Phase change materials can improve the efficiency of energy systems by time shifting or reducing peak thermal loads. The value of a phase change material is defined by its energy and power density—the total available storage capacity and the speed at which it can be accessed. These are influenced by material properties but cannot be defined with these properties alone. Here we show the close link between energy and power density by developing thermal rate capability and Ragone plots, a framework widely used to describe the trade-off between energy and power in electrochemical storage systems (that is, batteries). Our results elucidate how material properties, geometry and operating conditions influence the performance of phase change thermal storage. This research sets a clear framework for comparing thermal storage materials and devices and can be used by researchers and designers to increase clean energy use with storage.
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All data generated or analysed during this study are included in the published article, its Supplementary Information and Source Data files
The numerical model developed for this work was generated in MATLAB R2019b. Unrestricted access to the source code is available at https://github.com/NREL/ThermalRagone.
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This work was authored by the National Renewable Energy Laboratory (NREL), operated by Alliance for Sustainable Energy, LLC, for the US DOE under contract no. DE-AC36-08GO28308. Funding provided by US DOE Building Technologies Office. The views expressed in the article do not necessarily represent the views of the DOE or the US Government. We thank S. Mumme from the DOE Building Technologies Office for his support and insight on this paper. We also thank J. Vidal and M. Bianchi from NREL for their feedback on our work.
The authors declare no competing interests.
Peer review information Nature Energy thanks Patrick Shamberger and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
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Supplementary Figs. 1–8, Notes 1–6, Tables 1 and 2 and references.
The PCM phase and the PCM and fluid temperatures when the baseline device is discharged at 1 C.
The PCM phase and the surface heat flux at y = 0 when the baseline device is discharged at 1 C.
The raw experimental data used to generate Supplementary Figs. 3 and 4.
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Woods, J., Mahvi, A., Goyal, A. et al. Rate capability and Ragone plots for phase change thermal energy storage. Nat Energy 6, 295–302 (2021). https://doi.org/10.1038/s41560-021-00778-w
Nature Energy (2021)