an acrylic tube with an inner diameter of 0.50 inch between two stainless-steel rods. Then a Sn foil and a Na foil were successively pressed onto the other side of the bilayer assembly by applying a pressure less than 10 MPa to form a tri-layer cell, with two stainless steel rods as the current collectors. All the fabrication processes were conducted in an Ar-filled glove box. Then the whole cell was sealed with Parafilm and Teflon tape and cycled in ambient environment. The cell was cycled galvanostatically at a current density of 0.01 mA cm−2 within the voltage window from 0.9 V to 2.6 V using an Arbin BT2043 battery cycler at room temperature.

Data availability

All data analyzed during this study are included in this published article and the Supplementary Information file.


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This work was financially supported by the new faculty start-up fund of Georgia Institute of Technology. The synchrotron work was in part supported by NSF under grant number 1410936 and 1605692. The use of the Advanced Photon Source and the National Synchrotron Light Source II were supported by the U.S. Department of Energy, Office of Science, through the general user programs.

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H.C. and S.X. designed the study, proposed the mechanism, and wrote the manuscript. S.X. conducted most experiments. Z.L. collected synchrotron XRD data from APS. Z.L. and H.R. participated in the analysis of electrochemical data. H.W. and M.M. provided initial technical support for the synthesis of the material and the fabrication of the batteries. H.C. and S.X. analyzed most of the data. All authors reviewed the manuscript.

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Correspondence to Hailong Chen.

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Xiong, S., Liu, Z., Rong, H. et al. Na3SbSe4−xS x as Sodium Superionic Conductors. Sci Rep 8, 9146 (2018).

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