Skip to main content

Thank you for visiting You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries



Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.


Green, reliable and energy-efficient lithium ion storage platforms with fast rate capability, high energy density and high power density are essential for the new generation of electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs)1, 2. Conventionally graphite-based anodes used in commercial lithium ion batteries (LIBs) have a limited theoretical capacity of 372 mAh g−1 due to the inadequate Li-ion intercalation in LiC6. Silicon is extensively considered the most encouraging material for the next generation anodes owing to the low discharge potential (~0.1 V vs. Li/Li+) and the high theoretical capacity of 3572 mAh g−1 corresponding to the formation of Li15Si4 phase at room temperature3, 4. If commercially used LiCoO2 (~145 mAh g−1) is assembled as the common cathodes, the full cells based on Si anodes lead to a 34% increase in the total capacity over that of graphite-anode based full cells5, 6. However, Si is able to alloy with a large amount of Li-ions during lithiation, resulting in a large volume expansion upwards of 300%7. The lithium-induced mechanical stresses during alloying with subsequent contraction during dealloying can cause Si to fracture, which promote the pulverization of active materials and the deterioration of the conductive network. The repeated expansion and shrinkage during lithiation and delithiation destroy the integrity of solid electrolyte interphase (SEI), while increasing the decomposition of electrolyte to reform SEI on the newly exposed Si surface8, 9.

To remedy the above problems, various strategies have been utilized on alleviating the structural volume change and optimizing the electrochemical performance of Si anodes. Downscaling the dimensions of silicon structures has been verified to be an effective path to mitigate the capacity fading stemming from the cracking of Si during lithiation and delithiation10, 11. Well-designed nanostructures, such as Si nanoparticles, double walled Si nanotubes, and three-dimensional (3D) porous nano-Si have all been proven to be advantageous in efficiently modifying the volume expansion of Si via the void spaces generated by their porous or hollow structures12,13,14. Moreover, the incorporation of electronically conductive coatings across Si is an effective strategy to improve the cycling stability of Si anodes. Carbon coatings via thermal decomposition of carbon precursors act as soft buffer layers to accommodate the volume expansion of Si15, 16. In-situ polymerized conductive polymer coverings with tunable conductivity, diverse monomer chemistry and surface compatibility with electrolyte function as conductive shell-matrixes to enhance the rate capability of the electrodes17,18,19,20,21.

While a large number of routes for designing nanostructured Si with excellent electrochemical performance as anode materials have been established, many methods for synthesizing Si nanostructures are mainly limited to the costly raw materials, complex procedure and the low yield of active martial as shown in Fig. 1a22, 23. The pyrolysis of silane/halo-silane/polysilane precursors via chemical vapor deposition (CVD) can produce various nanostructured silicon, such as nanospheres, nanowires and nanotubes24,25,26. The electrodes based on these structures show stable cycling and high-rate capability. However, the pyrolysis process consumes a large amount of energy and requires expensive and highly toxic precursors, which make it non-economical and impractical for mass manufacturing. Electrochemical anodization of crystalline wafers in toxic acidic environment has been employed to produce porous silicon27. The silicon wafers have also been etched into tunable silicon nanowires via metal-assisted templated and non-templated approaches28, 29. However, the high-cost electronic grade wafers coupled with the milligram-per-wafer yield of active material limit the large-scale production on industry level. The hydrolysis of tetraethyl orthosilicate (TEOS) to produce nano-SiO2 with subsequent reduction into Si has been investigated to generate the high performance anode materials30. However, the extensive procedure to achieve TEOS as SiO2 precursor is inefficient for industry-level manufacturing.

Figure 1

(a) Flow chart showing existing synthesis routes for nano-Si, including our synthesis method from glass bottles. (b) A collected beverage glass bottle. (c) (From left to right) vials of crushed glass, milled glass and gSi powder. (d) Schematic of the Mg reduction process using NaCl as heat scavenger.

Magnesiothermic reduction has been demonstrated as a morphology-protected method to reduce SiO2 into nanostructured silicon due to its relatively low operating temperature (~650 °C, <melting point of Si)31, 32. In comparison, carbothermal reduction is used to produce metallurgical silicon at a very high temperature (>2000 °C)33. This high energy-consuming process melts or liquefies Si, which destroys the original morphology of SiO2. Luo et al. have shown that the addition of NaCl effectively scavenges a large amount of heat generated during the highly exothermic reaction, which prevents the exceeded heat surpasses the melting point of Si34. Qian et al. have demonstrated that the incorporation of a molten salt of AlCl3 to SiCl4 decreases the reduction temperature to 200 °C, which preserves the original structure of SiO2 35. Recently, silica derived from natural resources, such as rice husks36, beach sand37 and reed leaves38 have been reduced into porous Si via Mg-reduction as anode materials with excellent electrochemical performance. However, the strong acid leaching and high-temperature annealing process to remove metal ions and organic species contained in the natural precursors are time-consuming and energy-intensive, while large quantities of liquid and gaseous waste during etching and heating are produced. Also, the yield of SiO2 is low after the whole extraction and purification process. In this work, glass bottles are used as the SiO2 precursor to achieve high-purity Si with several advantages compared with the aforementioned silica sources above: (1) Glass bottles are directly utilized for reduction without pre-leaching and annealing, which offers a more environmentally-benign, energy-saving and efficient route to prepare silica. (2) Glass bottles are easily-collected and their abundance in silica without any loss due to the non-etching process result in the high yield of SiO2 as the reaction precursor. (3) Many tons of non-recycled glass ends up in the landfills aggravating the burden of waste disposal. This work provides a facile and green avenue to convert glass waste to beneficial materials. Accordingly, glass bottles are directly converted into high purity and interconnected Si network, and the carbon coated gSi exhibits stable cycling performance and high rate capability as anode material for LIBs in this work. We further design a Li-ion full cell using gSi@C anodes and LiCoO2 cathodes. The full cell demonstrates good initial cycling performance with high energy density. Compared with reported routes for the preparation of SiO2 (Fig. 1a), quartz powder derived from glass bottles can be directly used for the reduction process without pre-leaching in toxic acid and removing organic impurities at very high temperature. The content of quartz in glass is higher than those obtained from the majority of natural substances. In addition, many tons of un-recycled glass bottles produced every year may satisfy the demand for anode materials necessary in some energy storage applications. The Mg reduction process is conducted at a relatively low temperature, which inherits the original structure of the silica obtained from crushed glass bottles application. The overall process is facile, cheap and scalable for large scale fabrication of anode materials.


Silica as a common fundamental constituent obtained from sand is melt together with several minerals at high temperature to form the non-crystalline amorphous glass. Based on the glass ingredients including silica content and mineral components, glasses are primarily classified as fused silica glass, soda-lime-silica glass, sodium borosilicate glass and lead-oxide glass39. The usages of glasses are in food containers, housing and building, electronics and appliance, etc. Here we collect beverage glass bottles (corresponding to the soda-lime-silica type of glass with a high SiO2 content of 72%) as the quartz source in Fig. 1b. A glass bottle is put in thick bags and crushed into raw quartz (Fig. 1c, left). To reduce the size of quartz, mechanical milling in an alumina mortar is followed to downsize the raw SiO2 quartz to micrometer scale within minutes. The milled quartz powder is then transferred into tubes and dispersed in isopropanol (IPA) by ultra-sonication, which breaks the agglomeration while reducing the quartz into smaller size with nanometer and micrometer scale. The dispersion is then left referred to the settling process. The massive quartz particles precipitate to the bottom, while the lightweight quartz particles are small enough to remain suspended in IPA. These suspended particles are collected and assume a bright white appearance in stark (Fig. 1c, middle). Compared with the quartz sources derived from natural substances, the resultant glass powder is directly used as SiO2 precursor without leaching and annealing process. This simple and straight route to achieve relatively high-purity SiO2 is favorable for large-scale production.

The dried glass powder is mechanically milled and grounded with sodium chloride (NaCl, >99.5%, Fisher Scientific) in a weight ratio of 1:10 (w/w). The incorporation of NaCl acts as an effective heat scavenger to halt the reaction temperature rise at 801 °C during fusion, which assists in preserving the morphology of SiO2 particles below its melting point as illustrated in Fig. 1d. The well-mixed SiO2:NaCl powder is immersed in DI H2O and ultrasonicated for 2 hours with subsequent vigorously stirring at 60 °C for 3 hours. The solution is then dried at 105 °C in vacuum oven to remove the water. Dried SiO2:NaCl is grounded to pulverize NaCl crystals and mixed with Mg (99.5%, #325 mesh, Sigma Aldrich) powder in a 1:0.83 SiO2:Mg weight ratio followed by vortexing for ample mixing. The resultant powder is loaded into a SS 316 Swagelok-type reactor in Ar-filled VAC Omni-lab glovebox (H2O < 0.5 ppm, O2 < 0.5 ppm), and then immediately loaded into a MTI GSL-1200X 1″ diameter quartz tube and purged with argon. The reactor is heated to 700 °C at a heating rate of 5 °C and held for 6 hours to ensure the complete reduction of SiO2. After cooling down to room temperature, the resulting product is first washed with DI H2O several times to remove NaCl and then etched with 2 M HCl for 2 hours under stirring to remove excessive Mg, unwanted Mg2Si and MgO. The MgCl2 produced after etching can be recycled back to Mg by electrolysis, which is a sustainable process for the reproduction from waste to raw material40. The dispersion is centrifuged and further etched with 2 wt.% HF in tubes to remove the unreacted SiO2. The gSi powder is finally rinsed several times with DI H2O and ethanol, and dried under vacuum for 6 hours at 105 °C (Fig. 1c, right). The yield of gSi reduced from glass powder is close to the theoretical yield value of 46.7 wt.% (see supporting information), which offers an option for Si production on the industry level.

The purities and phases of small size glass powder and as-reduced gSi are examined by X-ray diffraction (XRD) measurements in Fig. 2a. The weak XRD peaks associated with glass powder (index as black spectra) indicate the as-prepared quartz powder comprises minor by-products. The red XRD spectra of gSi demonstrates narrow and sharp peaks without amorphous scattering, suggesting the successful reduction from glass quartz to high degree crystallinity of Si. The peaks at 2θ of 28.8°, 47.8°, 56.7°, 69.7° and 77.1° represent (111), (220), (311), (400) and (331) planes, respectively41. Raman spectroscopy is carried to further verify the compositions of glass powder and gSi. The sharp peak at 521.06 cm−1 signifies the relatively high-purity of as-reduced gSi in Fig. 2b30.

Figure 2

(a) XRD patterns and (b) Raman spectra of pre-reduction milled glass powder and post-reduction gSi.

Scanning electron microscopy (SEM) micrographs are used to describe the structures and morphologies of the glass powder and gSi. The milled SiO2 powder displays a highly irregular-shape morphology with the particle size ranging from micrometer to nanometer scale as shown in Fig. 3a,b. The quantitative analysis obtained from the Energy Dispersive X-ray Spectroscopy (EDS) of quartz powder in Fig. S1 reveals the impurities may include lime (CaO), sodium oxide (Na2O) and alumina (Al2O3), which are the common mineral components for soda-lime-silica glass. After reduction, the particles remain irregular in shape owing to the morphology-protected Mg reduction process at a relatively low reaction temperature. The gSi has slightly reduced size distribution and partial porosity existing in gSi compared with the solid bulk SiO2 in Fig. 3c,d. This resulting cross-linked gSi networks with void spaces are attributed to the breakdown of the large particles during reaction, while acid-etching to remove MgO and Mg2Si within the original solid structure. EDS in Fig. S2 shows the weight occupancy of elements present in the gSi. The quantitative analysis reveals Si is the most dominant element a low residue of Mg, and the absences of metallic impurities imply that those oxides are reduced by magnesium, and then etched by HCl and HF. The existence of carbon in reduced silicon may increase the network conductivity for battery applications.

Figure 3

(a) Low magnification and (b) High magnification SEM images of milled glass powder. (c) Low magnification and (d) High magnification SEM images of gSi after reduction and acid-etching.

Transmission electron microscope (TEM) is carried out to further examine the structural information of glass silicon. Figure 4a confirms the existing large sparingly gSi comprises interconnected 3D gSi networks with the particle size from ~50 nm to micro level rather than the solid structure. This bridge-like interconnectivity is created by the selective removal of embedded MgO and Mg2Si in the gSi particles via acid etching. The existence of the partially internal porosity is available for buffering the volume expansion of Si during lithiation, while the SEI is well preserved, leading to less capacity decay resulting from the pulverization of active martials and the regeneration of SEI on exposed Si42. High-resolution TEM (HRTEM) and selected area electron diffraction pattern signify the highly crystalline nature of the gSi due to the d-spacing of 0.310 nm as shown in Fig. 4b and S3. Scanning transmission electron microscope (STEM) verifies the small particle size of the connected Si, while the high-angle annular dark-field imaging (HAADF) demonstrates the high purity of the reduce Si in Fig. 4c,d. Despite some void spaces generated by gSi network can accommodate volume change during lithiation, the low conductivity of Si limits its fast charge-discharge capability43. Thus, a conformally amorphous carbon coating with a thickness of 8–25 nm is introduced across all surfaces of gSi particles via CVD as shown in Fig. 5a,b. The gSi powder is loaded in a quartz boat and placed in the center of quartz tube furnace purged with Ar/H2 mixture. Acetylene (C2H2) is introduced to form the C-coating at 950 °C. The weight ratio of Si-to-C is ≈80:20 calculated by the weight variation before and after C-coating. STEM and HAAF of gSi@C clearly show the uniform distribution of carbon coating surrounding gSi, validating the successful deposition of the conformal carbon layer surrounding gSi in Fig. 5c–e. The seamless connection between C-coating and gSi improves the electrical conductivity of gSi@C composite while mitigating the volume change of silicon by the carbon buffer shell.

Figure 4

(a) Low magnification TEM image of gSi particles. (b) HRTEM image of gSi showing the characteristic lattice spacing of Si (111). (c) STEM-HAADF image of gSi and (d) EDS elemental map showing the high purity of reduced Si.

Figure 5

TEM images of gSi@C displaying the conformal carbon coating and the carbon layer thickness across gSi particles with (a) low magnification and (b) high magnification. (c) STEM-HAADF image of carbon coated gSi particles. (d,e) EDS mapping showing the phase conformal carbon coating surrounding gSi.

Button-type half-cell batteries were assembled in an Ar-filled glove box (O2 < 0.10 ppm, H2O < 0.5 ppm) with gSi@C as the anode material and pure Li-metal as the counter-electrode. Anode electrodes comprised 70 wt.% gSi@C as active material, 20 wt.% PAA as binder, and 10 wt.% carbon black as conductive additive. PAA has been proven to be an effective binder system for long-term cycling compared with PVDF and CMC due to its good mechanical properties and higher concentration of carboxyl groups to bind Si nanoparticles44. A porous polypropylene membrane (Celgard 3501) was used as the separator. The electrolyte contained 1 M LiPF6 dissolved in a mixture of fluoroethylene carbonate (FEC) and dimethyl carbonate (DMC) in a volume ratio of 1:1. The gSi@C electrodes demonstrated a discharge capacity of 2936 mAh g−1 with a Coulombic efficiency of 85% at C/40 (1 C = 3.6 A g−1) for the 1st cycle in Fig. 6a. After the 2nd cycle at C/20, the battery showed consistent current-potential behaviors for the subsequent cycles at C/10. The capacity faded very slightly and demonstrated a capacity ~2500 mAh g−1 over 60 cycles as supported in Fig. 6b. The Coulombic efficiency calculated from all the cycles excluding the 1st cycle is >99%, which suggests the excellent reliability and reversibility for the gSi@C half cells.

Figure 6

(a) Cycling performance and Coulombic efficiency of gSi@C anodes at a current density of C/10. (b) The corresponding galvanostatic charge-discharge profiles of gSi@C based half cell. (c) Cyclic voltammetry characteristic of gSi@C anodes. Scan rate: 0.2 mV sec−1. (d) C-rates cycling performance of gSi@C electrodes. (e) Comparison of the cycling performance and Coulombic efficiency between gSi@C and gSi based electrodes at a higher current density of C/2.

Cyclic voltammetry (CV) was tested in a voltage window range of 0.01 to 1.5 V (vs. Li+/Li) with a scan rate of 0.2 mV sec−1 as shown in Fig. 6c. The first discharge curve showed a weak peak around 0.48 V and disappeared in the subsequent cycles, which demonstrated the Li-ions were consumed to form stable SEI components (LixSiOy, lithium ethylene discarbonate and LiF) and leads to the irreversible charge capacity in the first cycle45. The peaks (0.18 V and 0.10 V) associated with lithiation and the peaks (0.38 V and 0.53 V) corresponding to delithiation increased and coincided at the 12th and 13th cycles, which suggested a kinetic enhancement process for stabilizing active materials37. Conformal C-coating has been verified to be an effective route to improve cycling stability and rate capability15. Rate capability of gSi@C and gSi anodes were demonstrated with different current densities measured from C/20 to 2 C in Fig. 6d. Even up to 2 C, the gSi@C electrodes showed a much higher capacity of ~1000 mAh g−1 over that of gSi electrodes, which signified the substantial enhancement of conductive coatings on rate capability of Si anodes. The charge-discharge profiles of gSi@C and gSi electrodes under various C-rates are shown in Fig. S4a and c, respectively. For long-term cycling, the gSi@C electrodes were properly activated at 40/C, 20/C and 10/C at the initial cycles to achieve a stable SEI as confirmed by CV measurements (Fig. 6e). After the kinetic enhancement was completed at low current densities, the gSi@C anodes were cycled at a higher C-rate of C/2 and exhibited a reversible capacity of ~1420 mAh g−1 with capacity retention of 72% (Coulombic efficiency of >99.5%) after 400 cycles. In comparison, non-carbon coated gSi electrodes presented a lower capacity of 796 mAh g−1 with capacity retention of 20% (corresponding to Coulombic efficiency of 98.9%) after the same cycling process. The cycling results of gSi@C electrodes are comparable to several reported Si anodes via Mg-reduction. For instance, silicon electrodes obtained from diatomaceous earth showed fast decay from 1400 to 700 mAhg−1 after 30 cycles46. Reed leaves and rice husk derived Si based anodes demonstrated capacities of ~1050 and ~1580 mAhg−1 with capacity retentions of 50% and 86% at C/2 after 200 cycles and 300 cycles, respectively36, 38. The gSi@C half-cells exhibited ~1790 and ~1660 mAhg−1 (corresponding to capacity retentions of 91% and 84%) after 200 and 300 cycles at C/2, respectively, which are similar or even slightly superior over the mentioned silicon anode performances. The slopes of discharge-discharge curves of amorphous Li-Si are in good agreement with the peaks of CV curves in Fig. S4b and d12. This performance difference between gSi@C and gSi anodes was mainly due to the low conductivity of non-carbon coated gSi, leading to insufficient charge transfer between gSi and the micro-level carbon black within the electrode. Moreover, the carbon coating surrounding gSi improved the cycling stability of anodes, which was confirmed by the higher capacity retention and Coulombic efficiency of gSi@C electrodes over that of pure gSi after 400 cycles.

To further characterize the practical capability of the as-prepared gSi anodes, a full cell comprising gSi@C as anode and LiCoO2 (provided by TET USA Corporation) cathode was fabricated. In an aim to achieve a theoretically optimal total capacity of a full cell, the capacity ratio of anode to cathode is expected to be close to 1:147, 48. In this work, the gSi@C anodes with a Si loading of ~0.5 mg cm−2 demonstrate a reversible capacity of ~1800 mAh g−1 at C/2 (1 C = 3.6 A g−1) over the first 50 cycles, while the LiCoO2 cathodes with a mass loading of ~5.4 mg cm−2 show a reversible capacity of ~160 mAh g−1 at C/2 (1 C = 163 mA g−1). The practical capacities of gSi@C and LiCoO2 in half cells are calculated to be 0.900 mAh cm−2 mAh and 0.865 mAh cm−2. Accordingly, the actual capacity ratio of Si anode to LiCoO2 cathode is 1.04:1, which suggests this gSi@C/LiCoO2 full cell design is suitable for evaluation of anode and cathode effects on cycling stability. The slightly higher Si content is favorable to prevent the anodes from over-lithiated during full-cell charge. The cycling performance of the full cell is measured with a voltage window range from 2.7 to 4.3 V as shown in Fig. 7a. The initial cycle is tested at C/20 for the proper activation of active materials, and a total capacity of ~130 mAh g−1 (corresponding to a Coulombic efficiency of 78.9% in Fig. S4b) is displayed. Note that the capacity of full cell is calculated only based on the total mass of Si and LiCoO2. In the subsequent cycles, the capacity gradually decreases from 116 to 85 mAh g−1 at C/2 until the 50th cycle. An energy density of 460 Wh kg−1 is demonstrated by this full cell for the first cycle. Even after 50 cycles, the cell assembly still exhibits an energy density of 298 Wh kg−1, which is comparable to those of reported full cells based on Si anodes47, 49, 50. If the masses of binders (PAA, polyvinylidene fluoride), carbon black and current collectors (Cu and Al foils) for gSi@C anodes and LiCoO2 cathodes are also included, the full cell shows an energy density of 139 Wh kg−1 for the 1st cycle with 65 Wh kg−1 over 50 cycles (Table S1).

Figure 7

(a) Cycling performance of full cells employing gSi@C anode and LiCoO2 cathode for 50 cycles. (b) The corresponding galvanostatic charge-discharge curves of the full cells.


Electrochemical impedance spectroscopy (EIS) was used to characterize the electrochemical performance of the gSi@C anodes. A small sinusoidal of 10 mV was applied to gSi@C anodes and the resultant complex impedance was measured in a frequency range between 100 mHz and 1 MHz. The impedance information was modeled using an electrical equivalent circuit shown in Fig. S5a. The real axis interception at high frequency, also known as equivalent series resistance (Rs or ESR), denotes the ionic resistance of the electrolyte in summation with the electronic resistance of the active material within the electrode. Rs declines for the first 7 cycles and then stabilizes thereafter in Fig. S5b and Table S2. The high frequency semicircle represents the resistance of SEI layer (RSEI) coupled with resistance stemming from the imperfect contact between metal current collector and active materials (RINT)51, 52. The RSEI+INT decreases in diameter as the cycle increases, while the semicircle at mid frequency drops sharply for the first 7 cycles and then stabilizes, indicating the stabilization of charge transfer impedance as shown in Fig. S5c. Interfacial impedance remains constant as cycling, which signifies the contact impedance among active particles and current collect is independent with cycling53. This phenomenon can be attributed to the buffering effect of carbon coating on the Si volume expansion54. Besides the high frequency semicircle (corresponding to RSEI+INT) and the mid semicircle (owing to charge transfer impedance between electrolyte and electrode), another distinct arc, known as the low-frequency (<20 MHz) Warburg impedance tail, represents impedance resulting from diffusion of ions into the active materials55, 56. This parameter is related to the diffusion of lithium into gSi@C and salt transfer in the electrolyte. The arcs show big difference for the first 7 cycle, while the tails of 8th and 9th closely overlap, confirming the anodes tend to stabilize as cycling.

Effective strategies have been utilized to alleviate the volume change of gSi particles during lithiation/delithiation and improve the cycling stability. First, the addition of a large amount of NaCl to glass quartz power produces cross-liked structure during the highly exothermic magnesium reduction process. The reaction process generates a large amount of heat as shown in Equations 1–2 as follows33:

$$2{\rm{Mg}}({\rm{g}})+{{\rm{SiO}}}_{2}({\rm{s}})\to {\rm{Si}}({\rm{s}})+2{\rm{MgO}}({\rm{s}}),\,{\rm{\Delta }}{\rm{H}}=-546.42\,{\rm{kJ}}\,\,{{\rm{mol}}}^{-1}.$$

Mg is in excess in this work,

$$2{\rm{Mg}}({\rm{g}})+{\rm{Si}}({\rm{s}})\to {{\rm{Mg}}}_{2}{\rm{Si}}({\rm{s}}),\,{\rm{\Delta }}{\rm{H}}=-318.91\,{\rm{kJ}}\,{{\rm{mol}}}^{-1}.$$

The continuously feeding heat can cause the fusion of silicon, which destroys its original morphology and leads to aggregation of Si particles. However, the NaCl is used to cover SiO2 particles and behave as heat scavenger to absorb a large amount of heat for self-fusion, which has been verified to effectively protect the surface morphology of Si after reduction. NaCl is low cost, non-toxic and easily recycled to use. The etching of byproduct MgO and Mg2Si within Si structure generates the interconnected Si network with empty spaces, which mitigates volume change of silicon during alloying and improves Li-ions transfer into the active material. Second, a conformal carbon coating on the surface of gSi not only acts as buffer layer for accommodating volume expansion, but also enhances the rate capability of the electrodes. Moreover, the FEC-containing electrolyte assists the formation of SEI thin films with superior surface properties on Si particles compared to the thicker films formed in FEC-free electrolyte, and the presence of FEC lowers the impedance in electrolyte solutions, which reduces the irreversible capacity of the electrodes57.


In summary, we have demonstrated the direct conversion from glass bottles to high purity silicon using a scalable, facile and low-cost Mg reduction process. The excellent electrochemical performance of gSi@C anodes can be mainly attributed to the mitigated volume expansion and improved system conductivity resulting from the interconnected gSi network and the conformal carbon coating. A full cell with good initial cycling stability and high energy density using gSi@C as anode and LiCoO2 as cathode has been reported. The non-etching, easy-collet and abundant glass bottles as SiO2 source offers a promising avenue for the large-scale production of Si based anodes.


Materials synthesis

Collected beverage glass bottles were first sealed in several thick bags and crushed into small pieces by hammer. Crushed glass was hand-milled in an alumina mortar for several minutes, transferred into tubes with ultrasonication for 2 hours in isopropanol (IPA), and then left for settling big quartz down for 2 hours. Light-weight suspended quartz particles in IPA were collected and dried at 90 °C under vacuum for 2 hours. To sufficiently utilize the raw materials, the left big quartz were further milled into small size particles later. Dried small glass powder is mixed with NaCl (>99.5%, Fisher Scientific) in a weight ratio of 1:10 (3 g:30 g, w/w) and milled in an alumina mortar. The well-mixed SiO2:NaCl powder was added in DI H2O and ultrasonicated for 2 hours with subsequent stirring for 3 hours. The mixture was dried overnight at 105 °C in vacuum oven to remove water. The resulting SiO2:NaCl powder is grounded with Mg (99.5%, #325 mesh, Sigma Aldrich) in a weight ratio of 1:0.83 (Si:Mg: 3 g:2.49 g, w/w) ratio. The well-mixed powder was loaded into SS 316 Swagelok-type reactors in argon-filled VAC Omni-lab glove box (<0.5 ppm H2O, < 0.5 ppm O2). The reactors were loaded into MTI GSL-1200X quartz tube furnace and purged with argon. The furnace was ramped to 700 °C with a heating rate of 5 °C min−1, held for 6 hours at 0.5 sccm argon environment and cooled to room temperature. The resultant powder was washed with DI H2O and ethanol several times to remove NaCl, followed by etching unwanted MgO and Mg2Si in concentrated HCl with subsequent washing with DI H2O. Unreacted SiO2 is removed by etching in 5% HF for 1 hour and washed with DI H2O and ethanol, and dried under vacuum for 4 hours at 90 °C. The yield of high-purity gSi derived from glass powder is 40.0–40.3 wt.%. Thin carbon layer coated gSi is formed by CVD. The dried and milled gSi powder is loaded in a quartz boat and transferred into the center of a quartz tube furnace. 30 sccm C2H2 is introduced and carried by Ar/H2 (150/50, sccm) to produce the amorphous carbon coating across gSi surface at 950 °C for 15 minutes. Si-to-C weight ratio is calculated to be 4:1 based on the weight variation before and after carbon coating.

Materials characterization

The surface morphology is investigated using optical microscopy, scanning microscopy (SEM; Leo-Supra, 1550) with an X-ray energy-dispersive spectroscopy (EDS). Transmission electron microscopy (TEM, Titan Themis 300) operated at 300 KV is used to further characterize the purity and morphology of gSi and gSi@C. The TEM samples are prepared by dispersing the powder in water for 15 minutes, diluted and then dropped onto TEM grids. The phase identification is performed by X-ray diffraction (XRD, PANalytical Empyrean) from 10° to 80°. Raman spectroscopy (Renishaw DXR) with a 532 nm laser (8 mW excitation power, 100X objective lens) source is carried to check the purity of gSi. Electrochemical impedance spectroscopy (EIS) analysis is obtained with a Biologic VMPs.

Electrochemical measurements

The anode electrodes were prepared by doctor-blading a slurry on pre-cleaned Cu foil with a pre-area mass loading for 0.5–0.6 mg cm−2. The slurry comprises 70% active material (gSi@C), 20% PAA binder and 10% conductive additive (carbon black). A button-type (CR 2032) half-cell configuration was used for the electrochemical measurements. Cells were assembled in an Argon-filled VAC Omni-lab glovebox with oxygen and H2O level below 0.5 ppm. Pure Li metal was used as the counter electrode for half-cell tests. Full cells were prepared and evaluated in TET USA Corporation facility with custom made LiCoO2 (lithium cobalt oxide) cathodes with a LiCoO2 mass loading of 5.3–5.5 mg cm−2. A Celgard 3501 porous PP membrane was used as the separator. The electrolyte comprising 1 M LiPF6 in fluoroethylene carbonate and dimethyl carbonate (FEC:DMC = 1:1, v/v) was used as electrolyte for half and full cells. Cycling performance and galvanostatic charge-discharge behaviors were conducted on Arbin BT300 with a voltage window ranging from 0.01 to 1.5 V (vs. Li+/Li). Capacity and C-rates were determined using 1 C = 3.6 A g−1. Cyclic voltammetry scans were tested at a fixed voltage window between 0.01 V and 1.5 V (vs. Li+/Li). Electrochemical impedance spectroscopy measurements were performed to evaluate the impedance information of gSi@C anodes on a Biologic VMPs with a frequency range between 0.01 Hz and 1 MHz.


  1. 1.

    Dunn, B., Kamath, H. & Tarascon, J.-M. Electrical Energy Storage for the Grid: A Battery of Choices. Science 334, 928–935, doi:10.1126/science.1212741 (2011).

    ADS  CAS  Article  PubMed  Google Scholar 

  2. 2.

    Kovalenko, I. et al. A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries. Science 334, 75–79, doi:10.1126/science.1209150 (2011).

    ADS  CAS  Article  PubMed  Google Scholar 

  3. 3.

    Li, C. et al. Towards flexible binderless anodes: silicon/carbon fabrics via double-nozzle electrospinning. Chem. Commun. 52, 11398–11401, doi:10.1039/c6cc04074h (2016).

    CAS  Article  Google Scholar 

  4. 4.

    Liu, C., Li, C., Wang, W., Ozkan, M. & Ozkan, C. S. Facile Synthesis of Nickel Nanofoam Architectures for Applications in Li-Ion Batteries. Energy Technology 5, 422, doi:10.1002/ente.201600306 (2017).

  5. 5.

    Wang, W., Ruiz, I., Ahmed, K., Bay, H., George, A., Wang, J., Butler, J., Ozkan, M. & Ozkan, C. S. Silicon Decorated Cone Shaped Carbon Nanotube Clusters for Lithium Ion Battery Anodes. Small 10, 3389–3396, doi:10.1002/smll.v10.16 (2014).

    CAS  Article  PubMed  Google Scholar 

  6. 6.

    Park, J.-K. Principles and applications of lithium secondary batteries. (John Wiley & Sons, 2012).

  7. 7.

    Cho, J. Porous Si anode materials for lithium rechargeable batteries. J. Mater. Chem. 20, 4009–4014, doi:10.1039/b923002e (2010).

    CAS  Article  Google Scholar 

  8. 8.

    Wu, H. et al. Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nat Nano 7, 310–315, doi:10.1038/nnano.2012.35 (2012).

    CAS  Article  Google Scholar 

  9. 9.

    Ge, M. et al. Scalable preparation of porous silicon nanoparticles and their application for lithium-ion battery anodes. Nano Res. 6, 174–181, doi:10.1007/s12274-013-0293-y (2013).

    ADS  CAS  Article  Google Scholar 

  10. 10.

    Liu, X. H. et al. Size-Dependent Fracture of Silicon Nanoparticles During Lithiation. ACS Nano 6, 1522–1531, doi:10.1021/nn204476h (2012).

    ADS  CAS  Article  PubMed  Google Scholar 

  11. 11.

    Ryu, I., Choi, J. W., Cui, Y. & Nix, W. D. Size-dependent fracture of Si nanowire battery anodes. Journal of the Mechanics and Physics of Solids 59, 1717–1730, doi:10.1016/j.jmps.2011.06.003 (2011).

    ADS  CAS  Article  Google Scholar 

  12. 12.

    Ge, M., Rong, J., Fang, X. & Zhou, C. Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life. Nano Lett. 12, 2318–2323, doi:10.1021/nl300206e (2012).

    ADS  CAS  Article  PubMed  Google Scholar 

  13. 13.

    Liu, N. et al. A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes. Nat Nano 9, 187–192, doi:10.1038/nnano.2014.6 (2014).

    CAS  Article  Google Scholar 

  14. 14.

    Hassan, F. M., Chabot, V., Elsayed, A. R., Xiao, X. & Chen, Z. Engineered Si Electrode Nanoarchitecture: A Scalable Postfabrication Treatment for the Production of Next-Generation Li-Ion Batteries. Nano Lett. 14, 277–283, doi:10.1021/nl403943g (2014).

    ADS  CAS  Article  PubMed  Google Scholar 

  15. 15.

    Dimov, N., Kugino, S. & Yoshio, M. Carbon-coated silicon as anode material for lithium ion batteries: advantages and limitations. Electrochim. Acta 48, 1579–1587, doi:10.1016/S0013-4686(03)00030-6 (2003).

    CAS  Article  Google Scholar 

  16. 16.

    Cui, L.-F., Yang, Y., Hsu, C.-M. & Cui, Y. Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries. Nano Lett. 9, 3370–3374, doi:10.1021/nl901670t (2009).

    ADS  CAS  Article  PubMed  Google Scholar 

  17. 17.

    Pan, L. et al. Hierarchical nanostructured conducting polymer hydrogel with high electrochemical activity. Proc. Natl. Acad. Sci. 109, 9287–9292, doi:10.1073/pnas.1202636109 (2012).

    ADS  CAS  Article  PubMed  PubMed Central  Google Scholar 

  18. 18.

    Wu, H. et al. Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles. Nat. Commun. 4, 1943, doi:10.1038/ncomms2941 (2013).

    ADS  PubMed  Google Scholar 

  19. 19.

    Li, C. et al. Electrospun Polyaniline/Poly(ethylene oxide) Composite Nanofibers Based Gas Sensor. Electroanalysis 26, 711–722, doi:10.1002/elan.201300641 (2014).

    Article  Google Scholar 

  20. 20.

    Karen, L. et al. Polyaniline/poly(ε -caprolactone) composite electrospun nanofiber-based gas sensors: optimization of sensing properties by dopants and doping concentration. Nanotechnology 25, 115501, doi:10.1088/0957-4484/25/11/115501 (2014).

    Article  Google Scholar 

  21. 21.

    Low, K. et al. Composition-dependent sensing mechanism of electrospun conductive polymer composite nanofibers. Sensors and Actuators B: Chemical 207(Part A), 235–242, doi:10.1016/j.snb.2014.09.121 (2015).

    CAS  Article  Google Scholar 

  22. 22.

    Liu, N. et al. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. Nano Lett. 12, 3315–3321, doi:10.1021/nl3014814 (2012).

    ADS  CAS  Article  PubMed  Google Scholar 

  23. 23.

    Yoo, J.-K., Kim, J., Jung, Y. S. & Kang, K. Scalable Fabrication of Silicon Nanotubes and their Application to Energy Storage. Adv. Mater. 24, 5452–5456, doi:10.1002/adma.v24.40 (2012).

    CAS  Article  PubMed  Google Scholar 

  24. 24.

    Cui, Y., Lauhon, L. J., Gudiksen, M. S., Wang, J. & Lieber, C. M. Diameter-controlled synthesis of single-crystal silicon nanowires. Appl. Phys. Lett. 78, 2214–2216, doi:10.1063/1.1363692 (2001).

    ADS  CAS  Article  Google Scholar 

  25. 25.

    Law, M., Goldberger, J. & Yang, P. Semiconductor Nanowires and Nanotubes. Annu. Rev. Mater. Res. 34, 83–122, doi:10.1146/annurev.matsci.34.040203.112300 (2004).

    ADS  CAS  Article  Google Scholar 

  26. 26.

    Yao, Y. et al. Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life. Nano Lett. 11, 2949–2954, doi:10.1021/nl201470j (2011).

    ADS  CAS  Article  PubMed  Google Scholar 

  27. 27.

    Sun, X., Huang, H., Chu, K.-L. & Zhuang, Y. Anodized Macroporous Silicon Anode for Integrationof Lithium-Ion Batteries on Chips. J. Electron. Mater. 41, 2369–2375, doi:10.1007/s11664-012-2147-x (2012).

    ADS  CAS  Article  Google Scholar 

  28. 28.

    Huang, Z. et al. Extended Arrays of Vertically Aligned Sub-10 nm Diameter [100] Si Nanowires by Metal-Assisted Chemical Etching. Nano Lett. 8, 3046–3051, doi:10.1021/nl802324y (2008).

    ADS  CAS  Article  PubMed  Google Scholar 

  29. 29.

    Vlad, A. et al. Roll up nanowire battery from silicon chips. Proc. Natl. Acad. Sci. 109, 15168–15173, doi:10.1073/pnas.1208638109 (2012).

    ADS  CAS  Article  PubMed  PubMed Central  Google Scholar 

  30. 30.

    Wang, W., Favors, Z., Ionescu, R., Ye, R., Bay, H., Ozkan, M. & Ozkan, C. S. Monodisperse Porous Silicon Spheres as Anode Materials for Lithium Ion Batteries. Scientific Reports 5, 8781, doi:10.1038/srep08781 (2015).

    ADS  CAS  Article  PubMed  PubMed Central  Google Scholar 

  31. 31.

    Yu, Y. et al. Encapsulation of Sn@carbon Nanoparticles in Bamboo-like Hollow Carbon Nanofibers as an Anode Material in Lithium-Based Batteries. Angew. Chem., Int. Ed. 48, 6485–6489, doi:10.1002/anie.v48:35 (2009).

    CAS  Article  Google Scholar 

  32. 32.

    Zhang, R. et al. Highly Reversible and Large Lithium Storage in Mesoporous Si/C Nanocomposite Anodes with Silicon Nanoparticles Embedded in a Carbon Framework. Adv. Mater. 26, 6749–6755, doi:10.1002/adma.v26.39 (2014).

    CAS  Article  PubMed  Google Scholar 

  33. 33.

    Gribov, B. G. & Zinov’ev, K. V. Preparation of High-Purity Silicon for Solar Cells. Inorganic Materials 39, 653–662, doi:10.1023/A:1024553420534 (2003).

    CAS  Article  Google Scholar 

  34. 34.

    Luo, W. et al. Efficient Fabrication of Nanoporous Si and Si/Ge Enabled by a Heat Scavenger in Magnesiothermic Reactions. Scientific Reports 3, 2222, doi:10.1038/srep02222 (2013).

    ADS  PubMed  PubMed Central  Google Scholar 

  35. 35.

    Lin, N. et al. Preparation of Nanocrystalline Silicon from SiCl4 at 200 °C in Molten Salt for High-Performance Anodes for Lithium Ion Batteries. Angew. Chem., Int. Ed. 54, 3822–3825, doi:10.1002/anie.201411830 (2015).

  36. 36.

    Liu, N., Huo, K., McDowell, M. T., Zhao, J. & Cui, Y. Rice husks as a sustainable source of nanostructured silicon for high performance Li-ion battery anodes. Scientific Reports 3, 1919, doi:10.1038/srep01919 (2013).

  37. 37.

    Favors, Z., Wang, W., Bay, H., Mutlu, Z., Ahmed, K., Liu, C., Ozkan, M. & Ozkan, C. S. Scalable Synthesis of Nano-Silicon from Beach Sand for Long Cycle Life Li-ion Batteries. Sci. Rep. 4, 5623, doi:10.1038/srep05623 (2014).

    ADS  CAS  PubMed  PubMed Central  Google Scholar 

  38. 38.

    Liu, J., Kopold, P., van Aken, P. A., Maier, J. & Yu, Y. Energy Storage Materials from Nature through Nanotechnology: A Sustainable Route from Reed Plants to a Silicon Anode for Lithium-Ion Batteries. Angew. Chem., Int. Ed. 54, 9632–9636, doi:10.1002/anie.v54.33 (2015).

    CAS  Article  Google Scholar 

  39. 39.

    Hickman, D. A. A classification scheme for glass. Forensic Science International 17, 265–281, doi:10.1016/0379-0738(81)90176-6 (1981).

    CAS  Article  Google Scholar 

  40. 40.

    Sharma, R. A. A new electrolytic magnesium production process. JOM 48, 39–43, doi:10.1007/BF03223100 (1996).

    CAS  Article  Google Scholar 

  41. 41.

    Zhou, M. et al. Facile synthesis of novel Si nanoparticles-graphene composites as high-performance anode materials for Li-ion batteries. Phys. Chem. Chem. Phys. 15, 11394–11401, doi:10.1039/c3cp51276b (2013).

    CAS  Article  PubMed  Google Scholar 

  42. 42.

    Guo, J., Sun, A. & Wang, C. A porous silicon–carbon anode with high overall capacity on carbon fiber current collector. Electrochem. Commun. 12, 981–984, doi:10.1016/j.elecom.2010.05.006 (2010).

    CAS  Article  Google Scholar 

  43. 43.

    Xue, L. et al. Carbon-Coated Si Nanoparticles Dispersed in Carbon Nanotube Networks As Anode Material for Lithium-Ion Batteries. ACS Appl. Mater. Interfaces 5, 21–25 (2013).

    CAS  Article  PubMed  Google Scholar 

  44. 44.

    Magasinski, A. et al. Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid. ACS Appl. Mater. Interfaces 2, 3004–3010 (2010).

    CAS  Article  PubMed  Google Scholar 

  45. 45.

    Li, J., Dudney, N. J., Nanda, J. & Liang, C. Artificial Solid Electrolyte Interphase To Address the Electrochemical Degradation of Silicon Electrodes. ACS Appl. Mater. Interfaces 6, 10083–10088 (2014).

    CAS  Article  PubMed  Google Scholar 

  46. 46.

    Shen, L., Guo, X., Fang, X., Wang, Z. & Chen, L. Magnesiothermically reduced diatomaceous earth as a porous silicon anode material for lithium ion batteries. J. Power Sources 213, 229–232, doi:10.1016/j.jpowsour.2012.03.097 (2012).

    ADS  CAS  Article  Google Scholar 

  47. 47.

    Eom, K., Joshi, T., Bordes, A., Do, I. & Fuller, T. F. The design of a Li-ion full cell battery using a nano silicon and nano multi-layer graphene composite anode. J. Power Sources 249, 118–124, doi:10.1016/j.jpowsour.2013.10.087 (2014).

    ADS  CAS  Article  Google Scholar 

  48. 48.

    Ji, L. et al. Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cells. Nano Energy 1, 164–171, doi:10.1016/j.nanoen.2011.08.003 (2012).

    CAS  Article  Google Scholar 

  49. 49.

    Lee, J. H. et al. High-energy-density lithium-ion battery using a carbon-nanotube-Si composite anode and a compositionally graded Li[Ni0.85Co0.05Mn0.10]O2 cathode. Energy Environ. Sci. (2016).

  50. 50.

    Son, I. H. et al. Silicon carbide-free graphene growth on silicon for lithium-ion battery with high volumetric energy density. Nat Commun 6 (2015).

  51. 51.

    Liu, C., Li, C., Ahmed, K., Wang, W., Lee, I., Zaera, F., Ozkan, C. S. & Ozkan, M. Scalable, Binderless, and Carbonless Hierarchical Ni Nanodendrite Foam Decorated with Hydrous Ruthenium Dioxide for 1.6 V Symmetric Supercapacitors. Advanced Materials Interfaces 3, 1500503–n/a, doi:10.1002/admi.201500503 (2016).

    ADS  Article  Google Scholar 

  52. 52.

    Liu, C., Li, C., Ahmed, K., Mutlu, Z., Ozkan, C. S. & Ozkan, M. Template Free and Binderless NiO Nanowire Foam for Li-ion Battery Anodes with Long Cycle Life and Ultrahigh Rate Capability. Scientific Reports 6, 29183, doi:10.1038/srep29183 (2016).

    ADS  CAS  Article  PubMed  PubMed Central  Google Scholar 

  53. 53.

    Liu, C., Li, C., Ahmed, K., Wang, W., Lee, I., Zaera, F., Ozkan, C. S. & Ozkan, M. High energy and power density Li-O2 battery cathodes based on amorphous RuO2 loaded carbon free and binderless nickel nanofoam architectures. RSC Adv 6, 81712–81718, doi:10.1039/C6RA13007K (2016).

    CAS  Article  Google Scholar 

  54. 54.

    Guo, J., Sun, A., Chen, X., Wang, C. & Manivannan, A. Cyclability study of silicon–carbon composite anodes for lithium-ion batteries using electrochemical impedance spectroscopy. Electrochim. Acta 56, 3981–3987, doi:10.1016/j.electacta.2011.02.014 (2011).

    CAS  Article  Google Scholar 

  55. 55.

    Hu, L. et al. CoMn2O4 Spinel Hierarchical Microspheres Assembled with Porous Nanosheets as Stable Anodes for Lithium-ion Batteries. Scientific Reports 2, 986, doi:10.1038/srep00986 (2012).

    ADS  PubMed  PubMed Central  Google Scholar 

  56. 56.

    Wang, W., Ruiz, I., Guo, S., Favors, Z., Bay, H., Ozkan, M. & Ozkan, C. S. Hybrid carbon nanotube and graphene nanostructures for lithium ion battery anodes. Nano Energy 3, 113–118, doi:10.1016/j.nanoen.2013.10.005 (2014).

    CAS  Article  Google Scholar 

  57. 57.

    Etacheri, V. et al. Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes. Langmuir 28, 965–976, doi:10.1021/la203712s (2012).

    CAS  Article  PubMed  Google Scholar 

Download references

Author information




C.L., M.O. and C.S.O. designed the experiments and wrote the manuscript. C.L., C.L., K.A., Z.M., J.B., W.W. and R.Y. worked on glass derived-silicon synthesis; materials characterization; battery assembly; electrochemical characterization including charge-discharge profiles, cycling and rate curves, cyclic voltammetry and electrochemical impedance spectroscopy measurements. C.S.O. managed the research team. All authors reviewed the manuscript.

Corresponding authors

Correspondence to Mihrimah Ozkan or Cengiz S. Ozkan.

Ethics declarations

Competing Interests

The authors declare that they have no competing interests.

Additional information

Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Li, C., Liu, C., Wang, W. et al. Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries. Sci Rep 7, 917 (2017).

Download citation

Further reading


By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.


Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing