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Thermal decomposition as the activity driver of near-Earth asteroid (3200) Phaethon

Abstract

Near-Earth asteroid (3200) Phaethon exhibits activity during its perihelion passage at 0.14 au from the Sun and is the likely parent body of the annual Geminid meteor shower. Its low albedo and featureless B-type reflectance spectrum indicate a primitive composition, but a definitive meteorite analogue is currently indeterminate. Here we analyse a mid-infrared emissivity spectrum of Phaethon and find that it most closely matches the Yamato group (CY) of carbonaceous chondrites. The CY chondrites experienced aqueous alteration and recent thermal metamorphism in which extreme temperatures caused mineral decomposition, resulting in the production of gas species. Temperatures within Phaethon during its close approach to the Sun are conducive to the thermal decomposition of carbonates, iron sulfides and phyllosilicates that release CO2, S2 and H2O gas, respectively. Spectral detection of these minerals strongly implies that gas release from mineral decomposition is capable of triggering dust ejection. The planned flyby of Phaethon by the DESTINY+ spacecraft in 2028 will allow us to verify this hypothesis.

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Fig. 1: Modelled mid-IR emissivity spectrum of Phaethon.
Fig. 2: Spectral comparison between Phaethon and various meteorite samples.
Fig. 3: Modelled spectrum and component mineral spectra.
Fig. 4: Temperatures estimated at one diurnal thermal skin depth beneath the subsurface and surface of Phaethon during perihelion passage.
Fig. 5: Modeled gas pressures and production.

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Data availability

All datasets analysed in this study are publicly available. The mid-infrared flux spectrum of Phaethon measured by the Spitzer Space Telescope’s Infrared Spectrograph instrument (AOR 4890624) is publicly available on the Spitzer Heritage Archive (https://sha.ipac.caltech.edu/). The reduced spectrum was published in ref. 26 and shared with the author(s) by Joshua P. Emery, a co-author of that study. Laboratory spectra of meteorites and minerals (Supplementary Table 2) can be downloaded from the RELAB database via the PDS Geosciences Node Spectral Library (https://pds-speclib.rsl.wustl.edu/), ASU (https://speclib.asu.edu) and CRISM spectral libraries (http://speclib.rsl.wustl.edu/).

Code availability

The orbTPM code is available on GitHub at https://github.com/cosmicdustbeing/asteroid-thermal. R packages (stats) are publicly available for download.

References

  1. Jewitt, D. The active asteroids. Astron. J. 143, 66 (2012).

    Article  ADS  Google Scholar 

  2. Jewitt, D. & Li, J. Activity in Geminid parent (3200) Phaethon. Astron. J. 140, 1519–1527 (2010).

    Article  ADS  Google Scholar 

  3. Jewitt, D., Li, J. & Agarwal, J. The dust tail of asteroid (3200) Phaethon. Astrophys. J. Lett. 771, L36 (2013).

    Article  ADS  Google Scholar 

  4. Li, J. & Jewitt, D. Recurrent perihelion activity in (3200) Phaethon. Astron. J. 145, 154 (2013).

    Article  ADS  Google Scholar 

  5. Hui, M. T. & Li, J. Resurrection of (3200) Phaethon in 2006. Astron. J. 153, 23 (2016).

    ADS  Google Scholar 

  6. Whipple, F. L. 1983 TB and the Geminid meteors. IAU Circ. 3881, 1 (1983).

    ADS  Google Scholar 

  7. Williams, I. P. & Wu, Z. The Geminid meteor stream and asteroid 3200 Phaethon. Mon. Not. R. Astron. Soc. 262, 231–248 (1993).

    Article  ADS  Google Scholar 

  8. Battams, K. et al. Continued PSP/WISPR observations of a Phaethon-related dust trail. Astrophys. J. 936, 81 (2022).

    Article  ADS  Google Scholar 

  9. Szalay, J. R. et al. Impact ejecta environment of an eccentric asteroid: 3200 Phaethon. Planet. Space Sci. 165, 194–204 (2019).

    Article  ADS  Google Scholar 

  10. Wiegert, P. et al. Supercatastrophic disruption of asteroids in the context of SOHO comet, fireball, and meteor observations. Astron. J. 159, 143 (2020).

    Article  ADS  Google Scholar 

  11. Masiero, J. R., Davidsson, B. J. R., Liu, Y., Moore, K. & Tuite, M. Volatility of sodium in carbonaceous chondrites at temperatures consistent with low-perihelion asteroids. Planet. Sci. J. 2, 165 (2021).

    Article  Google Scholar 

  12. Bach, Y. P. & Ishiguro, M. Thermal radiation pressure as a possible mechanism for losing small particles on asteroids. Astron. Astrophys. 654, A113 (2021).

    Article  ADS  Google Scholar 

  13. MacLennan, E., Toliou, A. & Granvik, M. Dynamical evolution and thermal history of asteroids (3200) Phaethon and (155140) 2005 UD. Icarus 366, 114535 (2021).

    Article  Google Scholar 

  14. Lisse, C. M. & Steckloff, J. K. Thermal alteration and differential sublimation can create Phaethon’s ‘rock comet’ activity and blue color. Icarus 381, 114995 (2022).

    Article  Google Scholar 

  15. Geem, J. et al. (3200) Phaethon polarimetry in the negative branch: new evidence for the anhydrous nature of the DESTINY+ target asteroid. Mon. Not. R. Astron. Soc. Lett. https://doi.org/10.1093/mnrasl/slac072 (2022).

  16. Licandro, J., Campins, H., Mothé-Diniz, T., Pinilla-Alonso, N. & de León, J. The nature of comet-asteroid transition object (3200) Phaethon. Astron. Astrophys. 461, 751–757 (2007).

    Article  ADS  Google Scholar 

  17. Clark, B. E. et al. Spectroscopy of B-type asteroids: subgroups and meteorite analogs. J. Geophys. Res. Planets 115, E6 (2010).

  18. de León, J., Pinilla-Alonso, N., Campins, H., Licandro, J. & Marzo, G. Near-infrared spectroscopic survey of B-type asteroids: compositional analysis. Icarus 218, 196 – 206 (2012).

    Google Scholar 

  19. Lazzarin, M. et al. Phaethon variability during December 2017 closest approach to Earth. Planet. Space Sci. 165, 115–123 (2019).

    Article  ADS  Google Scholar 

  20. Kareta, T., Reddy, V., Pearson, N., Sanchez, J. A. & Harris, W. M. Investigating the relationship between (3200) Phaethon and (155140) 2005 UD through telescopic and laboratory studies. Planet. Sci. J. 2, 190 (2021).

    Article  Google Scholar 

  21. Ikeda, Y. An overview of the research consortium, "Antarctic carbonaceous chondrites with CI affinities, Yamato-86720, Yamato-82162, and Belgica-7904". in Sixteenth Symposium on Antarctic Meteorites. Proc. NIPR Symposium 5, 49 (National Institute of Polar Research, 1992).

  22. King, A. J. et al. The Yamato-type (CY) carbonaceous chondrite group: analogues for the surface of asteroid Ryugu? Geochemistry 79, 125531 (2019).

    Article  Google Scholar 

  23. Salisbury, J. W. & Wald, A. The role of volume scattering in reducing spectral contrast of reststrahlen bands in spectra of powdered minerals. Icarus 96, 121–128 (1992).

    Article  ADS  Google Scholar 

  24. Hamilton, V. E. Thermal infrared (vibrational) spectroscopy of Mg–Fe olivines: a review and applications to determining the composition of planetary surfaces. Geochemistry 70, 7–33 (2010).

    Article  Google Scholar 

  25. Lane, M. D. et al. Midinfrared spectroscopy of synthetic olivines: thermal emission, specular and diffuse reflectance, and attenuated total reflectance studies of forsterite to fayalite. J. Geophys. Res. Planets 116, E08010 (2011).

    Article  ADS  Google Scholar 

  26. Hanuš, J. et al. Near-Earth asteroid (3200) Phaethon: characterization of its orbit, spin state, and thermophysical parameters. Astron. Astrophys. 592, A34 (2016).

    Article  Google Scholar 

  27. Nakamura, T. Post-hydration thermal metamorphism of carbonaceous chondrites. J. Mineral. Petrol. 100, 260–272 (2005).

    Article  Google Scholar 

  28. Nakato, A., Nakamura, T., Kitajima, F. & Noguchi, T. Evaluation of dehydration mechanism during heating of hydrous asteroids based on mineralogical and chemical analysis of naturally and experimentally heated CM chondrites. Earth Planets Space 60, 855–864 (2008).

    Article  ADS  Google Scholar 

  29. Lindgren, P. et al. Signatures of the post-hydration heating of highly aqueously altered CM carbonaceous chondrites and implications for interpreting asteroid sample returns. Geochim. Cosmochim. Acta 289, 69–92 (2020).

    Article  ADS  Google Scholar 

  30. King, A., Schofield, P. & Russell, S. Thermal alteration of CM carbonaceous chondrites: mineralogical changes and metamorphic temperatures. Geochim. Cosmochim. Acta 298, 167–190 (2021).

    Article  ADS  Google Scholar 

  31. Matsuoka, M. et al. Spectral and mineralogical alteration process of naturally-heated CM and CY chondrites. Geochim. Cosmochim. Acta 316, 150–167 (2022).

    Article  ADS  Google Scholar 

  32. King, A. J., Schofield, P. F., Howard, K. T. & Russell, S. S. Modal mineralogy of CI and CI-like chondrites by X-ray diffraction. Geochim. Cosmochim. Acta 165, 148–160 (2015).

    Article  ADS  Google Scholar 

  33. King, A. J., Solomon, J. R., Schofield, P. F. & Russell, S. S. Characterising the CI and CI-like carbonaceous chondrites using thermogravimetric analysis and infrared spectroscopy. Earth Planets Space 67, 198 (2015).

    Article  ADS  Google Scholar 

  34. Suttle, M. D. et al. The alteration history of the CY chondrites, investigated through analysis of a new member: Dhofar 1988. Geochim. Cosmochim. Acta 295, 286–309 (2021).

    Article  ADS  Google Scholar 

  35. Schrader, D. L. et al. The Fe/S ratio of pyrrhotite group sulfides in chondrites: an indicator of oxidation and implications for return samples from asteroids Ryugu and Bennu. Geochim. Cosmochim. Acta 303, 66–91 (2021).

    Article  ADS  Google Scholar 

  36. Bates, H. C., Donaldson Hanna, K. L., King, A. J., Bowles, N. E. & Russell, S. S. A spectral investigation of aqueously and thermally altered CM, CM-An, and CY chondrites under simulated asteroid conditions for comparison with OSIRIS-REx and Hayabusa2 observations. J. Geophys. Res. Planets 126, e06827 (2021).

    Article  Google Scholar 

  37. Takir, D. et al. Near-infrared observations of active asteroid (3200) Phaethon reveal no evidence for hydration. Nat. Commun. 11, 2050 (2020).

    Article  ADS  Google Scholar 

  38. Tonui, E. K., Zolensky, M. E., Lipschutz, M. E., Wang, M. S. & Nakamura, T. Yamato 86029: aqueously altered and thermally metamorphosed CI-like chondrite with unusual textures. Meteorit. Planet. Sci. 38, 269–292 (2003).

    Article  ADS  Google Scholar 

  39. Tonui, E. et al. Petrographic, chemical and spectroscopic evidence for thermal metamorphism in carbonaceous chondrites I: CI and CM chondrites. Geochim. Cosmochim. Acta 126, 284–306 (2014).

    Article  ADS  Google Scholar 

  40. King, A. J. et al. Tracing the earliest stages of hydrothermal alteration on the CM chondrite parent body. Meteorit. Planet. Sci. 56, 1708–1728 (2021).

    Article  ADS  Google Scholar 

  41. Haberle, C. W. & Garvie, L. A. Extraterrestrial formation of oldhamite and portlandite through thermal metamorphism of calcite in the Sutter’s Mill carbonaceous chondrite. Am. Mineral. 102, 2415–2421 (2017).

    Article  ADS  Google Scholar 

  42. MacLennan, E., Marshall, S. & Granvik, M. Evidence of surface heterogeneity on active asteroid (3200) Phaethon. Icarus 388, 115226 (2022).

    Article  Google Scholar 

  43. Rozitis, B., Green, S. F., MacLennan, E. & Emery, J. P. Observing the variation of asteroid thermal inertia with heliocentric distance. Mon. Not. R. Astron. Soc. 477, 1782–1802 (2018).

    Article  ADS  Google Scholar 

  44. Alí-Lagoa, V. et al. Differences between the Pallas collisional family and similary sized B-type asteroids. Astron. Astrophys. 591, A14 (2016).

    Article  Google Scholar 

  45. Kaplan, H. H. et al. Bright carbonate veins on asteroid (101955) Bennu: implications for aqueous alteration history. Science 370, eabc3557 (2020).

    Article  ADS  Google Scholar 

  46. MacKinnon, I. D. R. & Buseck, P. R. New phyllosilicate types in a carbonaceous chondrite matrix. Nature 280, 219–220 (1979).

    Article  ADS  Google Scholar 

  47. Yang, B. & Jewitt, D. Identification of magnetite in B-type asteroids. Astron. J. 140, 692 (2010).

    Article  ADS  Google Scholar 

  48. Zhang, Q., Battams, K., Ye, Q., Knight, M. M. & Schmidt, C. A. Sodium brightening of (3200) Phaethon near perihelion. Planet. Sci. J. 4, 70 (2023).

    Article  Google Scholar 

  49. Hu, H. et al. Study on the kinetics of thermal decomposition of mechanically activated pyrites. Thermochim. Acta 389, 79–83 (2002).

    Article  Google Scholar 

  50. Karunadasa, K. S., Manoratne, C., Pitawala, H. & Rajapakse, R. Thermal decomposition of calcium carbonate (calcite polymorph) as examined by in-situ high-temperature X-ray powder diffraction. J. Phys. Chem. Solids 134, 21–28 (2019).

    Article  ADS  Google Scholar 

  51. Granvik, M. et al. Super-catastrophic disruption of asteroids at small perihelion distances. Nature 530, 303–306 (2016).

    Article  ADS  Google Scholar 

  52. Arai, T. et al. DESTINY+ Mission: flyby of Geminids parent asteroid (3200) Phaethon and in-situ analyses of dust accreting on the Earth. in Lunar and Planetary Science Conference 2570 (Lunar and Planetary Institute, 2018).

  53. Devogèle, M. et al. New evidence for a physical link between asteroids (155140) 2005 UD and (3200) Phaethon. Planet. Sci. 1, 15 (2020).

    Article  Google Scholar 

  54. Houck, J. R. et al. The Infrared Spectrograph (IRS) on the Spitzer Space Telescope. Astrophys. J. Suppl. Ser. 154, 18–24 (2004).

    Article  ADS  Google Scholar 

  55. Haberle, C. W. et al. The mineralogy of recently fallen carbonaceous meteorites, mukundpura and Sutter’s Mill, in the context of asteroid (101955) Bennu. in 50th Annual Lunar and Planetary Science Conference 2144 (Lunar and Planetary Institute, 2019).

  56. Shirley, K. A. & Glotch, T. D. Particle size effects on mid-infrared spectra of lunar analog minerals in a simulated lunar environment. J. Geophys. Res. Planets 124, 970–988 (2019).

    Article  ADS  Google Scholar 

  57. Donaldson Hanna, K. L. et al. Spectral characterization of Bennu analogs using PASCALE: a new experimental set up for simulating the near surface conditions of airless bodies. J. Geophys. Res. Planets 126, e06624 (2021).

    Article  Google Scholar 

  58. Glotch, T. D., Morris, R. V., Christensen, P. R. & Sharp, T. G. Effect of precursor mineralogy on the thermal infrared emission spectra of hematite: application to martian hematite mineralization. J. Geophys. Res. Planets 109, E07003 (2004).

    Article  ADS  Google Scholar 

  59. Glotch, T. D. & Rogers, A. D. Evidence for magma–carbonate interaction beneath Syrtis Major, Mars. J. Geophys. Res. Planets 118, 126–137 (2013).

    Article  ADS  Google Scholar 

  60. Ramsey, M. S. & Christensen, P. R. Mineral abundance determination: quantitative deconvolution of thermal emission spectra. J. Geophys. Res. Planets 103, 577–596 (1998).

    Article  ADS  Google Scholar 

  61. Kass, R. E. & Raftery, A. E. Bayes factors. J. Am. Stat. Assoc. 90, 773–795 (1995).

    Article  MathSciNet  Google Scholar 

  62. Macke, R. J., Consolmagno, G. J. & Britt, D. T. Density, porosity, and magnetic susceptibility of carbonaceous chondrites. Meteorit. Planet Sci. 46, 1842–1862 (2011).

    Article  ADS  Google Scholar 

  63. Rodriguez-Navarro, C., Ruiz-Agudo, E., Luque, A., Rodriguez-Navarro, A. B. & Ortega-Huertas, M. Thermal decomposition of calcite: mechanisms of formation and textural evolution of CaO nanocrystals. Am. Mineral. 94, 578–593 (2009).

    Article  ADS  Google Scholar 

  64. Zhou, S. et al. Kinetics study on the dehydroxylation and phase transformation of Mg3Si2O5(OH)4. J. Alloys Compd 713, 180–186 (2017).

    Article  Google Scholar 

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Acknowledgements

This work is based in part on observations made with the Spitzer Space Telescope, operated by the Jet Propulsion Laboratory, California Institute of Technology under a contract with NASA. We thank J. P. Emery for sharing the previously published Spitzer-IRS spectrum of Phaethon.

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E.M. conceived the original idea, carried out the analysis, interpreted the results and was lead writer of the paper. M.G. assisted with the interpretation of results and provided consultation for the paper. Both authors discussed the results and contributed to the final paper.

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Correspondence to Eric MacLennan.

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Nature Astronomy thanks Tomoko Arai, Carey Lisse and Martin Suttle for their contribution to the peer review of this work.

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Extended data

Extended Data Fig. 1 Meteorite principal component analysis results.

Principal components (PC#) of mid-infrared spectra of carbonaceous chondrites. Datapoints are labeled and colored by their meteorite group with ‘CMh’ indicating naturally heated carbonaceous chondrites and ‘Mur’ corresponding to samples of the Murchison meteorite heated to the indicated temperature. Phaethon is indicated by the red star.

Extended Data Fig. 2 Decomposition model results for different materials.

Fraction of decomposed material (carbonate, phyllosilicate, or sulfide in panels a., b., and c., respectively) after one perihelion passage as a function of depth beneath the surface, expressed in terms of the thermal skin depth (ls)42.

Extended Data Fig. 3 Comparison between the visible and near-infrared reflectance spectra of Phaethon and CY meteorites.

Visible and near-infrared reflectance spectra of Phaethon and two CY meteorites ground into different size fractions or left as whole rock ‘chips’. The 1σ uncertainty for each reflectance value are shown as orange vertical bars. The blue line represents the average near-infrared (0.75 − 2.5 μm) spectral slope of 2005 UD, as observed by Kareta et al. (2021)20.

Extended Data Table 1 Spectral mixing models with different olivine and carbonate components

Supplementary information

Supplementary Information

Supplementary Tables 1-3.

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MacLennan, E., Granvik, M. Thermal decomposition as the activity driver of near-Earth asteroid (3200) Phaethon. Nat Astron 8, 60–68 (2024). https://doi.org/10.1038/s41550-023-02091-w

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