Abstract
The investigation of cold interactions between ions and neutrals has recently emerged as a new scientific frontier at the interface of physics and chemistry. Here, we report a study of chargetransfer (CT) collisions of Rb atoms with N\({}_{2}^{+}\) and O\({}_{2}^{+}\) ions in the mK regime using a dynamic ionneutral hybrid trapping experiment. We observe markedly different CT kinetics and dynamics for the different systems and reaction channels studied. While the kinetics in some channels are consistent with classical capture theory, others show distinct nonuniversal dynamics. The experimental results are interpreted with the help of classicalcapture, quasiclassicaltrajectory and quantumscattering calculations using abinitio potentials for the highly excited molecular states involved. The theoretical analysis reveals an intricate interplay between short and longrange effects in the different reaction channels which ultimately determines the CT dynamics and rates. Our results illustrate salient mechanisms that determine the efficiency of cold molecular CT reactions.
Introduction
Studies of ionneutral interactions at very low temperatures have progressed considerably in recent years as a result of the development of techniques for the combined (hybrid) trapping of cold atoms and ions^{1,2,3,4,5,6}. At temperatures in the mK regime achievable in these experiments, new possibilities open up for the detailed exploration of collisional and chemical dynamics at the quantum level. Interactions between cold atomic ions and neutral atoms have been widely studied with these setups over the last decade. These investigations have provided insights into cold reactive processes^{7,8,9,10,11}, the sympathetic and internal cooling of ions by ultracold atoms^{12,13,14}, cold threebody recombination dynamics^{15}, spinexchange and relaxation processes^{16} and the statistical mechanics of trapped ions in a cold buffer gas^{17,18}.
While a large body of data by now exists on a range of atomic collisions systems, studies of cold collisions with molecular ions are still sparse. Previous experiments, included the combination of cold molecular beams or cryogenic gases with trapped ions^{19,20}, the merging of molecular beams containing Rydberg molecules^{21}, and the sympathetic cooling of molecular ions in hybrid trapping experiments^{13,22,23,24}. These latter studies uncovered unusually fast kinetics^{22}, the formation of exotic molecular species^{23} and reaction blockading of shortlived excited species^{24} in cold molecular ionneutral atom systems. These investigations gave a first glimpse at the wealth of additional phenomena which can be explored by extending hybrid trapping experiments from atomic to molecular systems.
In most of the systems studied so far in hybrid trapping experiments, charge transfer (CT) between the neutral atoms and ions was found to be a dominating reactive process. CT can be promoted either by radiative coupling of the entrance channel to energetically lowerlying CT channels^{25} or by nonadiabatic coupling between channels^{26}. In a previous study on reactions between N\({}_{2}^{+}\) molecular ions and Rb atoms^{22} at collision energies around 20 mK, a strong dependence of the CT rate coefficient on the electronic state of Rb was observed. CT was found to be extremely fast in collisions with excited Rb \((5p){}^{2}{P}_{3/2}\) atoms. By contrast, reactions with groundstate Rb \((5s){}^{2}{S}_{1/2}\) atoms were observed to be considerably slower than the Langevin limit which frequently serves as a benchmark for ion–molecule reactions^{27}. In the Langevin picture, the rate coefficient is limited by capture of the collision partners by longrange ioninduced dipole interactions whereas the shortrange reaction probability is assumed to be unity^{28}.
The results of ref. ^{22} already hinted at the importance of the interplay between short and longrange effects in cold CT reactions. Motivated by these findings, we explore this topic here in a comparative study of the CT between molecular oxygen (\({}^{32}\)O\({}_{2}^{+}\)) and nitrogen (\({}^{28}\)N\({}_{2}^{+}\)) ions with \({}^{87}\)Rb atoms using experiments in the cold regime together with computational work to interpret the dynamics at a molecular level.
The energetics of the reactions considered are illustrated in Fig. 1. N\({}_{2}^{+}\) and O\({}_{2}^{+}\) ions in their electronic ground states collide with Rb atoms in either the \((5s){}^{2}{S}_{1/2}\) ground or \((5p){}^{2}{P}_{3/2}\) first excited electronic state to produce \({{\rm{Rb}}}^{+}\) ions in the \({}^{1}{S}_{0}\) ground electronic state and neutral N\({}_{2}\) / O\({}_{2}\) molecules. On purely energetic grounds, the molecular CT products can form in a range of highly exited electronic states in both cases, in particular in collisions with excited Rb atoms in which case a range of low Rydberg states of the neutral product molecules are energetically accessible. Figure 1 also makes apparent that the entrance channels of the reactions considered here correspond to highly excited electronic states of the collision system.
In a first approximation, CT is considered to be most efficient if it is near resonant, i.e., if the entrance and product channels are energetically similar, and if it does not involve a marked reconfiguration of the electrons in the molecule^{29}. On these grounds, it could be expected that CT with Rb atoms in the \({}^{2}{P}_{3/2}\) excited state should be more efficient owing to the higher density of nearresonant, electronically favourable product channels (see Fig. 1).
In the present work, we have employed recently established experimental methods which allow an improved control over both the electronic state of the reactants as well as the collision energy in the mK regime^{30} to study the kinetics of CT in the different collision channels. We found a marked dependence of the dynamics on the initial state of Rb. CT was observed to be generally fast and the trends were found in many cases not to be compatible with the expectations outlined above. The experiments were analysed and modelled with the help of electronicstructure as well as quasiclassical trajectory simulations and quantumdynamics calculations. This theoretical modelling revealed an intricate interplay of longrange interactions and localised shortrange nonadiabatic couplings which, guided by the topology of the relevant potentialenergy surfaces, determine the details of the CT dynamics and kinetics. This situation stands in stark contrast to cold CT collisions in atomic systems which are usually slow and often dominated by radiative couplings ^{2,4,5,6}.
Results
Overview of experimental procedures
The experiments were conducted in an ionneutral hybrid trapping experiment consisting of a linear radiofrequency (rf) ion trap embedded in a magnetooptical trap (MOT) for Rb atoms (Methods)^{7,30}. Briefly, N\({}_{2}^{+}\) and O\({}_{2}^{+}\) ions were produced by REMPI and sympathetically cooled to mK temperatures by the interaction with a Coulomb crystal of lasercooled \({{\rm{Ca}}}^{+}\) ions. The molecular ions were thus prepared translationally cold in their vibrational ground states, but exhibited a roomtemperature distribution of rotational state populations. The experiment was operated in two modes. A static mode in which a cloud of lasercooled Rb atoms was overlapped with the Coulombcrystallised ions and a dynamic mode in which the cloud of cold Rb atoms was shuttled back and forth through the ions at a welldefined velocity using radiationpressure forces^{30}. While the static mode enables the measurement of CT rate coefficients as a function of the Rb state populations and thus the determination of statedependent rate coefficients, the dynamic mode allows in addition the measurement of reaction rates as a function of the collision energy with the Rb atoms in either the ground or a mixture of the ground and excited states. Note that the reactions of \({{\rm{Ca}}}^{+}\) with Rb are slower by several orders of magnitude^{7,22,30} compared to the processes studied here and therefore play a negligible role in the present experiments.
Statedependent chargetransfer rate coefficients
In a stationary MOT overlapped with the ions, both the \({}^{2}{S}_{1/2}\) and \({}^{2}{P}_{3/2}\) electronic states of Rb addressed by laser cooling on the Rb D II line are populated^{7}. The relative populations are determined by the photonscattering rate controlled by the intensity of the cooling laser and its detuning from the atomic resonance.
Figure 2 shows the dependence of the effective, i.e., stateaveraged, CT rate coefficient as a function of the Rb(\({}^{2}\)P\({}_{3/2}\)) population for reactions with \({{\rm{N}}}_{2}^{+}\) in Fig. 2a and with \({{\rm{O}}}_{2}^{+}\) in Fig. 2b. The green symbols represent the experimental results and the dashdotted lines are linear fits to the data. For N\({}_{2}^{+}\) + Rb (Fig. 2a), a clear dependence of the rate coefficient on the Rb(\({}^{2}{P}_{3/2}\)) population is observed. These results can be compared with our previous study^{22} in which this observation has been rationalised by an enhanced CT rate in the excited channel dominated by the capture of the ion by the permanent quadrupole of Rb in the \({}^{2}{P}_{3/2}\) state^{22}. The fit yields a rate coefficient \({k}_{p}({\text{N}}_{2})\)=1.7(6) \(\times\) 10^{−}^{8} cm^{3} s^{−1} for reactions with Rb(\({}^{2}{P}_{3/2}\)) (in line with the result of ref. ^{22}) and \({k}_{s}({\text{N}}_{2})\)=1.6(3) \(\times\)10^{−9} cm^{3} s^{−1} for reactions with Rb(\({}^{2}{S}_{1/2}\)). This new value for \({k}_{s}\) replaces the previous upper bound of \(\le\)2 \(\times\) 10^{−10} cm^{3} s^{−1} reported in ref. ^{22} where only an imprecise estimate for this quantity could be given because of the noisier data.
By contrast, the results for \({{\rm{O}}}_{2}^{+}\) + Rb shown in Fig. 2b reveal no clear dependence of the effective CT rate on the Rb excitedstate population. The hypothetical case of an effective rate coefficient expected for Langevin capture in the ground channel and, as with N\({}_{2}^{+}\), dominant ionquadrupole capture in the excited channel (solid orange line) does not agree with the observed data. Surprisingly, the effective rate coefficient closely follows a limiting value set by Langevin theory (blue solid line), implying Langevintype dynamics in both the ground and excited channels of O\({}_{2}^{+}\) + Rb. The Langevin rate coefficient for \({{\rm{O}}}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)) is \({k}_{s}^{\,\text{L}\,}({\text{O}}_{2})\) = 3.3 \(\times\) 10^{−9} cm^{3} s^{−1} (blue solid line) and a fit of a constant function to the data yields an effective rate coefficient \({k}_{\text{eff}}({\text{O}}_{2})\) = 2.9(8) \(\times\) 10^{−9} cm^{3} s^{−1} (black dashdotted line).
Collisionenergy dependent chargetransfer rate coefficients
The dynamic mode of the experiment allows both collisionenergy and statedependent measurements of CT rate coefficients by enabling or disabling laser cooling of the Rb atoms during the shuttling process (Supplementary Note 1). Figure 3 shows the collisionenergy and statedependent rate coefficients for (a) \({{\rm{N}}}_{2}^{+}\)+ Rb and (b) \({{\rm{O}}}_{2}^{+}\)+ Rb in the collisionenergy range from \(\approx 1030\) mK. Theoretical Langevin rate coefficients for the two channels are indicated by solid orange and blue lines. For reactions with \({{\rm{N}}}_{2}^{+}\) in (a), the Langevin predictions are \({k}_{p}^{\,\text{L}\,}({\text{N}}_{2})\) = 6.1 \(\times\) 10^{−9} cm^{3} s^{−1} and \({k}_{s}^{\,\text{L}\,}({\text{N}}_{2})\) = 3.5 \(\times\) 10^{−}^{9} cm^{3} s^{−}^{1} in the excited and ground channels, respectively. For \({{\rm{O}}}_{2}^{+}\) in (b), the corresponding values are \({k}_{p}^{\,\text{L}\,}({\text{O}}_{2})\) = 5.8 \(\times\) 10^{−9} cm^{3} s^{−1} and \({k}_{s}^{\,\text{L}\,}({\text{O}}_{2})\) = 3.3 \(\times\) 10^{−9} cm^{3} s^{−1}.
The blue dashdotted lines in Fig. 3a, b represent fits of the data to a constant function corresponding to the expected collisionenergy dependence of the rate coefficient for Langevintype dynamics. The fits yield rate coefficients \({k}_{s}({{\rm{N}}}_{2})\) = 1.5(2) \(\times\) 10^{−9} cm^{3} s^{−}^{1} and \({k}_{s}({{\rm{O}}}_{2})\) = 3.4(1) \(\times\) 10^{−9} cm^{3} s^{−1} for reactions of \({{\rm{N}}}_{2}^{+}\) and \({{\rm{O}}}_{2}^{+}\) with Rb(\({}^{2}{S}_{1/2}\)), respectively. In line with the results obtained in the static mode of the experiment, the rate coefficient for O\({}_{2}^{+}\ +\) Rb(\({}^{2}{S}_{1/2}\)) is in good agreement with the Langevincapture prediction over the entire collisionenergy range studied. This suggests that the dynamics is indeed dominated by longrange ioninduced dipole interactions and that the shortrange reaction probability is close to unity in this channel. Conversely, the rate coefficient for N\({}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)) is only about onethird of the universal Langevin value, indicating a pronounced effect of shortrange interactions on the kinetics.
For N\({}_{2}^{+}\) + Rb(\({}^{2}{P}_{3/2}\)), both the magnitude and collisionenergy dependence of the rate coefficient are consistent with a CT dominated by longrange ionquadrupole capture in line with previous findings^{22}. The orange dashdotted line in Fig. 3a represents a fit of the data for N\({}_{2}^{+}\) + Rb(\({}^{2}{P}_{3/2}\)) to a classical capture model including ionquadrupole interactions (Supplementary Note 2) yielding a quadrupole moment of \(Q=15.45(1.22)\) a.u. for the Rb (\({}^{2}{P}_{3/2}\)) state. This result can be compared with a theoretical value of \(Q=12.9\) a.u. computed at the MRCISD level of theory (Methods). At a collision energy \({E}_{\text{coll}}/{k}_{\text{B}}\) = 20 mK, a rate coefficient \({k}_{p}({{\rm{N}}}_{2})\) = 1.1(1) \(\times\)10^{−8} cm^{3} s^{−1} was determined from these data.
For O\({}_{2}^{+}\) + Rb(\({}^{2}{P}_{3/2}\)) in Fig. 3b, the experimental rate coefficients (orange triangles) appear to be considerably smaller than their predicted ionquadrupole capture limit (dashdotted orange line) and even slightly smaller than the corresponding Langevin limit (solid orange line). This finding points to a pronounced influence of shortrange interactions on the dynamics, in contrast to N\({}_{2}^{+}\) + Rb (\({}^{2}{P}_{3/2}\)) where this channel seems to be clearly dominated by universal longrange capture behaviour.
Potential energy surfaces
Insights into the widely varying CT dynamics across the systems and channels studied can be gained from analysing the relevant potential energy surfaces (PESs). Figure 4 shows the potential curves of both singlet and triplet electronic states of the N\({}_{2}\) and O\({}_{2}\) molecules as a function of the molecular bond length \(r\). The curves for the relevant cationic ground states are the solid green lines. Solid blue lines indicate the cationic curves shifted by the ionisation potential of Rb which correspond to the relevant energies of the lowest entrance channels for the CT reaction. The dashed lines represent the same curves offset by the energy of excitation to the Rb (\({}^{2}{P}_{3/2}\)) state. The potential curves shown are cuts through the threedimensional PES of the collision system with the Rb moiety at an infinitely large distance from the molecule. Curve crossings (indicated by circles) between the shifted ionic and neutral curves appear close to the molecular equilibrium geometry in both systems providing opportunities for nonadiabatic transitions and therefore CT around the crossing points.
As the collision partners all have doublet electron–spin character, collisions can occur on either singlet or triplet PESs. Figure 5 shows cuts of the adiabatic potential surfaces for (a) N\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)) and (b) O\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)) close to the computed minimum energy path for CT in the singlet channels at a linear collision geometry. For N\({}_{2}^{+}\) + Rb, an electronic barrier is found along this reaction path. While a CT reaction along this coordinate is thus in principle possible, the height of the barrier exceeds 5000 cm^{−1} and thus inhibits CT at the low collision energies of order \(\approx 1{0}^{2}\) \({{\rm{cm}}}^{1}\) of the present experiments.
The potentialenergy profile for O\({}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)) in Fig. 5b also exhibits a barrier along the shown reaction coordinate for CT. In this case, however, the barrier is submerged and thus provides no significant impediment to CT at the experimental collision energies. A similar curve crossing can also be found in the corresponding triplet reaction channel (see the red curve in Fig. 4b crossing the entrance channel close to the equilibrium geometry within the magenta circle). Thus, together with the experimental findings it can be surmised that the shortrange CT probability is near unity in both the singlet and triplet collision channels for O\({}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)) and that the CT rate coefficient is near the capture limit dominated by longrange Langevintype interactions.
Since CT in N\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)) is unlikely to occur via the singlet collision channel, Fig. 6 shows cuts of the triplet PES of the collision systems along the N\({}_{2}\)–Rb coordinate \(R\) for different N\({}_{2}\)Rb orientation angles \(\theta\). In the linear geometry (\(\theta =0\), Fig. 6a) the entrance channel with symmetry \({}^{3}{\Sigma }^{+}\) crosses with a \({}^{3}\Pi\) surface asymptotically connecting to the \(C{}^{3}{\Pi }_{u}\) state of N\({}_{2}\). In a nonlinear (\(\theta\, \ne\, 0\)) collision geometry (Fig. 6b–d), the \({}^{3}\Pi\) surface splits into an \(A^{\prime}\) and an \(A^{\prime\prime}\) component with the \(A^{\prime}\) surface undergoing avoided crossings with the entrance channel surface (also \(A^{\prime}\) in this symmetry). The separation of the resulting adiabatic surfaces at the crossing points, and hence the nonadiabatic coupling between them, increases with increasing orientation angle \(\theta\). The probability of nonadiabatic transitions around the crossings, and therefore CT, is thus expected to be strongly dependent on the orientation of the collision partners.
Quasiclassical trajectory and quantum dynamics calculations
To gain quantitative insight into the nonadiabatic dynamics of N\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)), we performed both quasiclassical trajectory simulations and quantum scattering calculations of the CT. The classical trajectory simulations employed a modified Landau–Zener formalism on the two coupled twodimensional \(A^{\prime}\) surfaces of Fig. 6 for modelling the CT (Methods). In the simulations, the bond length was frozen at the equilibrium value for N\({}_{2}^{+}\), thus yielding a twodimensional dynamics along the distance \(R\) between the centresofmass of N\({}_{2}^{+}\) and Rb and the orientation angle \(\theta\). Rate coefficients have been calculated for \({E}_{\text{coll}}/{k}_{{\rm{B}}}=10\), 20, and 30 mK from running 5000 independent trajectories each. The CT rate coefficients obtained are shown as red diamonds in Fig. 3 and are in good agreement with the experimental values.
Further insights into the CT dynamics can be gained from an analysis of the trajectories. Reactive CT trajectories are divided into two categories: (i) trajectories with a single collision, i.e., direct trajectories, and (ii) trajectories with multiple collisions, i.e., indirect trajectories. To categorise the trajectories, we classify them according to the collision time defined as the time elapsed between the first and last time a trajectory satisfies a geometrical criterion, here the sum of the three interatomic distances has to be smaller than 35 a.u. Most of the trajectories have collision times around \(\sim 0.5\) ps and the processes are, therefore, direct. This is illustrated in Supplementary Fig. 1, which shows a scatter plot of collision time vs. impact parameter at \({E}_{\text{coll}}/{k}_{\text{B}}=20\) mK. At 20 mK, 4374 of the 5000 trajectories show CT (3294 direct and 1080 indirect), whereas 626 end as N\({}_{2}^{+}\) + Rb (with 67 flyby or no collision, 513 direct and 46 indirect).
Three illustrative example trajectories, one direct and two indirect, are shown in Fig. 7. The dynamical path of the indirect trajectory with two collisions shown in Fig. 7b is displayed in Fig. 8 as its projection onto the two PESs. Large parts of the available configurational space are sampled despite the low collision energy. Crossings of the trajectory between the two PESs are distributed along all values of \(\theta\) and concentrated around \(R \sim 8\) and 12 a.u. as can be expected from the 1D cuts through the PES shown in Fig. 6. Multiple recrossings (labelled as events “A” and “B”) occur over the duration of the dynamics (indicated by the changing colours of the trajectory).
The trajectories, both direct and indirect, typically show multiple crossings between the surfaces (note that even a direct trajectory typically traverses four crossing regions). After the first collision, an outward trajectory ending up on the upper (entrance) surface is frequently trapped in the deep potential well as the low initial collision energy has been redistributed into other internal degrees of freedom and is not available for dissociation of the complex anymore. These trajectories often show pronounced largeamplitude internal rotations of the complex, i.e., the Rb orbits the N\({}_{2}\) moiety at large distances several times, see Fig. 8. These trajectories can then undergo multiple collisions. However, once an outward trajectory ends up on the lower (CT) surface after traversing the outer crossing point, it cannot return anymore because of the repulsive character of the lower potential surface in this region (see Fig. 6). Thus, the distinct shortrange topology of the two coupled surfaces ultimately contributes to explaining the high, but not unit, efficiency for CT in this channel. It is also evident that a longrange Langevincapture picture cannot explain the complex shortrange dynamics and its impact on the kinetics as observed in the experiments.
The insights from classical dynamics were corroborated by 1D quantumscattering calculations of the CT (Methods) performed at different orientation angles \(\theta\) (Supplementary Fig. 2). This 1D treatment is in the spirit of an infiniteorder sudden approximation (IOSA) previosuly employed for ionneutral collisions^{31}. The quantum results for the CT rate coefficients averaged over all orientation angles are indicated by the green symbols in Fig. 3a and are in good agreement with both the experimental and classicaldynamical results.
Discussion
From the good agreement between experimental results and the two different theoretical treatments of the CT rate coefficients for N\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)), several conclusions can be drawn. First, the CT dynamics can be understood in classical terms and apart from surface hopping, distinct quantum effects such as tunnelling and zeropoint motion do not seem to play a major role due to the large mass of the collision partners involved.
Second, it appears adequate to approximate the dynamics in reduced dimensionality, i.e., in 2D or even in 1D within an IOSAtype approximation, in order to correctly reproduce the observed kinetics. Note, however, that this cannot be expected for O\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)) in which case the reaction coordinate is more complex, see Fig. 5b. Note also that an 1D treatment cannot capture the roamingtype behaviour which seems to be important for certain types of collisions.
Third, in spite of the complex and dense electronic structure in the energy region of the entrance and exit channels (see Fig. 4), it seems sufficient to describe CT in N\({}_{2}^{+}\) + Rb (\({}^{2}{S}_{1/2}\)) by including only two coupled PESs. This can be rationalised in terms of the strong nonadiabatic couplings which happen around the crossing points between the two surfaces. Couplings to other states which show no crossings with the entrance channel in the energy region sampled by the experiments are expected to be considerably weaker and do not appear to affect the CT dynamics appreciably.
Fourth, the QCT calculations reveal that the reaction mechanism is a combination of direct and complexforming collisions. The latter typically show largeamplitude orbiting motions of the Rb around the N\({}_{2}\) moiety before the reaction occurs. This behaviour is somewhat reminiscent of the roaming dynamics recently discovered in a range of polyatomic reaction systems^{32,33,34,35}. Indeed, the type of dynamics uncovered here can be expected to be a common feature in cold reactions which proceed via the formation of a reactive complex with very little excess energy^{36}. Note that in a full 3D model of the dynamics, one can also expect the excitation of the N–N stretching vibration in the complex which was frozen in the present 2D treatment potentially leading to an even more diverse collision dynamics.
A quantitative modelling of the dynamics of the O\({}_{2}^{+}\) + Rb (\({}^{2}{P}_{3/2}\)) CT was outside the scope of the present study because of the considerably increased computational cost of the quantumchemistry calculations for this excited channel.
The cold CT dynamics explored in the present molecular collision systems has to be contrasted with the results of the atomic systems studied so far. In the vast majority of cases reported, CT was observed to be slow, i.e., the rate coefficients were found to be several orders of magnitude smaller than the universal capture limit, and dominated by radiative couplings^{9,11,16,25,37,38,39}. Notable exceptions are specific channels in \({{\rm{Ca}}}^{+}\ +\) Rb^{7}, \({\rm{Y}}{{\rm{b}}}^{+}\ +\) Ca^{8}, \({\rm{Y}}{{\rm{b}}}^{+}\ +\) Rb^{40}, \({\rm{Y}}{{\rm{b}}}^{+}\ +\) Li^{11} and \({{\rm{Ca}}}^{+}\ +\) Li^{39} in which CT was found to be nonadiabatic, but still considerably slower than the capture limit. By contrast, the CT rate coefficients of the systems considered here were all found to be close to the capture limit or only slightly slower. The good agreement between the experimental and the theoretical nonadabatic CT rate coefficients suggest that CT is indeed dominated by nonadiabatic effects in the present case. This conclusion is also corroborated by a recent theoretical study which found that radiative couplings are small in the N\({}_{2}^{+}\) + Rb system^{41}. Because the increased complexity of molecular compared to atomic collision systems provides more numerous opportunities for channel crossings, it can be expected that the situation observed here for N\({}_{2}^{+}\) + Rb and O\({}_{2}^{+}\) + Rb is fairly general. It can be surmised that CT will often be nonadiabatic and fast in the molecular systems of interest for coldcollision studies.
The trends observed here could be rationalised in terms of the efficiency of the nonadiabatic couplings involved. When the nonadiabatic transition probability during a collision is close to unity, the kinetics can be modelled by universal classical capture theory and is governed by the specific longrange interactions in the system, as observed here for N\({}_{2}^{+}\) + Rb(\({}^{2}{P}_{3/2}\)) and O\({}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)). Otherwise, the exact CT rates depend on the specific positions of curve crossings and the strengths of the relevant nonadiabatic couplings as well as on the topologies of the PESs involved, as observed here in N\({}_{2}^{+}\) + Rb(\({}^{2}{S}_{1/2}\)). The shortrange dynamics in this system was found to exhibit multiple transits of crossing regions in single and multiple collision events with the latter showing largeamplitude internal motions of the reaction complex. In this case, the effects of the longrange dynamics on the kinetics are superseded by shortrange effects which cannot be predicted without detailed theoretical modelling. This illustrates that it cannot, a priori, be anticipated whether universal behaviour applies and in particular whether the universal Langevin picture which is often invoked in the explanation of cold ionneutral reactive processes is valid.
Methods
Experimental methods
The experimental setup used in the present study has been described in detail previously^{7,30,37}. Briefly, an ionneutral hybrid trap was implemented by superposing a linear rf trap^{19} for the trapping and cooling of ions with a MOT for \({}^{87}\)Rb atoms^{7}. The ion trap was operated at a frequency of 3.25 MHz with an amplitude of \({V}_{\text{rf}}=\text{400}\,\ \,\text{V}\,\) and featured 12 separately addressable electrodes for applying static and rf voltages. An atomic beam of Ca was generated from a resistively heated oven from which \({{\rm{Ca}}}^{+}\) ions were loaded into the trap by nonresonant photoionization. The \({{\rm{Ca}}}^{+}\) ions were subsequently laser cooled to form Coulomb crystals^{1}. Molecular ions were generated inside the trap from photoionization of room temperature background gas at a background pressure of 1 \(\times\) 10^{−8} mbar using a \(\left[2+1\right]\) resonanceenhanced multiphoton ionisation (REMPI) via the \({a}^{{\prime\prime} }{}^{1}{\Sigma }_{g}^{+}\) electronic state for N\({}_{2}\)^{42} and via the \({}^{3}{\Phi }_{g}\)(\(\nu =1\)) Rydberg state for O\({}_{2}\)^{43}. The molecular ions were sympathetically cooled by the \({{\rm{Ca}}}^{+}\) ions to form strings localised on the rf null line of the trap. Following photoionization, the background pressure was kept at 1 \(\times\) 10^{−8} mbar for 30 s to allow collisions to establish a room temperature distribution of rotationalstate populations in the vibrational ground state of the ions. An EMCCD camera coupled to a microscope was used to obtain images of the Coulomb crystals by collecting the spatially resolved fluorescence of the trapped ions. The MOT was continuously loaded from background Rb vapour replenished by an alkali–metal dispenser. The MOT is capable of operating in three modes: stationary operation, bright shuttling and dark shuttling. In the stationary mode, the cold atom cloud was superimposed on the ions, while in shuttling mode the cold atoms were repeatedly shuttled through the ions at well defined velocities using radiation pressure forces^{30} enabling the tuning of the collision energies in the experiments. In the bright shuttling mode, the transversal Rb cooling lasers were left on so that parts of the Rb atoms were excited to the \({}^{2}{P}_{3/2}\) state during transit. In the dark shuttling mode, all lasers were switched off after accelerating the atom cloud so that the populations were confined to the ground state.
Electronic structure calculations
The PESs for the ground and excited electronic states were obtained using the multireference configuration interaction method restricted to single and double excitations, MRCISD, starting from orbitals obtained with the multiconfigurational selfconsistent field method, MCSCF^{44}. All atomic valence orbitals, i.e., both binding and antibinding molecular orbitals, were included in the completeactivespace reference wave functions. The N and O atoms were described using the augmented correlationconsistent polarised corevalence quintuple\(\zeta\) quality basis sets (augccpCV5Z)^{45}. The scalar relativistic effects in Rb were included by employing the smallcore relativistic energyconsistent pseudopotential ECP28MDF to replace the innershells electrons^{46}, while remaining electrons were described with the large \([14s14p7d6f1g]\) basis set^{47}. The electronic structure calculations were performed with the MOLPRO package of ab initio programs^{48}.
Ab initio energies were calculated for two excited \({}^{3}\)A\(^{\prime}\) electronic states of RbN\({}_{2}^{+}\) on a twodimensional grid in Jacobi coordinates (\(R,\theta\)) for a fixed N–N distance \(r=2.074\) a.u. corresponding to the equilibrium bond length in N\({}_{2}^{+}\). Here, \(R\) is the distance from the centre of mass of N\({}_{2}\) to Rb, \(r\) is the distance between the two N atoms and \(\theta\) is the angle between r and R. The upper PES adiabatically correlates with the N\({}_{2}^{+}\)(\({{\rm{X}}}^{^{\prime} 2}{\Sigma }_{g}^{+}\)) + Rb(\({}^{2}\)S\({}_{1/2}\)) asymptote while the lower surface dissociates towards N\({}_{2}\)(\({{\rm{C}}}^{3}{\Pi }_{u}\)) + \({{\rm{Rb}}}^{+}\).
Twodimensional analytical PESs for the two coupled \({}^{3}\)A\(^{\prime}\) electronic states were constructed from the ab initio energies using the reproducing kernel Hilbert space (RKHS) technique^{49,50}. For the radial dimension (\(R\)), a reciprocal power decay kernel was used which smoothly decays to zero \(\propto \frac{1}{{R}^{4}}\) and gives the correct longrange behaviour for ionneutral type interactions. For the angular degree of freedom, a Taylor spline kernel was used.
Quantum scattering calculations
The rate coefficients for the nonadiabatic CT collisions were calculated in the spirit of an infiniteorder sudden approximation (IOSA). Onedimensional cuts of the two crossing PESs were transferred from an adiabatic to diabatic representation assuming a Lorentzian shape of nonadiabatic couplings centred at the crossing points. Next, 1D quantumscattering calculations of the CT between two coupled diabatic potential energy curves were realised for several angles as presented in Supplementary Fig. 2. Subsequently, angleresolved rate coefficients were integrated over all possible orientation angles. To get 1D CT rate coefficients, the coupledchannels equations for the nuclear motions were solved using a renormalized Numerov propagator^{51} with stepsize doubling and about 100 step points per de Broglie wavelength in the exit channel as implemented in ref. ^{52}. The ratios of the wave function at two adjacent grid points were propagated from small finite interatomic separations in the classically forbidden region where the scattering wavefunction amplitude is negligible to large particle separations \(R\), and where polarisation potentials are negligible as compared to the collision energy. The \(K\) and \(S\) matrices were extracted by imposing longrange scattering boundary conditions in terms of Bessel functions. The inelastic rate coefficients were obtained from the elements of the \(S\) matrix summed over all relevant partial waves \(l\) and thermally averaged assuming a Maxwell–Boltzmann distribution. The results of the quantum scattering calculations were numerically converged with respect to grid parameters, collisions energies, and partial waves.
Quasiclassical dynamics simulations
The quasiclassical trajectory (QCT) method followed in this work has been discussed in detail in ref. ^{53} based on refs. ^{54,55}. Hamilton’s equations of motion were solved using a sixthorder symplectic method. Initial conditions for a trajectory were sampled from a standard Monte Carlo sampling method^{54}. The rotational states of N\({}_{2}^{+}\) were sampled from a Boltzmann distribution at room temperature (300 K). Stratified sampling^{54,56} was used to sample the impact parameter \(b\). Two time steps (\(\Delta t\)) of 0.6 (from the beginning of a trajectory until it reaches \(R\, <\, 35\) a.u.) and of 0.05 fs (for the first time a trajectory reaches \(R\, <\, 35\) a.u. to the end) were used for the numerical integration to ensure conservation of total energy and total angular momentum.
The trajectory surface hopping method^{57} was used to determine CT rates including nonadiabatic transitions within a modified Landau–Zener^{58,59,60,61} formalism. The modified Ladau–Zener formula depends on the adiabatic potential energies of the states involved in the transition and at time \({t}_{c}\) is
Here, \({P}_{{\rm{LZ}}}^{j\to k}\) is the transition probability from state \(j\) to state \(k\) and \(\Delta {V}_{jk}^{a}(x)\) is the adiabatic energy difference between these states. Whenever \(\Delta {V}_{jk}^{a}(x)\) reached a local minimum, transition probabilities were calculated and momentum corrections along different degrees of freedom were applied^{62} after a successful hop to keep the total energy and angular momentum conserved for a given trajectory.
The rate coefficients at a particular collision energy (\({E}_{{\rm{coll}}}\)) were calculated from
where \(\mu\) is the reduced mass of the collision system, \({N}_{{\rm{r}}}\) is the number of reactive (CT) trajectories (weighted by stratum statistical weight), \({N}_{{\rm{tot}}}\) is the total number of trajectories, \({g}_{e}\) is the electronic degeneracy factor (here 3/4) and \({b}_{\max }\) is the maximum impact parameter for which a CT reaction can occur.
Data availability
The data that support the findings of this study are available from the corresponding authors upon request.
Code availability
The codes that support the findings of this study are available from the corresponding authors upon reasonable request. The code for generating a RKHS representation of the electronic structure data is available at https://github.com/MeuwlyGroup/RKHS.
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Acknowledgements
The current work was supported by the Swiss National Science Foundation, grant nr. 200020_175533, the NCCR MUST and the University of Basel. M.T. was supported by the National Science Centre Poland (Sonata Grant nr. 2015/19/D/ST4/02173) and the PLGrid Infrastructure.
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A.D. performed all the experiments except for the reactions of O\({}_{2}^{+}\) with a stationary Rb cloud which were performed by P.E. S.W. supervised the experimental part of the project. M.T. performed the electronicstructure and quantumdynamics calculations. D.K. and M.M. performed the classicaldynamics calculations. A.D., M.T., D.K., M.M. and S.W. wrote the paper.
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Correspondence to Michał Tomza or Markus Meuwly or Stefan Willitsch.
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Dörfler, A.D., Eberle, P., Koner, D. et al. Longrange versus shortrange effects in cold molecular ionneutral collisions. Nat Commun 10, 5429 (2019). https://doi.org/10.1038/s4146701913218x
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