Abstract
Investigating in detail the physics of energy filtering through a single planar energy barrier in nanostructured thermoelectric generators, we reinforce the non-trivial result that the anticipated enhancement in generated power at a given efficiency via energy filtering is a characteristic of systems dominated by incoherent scattering and is absent in ballistic devices. In such cases, assuming an energy dependent relaxation time τ(E) = kE r, we show that there exists a minimum value r min beyond which generation can be enhanced by embedding nanobarriers. For bulk generators with embedded nanobarriers, we delve into the details of inter sub-band scattering and show that it has finite contribution to the enhancement in generation. We subsequently discuss the realistic aspects, such as the effect of smooth transmission cut-off and show that for r > r min , the optimized energy barrier is just sufficiently wide enough to scatter off low energy electrons, a very wide barrier being detrimental to the performance. Analysis of the obtained results should provide general design guidelines for enhancement in thermoelectric generation via energy filtering. Our non-equilibrium approach is typically valid in the absence of local quasi-equilibrium and hence sets the stage for future advancements in thermoelectric device analysis, for example, Peltier cooling near a barrier interface.
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Introduction
An important direction in the context of electronic engineering to enhance the performance of nanostructured thermoelectric generators1,2,3,4,5,6,7,8,9,10, is to utilize the physics of electronic energy filtering through nanoscale barriers and nanoinclusions11,12,13,14,15,16,17,18,19,20,21,22,23,24. To put it simply, energy filtering aims to provide a unidirectional flow of electrons from the hot contact to the cold contact while prohibiting the reverse flow of electrons, which occurs typically when lower energy electrons are scattered off due to the interface potentials9, 20,21,22, 25. In the case of semiconductors, there is the flexibility of varying the equilibrium Fermi energy via appropriate doping. In such a case, a ‘good thermoelectric’ as schematized in Fig. 1(a) is ideally achieved by tuning the Fermi energy near the conduction band edge so that the resulting transport is devoid of electrons below the Fermi energy. This off-resonant conduction typifies good thermoelectric behavior and has been the object of several initial proposals1,2,3, 5, 8. Such an approach however leads to a drastic reduction in the conductivity while enhancing the Seebeck coefficient. We will refer this as Approach A. Energy filtering, as schematized in Fig. 1(b), on the other hand, strives to achieve a desirable performance via engineering nano-barriers12, 15, 16, 18,19,20,21,22,23, 26,27,28,29. In this case, the Fermi level resides inside the conduction band and the principal aim is to enhance the Seebeck coefficient by reflecting low energy electrons from the energy barrier. This approach also promotes a unidirectional flow of electrons from the hot contact to the cold contact. We will refer to this as Approach B. Ideally, we can say that energy filtering is successful if the latter yields a better performance than the former, especially with a thinner barrier.
While recent works throw some light on this topic18,19,20,21,22,23,24, 26,27,28,29, we believe that a few aspects about energy filtering require attention: (1) Most of the current work is based on a linear response analysis of the Seebeck coefficient despite the fact that the regions in the vicinity of the barrier are strongly out of equilibrium. Linear response analysis typically masks the crucial transport physics that determines the delivered terminal power output and efficiency of the generator30,31,32,33,34,35,36. (2) The role of various scattering mechanisms contributing to the physics of energy filtering is still unclear. (3) A generalized picture of the physics of energy filtering independent of various material parameters is also unclear. In this paper, our focus is hence to develop a general and intuitive understanding of energy filtering and to systematically point out the role played by various scattering mechanisms. Besides that our work uses the non-equilibrium Green’s function method which accounts for the non-equilibrium nature of transport and directly evaluates the power and efficiency to provide an overall picture of the device operation.
Our goal here is to present important clarifications on the aforesaid aspects. As a principal contribution, we clarify that the power generation enhancement via energy filtering in both nanowire and bulk devices is dependent on a specific property of the scattering mechanism, which we call the order of scattering. It is first shown that for the ballistic case, both Approach A and Approach B lead to an identical performance and hence energy filtering is of limited use. On the other hand, in the diffusive limit for both nanowire and bulk thermoelectric generators, it is shown that the type of scattering mechanism is the principal deciding factor in order to gauge the advantage gained via Approach B. Assuming an energy dependent relaxation time τ(E) = kE r, we then show that there is a minimum value of the exponent r (termed r min ), beyond which energy filtering via Approach B leads to a better enhancement in the generated power compared to Approach A. For such cases, the generated power at a given efficiency increases with an increase in the height of the embedded energy barrier. In addition, we show that for bulk thermoelectric generators with embedded energy barriers, electronic scattering between the high energy and low energy sub-bands enhances the generated power. We also discuss some practical aspects, like the adverse effects of a smooth transmission cut-off due to finite barrier width and investigate further to conclude in case of r > r min , the thermoelectric performance peaks when the energy barrier is made just sufficiently wide enough to scatter off the low energy electrons.
We utilize the non-equilibrium Green’s function (NEGF) formalism to deduce various currents, following which a direct calculation of power and efficiency is performed using the following equations:
where I C is the charge current, I Qe is the electronic heat current at the hot contact and V is the applied voltage assuming a voltage controlled set up described in recent literature30,31,32,33,34,35,36. Since thermal conductivity due to phonon doesn’t vary significantly with the method employed to improve the thermoelectric performance (that is, Approach A or Approach B), we have simplified our calculations in (2) by neglecting the degradation in efficiency due to phonon heat conductivity. We consider thermoelectric generators in which the active regions are smaller than the energy relaxation lengths18 such that the energy current is almost constant throughout the device region. This assumption simplifies the discussion to a great extent and aids in understanding the physics of energy filtering from an intuitive mathematical viewpoint. For the purpose of the simulations, we use the band parameters of the Δ2 valley of lightly doped silicon37 with a longitudinal effective mass, m l = m e , and a transverse effective mass, m t = 0.2 m e , m e being the mass of a free electron. The transverse geometries of the device region considered here include bulk, where the transverse extent is infinite and nanowires, where the transverse extent consists of only one sub-band. A schematic of the generic device structure used is shown in Fig. 1(c) for nanowire generators and Fig. 1(d) for bulk generators. The band diagram schematic of our energy filtering based thermoelectric generator is shown in Fig. 1(e). It consists of a 20 nm long doped semiconductor thermoelectric generator with an embedded Gaussian energy barrier (U).
where z 0 = L/2 is the the mid-point of the device region, L being the total length of the thermoelectric generator. The leads or contacts connected to the 20 nm long device in Fig. 1(c) and (d) are assumed to be reflection-less macroscopic bodies of infinite cross-section, in equilibrium with their respective lattice temperatures and electrochemical potentials (quasi-Fermi levels). For simulation, we use a voltage controlled model, shown in Fig. 1(f), where by varying the bias voltage continuously a the current flow is emulated, to generate a set of points in the the power-efficiency (η) plane33, 38 for a particular position of the equilibrium electrochemical potential (or equivalently the Fermi energy) μ 0.
In order to assess the relative efficacy of power generation due to energy filtering and compare the relative benefit of Approach B compared to Approach A, we now define a metric called the filtering coefficient (λ) defined as
where P A (η) and P B (η) are the maximum power densities obtained at efficiency η via Approach A and Approach B respectively, while P A (η) and P B (η) are taken along the operating line of our device35. It should be noted that although we use some specific parameters for simulation, the qualitative discussion as well as the trends noted in the simulated results are general and are valid irrespective of material specific parameters for a particular scattering mechanism.
Results
We now perform a detailed analysis of power generation for Approach A and Approach B using nanowire and bulk thermoelectric generators. The power-efficiency curves are plotted in the η-P plane for several value of the reduced Fermi energy η f defined as:
E b being the height of the energy filtering barrier in case of Approach B. In all the discussions to follow, the efficiency of operation will be evaluated relative to the Carnot efficiency given by η C = 1 − T C /T H .
Energy filtering in the ballistic limit
We start by considering nanowire and bulk thermoelectric generators in the ballistic or coherent limit. We plot, in Fig. 2, the power density versus efficiency curves for a range of η f for both Approach A and Approach B. In particular, Fig. 2(a–d) depict power generation characteristics for single-moded nanowire generators while Fig. 2(e–h) depict the same for bulk generators. For both nanowire and bulk generators, the maximum power density as well as the power density at a given efficiency for Approach B increase with the width of the energy barrier. The peak performance in this case is achieved for a perfect energy filter with sharp transmission cut-off. This peak performance in Approach B is identical with that of Approach A.
The corresponding filtering coefficients for nanowire and bulk systems, plotted in Fig. 2(d) and (h) respectively, decrease in the high efficiency regime which also corresponds to a high value of η f . This trend can be attributed to the smooth transmission cut-off at energies close to the barrier height E b (details in Supplemetary material). We hence conclude that in the ballistic limit, for both nanowire or bulk thermoelectric generators, the maximum power generation at a given efficiency is achieved via Approach A. This makes energy filtering via embedded nano barriers of very limited use in the ballistic limit. Hence, in the ballistic limit, when considering generators shorter than the mean free path, energy filtering with a single barrier (Approach B) does not provide any additional benefit over the traditional good thermoelectric generator (Approach A).
Energy filtering in the diffusive limit
Energy filtering with acoustic phonon scattering
We turn our attention to the diffusive limit with the inclusion of acoustic phonon scattering and plot in Fig. 3, the filtering analysis of the devices considered previously. In particular, Fig. 3(a–c) demonstrates the generation characteristics for single-moded nanowires and Fig. 3(d–f) demonstrates the power generation characteristics for bulk generators. Contrary to the ballistic limit, acoustic phonon scattering ensures an improved thermoelectric performance in Approach B rather than Approach A. To explain the unusual trends noted in Fig. 3, specifically, the increase in filtering coefficient λ for single-moded nanowire generators with increase in energy barrier height E b (Fig. 3(c)), we use the parameter Υ(E), which is identical to the Boltzmann transport coefficient (details given in supplementary information):
where v z (E), τ(E) and D 1D (E) represent the electronic transport velocity, relaxation time and the 1-D density of states respectively. In case of perfect filtering or sharp transmission cut-off, Approach B theoretically ensures an enhanced performance compared to Approach A, with the relative enhancement being an increasing function of the energy barrier height E b , provided the parameter Υ is an increasing function of energy. For bulk thermoelectric generators, under the assumption of uncoupled sub-bands and sharp transmission cut-off, we can define a parameter \(\zeta (E)=\frac{({E}^{\frac{3}{2}}-{E}_{b}^{\frac{3}{2}}){E}^{r}}{\{{(E-{E}_{b})}^{r+\frac{3}{2}}\}}\) with E > E b to access the relative enhancement in generated power via Approach B compared to Approach A (details given in supplementary information). It can be shown that for acoustic phonon scattering, the parameter ζ > 1, which implies an enhanced generated power via Approach B (details given in supplementary information).
We thus note the non-trivial result that indicates an improvement of thermoelectric performance via energy filtering (Approach B) in the presence of acoustic phonon scattering. Energy filtering is thus beneficial for devices dominated by “acoustic phonon scattering”-like mechanisms \(\tau (E)\propto {E}^{\frac{1}{2}}\) for nanowires and \(\tau (E)\propto {E}^{-\frac{1}{2}}\) for bulk) when they are longer than the mean free path. We now explore what happens for the higher order scattering mechanisms.
Energy filtering with higher order scattering mechanisms
A scattering mechanism, with relaxation time given by τ(E) = k 0 E r, is said to be of order ‘−r’, with a lower value of the exponent r denoting a higher order scattering process. For acoustic phonon scattering, the relaxation time is given by \(\tau (E)\approx {k}_{o}{E}^{\frac{1}{2}}\) in the case of nanowires and \(\tau (E)\approx {k}_{o}{E}^{-\frac{1}{2}}\) in the bulk case. Then, the question arises, what is the effect of r on the filtering coefficient? Another related question is, if there is a minimum value of r, termed r min , beyond which energy filtering viz. Approach B ensures an enhanced performance compared to approach A?
As already discussed, for single-moded nanowires, Approach B always ensures an enhanced thermoelectric performance when the parameter Υ(E) is an increasing function of energy (details given in supplementary information), provided that energy filtering is perfect. Hence, in the case of non-parabolic bands or in the case where different scattering mechanisms dominate, the height of the energy barrier, for optimum performance, should be approximately identical to the energy at which the rate of increase of \(D\tau {v}_{z}^{2}\) saturates. The optimum doping for such a case should fix the Fermi level close to the energy barrier height depending on the desired efficiency. The rate of increase of Υ(E) with energy determines the relative advantage gained via Approach B, that is, for the same energy barrier height with τ(E) = kE r and parabolic dispersion, filtering coefficient at a given efficiency is an increasing function of r. For a single-moded nanowire, \({v}_{z}^{2}(E)=\frac{2E}{{m}_{l}}\) and \(D(E)=\frac{1}{\hslash \pi }\sqrt{\frac{{m}_{l}}{2E}}\), implying \({r}_{min}=-\frac{1}{2}\). For r < r min , Approach A leads to an optimized power generation degrading the filtering coefficient less than unity. An analytical calculation of r min for bulk generators is not trivial due to inter sub-band coupling. However, assuming uncoupled sub-bands and perfect energy filtering, for E b = 150 meV, it can be shown that Approach B is advantageous for \(r\gtrsim -0.7\). (see supplementary information). We hence note that in case of devices longer than the mean free path, the benefit obtained from energy filtering decreases as the order of the dominating scattering mechanism increases.
We plot, in Fig. 3(g) and (h), the filtering coefficient (λ) versus efficiency (η/η C ) for nanowire and bulk generators affected by scattering mechanisms of order higher than that of acoustic phonon scattering. The filtering coefficient vs. efficiency plots in Fig. 3(h) indicate that for bulk thermoelectric generators, the calculated upper bound r min = −0.7 under the simplified assumption of uncoupled sub-bands is indeed an overestimate. To explain this behavior, we thus need to delve into the details of inter sub-band scattering and understand its contribution to power generation.
Role of intermode coupling in bulk generators
We now uncover the role of coupling between the various transverse sub-bands in the bulk case, in particular, the role of incoherent scattering in enhancing the filtering coefficient. Conservation of lateral momentum in the ballistic limit implies that, electrons from the high energy transverse sub-bands are reflected from the energy barrier39,40,41,42,43 and hence cannot contribute to the generated power. However, in the diffusive limit, transverse sub-bands are coupled which may result in an electronic flow between them. The net scattering current between the sub-bands is however dictated by the relative non-equilibrium conditions of the respective sub-bands and will henceforth be referred to as the intermode coupling current. Such a flow of the intermode coupling current between the sub-bands occurs in the region between the hot contact and the barrier interface. This current subsequently flows to the cold contact and can significantly enhance the generated power in the case of energy filtering.
The situation described above is schematically illustrated in Fig. 4(a) and (b) considering electronic transport through two sub-bands with transverse momentum ħk l and ħk h . In the classical limit the approximate transmission cut-off of these modes are \({E}_{l}^{max}\) and \({E}_{h}^{max}\) respectively. Incoherent scattering can drive an electron (which would otherwise be reflected from the energy barrier) with energy \({E}_{l}^{max} < E < {E}_{h}^{max}\) from the h th sub-band to the l th sub-band and contribute to the current flow. For bulk thermoelectric generators the density of sub-bands \(M(E)=\frac{{m}_{t}}{2\pi {\hslash }^{2}}(E-{E}_{C})\) increases with energy resulting in an increase in the intermode coupling current with the energy barrier height.
We plot in Fig. 4(c), the energy resolved intermode coupling current per unit area at the maximum power for various barrier heights taking acoustic phonon scattering into account. The electronic current flows out (positive value) of the higher energy sub-bands into (negative value) the lower energy modes. We plot in Fig. 4(d–f), the different current profiles at the maximum power at different voltage biases. The total current per unit area (I Total ) at the cold contact consists of two parts: (a) the direct current (I Direct ) that flows per unit area from the hot contact to the cold contact without changing sub-bands (b) the intermode coupling current I Intermode that flows per unit area from the higher energy sub-bands to the lower energy sub-bands between the hot contact and the energy barrier interface and consequently flows toward the cold contact. Figure 4(e) demonstrates that I Direct remains almost unchanged with an increase in the height of the energy barrier. Hence, the increase in the generated power with the height of the energy barrier in this case is attributed to an increase in I Intermode as shown in Fig. 4(f). Such an enhancement in generated power due to intermode coupling current is dependent on incoherent scattering and is absent in the ballistic limit.
Optimizing the filtering coefficient in the diffusive limit
In this section, we reinforce that in the diffusive limit for r > r min , the filtering coefficient tends to maximize when the barrier width is ‘just sufficient’ to block an appreciable reverse flow of electrons from the cold contact to the hot contact, a wider barrier than the optimized one being detrimental to the thermoelectric performance.
Dependence of the filtering coefficient on device length
For both nanowire and bulk generators with r > r min , Υ(E) is minimum at the top of the energy barrier when energy filtering viz. Approach B is employed. Hence, Approach B is most useful when the device region between either of the contacts and the barrier interface is much longer compared to the width of the energy barrier. Such a design facilitates most of the electronic transport in the region where the kinetic energy and Υ(E) are very high. This effect is demonstrated in Fig. 5(a) where it is shown that for the same energy barrier width, the filtering coefficient increases for longer generators.
Optimized energy barrier for maximizing the filtering coefficient
While it is obvious that a very thin energy barrier adversely affects the thermoelectric performance due to reverse flow of electrons, a very wide barrier is also detrimental to the thermoelectric performance due to decrease in the parameter Υ(E) at the top of the barrier resulting in an overall decrease in the transmission probability (details in supplementary material). This phenomenon is demonstrated in Fig. 5(b) taking incoherent (acoustic phonon) scattering into account where it is shown that barriers wider than 2.7 nm are detrimental to the thermoelectric performance.
Hence, we conclude that for Approach B with r > r min , the optimum energy filtering barrier is ‘just sufficiently wide’ to block an appreciable reverse flow of electrons from the cold contact to the hot contact, the suitable generator length for employing energy filtering being at least a few times greater than the optimum barrier width.
Impact of phonon heat conduction
So far, in the above discussion, we have neglected the effect of phonon heat conduction. In realistic thermoelectric generators, however, the efficiency of operation is often limited by phonon or lattice heat conduction44,45,46,47,48,49 if
where I Qp and I Qe are the heat currents due to phonon and electronic conduction respectively at the hot contact. The efficiency of operation in this case is given as:
The expressions (5) and (6) naturally question the validity of our investigation where I Qp is neglected.
Hence, we extend our proposed theory to the case where heat conduction is dominated by lattice heat conductance. In the case where I Qpp ≫ I Qe , the operating point with maximum power becomes identical to the operating point with maximum efficiency. In this case, we define two parameters which may be used to gauge the relative advantage gained via Approach B compared to Approach A.
where \({P}_{A\mathrm{\ (}B)}^{MAX}\) and \({\eta }_{{P}_{MAX}}^{A\mathrm{\ (}B)}\) are the maximum power generated via Approach A(B) and the efficiency at the maximum generated power in case of Approach A(B) respectively.
We plot, in Fig. 6(a) and (b), ρ vs. r for nanowire and bulk thermoelectric generators respectively in the limiting case of I Qp ≫ I Qe for various heights of the energy filtering barrier. ρ or ν increase monotonically with an increasing value of r. In case of perfect filtering in nanowires, Approach B ensures an enhanced performance compared to Approach A in terms of maximum power generation when Υ(E) is an increasing function of energy. For such cases, both ρ and ν increase with the height of the energy barrier. This general trends in ρ or ν for nanowires are also manifested in bulk generators for the case I Qp ≫ I Qe . We hence note that preceding discussion on energy filtering is valid even in the limit where lattice heat conduction dominates.
Discussion
So far, we have discussed the general conditions under which energy filtering enhances generated power in nanoscale and bulk thermoelectric generators. To demonstrate such conditions we have assumed smooth Gaussian barriers. However our discussion is valid for energy filtering achieved via other means, for example, embedding nanoinclusions randomly throughout the generator. Although disproven theoretically21, such nanoinclusions are generally thought to create resonant states which can further aid in enhancing the efficiency of thermoelectric generation. In realistic devices, a number of electronic scattering mechanisms may be dominant such that the relaxation time of the electrons is a polynomial function of kinetic energy (E).
We split the contributions r i into two groups (a) r i ≥ r min (b) r i < r min . With energy filtering, thermoelectric power generation is enhanced in the presence of the scattering mechanisms satisfying r i ≥ r min while the same is degraded in the presence of the scattering mechanisms satisfying r i < r min . In a case where both types of scattering mechanisms are dominant or the energy band is non-parabolic, there is an optimum height of the energy filtering barrier at which the enhancement of generated power is maximum in the case of Approach B20. The optimum barrier height in such a case should approximately be identical to the energy at which the parameter \(D\tau {v}_{z}^{2}\) starts to saturate, the optimum position of the Fermi energy being in the range of a few k B T with respect to the top of the energy barrier depending on the desired efficiency. Our discussion in this paper, although general, should provide a qualitative idea on the physics of the enhancement in generated power via energy filtering in the ballistic and the diffusive limit and hence should provide general optimization guidelines for thermoelectric generators with material specific properties.
Methods
In order to perform the transport calculations to be presented, we employ the NEGF transport formalism under the self-consistent Born approximation40, 50 to incorporate scattering in the device region (details given in the supplementary material). We employ the single particle Green’s function \(G(\vec{{k}_{m}},E)\), for each transverse sub-band m 40, evaluated from the device Hamiltonian matrix [H] given by:
where [H] = [H 0] + U, with [H 0] being the device tight-binding Hamiltonian matrix constructed using effective mass approach40 and I being the identity matrix of the same dimension as the Hamiltonian. The free variable denoting the energy of electronic wavefunction is E and the spatial variation in the conduction band minimum is described by the matrix U. The sub-band energy of the m th sub-band is \({E}_{m}=\frac{{\hslash }^{2}{k}_{m}^{2}}{2{m}_{t}}\). The vector \(\vec{{k}_{m}}\) represents the wavevector of the electron in the transverse direction for the m th mode. The net scattering self energy matrix \([{\rm{\Sigma }}(\vec{{k}_{m}},E)]\) includes that due to the scattering of the electronic wavefunctions from the contacts into the device region, denoted by \({{\rm{\Sigma }}}_{L}(\vec{{k}_{m}},E)+{{\rm{\Sigma }}}_{R}(\vec{{k}_{m}},E)\) as well as the scattering of electronic wavefunctions inside the device due to incoherent processes such as phonons and non-idealities, denoted by \({{\rm{\Sigma }}}_{{\rm{s}}}(\vec{{k}_{m}},E)\) (detailed in the supplementary information). The calculation of the in-scattering and the out-scattering functions involve a self consistent procedure, (detailed in the supplementary information), with the electron and the hole density operators \({{\rm{G}}}^{n}(\vec{{k}_{m}},E)\), \({{\rm{G}}}^{p}(\vec{{k}_{m}},E)\) defined as
Upon convergence of the self-consistent quantities, the charge and heat currents are evaluated in the lattice basis as:
where μ H is the electrochemical potential of the hot contact, M i,j is a generic matrix element of the concerned operator between two lattice points i and j. In the tight-binding scheme used here, we only consider the next nearest neighbor such that j = i ± 1. A list of parameters used for the simulation of the NEGF equations are given in Table 1.
References
Hicks, L. D. & Dresselhaus, M. S. Effect of quantum-well structures on the thermoelectric figure of merit. Phys. Rev. B 47(19), 12727 (1993).
Hicks, L. D. & Dresselhaus, M. S. Thermoelectric figure of merit of a one-dimensional conductor. Phys. Rev. B 47, 16631 (1993).
Dresselhaus, M. S. et al. Adv. Mater. 19, 1043, 2007.
Goldsmid. Introduction to Thermoelectricity. Springer, 2009.
Mahan, G. D. & Sofo, J. O. The best thermoelectric. Proceedings of National Academy of Sciences of the United States of America 93(15), 7436–7439 (1996).
Poudel, B. et al. High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys. Science 320, 634 (2008).
Snyder, G. J. & Toberer, E. S. Complex thermoelectric materials. Nat. Mater. 7, 105 (2008).
Heremans, J. P. et al. Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States. Science 321, 554 (2008).
Zebarjadi, M. et al. Power factor enhancement by modulation doping in bulk nanocomposites. Nano Letters 11(6), 2225–2230 (2011).
Natalya, A. Zimbovskaya. Seebeck effect in molecular junctions. Journal of Physics: Condensed Matter 28(18), 183002 (2016).
Thesberg, M., Kosina, H. & Neophytou, N. On the effectiveness of the thermoelectric energy filtering mechanism in low-dimensional superlattices and nano-composites. Journal of Applied Physics 120(23), 234302 (2016).
Mi, J. L., Zhao, X. B., Zhu, T. J. & Tu, J. P. Thermoelectric properties of Yb 0.15 Co 4 Sb 12 based nanocomposites with CoSb 3 nano-inclusion. Journal of Physics D: Applied Physics 41(20), 205403 (2008).
Li, J. F., Liu, W. S., Zhao, L. D. & Zhou, M. High-performance nanostructured thermoelectric materials. NPG Asia Mater 2, 152–158 (2010).
Sumithra, S. et al. Effect of nite nanoinclusions on thermoelectric properties of Bi 2 Te 3. Journal of Electronic Materials 41(6), 1401–1407 (2012).
Lin, H., Božin, E. S., Billinge, S. J. L., Quarez, E. & Kanatzidis, M. G. Nanoscale clusters in the high performance thermoelectric AgPb m SbTe m+2. Phys. Rev. B 72, 174113 (2005).
Zide, J. M. et al. Thermoelectric power factor in semiconductors with buried epitaxial semimetallic nanoparticles. Applied Physics Letters, 87(11) 2005.
Heremans, J. P., Thrush, C. M. & Morelli, D. T. Thermopower enhancement in pbte with pb precipitates. Journal of Applied Physics, 98(6) 2005.
Kim, R. & Lundstrom, M. S. Computational study of energy filtering effects in one-dimensional composite nano-structures. Journal of Applied Physics, 111(2) 2012.
Kim, R. & Lundstrom, M. S. Computational study of the seebeck coefficient of one-dimensional composite nano-structures. Journal of Applied Physics, 110(3) 2011.
Bahk, J. H., Bian, Z. & Shakouri, A. Electron energy filtering by a nonplanar potential to enhance the thermoelectric power factor in bulk materials. Phys. Rev. B 87, 075204 (2013).
Faleev, S. V. & Léonard, F. Theory of enhancement of thermoelectric properties of materials with nanoinclusions. Phys. Rev. B 77, 214304 (2008).
Neophytou, N. & Kosina, H. Optimizing thermoelectric power factor by means of a potential barrier. Journal of Applied Physics, 114(4) 2013.
Martin, J., Wang, L., Chen, Lidong & Nolas, G. S. Enhanced seebeck coefficient through energy-barrier scattering in pbte nanocomposites. Phys. Rev. B 79, 115311 (2009).
Berland, K. et al. Enhancement of thermoelectric properties by energy filtering: Theoretical potential and experimental reality in nanostructured znsb. Journal of Applied Physics, 119(12) 2016.
Vashaee, D. & Shakouri, A. Improved thermoelectric power factor in metal-based superlattices. Phys. Rev. Lett. 92, 106103 (2004).
Popescu, A., Woods, L. M., Martin, J. & Nolas, G. S. Model of transport properties of thermoelectric nanocomposite materials. Phys. Rev. B 79, 205302 (2009).
Neophytou, N. et al. Power factor enhancement by inhomogeneous distribution of dopants in two-phase nanocrystalline systems. Journal of Electronic Materials 43(6), 1896–1904 (2014).
Thesberg, M., Pourfath, M., Kosina, H. & Neophytou, N. The influence of non-idealities on the thermoelectric power factor of nanostructured superlattices. Journal of Applied Physics 118(22), 224301 (2015).
Yoshimasa, N. and Tohru Hirano. Improvement of the efficiency of thermoelectric energy conversion by utilizing potential barriers. Japanese Journal of Applied Physics 36(1R), 170 (1997).
Leijnse, M., Wegewijs, M. R. & Flensberg, K. Nonlinear thermoelectric properties of molecular junctions with vibrational coupling. Phys. Rev. B 82, 045412 (2010).
Sothmann, B., Sánchez, R. & Jordan, A. N. Thermoelectric energy harvesting with quantum dots. Nanotechnology 26, 32001 (2014).
Muralidharan, B. & Grifoni, M. Performance analysis of an interacting quantum dot thermoelectric setup. Phys. Rev. B 85, 155423 (2012).
Nakpathomkun, N., Xu, H. Q. & Linke, H. Thermoelectric efficiency at maximum power in low-dimensional systems. Phys. Rev. B 82, 235428 (2010).
Choi, Y. & Jordan, A. N. Three-terminal heat engine and refrigerator based on superlattices. Physica E 74, 465 (2016).
Singha, A., Mahanti, S. D. & Muralidharan, B. Exploring packaging strategies of nano-embedded thermoelectric generators. AIP Advances, 5(10) 2015.
Agarwal, A. & Muralidharan, B. Power and efficiency analysis of a realistic resonant tunneling diode thermoelectric. Applied Physics Letters 105(1), 013104 (2014).
Esseni, L.S.D., Palestri, P. Nanoscale MOS Transistors Semi-Classical Transport and Applications. Cambridge, 2011.
Whitney, R. S. Most Efficient Quantum Thermoelectric at Finite Power Output. Physical Review Letters 112(13), 130601 (2014).
Datta, S. Electronic Transport in Mesoscopic Systems. Cambridge University Press, 1997.
Datta, S. Quantum Transport:Atom to Transistor. Cambridge Press, 2005.
Datta, S. Lessons from nanoelectronics: a new perspective on transport. Lessons from nanosciences: A lecture note series. (World Scientific, Singapore, 2012).
Vashaee, D. & Shakouri, A. Conservation of lateral momentum in heterostructure integrated thermionic coolers. MRS Proceedings 691, 001 (2001).
Kim, R., Jeong, C. & Lundstrom, M. S. On momentum conservation and thermionic emission cooling. Journal of Applied Physics, 107(5) 2010.
Mingo, N. & Broido, D. A. Lattice thermal conductivity crossovers in semiconductor nanowires. Phys. Rev. Lett. 93, 246106 (2004).
Mingo, N. Thermoelectric figure of merit and maximum power factor in iii–v semiconductor nanowires. Applied Physics Letters 84(14), 2652–2654 (2004).
Zhou, F. et al. Determination of transport properties in chromium disilicide nanowires via combined thermoelectric and structural characterizations. Nano Letters 7(6), 1649–1654 (2007).
Zhou, F. et al. Effect of growth base pressure on the thermoelectric properties of indium antimonide nanowires. Journal of Physics D: Applied Physics 43(2), 025406 (2010).
Boukai, A. I. et al. Silicon nanowires as efficient thermoelectric materials. Nature 451, 168–171 (2008).
Hochbaum, A. I. et al. Enhanced thermoelectric performance of rough silicon nanowires. Nature Publishing Group 451, 163–167 (2008).
Lake, R. & Datta, S. Energy balance and heat exchange in mesoscopic systems. Phys. Rev. B 46, 4757–4763 (1992).
Acknowledgements
This work was partly supported by the IIT Bombay SEED grant and the Indian Space Research Organization RESPOND grant. The authors acknowledge Gang Chen for valuable suggestions and S.D. Mahanti for insightful discussions.
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A.S. conceived the idea. A.S. and B.M. contributed to the mathematical analysis, simulations, development of the blue prints and the writing of the paper. A.S. and B.M. extensively discussed the science, the simulations and the results obtained.
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Singha, A., Muralidharan, B. Incoherent scattering can favorably influence energy filtering in nanostructured thermoelectrics. Sci Rep 7, 7879 (2017). https://doi.org/10.1038/s41598-017-07935-w
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DOI: https://doi.org/10.1038/s41598-017-07935-w
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