Review Article | Open | Published:

Electrochemically driven conversion reaction in fluoride electrodes for energy storage devices

npj Computational Materialsvolume 4, Article number: 22 (2018) | Download Citation



Exploring electrochemically driven conversion reactions for the development of novel energy storage materials is an important topic as they can deliver higher energy densities than current Li-ion battery electrodes. Conversion-type fluorides promise particularly high energy densities by involving the light and small fluoride anion, and bond breaking can occur at relatively low Li activity (i.e., high cell voltage). Cells based on such electrodes may become competitors to other envisaged alternatives such as Li-sulfur or Li-air systems with their many unsolved thermodynamic and kinetic problems. Relevant conversion reactions are typically multiphase redox reactions characterized by nucleation and growth processes along with pronounced interfacial and mass transport phenomena. Hence significant overpotentials and nonequilibrium reaction pathways are involved. In this review, we summarize recent findings in terms of phase evolution phenomena and mechanistic features of (oxy)fluorides at different redox stages during the conversion process, enabled by advanced characterization technologies and simulation methods. It can be concluded that well-designed nanostructured architectures are helpful in mitigating kinetic problems such as the usually pronounced voltage hysteresis. In this context, doping and open-framework strategies are useful. By these tools, simple materials that are unable to allow for substantial Li nonstoichiometry (e.g., by Li-insertable channels) may be turned into electroactive materials.


Higher energy density is required for energy storage devices, in particular for large-scale application in the electromobility market of the near future. For this purpose, Li metal batteries (LMBs) with Li metal as anode are receiving renewed attention after the short-lived research enthusiasm during 1970–1980. Later, the prevalence of LMBs was replaced by the advent of powerful Li-ion batteries (LIBs) offering a greater safety due to absence of Li dendrite growth. Owing to the progress in nanotechnology and in solid electrolyte research, there is hope that Li dendrite can be effectively suppressed and LMBs can be returned to.1,2 Li metal has the highest theoretical capacity of 3860 mAh/g (one magnitude higher than the 372 mAh/g of graphite C or LiC6, the commercial anode for LIBs) and lowest redox potential (3.04 V vs. the standard hydrogen electrode).3 In order to match well with the high capacity of the metal Li anode, conversion cathodes with their large capacities are desired, resulting in the recent development of Li-S and Li-O2 batteries.4 They can release a reversible capacity of more than 1000 mAh/g provided careful cathode designs are developed to, in particular, mitigate problems such as polysulfide dissolution for Li-S-induced and peroxide-induced side reaction for Li-O2. The dissolution problem in Li-S batteries gives rise to shuttle effects and active material losses, and the side reaction problem in Li-O2 batteries to poor energy efficiency. To alleviate these issues, complex porous conductive networks are often resorted to in order to either spatially confine reaction products, or construct gas passage and catalyst bonding sites.4 However such non-active components lower the specific capacity of practical electrodes.

Alternative candidates for conversion cathodes are transition metal fluorides owing to their high theoretical voltage and multi-electron transfer based on the reduction of transition metal cation to the neutral metal.5,6 Compared with oxide and sulfide counterparts, the high ionicity of M–F bonding favors higher reaction voltage frequently, however, at the cost of lower electronic conductivity and—not independently from this—of a smaller solubility range. Different from Li-S and Li-O2 systems, fluorides usually undergo solid–solid conversion reaction. Notwithstanding the interfacial and diffusional problems that conversion reactions bring about, they may have the advantage that admixtures of additional current collectors can be minimized if the spatial distribution of pristine fluoride nanoparticles and conversion (intermediate) products (e.g., M and LiF) is optimized.7,8 Such optimization critically depends on the interconnection of product M nanodomains forming a built-in electron-conductive percolating network;9 the other product LiF is neither a perceptible electron nor ion conductor. The ion conductivity is particularly bad if it is crystallized. However the electrochemical process can lead to amorphization, which seems beneficial with respect to mass transport issues.10 Electrochemistry-driven solid–solid phase transformation remarkably influences the pathway of Li/Na transport and storage in fluoride lattices. Grain boundaries and intra-grain multiphase interfaces should not markedly hinder the transport of the mobile carriers. In practice, however, even for the insertion reaction without breaking M–F bonding, the occurrence of multiphase reactions is a problem for achieving high-rate performance.11 Conversion reactions are characterized by interface formation/annihilation and hence by severe charge transfer and transport issues, all critically depending on the phase distribution. Therefore, investigating, simulating, and possibly tuning the microstructure evolution is of significant importance.

Recently, anion doping (e.g., O-doping in FeF2) was shown to significantly enhance the electron conductivity while the original crystalline structure was preserved.12 Another strategy is to introduce open frameworks (e.g., introduction of bronze and pyrochlore phases) and hence spacious ion channels and extended solid-solution reaction zone;13,14 these modifications of the ligand units or of the way how they are linked are expected to further complicate the microstructure evolution and phase transformation pathway in conversion fluorides.

Here, we summarize the recent progress on electrochemistry-driven phase transformation in conversion fluorides for Li-based and Na-based batteries and outline the corresponding phase transformation scenarios as available from electrochemical and microstructural characterizations, as well as from theoretical simulation. We do not intend to go into detail with respect to performance or synthesis. Rather we wish to set out characteristic features. As far as characterization is concerned, we refer to results stemming from physical characterizations such as transmission electron microscopy (TEM), electron energy-loss spectroscopy (EELS), solid nuclear magnetic resonance (NMR), X-ray absorption spectroscopy (XAS), pair distribution function (PDF) analysis, and transmission X-ray microscopy (TXM).9,15,16 Routine tools such as X-ray diffraction (XRD) are not appropriate for obtaining information on poorly crystallized conversion products. Amorphization or nanosizing of conversion products is often met, and it increases the difficulty of elaborate and quantitative characterization.17

In this review, we first describe the conversion reaction mechanism of iron-based fluorides (FeF2 and FeF3), the most popular and commercially available conversion salts. Then we discuss the impact of compositional modifications (mixed-anion effects, water incorporation within the open-framework strategy) on the performance of the conversion mechanism. Hereafter, we address the use and usefulness of non-iron fluorides. In particular, we describe the mixed cation effect in Cu-based ternary fluorides as well as the electrochemical splitting of LiF with the help of low-valence-state fluorides or oxides.

Conversion reaction in FeF x electrodes

In 1997, Arai et al.18 firstly introduced fluorides as potential insertion-type cathode materials in view of a larger theoretical capacity (e.g., 237 mAh/g for 3 V region FeF3 based on one-electron transfer) than that of LiFePO4 (170 mAh/g). However, even the most electroactive FeF3 material only released a reversible capacity of 80 mAh/g. Later, Badway et al.11,19 fabricated FeF3-C nanocomposites by ball milling commercially available ReO3-type FeF3 and activated carbon (15 wt%). Notwithstanding the various reaction stages FeF3 exhibits a voltage that is higher by 1–2 V than Fe2O3 owing to the induction effect of fluorine on the metal–nonmetal bond (Fig. 1a). Apart from a 3 V insertion reaction, a conversion reaction around 2 V can be observed and its quasi-plateau was remarkably prolonged when the working temperature was increased to 70 °C, leading to a total discharge capacity (including insertion and conversion contributions) of 660 mAh/g (Fig. 1b). This value is very close to the theoretical capacity of 712 mAh/g based on three-electron transfer. The achievement of high-voltage conversion reaction renders FeF3 a potential cathode candidate for LMBs while most conversion reactions are relevant for anodic functions. However, its conversion activity and efficiency are limited by kinetics, which is sensitive to temperature, grain size, and phase boundary conditions. The kinetic limitation lowers the practical voltage (~2 V) where FeF3 or FeF2 is converted into Fe and LiF with respect to the thermodynamic value (~2.7 V) reported by Li et al.20 As final conversion products Fe and LiF nanodomains were found according to high-resolution TEM (HRTEM) and selected area electron diffraction (ED) characterizations. However, local observations cannot reliably disclose the characteristic details of the overall phase transformation, especially for the regions where serious disordering or amorphization occurs. Also, exact information about intermediate products is not extractable, especially at the transition stage from insertion to conversion.

Fig. 1
Fig. 1

a The comparison of discharge curve of FeF3-C nanocomposite as cathode with that of Fe2O3 as anode at the same current density of 7.58 mA/g at 70 °C. b Discharge–charge voltage profiles of FeF3-C nanocomposite at 7.58 mA/g depending on different running temperatures of 22 °C and 70 °C. c Discharge curve of FeF3-C nanocomposite under a GITT mode. d Cell volume evolution as a function of Li insertion number in FeF3 (reproduced with permissions from refs. 11,19, copyright The Electrochemical Society 2003)

The degree of Li insertion during the preceding insertion reaction has a remarkable influence on nucleation and phase separation behavior in the subsequent conversion reaction. Based on galvanostatic intermittent titration technique (GITT) and diffraction, providing information on the cell volume, Li insertion into ReO3-FeF3 was reported to firstly undergo a two-phase reaction whereby the x-value in Li x FeF3 changes roughly from x = 0 to x = 0.5. This is followed by solid-solution behavior roughly ranging from x = 0.5 to x = 1 (Fig. 1c, d).11 The stoichiometry was predicted by density functional theory (DFT) when investigating the Li-Fe-F phase diagram.21 A topotactic intercalation of Li into FeF3 was predicted only up to the thermodynamically stable Li1/4FeF3. Further Li injection would result in non-topotactic phase evolution and even Fe precipitation, although the topotactic lithiation is still competitive up to at least Li1/2FeF3. However, this thermodynamic reaction path appears not to be in accordance with the experimental observation. Electrochemical energy storage often involves kinetically rather than thermodynamically stable reaction products. The deepest reduction of Fe within Li x FeF3 is determined by the solubility limit of Li in Li x FeF3 when being in equilibrium with LiF and Fe. In view of the much higher diffusivity of Li than of Fe, a kinetic reaction path with reduction of all Fe into Fe2+ (the lowest realistic valence state in such an ionic material) is expected along with a maximum Li content in Li x FeF3 of x = 1 before precipitation of metallic Fe begins. The predicted voltage evolution along a reaction path with maximal reduction to Fe2+ and following nano-Fe precipitation is plotted in Fig. 2a (red dashed line). From x = 1 to x = 3 in Li x FeF3 (with the generation of LiF and nano-Fe), a discharge voltage of ~2.15 V is predicted, which is very close to the experimentally conversion voltage (~2 V). In the Li-FeF phase diagram, the reaction path with initial topotactic lithiation of FeF3 to LiFeF3 and consequent conversion to Li3/2Fe3/4F3 and finally LiF is correspondingly tracked (red dashed line, Fig. 2b). One should note that in the kinetically stable LiFeF3 cation rearrangement minimizes face sharing between Fe and Li octahedra. Assuming a much lower mobility for Fe than for Li, the kinetic path was now determined in ref. 21 as the lowest energy path of the pathways characterized by the highest Fe valence. This difference in conversion and reconversion pathways naturally leads to a strong hysteresis as observed experimentally. The same kinetic pathway explains the occurrence of a rutile fluoride phase at full removal of three Li; these calculations do not suggest FeF2 (rutile) to be formed during charging, rather a defect rutile of the composition FeF3. For larger clusters this is more reasonable than resorting to a surface charge \(\left( {{\mathrm{FeF}}_2} \right)_{x^{\mathrm{\square}}}^{x + }\) given a removal of three Li in the delithiation process.

Fig. 2
Fig. 2

a Calculated discharge voltage profile of FeF3 considering the formation of nanoscale Fe during conversion reaction (red dashed line). c Calculated charge voltage profile of FeF3 during reconversion reaction (blue solid line). The experimental profiles are displayed in black dotted lines. Corresponding reaction paths of FeF3 during (b) conversion (red dashed arrows) and (d) reconversion (blue dashed arrows) processes (reproduced with permission from ref. 21, copyright American Chemical Society 2008)

The predict nonequilibrium reconversion path includes generation of (Fe-deficient) spinel Li15/8Fe3/8F3, ilmenite Li3/2Fe1/2F3, and rutile Li3/4Fe3/4F3 intermediate phases before arriving at defect-rutile FeF3 as shown in Fig. 2d (blue dashed line). The voltage evolution based on this nonequilibrium path is in reasonable accordance with the measured voltage profile (blue line in Fig. 2c). Although DFT predicted defect-rutile FeF3 as the ultimate recharged phase by favorably extracting Li from rutile-like Li3/4Fe3/4F3, the formation of rutile FeF2 is invoked based on the experimental observation by Badway et al.19 Note that the (simulated) XRD patterns between the two phases are very similar.19,21 An important conclusion drawn from the DFT calculation is that the voltage hysteresis is intrinsic and caused by different nonequilibrium (kinetic) reaction paths between discharge and charge according to Li-FeF phase diagram. The effect is rooted in the remarkably different mobility of Fe and Li cations in the fluoride host, as a consequence of which the Fe concentration always lags behind the equilibrium concentration for a given Li content (i.e., Fe excess during Li insertion and Fe deficiency during Li extraction).

With the development of advanced and especially in situ analysis technologies, more information about conversion reaction mechanism became available. In order to avoid the interference of intercalation, FeF2 with a negligible intercalation region was used as the model material by Wang et al.9 The conversion plateau during the first discharge is located at ~1.7 V at room temperature (Fig. 3a), which is lower than the thermodynamic equilibrium value of 2.7 V.20 Although the plateau voltage during the following discharge is increased to 2.3 V, it is still lower than the thermodynamic value. The voltage hysteresis between conversion and reconversion exceeds 0.7 V. These results indicate the relevance of kinetic pathways as inferred from DFT simulation.21 The rise of the FeF2 discharge potential after first conversion is kinetically caused and attributed to electrochemical grinding of active grains. During the conversion reaction, tiny Fe nanoparticles of < 5 nm were found to nucleate near the simultaneously converted LiF as a consequence of low mobility of Fe. Furthermore, these Fe nanoparticles are interconnected with each other to form a percolative electronic network superimposed to the inhomogeneously distributed insulating LiF matrix. Additional ionic transport pathways are provided by the newly generated interfaces and pores between these nanoscale phases. This scenario is concluded mainly from the combination of TEM, EELS, and PDF characterizations. HRTEM only provides the contrast for converted metallic particles, and is not effective for the contrast for lithium-containing fluorides due to weak scattering of light component elements. Therefore, the reaction mechanism cannot be clarified by TEM characterization only. EELS is sensitive to light elements and enables high-resolution (1 nm scale) compositional images of cycled electrodes. X-ray-induced PDF is sensitive to short-range order and finer microstructural details. The PDF patterns at different stages of the conversion process are shown in Fig. 3b according to the corresponding synchrotron XRD patterns (Fig. 3a). From the stages A to C (shallow lithiation from 0 to 0.29 mol Li), the PDF patterns do not show any remarkable change, although the nucleation of conversion products initiates at this stage of lowest potential between B and C. The facile agglomeration of FeF2 nanoparticles leads to a longer electron transport distance which is responsible for the poor kinetics during initial lithiation (voltage dropping and then climbing). This stage is characterized by a higher voltage and is likely associated with the surface reduction of Fe3+ to Fe2+. The Fe-Fe peaks corresponding to the formation of α-Fe become pronounced in stage D characterized by lithiation to 0.87 mol Li. The α-Fe signals are further intensified at the expense of those of FeF2 when the discharge process proceeds (from stages D to F). The PDF peak intensity indicates the ordering (coherence) degree or particle dimension, and its evolution here confirms a gradual particle shrinkage under electrochemical grinding. The fitting of PDF pattern at stage F (fully discharged state) discloses that the average particle size of α-Fe (Im3m) is around 2.6 nm. This estimated grain size is in accordance with the atomic-scale observation of 3–5 nm Fe nanoparticles by aberration-corrected scanning TEM. These nanoparticles are interconnected by sharing a common crystallographic orientation, for example, {110} plane. The coherence of Fe nanoparticles is likely caused by the fast diffusion of F out of FeF2 lattices, which promotes the nucleation and growth of Fe particles with preferred lattice alignment with the parent crystal to a certain degree.

Fig. 3
Fig. 3

a Voltage profile of FeF2 during the first discharge at 0.01C with different lithiation stages labeled as af. b Ex situ X-ray PDF profiles at corresponding electrochemical stages as shown in a (reproduced with permission from ref. 9, copyright American Chemical Society 2011). c Scheme of electrochemical cell for in situ TEM measurements. d TEM images of a collection of particles reacting with Li as a function of reaction time. e TEM image of Fe nanoparticles converted from a single FeF2 particle, inset: fast Fourier transform (FFT) pattern of selected region. f Li-Fe-F phase diagram by first-principle calculations. g Scheme of conversion reaction propagation within a single FeF2 particle via a “layer-by-layer” process (reproduced from ref. 22)

Later, Wang et al.22 developed an in situ electrochemical cell to further investigate the Li-driven conversion reaction of FeF2 nanoparticles by in situ TEM, ED, and EELS (Fig. 3c).22 It was found that the conversion reaction starts at the surface and propagates quickly across the FeF2 nanoparticles with gradual phase segregation in the individual particles (Fig. 3d). Inside the particles, FeF2 decomposes into Fe crystallites of 1–3 nm size and amorphous Li-F, which likely retards Fe interdiffusion and its coarsening. According to ref. 10, the disordered LiF should have a much higher ion conductivity than well-crystallized LiF.10 Similar to ex situ characterization, the interconnection of Fe crystallites with lattice alignment was also clearly observed from this in situ TEM measurement (Fig. 3e). In fact, the reaction within individual particles is quite fast, corresponding to a discharge rate of 5–20C. This real-time observation challenges the traditional viewpoint that solid–solid conversion kinetics is intrinsically sluggish. It is believed that high rate in practical batteries may be feasible provided a suitable electrode architecture is achieved with most fluoride nanoparticles homogeneously linking to current collector or at least a conductive network. By first-principle calculations based on DFT, Wang et al.9,22 predicted an equilibrium path with the formation of a tri-rutile LiFe2F6 intermediate, which is then converted to Fe and LiF (Fig. 3f). Unexpectedly, the Fe3+ component in LiFe2F6 cannot be detected by in situ EELS and also the lattice parameter change by in situ ED, indicating that the actual reaction follows a nonequilibrium path (cf. ref. 21). The in situ measurement disclosed that Li ions move rapidly at the surface, but much more slowly when having been incorporated into bulk FeF2. The coupling of ion and electron transports across nanoscale bulk and multiphase interfaces complicates the reaction path, which overall follows a “layer-by-layer” propagation process (Fig. 3g).

Ma and Garofalini23,24 used a dynamically adaptive force field approach to get deeper insight into the molecular mechanism of the FeF2 conversion reaction. Two potential diffusion channels along [001] and [110] directions with different energy were investigated. The barrier along the [001] channel is only 0.05 eV, whereas that along [110] is as high as ~1 eV. The former enables “high-rate” Li transport even with a small fraction of intercalation, followed by the formation of amorphous Li-F and Fe clusters. Clustering of Fe leaves under-bonded F ions, which combine with adjacent Li to form a Li-F network. This network is highly Li deficient and allows extra Li ions to pass and enter into the next subsurface layer. More Li uptake triggers the transformation of amorphous Li-F to crystalline LiF. At any rate, the insulating nature of crystalline LiF is detrimental for the electronic and ionic transport in the electrode.

Investigating thin-film architectures that are free of conductive additive and binder is beneficial for scrutinizing intrinsic electrochemical parameters.25 FeF2 thin films are easier to fabricate than FeF3 films using physical vapor deposition.26 The conversion reaction can even be investigated by lithiation of the FeF2 thin film. If very thin films are used, the kinetic influence is lowered and the conversion reaction should be rather thermodynamically controlled. Rangan et al.27 observed that ultrathin (~5 nm) FeF2 films facilely convert to interconnected metallic Fe nanodomains of ~3 nm surrounded by LiF under deposition of atomic Li. LiF was found to be better crystallized than under electrochemical lithiation. The inhomogeneous distribution of Li and Fe components was clearly observed by EELS mapping. During this chemical lithiation, no Fe+ signal was detected by X-ray and ultraviolet photoemission spectroscopy (XPS and UPS) performed in an ultrahigh vacuum environment. Thorpe et al.28 grew an epitaxial FeF2 (110) film on a MgF2 (110) single crystal substrate for atomic lithium exposure. They discovered that the lithiation of FeF2 initiates in a layer-by-layer manner (with a depth of ~1.2 nm) because of a high (~1 eV) kinetic barrier for the (110) channel as predicted by Garofalini et al.23,24 Then the reaction progresses in a non-planar manner, since the newly generated interfaces between nano-Fe and LiF provide additional paths for Li penetration and therein preferential nucleation occurs. As intermediate product of atomic lithiation Fe x Li2−2xF2 was detected by angle-resolved XPS and the Fe solubility was ascribed to substitution in the LiF lattice. Ko et al.29 chemically lithiated FeF2 thin films by n-butyl-lithium in order to generate an optimized metal network. They estimated the electron conductivity of the lithiated film electrode based on the architecture of interdigitated electrodes by electrochemical impedance spectroscopy and direct current polarization. The high value of 1–8 S/cm indicates the formation of an electronically percolating Fe network. This percolating path is somewhat epitaxial with less grain boundaries and therefore helpful to further improve the electron conductivity.

Most recently, a different picture of the FeF3 conversion reaction was given based on hard X-ray spectro-imaging, in situ synchrotron XAS, hybrid functional DFT calculations, and GITT.16,30 Hard X-ray spectro-imaging enables the visualization of electrochemically driven phase transformation even on a nanoscale (Fig. 4a, b). It was observed that the phase transformation is quite homogeneous for both conversion and reconversion reactions, unlike the inhomogeneous intercalation behavior in LiFePO4. This imaging suggests that the final charge product is characterized by an Fe oxidation state of +2. This statement disagrees with first-principle calculation claiming appearance of Fe3+-containing products after recharging the LiF:Fe nanocomposite. The authors propose that the phase transformation paths are symmetrical during discharge and charge processes (in contrast to the previous statement that the reaction paths are asymmetric with the generation of different intermediate products, leading to intrinsic voltage hysteresis),21 and that the voltage hysteresis mainly stems from the ohmic voltage drop, reaction overpotential, and different spatial distributions of electroactive (intermediate) products (i.e., compositional inhomogeneity). Their suggested reversible reaction path is: rhombohedral FeF3 → tri-rutile Li0.25FeF3 → tri-rutile Li0.5FeF3 ↔ rutile FeF2 + LiF ↔ Fe + 3LiF (Fig. 4d). This leaves much room for mitigating the voltage hysteresis and improving the energy efficiency. They noted another interesting phenomenon. They found a remarkable amount of metallic Fe when x = 0.6 in Li x FeF3 corresponding to an intermediate oxidation state of Fe (Fig. 4c). It indicates that the reduction of Fe2+ to metallic Fe may begin at outer surfaces (where Fe3+ has been reduced to Fe2+) before the intercalation-type reduction of Fe3+ to Fe2+ is completed. The lithiation of FeF3 is thought to proceed from the surface to the core of an individual active particle. Due to kinetic limitation, the reaction in an electroactive particle likely does not progress when the subsequent reaction in another particle starts under galvanostatic condition. Based on the core-shell reaction model, unreacted FeF x is mainly located at the core and LiF and Fe nanodomains form at the shell during discharging, whereas during recharging the situation is opposite. This leads to compositional inhomogeneity and an asymmetric voltage profile. A distinct overpotential is required to initiate nucleation and growth of new phases, and to drive the mass and interface transport. Liu et al.31 observed a hysteresis of 280 mV (vs. >1 V as usually observed even at low rate) by GITT with a long relaxation time of 72 h. They thought that this hysteresis is caused by the energy barrier for nucleation of LiF and Fe nanodomains (followed by coalescence of Fe nanoparticles and a reduced Fe/LiF interfacial area), rather than by intrinsically different reaction paths. Zhang et al.32 obtained information on coordination numbers and bond lengths of Fe-F and Fe-Fe bonds during insertion and conversion reactions of FeF3 by fitting in situ XAS, and deduced sequential reaction pathways consisting of two-phase intercalation (from x = 0 to 0.46), single-phase intercalation (from x = 0.46 to 0.92), and conversion reaction (from x = 0.92 to 2.78) steps for Li x FeF3. These examples from literatures clearly show the complexity of the process and that no final conclusion on the mechanism has been achieved so far.

Fig. 4
Fig. 4

a Voltage profile of FeF3 during recharging process to 4.5 V in an operando cell with four stages (small black circles) for data collection by hard X-ray spectro-imaging. b Mapping images of Fe element with different valence states at corresponding electrochemical stages as shown in a (reproduced from ref. 16). c Fe valence state and phase evolution of FeF3 nanowires during cycling, estimated by linear combinational fitting analysis of in situ XAS spectra. d Reaction pathways and structure evolution of FeF3 during conversion reaction concluded from both experimental and calculation results (reproduced with permission from ref. 30, copyright American Chemical Society 2016)

Room temperature Na-based batteries are receiving more and more attention in view of their resource abundance and lost cost. Although the larger size of the Na ion lowers the polarizing force and potentially enables higher rate performance during intercalation, the transport of Na ions across multiphase interfaces is expected to be sluggish due to its large volume. It has been reported that the Na-driven conversion capacity is typically inferior to the corresponding Li-driven one under comparable conditions.33 Na-based conversion reactions usually lead to insufficient conversion depth and less conductive wiring network owing to mass transport limitation. For these reasons, dense FeF x was rarely reported as conversion cathode for Na batteries. He et al.34 showed that the reversible Na-storage capacity for FeF2 nanoparticles is merely 100 mAh/g even when the cut-off discharge voltage is extended to 1 V. The poor performance is rooted in the heterogeneous sodiation mechanism, characterized by regular conversion at the surface (FeF2 + 2Na+ + 2e → 2NaF + Fe) and disproportionation reaction in the core (FeF2 + Na+ + e → 1/3Na3FeF6 + 2/3Fe). The Fe nanocrystallites in sodiated particles are 1–4 nm in size and are embedded in the Na3FeF6 matrix, which is coated by a NaF layer stemming from the surface conversion reaction. Fe nanocrystallites are also interconnected to form an electron-conductive network as in the case of the Fe/LiF system. The NaF coating can passivate the particle surface and retard inward diffusion of Na, leading to insufficient Na supply, which promotes the disproportionation reaction.

Phase transformation in iron oxyfluorides

Pure FeF2 and FeF3 are electronically and ionically insulating. Doping appears to be a good strategy to improve their intrinsic conductivities. Pereira et al.12 firstly reported a series of nanostructured O-doped fluorides (i.e., iron oxyfluoride) with different oxygen contents as conversion cathodes for Li batteries.12 They were prepared by a solution method with Fe metal and H2SiF6 solution as precursors, followed by heating treatment under different atmosphere, temperature, and time, and then by ball milling with activated carbon to achieve a composition in the range from FeF2 to FeOF. Among these oxyfluorides, FeOF is more stable than other FeO x F2−x compositions and has a theoretical capacity of 885 mAh/g based on a three-electron conversion reaction into Fe + LiF + Li2O, which is distinctly higher than for FeF3 (712 mAh/g) and for FeF2 (571 mAh/g). FeOF also exhibits a higher reaction voltage, better cycling performance, and higher energy efficiency than FeF2. FeOF exhibits the rutile structure of FeF2 but the high oxidation state of Fe3+ as in FeF3. As a charge-transfer semiconductor its electronic conductivity is higher than for the Mott–Hubbard insulator FeF2.35 The decrease of the c-lattice parameter is an indicator for the oxygen content and the oxidation degree. Since O2− and F have similar sizes, the substitution of O2− may occur randomly throughout the anion sublattice, without long-range ordering of O and F (some short-range ordering is still maintained).

The loss of long-range ordering and the possibility of a varying mixed anionic environment in FeOF severely aggravate the structure analysis especially during the conversion reaction. Wiaderek et al.36 used PDF and NMR, the typical tools for local microstructure characterization, to separately probe the local environments of Li, O, and F and to gain insight into the atomic structure, phase, and even particle evolution. It was found that during cycling of FeOF anionic partitioning occurs, with the formation of an amorphous F-rich rutile phase and a nanocrystalline O-rich rock salt phase. The charged electrode no longer consists of a single oxyfluoride phase. The reaction of F-rich and O-rich phases progresses sequentially with an unexpected preferential reaction with the former during both discharge and recharge. The discharge curve consists of a sloped high-voltage region (solid-solution-like intercalation from ~3 to ~2 V terminated at x = ~0.5 for Li x FeOF) and a plateau region (two-phase-like conversion mainly around 2 V terminated at x = ~1.9) at 50 °C. PDF disclosed a highly reversible phase transition during cycling. The intensity of PDF peaks is associated with the relative abundance of the corresponding atom–atom distances (i.e., coordination number or phase abundance), and their positions are related with the bond length. The first PDF peak at ~2.0 Å corresponds to both Fe-O (for rock salt) and Fe-F (for rutile) bonds. The short distance of 2.5 Å corresponds to the nearest-neighbor Fe-Fe bonds in Fe nanoparticles (2.5–3.0 nm) as discharge products based as simulations show (Fig. 5a, b). The peak at 5.0 Å corresponds to the formation of an intermediate rock salt product and was not observed in the pristine or discharged electrodes, but it still exists in the recharged state. The PDF curve features of the charged products are similar to those of the pristine electrode when the x-axis value (r) is smaller than ~5 Å. However, the features are weakened at higher r-value, indicating degradation of crystallinity or decrease of particle size after cycling. For a similar reason, the pristine rutile phase can be expected to become disordered during discharge and the reformed rutile phase to be amorphous during recharging. The rock salt intermediate has a similar microstructure and lattice distortion as α-LiFeO2 and becomes significant at x = ~0.4 before the conversion plateau begins (Fig. 5c). Residuals of this rock salt phase are still present even after termination of the charging when all the Fe nanoparticles have been converted into amorphous rutile. The residual amount of the rock salt phase is proportional to the O content in the oxyfluoride. Similar to the case of FeF3, it is confirmed that the formation of Fe nanoparticles occurs also prior to the conversion plateau. The fact that the charged phases are a mixture of O-rich and F-rich phases indicates that providing a single phase with mixed anions is unnecessary as long as an extremely intimate physical mixture of oxide and fluoride can be achieved. An irreversible O/F reaction sequence should be responsible for the observed voltage hysteresis during cycling. A reverse-step potentiostatic intermittent titration technique (PITT) was used to estimate the true hysteresis by eliminating the nucleation-induced overpotential.37 Under high-resolution PITT conditions with 10 mV steps involving extremely small current densities (C/1000), the hysteresis of conversion region for oxyfluoride is estimated as 0.7 V, remarkably smaller than the 1.3 V for FeF2 and FeF3.

Fig. 5
Fig. 5

a In situ X-ray PDF profiles of oxyfluoride during the first cycling. Distances characteristic of rock salt intermediate is indicated by arrows. Relative peak intensity is reflected from the color change. b Simulated PDFs corresponding to pristine and amorphous rutile phases, rock salt phase, and Fe nanoparticles. c Fe contained phase ratio and evolution during conversion reaction, estimated from PDF profile fitting. d Scheme of converted Fe nanostructure comparison among Fe oxyfluorides, fluorides, and oxides. The dominant Fe particle size (bars), average particle–particle separation (arrows), and number of well-defined neighboring particles are indicated (reproduced with permission from ref. 36,38, copyright American Chemical Society 2013 and 2014, respectively)

Wiaderek et al.38 further compared the oxyfluoride with a series of Fe-based fluorides and oxides to explore the influence of anion chemistry of pristine electrodes on the defect density in Fe lattices, particle size, shape, and interparticle interaction. The defect concentration in Fe lattices can be estimated by the intensity change of the Fe-Fe PDF peaks and the deviation of the second nearest-neighbor Fe-Fe distance. Compared with the single anion system, the mixed-anion system leads to a different nanostructure distribution scenario. The Fe nanostructures after lithiating oxyfluoride have no well-defined neighbors (at 60 °C), whereas they have two to four neighbors for FeF x or FeO x (Fig. 5d). In other words, for FeO x F y the converted Fe nanoparticles usually do not interconnect to form conductive networks or chains as in the case of FeF x . The particle size of Fe increases with the increase of the F content, and the local defect concentration increases with higher O content. According to ref.38, the strong affinity of O to Fe is likely to limit Fe mobility and defect healing. Accordingly, the conversion reaction of the O-rich phase results in a smaller size of discrete nanoparticles, whereas an improved mobility of Fe atoms for F-rich phase leads to larger particle size or favorable particle growth.

Fe-based oxyfluoride can also exist in an inhomogeneous form (e.g., core-shell structure) with a different O/F concentration distribution within a single particle, either by thermal oxidation of the fluoride (FeF3) or by surface fluorination of the oxide (Fe2O3, Fe3O4).39,40,41 Both the inhomogeneous doping and the surface treatment improved the electrochemical performance, for example, uplifting reaction voltage and promoting capacity retention. According to Zhou et al.40 the metastable FeOF is difficult to be tailored by thermal fluorination of Fe oxide; rather, FeOF is prone to decompose into interconnected FeF3 and Fe2O3 nanodomains resulting in a porous morphology. Kim et al.42 investigated the phase evolution of FeO0.7F1.3 nanoparticles with an F-rich core covered by a thin O-rich shell during conversion reaction. They reported that the O-rich rutile shell converts to rock salt Li-Fe-O(-F) and metallic Fe during lithiation. Both products show high lattice coherency, which is not diadvantageous for charge transport. The generated O-rich rock salt phase stays stable during the following cycling and its surface accumulation enables the particle integrity. The particle morphology is stable and characterized by the initial core-shell structure, indicating limited interdiffusion of F and O during conversion. The dominant redox reaction occurs at the F-rich core, where the Fe (2–3 nm) and LiF nanodomains are reversibly generated. In such core-shell structures, percolating conductive networks consist of rock salt Li-Fe-O(-F) and metallic Fe with high lattice alignment. This phase evolution scenario roughly conforms with that of ball-milled FeO x F2−x/C nanocomposites with homogeneous O/F distributions as reported by Cosandey and colleagues.43 These authors also observed the formation of a Li-Fe-O-F-like rock salt phase during the conversion process together with Fe and LiF nanodomains. This rock salt phase is also electrochemically irreversible and co-exists with an amorphous rutile phase during reconversion. The authors assume that the capacity degradation is caused by the gradually decreased amount of amorphous rutile phase and the corresponding increase of less active rock salt phase during further cycling.44

As far as Na storage is concerned, the more conductive oxyfluoride displayed a much better storability than pure FeF x , especially when resorting to tailored nanostructures, as they are often obtained by wet-chemical methods.45 Zhou et al.46 investigated the Na-storage phase transformation behavior in ball-milled FeO0.7F1.3/C nanocomposites with active particle sizes as small as 12 nm. The first discharge process showed a sloped curve from 2.4 to ~1.5 V and then a plateau around 1.5 V at 50 °C. The released capacity is found to be as high as 496 mAh/g, corresponding to 1.7 Na per FeO0.7F1.3, which is still lower than the theoretical capacity of 787.7 mAh/g based on three-electron transfer. The second discharge process releases a capacity of 414 mAh/g with a different electrochemical curve profile, indicating the development of a conversion mechanism. During the initial intercalation from 2.4 to 1.5 V, the rutile structure of FeO0.7F1.3 is preserved after 0.7 Na insertion (corresponding to 210 mAh/g). After the following conversion from 1.5 to 1 V, rutile Na0.7FeO0.7F1.3 is decomposed into fine Fe nanoparticles (2 nm) and NaF matrix coexisting with the newly formed rock salt Na1.4FeO1.4F0.6. During the reconversion to 2.3 V, Fe reacts favorably with NaF to form an amorphous rutile Na0.6FeF2.6 still with the rest of unconverted rock salt phase. During further recharging up to 3.5 V, Na ions are further extracted from both the intermediate rutile and rock salt phases. The authors assume that the Na-driven conversion paths for FeO0.7F1.3 are roughly similar to Li-driven ones. This statement is different from previous reports on other conversion systems (e.g., pure fluorides, oxides, and nitrides), where cation size can significantly impact reaction path and conductive network evolution.33,34

Variations of the storage properties can also be achieved by introducing hydration water into fluoride lattices, however likely, leading to the structural evolution to open-framework phases, for example, hexagonal tungsten bronze (HTB) or pyrochlore.13,14 In such an open-framework phase, inserted H2O molecules would be seriously distorted or delocalized owing to the strong hydrogen bonding with ligands. The conversion mechanism (path) and spatial distribution of (intermediate) products are thought to be associated with the original phase structure. Based on first-principle calculations, Li et al.47 reported that the water molecules are isolated in the HTB tunnels and form strong hydrogen bonding with F ions, enabling the mitigation of structure distortion in HTB framework (FeF3·0.33H2O). Li+ insertion into the water-accommodating tunnel can change the torsion angles of FeF63− octahedral chains, responsible for a wide reaction voltage window. Li0.66FeF3·0.33H2O is most stable with a maximum amount of Li. More Li insertion leads to a cleavage of the Fe-F bond and to the conversion reaction Li3FeF6 → LiFeF4 + 2LiF (i.e., decomposing a chain of octahedral structure (FeF63−) into tetrahedral structure (FeF4) and LiF). PDF analysis was also applied to disclose the conversion mechanism of HTB framework by Dambournet et al.48 According to this work, disordered rutile and rock salt phases and finally Fe/LiF nanodomains are generated along with the collapse of HTB framework with anionic vacancies (FeF2.2(OH)0.8−xOx/2x/2) during conversion reaction. The existence of anionic vacancies is observed to be beneficial for the enhancement of the reversible capacity, and however the exact reason for this still remains unclear. Similar to the case of FeOF, the disordered rutile phase rather than the pristine one is the dominating charged product. Later, Pohl et al.49 and Conte et al.50 found by combining multiple advanced characterization tools, for example, in situ XAS and Mossbauer spectroscopy, that also amorphous FeF3 or a bronze phase may form after cycling the hydrated HTB framework. Although the exact phase evolution mechanism for open-framework systems is still under debate, the voltage profile for a conversion-type open framework is indeed different from that of dense FeOF or FeF3. Most recently, Li and colleagues17 and Li et al.51 discovered that under long-term cycling of such a conversion reaction, the intercalation-like region at higher voltage (2.5–3 V) is still well maintained and the capacity loss gradually occurs in the conversion region (1.5–2 V), regardless of whether well-crystallized HTB or disordered pyrochlore phases are involved. In other words, the degradation of the low-voltage conversion region does not compromise the intercalation-like region at higher voltage, which is always highly reversible. However, for a densely structured fluoride, the capacity degradation occurs simultaneously in both electrochemical stages, resulting in a more serious de-activation. Na-storage is expected to be further activated by an open-framework strategy, especially for the pyrochlore phase (FeF3·0.5H2O) with interconnected 3D open channels.14 Li et al.14 firstly reported that the reversible capacity of FeF3·0.5H2O can be as high as 250 mAh/g, exceeding the theoretical intercalation capacity based on one-electron transfer. It indicates involvement of a Na-driven conversion reaction. By near-edge X-ray absorption fine structure spectra (NEXAFS), Ali et al.52,53 confirmed the reversible formation and splitting of NaF during (de)sodiation, which is responsible for the good reversibility of Na-based conversion in pyrochlore fluoride.

Conversion systems with other redox elements

In contrast to transition metal oxides, in transition metal fluorides non-Fe redox centers such as Mn, Co, and Ni have not shown to be electrochemically active at expected thermodynamic potentials. However, two kinds of conversion fluorides based on Bi or Cu redox chemistry (BiF3, BiOF, and CuF2) are worthy of concern.54,55,56 The related conversion reactions occur in the cathodic voltage range and do not undergo formation of intermediate intercalation products as in the case of FeF3. CuF2 has a theoretical capacity of 528 mAh/g based on two-electron conversion to Cu and LiF with a high thermodynamic potential of 3.55 V.56 It therefore results in an exceptionally high energy density of 1874 Wh/kg (~300% higher than that of LiCoO2 intercalation cathode). Its volumetric energy density is also very high, viz. 7870 Wh/L, exceeding even the value for CF x (~6000 Wh/L). The usual preparation route is via energy ball milling which results in CuF2-C or CuF2-oxide nanodomains. Tools such as admixing carbon or oxide have not succeeded in preventing the dissolution of Cu+ species, which is a problem especially during recharging.57 This dissolution process causes a loss of electroactive species and so far restricts the use of CuF2 as a cathode to primary Li batteries. CuF2 typically displays a distinct plateau at 3.0 V (up to 1 Li reaction number) and a subsequent sloped region down to 1 V (up to 2.1 Li reaction number). From the relatively sharp XRD peaks assigned to Cu metal, Yamakawa et al.58 concluded that the first formed Cu particles are large (~60 nm), while these peaks become broad when the Li content exceeds 0.5, indicating formation of smaller Cu particles (9 nm based on Scherrer formula). High Cu mobility and electron conductivity are held responsible for the formation of unexpectedly large Cu particles at the early stage of reaction. These early Cu particles generate and grow mainly near the conductive network (e.g., activated carbon). The released F ions are transported from the CuF2–Cu interface to the CuF2–electrolyte interface and therein react with more Li to form LiF. As the LiF layer grows a rather passivating coating is formed. This extra resistance for F-ion transport makes Cu start to nucleate within larger CuF2 particles, leading to the formation of CuF2/Cu nanodomains (Fig. 6a) and hence to particle pulverization (matrix destruction). However, the formation of Cu nanoparticles appears not to be helpful in significantly reducing the overpotential, since these Cu particles are surrounded initially by insulating CuF2 and then by LiF, and assembling into an electronic chain or network as in the case of FeF x is difficult.

Fig. 6
Fig. 6

a Scheme of potential reaction pathway of CuF2 during cycling (reproduced with permission from ref. 58, copyright American Chemical Society 2009). b Scheme of potential reaction pathway of Cu1−xFe x F2 during cycling. The conversion reduction to Cu and Fe occurs sequentially during discharge (stages I and II). The following oxidation processes of Fe and Cu (stages III and IV) overlap during charge, enabling the reformation of rutile-like Cu-Fe-F phase but with disordering (reproduced from ref. 59)

Recently, Wang et al.59 developed a novel strategy to fully utilize the Cu2+/Cu0 redox range and achieved the first application of Cu-based fluoride in rechargeable Li batteries. The prepared solid solutions of FeF2 (tetragonal rutile) and of CuF2 (monoclinic distorted rutile) result in Cu1−xFe x F2 with a tetragonal rutile structure of a higher symmetry than the pure CuF2. FeF2 doping is also beneficial for the introduction of a percolating conductive network consisting of converted Fe nanoparticles in Cu/LiF nanodomains. Cu1 x Fe x F2 displays a two-stage lithiation process: a Cu-based conversion reaction (upper plateau at ~2.9 V) in a similar potential range as CuF2 and a Fe-based conversion reaction at a much higher potential (~2.2 V) than FeF2 (Fig. 6b). The kinetic improvement also lies in the removal of the voltage dip observed in FeF2 and a reduction of the voltage hysteresis (<150 mV for Cu2+/Cu0 estimated by GITT). Cu0.5Fe0.5F2 shows a capacity of 575 and 543 mAh/g during the first discharge and recharge processes, respectively, both close to the theoretical capacity (549 mAh/g) based on two-electron transfer. It indicates a full reoxidation of Cu in the delithiated cathode. The reconversion of Cu starts from a low potential and largely overlaps with the oxidation of Fe. This may be responsible for the regeneration of solid-solution rutile Cu1−xFe x F2 despite the higher disorder. During the first-half conversion, the scenario that as-formed nanostructured FeF2 intermediates are surrounded by metallic Cu likely accelerates the second-half conversion to metallic Fe due to the improved electron (from already formed conductive Cu nanodomains) and ion (from more LiF/FeF2 interfaces) transport. The lattice disorder in FeF2 likely increases with down-sizing of FeF2 after first-half conversion, which is held responsible for the disappearance of voltage dip and higher discharge voltage during the initial second-half conversion. The small voltage hysteresis of Cu2+/Cu0 conversion is attributed to the low nucleation barrier for Cu-fluoride formation/decomposition. This report emphasizes the advantage of a synergetic conversion system using multiple redox centers (mixed cations herein) in the same lattices.59

BiF3 is another highly active fluoride cathode characterized by direct conversion to metallic Bi and LiF. Although Bi is a relatively heavy element, its three-electron transfer and high theoretical potential of 3.21 V still provide a considerable energy density of 969 Wh/kg.54 The major advantage of BiF3 lies in the extraordinarily high volumetric energy density of 8042 Wh/L. Kinetic limitations and probably the dominance of a nonequilibrium reaction path results in that the discharge voltage equilibrated by GITT is still by ~300 mV lower than the theoretical value. The plausible O-doping strategy was also applied in Bi-based fluoride.55 Some oxyfluorides (e.g., BiOF and BiO0.5F2) were successfully prepared. In contrast to FeOF, formation of oxyfluoride BiO x F3−2× (rather than a two-phase mixture of Bi2O3 and BiF3) is achievable after electrochemical cycling. The conversion reaction occurs sequentially with the formation of Bi0, LiF, and Bi2O3 at higher voltage and further reduction of Bi2O3 to Li2O and Bi0 in the second plateau. The delithiation process is roughly reversed with the splitting of Li2O first and LiF later. For the Bi-based fluoride, it was found that the carbonate electrolyte is not stable in the presence of Bi nanoparticles that are formed after the conversion, which induce the catalytic decomposition of solid electrolyte interface (SEI) layer at high voltage.60 This phenomenon causes the release of an O-containing species, which can diffuse into the subsurface of the fluoride structure and trigger the formation of oxyfluoride (BiO x F3−2×). The portion of this in situ generated oxyfluoride increases with increasing cycle number. This result also indicates a novel electrochemical synthesis route to oxyfluoride electrode. So far, other fluorides based on Mn, Co, Ni, and Ti are not promising as cathodes, since their conversion reactions are shifted to the anode voltage range.61,62,63,64 Strategies such as doping (NiO-doped NiF2), ion conductive coating (LiPON-coated CoF2), textured thin film architecture (CoF2 thin film), or self-assembly of metallic conductive networks (for nanostructured MnF2) have not shown to be effective in improving the cathodic function. Making use of structural variations such as employing rutile (LiMnF4) or spinel (Li2NiF4) have also not led to an improvement of the capacity and its retention in the cathode voltage range.65,66 But some encouraging information can be gained from these investigations. For example, fluorination of Ti-based oxide appears to be helpful in the reduction to metallic Ti0, which increases the electrochemical reversibility and enables facile splitting of LiF to form TiF3.67 Reduction to the metallic state of Ti is unfeasible for oxides.

Conversion systems with prior LiF splitting

Since most fluorides are Li-free, common Li-free anodes (e.g., graphite, Si) cannot be used in the LIB framework. Similar to electrochemical splitting of Li2O x and Li2S, LiF can also be split under the participation of transition metal, low-valence transition metal oxide or fluoride, enabling the construction of ′ion batteries′.68,69,70 Inspired by the decomposition products of FeF3, a pristine composite electrode consisting of nanostructured Fe and LiF was prepared.68,71 However, the Fe/LiF electrode failed to achieve the expected capacity owing to lattice mismatch and poor phase distribution. The conversion of Fe/LiF to FeF3 requires multiple nucleation and phase transformation processes. The reversible capacity is limited to 300 mAh/g with large voltage polarization even if discharged to 1 V or below. Later, Kim et al.69 enhanced the oxidation state of the Fe-based component by using FeF2 precursor (instead of metallic Fe) and achieved a better lattice matching with LiF at the cost of the capacity (Fig. 7a). LiF-FeF2 provides a reversible capacity of around 200 mAh/g with negligible polarization with most capacity being located above 3 V (Fig. 7d). In the first cycle a remarkable structure reconstruction takes place that is responsible for the large overpotential during that cycle. After the first cycle formation of a trigonal defective FeF3-like phase is suggested to occur as a consequence of F-ion incorporation into FeF2. In the following cycle, a reversible phase evolution from trigonal FeF3 to tri-rutile Li x FeF3 was proposed to occur, similar to the (de)intercalation reaction of FeF3. In ref. 69 a full cell was constructed by pairing a LiF-FeF2 composite cathode with a carbon anode. The cycling stability of this C-LiF-FeF2 cell was found to be satisfactory with a reversible capacity of 165 mAh/g and discharge voltage range of 1.5–3 V at least during early cycling. Equally, we expect a good full-cell performance for a Li-free (oxy)fluoride cathode and a lithiated graphite anode. Different from the immiscible LiF-FeF2 system, NaF and FeF2 can form a solid-solution phase (NaFeF3), which functions as insertion cathode for Na-ion batteries.72

Fig. 7
Fig. 7

a Scheme of reaction mechanism of FeF2-LiF composite (reproduced with permission from ref. 69, copyright Elsevier 2012). b Ex situ XPS spectra of Li 1s at different electrochemical stages. XPS peaks were normalized to the included Mn 3p peaks in order to estimate Li content in electrode. c Ex situ XPS spectra of F 1s at corresponding electrochemical stages. In order to avoid the interference by other F source signals, polyacrylonitrile (PAN) was used as the binder and ethyl carbonate/dimethyl carbonate (EC/DMC; v/v = 1:1) with 1 M LiClO4 as electrolyte. Charge–discharge curves of (d) LiF-FeF2, (e) LiF-MnO, and (f) LiF-FeO nanocomposites as cathodes for Li-ion batteries during the early cycling (reproduced with permission from ref. 70, copyright Springer Nature 2017)

In view of the advantage of oxyfluoride, more conductive MO (M = Fe, Mn, Ni, Co) precursors appear to enable the improvement of conversion kinetics when mixing or bonding with LiF.70,73,74,75 Most recently, Jung et al.70 developed a LiF-MnO conversion cathode with a dominant pseudocapacitive contribution (as high as 94%). The unusual electrochemistry is ascribed to a surface conversion mechanism realized by decorating nano-sized LiF on monoxide surface, which can cause a fast F absorption by MnO surface once reaction initiates. The electrochemical splitting of LiF was confirmed by XPS (Fig. 7b, c), where Li 1s peak at 56 eV disappears after first charge and recovers after following discharge. The binding energy of F 1s peak shifts from 685.3 to 686.0 eV after charge and is also recoverable after discharge. The peak signal at 686.0 eV stems from the formation of Mn-F bonding in order to compensate for the charge when Mn is oxidized beyond Mn2+ (e.g., defective spinel-like Mn3+ O-F). For both LiF-MnO and LiF-FeO systems, the discharge capacity can exceed 240 mAh/g (Fig. 7e, f). Under a high current density of 5 A/g, LiF-MnO can still deliver a reversible capacity of 110 mAh/g for at least 100 cycles, in agreement with a fast surface process. Note that in spite of the conversion, the way how this electrode functions looks like a surface storage rather than conventional conversion storage. It is pointed out in ref. 76 that the stationary cathode function of this system is a special case of the job-sharing principle,77 according to which the F-rich adsorption layer takes up the Li+ and the MnO the electron. The process does not work for the LiF-FeO system, LiF-FeO likely alloys to form a “LiFeOF” single phase.78

Challenges and perspectives

Solid–solid conversion reactions are typically accompanied by the breaking and forming of bonds with transition metal, and involve generation or annihilation as well as motion of multiphase interfaces. These features as well as the complexity of the reaction pathways are responsible for the voltage polarization and cycling problems. Previous reports have provided some insight into such questions and more detailed insight is expected by advanced characterization and simulation tools. Since conversion reactions in fluoride electrodes often result in poorly crystallized conversion products due to amorphization or nanosizing, routine tools such as XRD are not appropriate to obtain deeper information. Therefore, advanced tools including HRTEM, EELS, NMR, XAS, PDF, and TXM are to be explored for conversion processes.9,15,16 HRTEM only provides the contrast for the metallic phase and is not effective for the Li fluoride phase due to weak scattering of the light component elements. EELS is sensitive to light elements and enables high-resolution (1 nm scale) compositional images. PDF, XAS, and NMR are sensitive to short-range order and finer microstructural details of local structure, phase, and grain. TXM enables the visualization of electrochemically driven phase transformation even on a nanoscale.

The diffusion problems that are involved in the formation of various phases are not so problematic as it looks at a first glance. If the transport is very insufficient then automatically the composite formed will be a nanocomposite of very small scale. An important asset of the conversion reaction and of dealing with nanocomposites is the additional advantage to use interfacial storage which may be substantial when the interfacial density is high. A general recipe to make conversion reactions reversible has been given in ref. 79 If one succeeds to go to the sub-nanoscale and to implement reactive “clusters” into a 1D current collector such as carbon fibers, one can expect a reversible situation, as recently realized for MoS2. In such cases, the differences of the various storage modes, intercalation, conversion and interfacial, are blurred and the full capacity range can be taken advantage of. The challenge here consists in the preparation and the use of such a recipe for fluorides has not yet succeeded.

The biggest challenge for fluorides is to find the solution to further lower the reaction overpotential and improve the conversion energy efficiency (EE). As shown in Fig. 8, the EE values are 70.7% and 74.1% for FeF3 and FeOF, respectively, which are lower than those for LiFePO4 (93.9%) and typical transition metal oxides (NMC, 95.8%), but the energy densities of (oxy)fluorides are much higher, up to 1341.7 and 745.2 Wh/kg for FeF3 and FeOF, respectively, at 100 mA/g. The manipulation of the topological structure and its channel geometry, as well as the design of external wiring network should be paid more attention into the future research, in order to enhance the transport properties of the effectively mixed conducting network. It is also recommendable to lay more emphasis on the surface defect chemistry of fluorides (especially of the metastable or framework phases), which may enable further optimization of spatial distribution of pristine phases, conversion products and conductive network components in electrode. A decisive tool is the defect chemistry of the involved phases including stoichiometric variations and doping. A promising way of improving the kinetics would also be (partially) bypassing the solid–solid conversion path and making use of liquid–solid conversion mechanisms.80,81 In this context it is worthwhile to address conversion reactions involving Fe and LiBF4 instead of LiF, or to consider boron-based additives as F receptors to dissociate LiF. Exploring adapted electrolytes, additives, binders, and separators such that cathode dissolution effects as well as anode dendrite growth are suppressed is also necessary for commercializing energy storage fluoride materials in the future.82

Fig. 8
Fig. 8

Comparison of energy efficiency and energy density of (a) FeF3, (b) FeOF, (c) LiFePO4, and (d) transition metal oxide (NMC) based on their discharge–charge curves. The energy efficiency values are 70.7% and 74.1% for FeF3 and FeOF, respectively, which are lower than those of typical LiFePO4 (93.9%) and NMC (95.8%), although the energy densities of (oxy)fluorides are much higher and amount up to 1341.7 and 745.2 Wh/kg for FeF3 and FeOF, respectively, at 100 mA/g

The SEI effect on the electrochemistry of Fe-based (oxy)fluorides has been neglected for a long time. In fact, (oxy)fluorides show unique SEI features on the grain surfaces during cycling. The SEI consists of LiF, Fe0, trapped Fe2+, and likely FeO on the outer surface.44,83 The SEI layer would grow and become thicker, and cause increased dissolution of Fe and accumulation of insulating LiF, connected with the loss of active species and larger Fe interparticle distance. Therefore, the reconversion step is seriously impeded on progressing cycling, resulting in capacity fading of fluoride materials as observed. The growth of LiF-rich SEI layers is not desired as it would slow down ionic and electronic transport. To address the problems of electrode dissolution and SEI passivation, an electrolyte based on a high-concentration LiFSI salt was recently developed to suppress cathode dissolution by in situ formation of Li-ion-permeable protection layer at the electrode surface.82 Most recently, ultrathin artificial SEI layers (e.g., Al2O3 and LiPON) were prepared by atomic layer deposition and reported to conformally coat fluoride particles and mitigate side reaction between fluoride and electrolyte.84,85 Therefore, increased importance should be devoted to SEI issues in order to significantly improve the cycling stability of fluorides.

In summary, the strategies to electrochemically activate fluorides may include (1) building-block and defect-chemical variation in structure to achieve faster mass-charge transport, (2) construction of better effectively mixed conductive networks with nanoscale wiring,86 and (3) use of potential solid–liquid conversion (interface) reaction to bypass solid–solid conversion. Specifically for FeF3 with a reversible capacity of 500 mAh/g, a loading of 6 mg/cm2 is required to achieve an areal capacity of 3 mAh/cm2 (the standard for commercial use). The main challenge of such thick electrodes with still satisfactory cycling and rate performance lies in mitigating contact degradation and volume effects of the total architecture.

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This work was supported by National Key R&D Program of China (2016YFB0901600), National Natural Science Foundation of China (51772313, 51372263), Key Research Program of Chinese Academy of Sciences (KGZD-EW-T06), and “Hundred Talents” Program of Chinese Academy of Sciences and“Thousand Talents”Program of Shanghai.

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  1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China

    • Chilin Li
    • , Keyi Chen
    •  & Xuejun Zhou
  2. University of Chinese Academy of Sciences, Beijing, 100039, China

    • Keyi Chen
  3. Max Planck Institute for Solid State Research, Heisenbergstraße 1, D-70569, Stuttgart, Germany

    • Joachim Maier


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C.L. wrote the paper with input and suggestion from J.M., as well as with data processing from K.C. and X.Z.

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The authors declare no competing interests.

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Correspondence to Chilin Li.

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