The applicability of organic battery materials in conventional rocking-chair lithium (Li)-ion cells remains deeply challenged by the lack of Li-containing and air-stable organic positive electrode chemistries. Decades of experimental and theoretical research in the field has resulted in only a few recent examples of Li-reservoir materials, all of which rely on the archetypal conjugated carbonyl redox chemistry. Here we extend the chemical space of organic Li-ion positive electrode materials with a class of conjugated sulfonamides (CSAs) and show that the electron delocalization on the sulfonyl groups endows the resulting CSAs with intrinsic oxidation and hydrolysis resistance when handled in ambient air, and yet display reversible electrochemistry for charge storage. The formal redox potential of the uncovered CSA chemistries spans a wide range between 2.85 V and 3.45 V (versus Li+/Li0), finely tunable through electrostatic or inductive molecular design. This class of organic Li-ion positive electrode materials challenges the realm of the inorganic battery cathode, as this first generation of CSA chemistries already displays gravimetric energy storage metrics comparable to those of the stereotypical LiFePO4.
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The datasets generated and analysed during the current study are available from the corresponding author upon reasonable request.
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J.W. and X.L. acknowledge the China Scholarship Council for funding. L.S. acknowledges partial support from FSR-UC Louvain for his fellowship. A.V acknowledges funding from a European Research Council (ERC) grant, project 770870-MOOiRE, as well as support from F.R.S.-FNRS through the grants J.0111.16–Equinox, J.0043.18–MESOPOL and U.N011.18–DEMIST. C.M. acknowledges financial support by the MEC, Nucleu-Program, project PN19 35 01 01. J.W. thanks A. Jouhara and E. Deunf for help with the initial experiments.
The authors declare no competing interests.
Peer review information Nature Materials thanks Kenichi Oyaizu and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
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Wang, J., Lakraychi, A.E., Liu, X. et al. Conjugated sulfonamides as a class of organic lithium-ion positive electrodes. Nat. Mater. 20, 665–673 (2021). https://doi.org/10.1038/s41563-020-00869-1