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Bio-based polymers with performance-advantaged properties

Abstract

Bio-based compounds with unique chemical functionality can be obtained through selective transformations of plant and other non-fossil, biogenic feedstocks for the development of new polymers to displace those produced from fossil carbon feedstocks. Although substantial efforts have been invested to produce bio-based polymers that are chemically identical to and directly replace those from petroleum, a long-pursued goal is to synthesize new, sustainable, bio-based polymers that either functionally replace or exhibit performance advantages relative to incumbent polymers. Owing to anthropogenic climate change and the environmental consequences of global plastics pollution, the need to realize a bio-based materials economy at scale is critical. To that end, in this Review we describe the concept of performance-advantaged, bio-based polymers (PBPs), highlighting examples wherein superior performance is facilitated by the inherent chemical functionality of bio-based feedstocks. We focus on PBPs with C–O and C–N inter-unit chemical bonds, as these are often readily accessible from bio-based feedstocks, which are heteroatom-rich relative to petroleum-derived feedstocks. Finally, we outline guiding principles and challenges to aid progress in the development of PBPs.

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Fig. 1: Van Krevelen diagram for select polymers.
Fig. 2: Polymers from biomass.
Fig. 3: Fundamental thermomechanical polymer properties.
Fig. 4: Variety of available bio-based polymer architectures with C–O inter-monomer linkages.
Fig. 5: Design and synthesis of bio-epoxy resins.
Fig. 6: Use of bio-derived functionalities in C–N linked polymers.

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Acknowledgements

This work was authored in part by the National Renewable Energy Laboratory, operated by Alliance for Sustainable Energy, LLC, for the US Department of Energy (DOE) under Contract No. DE-AC36-08GO28308. Funding provided by the US DOE, Office of Energy Efficiency and Renewable Energy Bioenergy Technologies Office. The views expressed in the article do not necessarily represent the views of the DOE or the US Government. The US Government retains and the publisher, by accepting the article for publication, acknowledges that the US Government retains a non-exclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for US Government purposes. E.Y.-X.C acknowledges support from the US National Science Foundation (NSF-1955482).

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R.M.C., N.A.R., C.B.H. and G.T.B. wrote the manuscript and designed the figures. G.T.B. and E.Y.-X.C. prepared the initial draft outline. All authors edited the manuscript prior to submission.

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Correspondence to Gregg T. Beckham or Eugene Y.-X. Chen.

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Cywar, R.M., Rorrer, N.A., Hoyt, C.B. et al. Bio-based polymers with performance-advantaged properties. Nat Rev Mater (2021). https://doi.org/10.1038/s41578-021-00363-3

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