Interlocked molecules can exhibit chiral stereogenic elements that are not found in covalently bound systems. Now, the shuttling of the ring in a [2]rotaxane has been shown to result in enantiomeric co-conformations that selectively bind chiral guests.
This is a preview of subscription content, access via your institution
Relevant articles
Open Access articles citing this article.
-
Mechanically interlocked networks cross-linked by a molecular necklace
Nature Communications Open Access 16 March 2022
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Gal, J. Nat. Chem. 9, 604–605 (2017).
Corra, S. et al. J. Am. Chem. Soc. 141, jacs.9b00941 (2019).
Mislow, K. & Siegel, J. J. Am. Chem. Soc. 106, 3319–3328 (1984).
Eliel, E., Wilen, S. & Mander, L. Stereochemistry of Organic Compounds (Wiley, 1994).
Bruns, C. J. & Stoddart, J. F. The Nature of the Mechanical Bond: From Molecules to Machines (Wiley, 2016).
Jamieson, E. M. G., Modicom, F. & Goldup, S. M. Chem. Soc. Rev. 47, 5266–5311 (2018).
Schill, G. Catenanes, Rotaxanes and Knots (Academic Press, 1971).
Hirose, K. et al. Symmetry 10, 20 (2018).
Jinks, M. A. et al. Angew. Chem. Int. Ed. 57, 14806–14810 (2018).
Mochizuki, Y., Ikeyatsu, K., Mutoh, Y., Hosoya, S. & Saito, S. Org. Lett. 19, 4347–4350 (2017).
Quack, M. Angew. Chem. Int. Ed. 41, 4618–4630 (2002).
Wolf, C. & Bentley, K. W. Chem. Soc. Rev. 42, 5408–24 (2013).
Shabbir, S. H., Regan, C. J. & Anslyn, E. V. Proc. Natl Acad. Sci. 106, 10487–10492 (2009).
Herrera, B. T., Pilicer, S. L., Anslyn, E. V., Joyce, L. A. & Wolf, C. J. Am. Chem. Soc. 140, 10385–10401 (2018).
Jinks, M. A. et al. Angew. Chem. Int. Ed. 57, 14806–14810 (2018).
Cakmak, Y., Erbas-Cakmak, S. & Leigh, D. A. J. Am. Chem. Soc. 138, 1749–1751 (2016).
Alvarez-Pérez, M., Goldup, S. M., Leigh, D. A. & Slawin, A. M. Z. J. Am. Chem. Soc. 130, 1836–1838 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Twitter: @sgoldup
Rights and permissions
About this article
Cite this article
Jamieson, E.M.G., Goldup, S.M. Chirality makes a move. Nat. Chem. 11, 765–767 (2019). https://doi.org/10.1038/s41557-019-0320-z
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41557-019-0320-z
This article is cited by
-
Mechanically interlocked networks cross-linked by a molecular necklace
Nature Communications (2022)