Abstract
The phoretic mechanisms at stake in the propulsion of asymmetric colloids have been the subject of debates during the past years. In particular, the importance of electrokinetic effects on the motility of PtPS Janus sphere was recently discussed. Here, we probe the hydrodynamic flow field around a catalytically active colloid using particle tracking velocimetry both in the freely swimming state and when kept stationary with an external force. Our measurements provide information about the fluid velocity in the vicinity of the surface of the colloid, and confirm a mechanism for propulsion that was proposed recently. In addition to offering a unified understanding of the nonequilibrium interfacial transport processes at stake, our results open the way to a thorough description of the hydrodynamic interactions between such active particles and understanding their collective dynamics.
Introduction
The ability to design active colloids and to accurately control their motion in a fluid environment is one of the cornerstones of modern physical sciences, and has motivated a significant amount of work over the past years^{1,2,3}. In particular, it has enabled experimental efforts to mimic functions inspired by cellular biology, such as cargo transport or chemical sensing, which might lead to radically new medical applications. From a theoretical point of view, such objects do not obey the laws of equilibrium statistical physics, and the description of their nonequilibrium dynamics remains a major challenge. Understanding these nonequilibrium phenomena could help us develop a new paradigm in engineering by designing emergent behaviour.
Phoretic transport has emerged as a prominent mechanism for nonequilibrium activity. It has been known for many decades that the interactions between a particle immersed in a fluid and an inhomogeneous field—which can be chemical concentration, temperature, or electrostatic potential—can lead to forcefree and torquefree propulsion^{4,5,6}. Although the field gradients can be externally imposed on the phoretic particles, a most interesting situation arises when the particle generates them itself. For instance, the particle can bear an “active site”, which degrades solute particles present in the bulk. The resulting asymmetric distribution of reaction products creates a nonzero slip velocity at the surface of the particle and yields selfpropulsion^{7,8,9,10}.
A number of different particles that break foreaft symmetry have been designed, including bimetallic rods^{11} and insulator spheres with only one metalcoated hemisphere^{12} that are able to decompose hydrogen peroxide with Pt as a catalyst. It was shown that bimetallic swimmers are able to decompose fuel simultaneously at both ends. Such an electrochemical process results in an electron transfer across the object, and the associated proton movement in the solution permits selfelectrophoretic propulsion. However, despite extensive studies, the phoretic mechanisms at stake in Janus sphere propulsion are not yet well established, and have been the subject of recent debates. Although their constitutive material (typically polystyrene) is an insulator, recent experimental investigations have revealed that electrokinetic effects need to be taken into account together with diffusiophoretic effects to fully describe the propulsion mechanism^{13,14,15,16}. The emergence of such effects is permitted by the inhomogeneity of Pt coating, which is thicker at the pole of the colloid than at its equator. We recently proposed a mechanism where the motility of the PtPS sphere is linked to closed current loops, which start at the equator of the particle and end at its pole (Fig. 1a). These conjectured closed proton loops are expected to yield a strongly asymmetric slip velocity across the surface of the colloid^{13,16}. This proposal allowed us to explain the ionic strength sensitivity of the swimming velocity and the nonequilibrium surface alignment phenomenon observed in our experiments^{17}. However, direct experimental evidence that proves this conjecture has been lacking so far.
Here, we measure the flow fields around moving PtPS Janus particles using particle tracking velocimetry (PTV). This approach has previously provided insight in to flow fields around stagnant Janus colloids actuated by AC electric fields^{18,19}. However, extending this method to our chemically driven system is comparatively more challenging due to the random stochastic Brownian reorientation of the moving PtPS Janus particles. In a related study, the flow field around swimming microorganisms was reported, using phototactic guidance to prevent rotation in one case, and also by analysis of tracer particle motion near freely moving cells subject to rotation^{20}. In absence of a mechanism to prevent PtPS Janus particle rotation, here we developed pattern matching image analysis algorithms to allow tracer particle motion to be quantified relative to the frame of reference of a freely moving and rotating PtPS Janus particle. Control experiments conducted near a symmetrical catalytically active Pt colloid showed that the tracer motion is dominated by fluid flow rather than chemical gradients. This method consequently allowed us to arrive at average flow fields derived from observations of many different PtPS Janus particles.
Results
Experimental methods
An optical cuvette filled with a mixture of tracer particles and Ptcoated Janus colloids was prepared, and the tracer particles at the top of the cuvette were brought into focus. After a few minutes equilibration time some of the gravitactic Janus sphere swimmer particles^{21} had travelled to the top of the cuvette and could be seen translating parallel to the glass surface. After a period some of the Janus spheres became stuck to the surface, probably due to impurities on the surface. We recorded images of the Janus spheres moving through the field of tracer particles. We note that focussed at the top of the cuvette the bulk of the tracer particles are not in focus. This provided a background level of illumination that enabled us to image the nonfluorescent Janus spheres, where they appeared as a transparent disc with a shadow covering onehalf of the disc indicating the position and rotation of the Pt cap. For both the moving and stuck colloids the Janus particle appeared as a “halfmoon” shape consistent with the near surface alignment effect reported in ref. ^{17}. This was confirmed by image analysis that found the polar angle to be close to 90°. The observation that the static colloids also showed this alignment relative to the substrate, suggests they were translating along the surface before becoming stuck. Tracking of the tracer particles has been described before^{12,22} but the Janus spheres required a different approach. We used pattern matching to obtain the center position of a Janus sphere and the angle of rotation of its Pt cap. This data was further analysed as described in the Methods section to arrive at flow fields averaged over the observation of many different colloids. Figure 1 shows the experimentally determined flow fields around both stuck and translating Janus spheres.
To assess phoretic effects in a closely related system that is expected to only produce a chemical gradient, and no flow field, a = 2.5 μm polystyrene particles were symmetrically coated in Pt metal. This was achieved using the solution phase salt reduction method that has been previously described, performed without the Pickering emulsion mask step, resulting in a uniformly Ptcoated colloid^{23}. Tracer motion was again observed and quantified as described above both in the presence and absence of 10 wt% H_{2}O_{2}.
Theoretical description
In the low Reynolds number limit, the flow field u around the Janus colloid is the solution of the Stokes problem:
with boundary conditions imposed by the phoretic mechanisms taking place at the surface of the colloid.
We first present the solution of these equations in free space, neglecting the nearby solid wall at the top of the experimental cell (see below for a discussion regarding this approximation). The phoretic contribution to the total flow field u^{ph} originates from a nonzero tangential slip velocity at the surface of the colloid that arises from the current loops^{13,16}, denoted as \(v(\theta ) \equiv {\mathbf{u}}^{{\mathrm{ph}}}\left( {r = a,\theta } \right) \cdot {\hat{\mathbf{e}}}_\theta\) for simplicity. The slip velocity v(θ) is written as an expansion on Legendre polynomials P_{n}:
The coefficients B_{n} (which have the dimension of a velocity) are not known a priori and depend on the details of the phoretic mechanisms taking place at the surface of the colloid.
In the situation where the Janus swimmer is stuck to the glass slide, the total flow field may be written as u = u^{ph} + u^{mono}, where u^{ph} is the phoretic contribution and u^{mono} is the contribution from the force monopole that maintains the colloid steady in the laboratory frame of reference. The contribution from the force monopole \({\mathbf{f}} =  f{\hat{\mathbf{e}}}\) that holds the colloid to the glass slide takes the simple form
where \({\hat{\mathbf{e}}}\) is the direction of swimming. The value of the force f is computed by enforcing the steadiness of the colloid in the laboratory frame of reference. The flow field around the colloid when it is freely moving is obtained in a similar fashion, but without the contribution from the force monopole and subject to the boundary condition \(\mathop {{{\mathrm{lim}}}}\nolimits_{r \to \infty } {\mathbf{u}} =  U{\hat{\mathbf{e}}}\), where \(U = 2B_1/3\) is the swimming velocity of the colloid. In this experiment, the average velocity for the moving Janus colloids determined by meansquared displacement fitting was U = 5.37 ± 1.64 μm s^{−1}, and this value was used to normalise the presented data.
In the Methods section, we give the expression of the velocity field around the stuck colloid u_{s}(r, θ) and around a freely moving colloid u_{m}(r, θ) in the equatorial plane. They only depend on the sets of Legendre coefficients \(\{ B_n\} _{n \ge 1}\). Each of these two fields has components along \({\hat{\mathbf{e}}}_r\) and \({\hat{\mathbf{e}}}_\theta\), and are measured experimentally. We therefore get four data sets, that depend on the two variables (r, θ) and the parameters {B_{n}}. We assume that the sums over the Legendre polynomials are truncated at some order N (here we use N = 5). We use the functions determined analytically (see Methods) as fitting functions for the experimental data, so that we obtain four sets of fit parameters B_{1},…, B_{5}. The data sets are shown in the inset of Fig. 1b, together with the average and the standard deviation for each case. In this figure, we also show the slip velocity \(\tilde v(\theta ) = \mathop {\sum}\nolimits_{n = 1}^5 B_nV_n({\mathrm{cos}}\theta )\) reconstructed from these fit parameters. We observe that it is greater in magnitude on the Pt hemisphere, very close to zero at θ = π/2 and π, and has a maximum between π/2 and π.
A simplified slip velocity function
For further applications, it can be useful to use the simplified form^{17}
See Fig. 1a for a definition of the notations, and Fig. 1b for a representation of the slip velocity as a function of the polar angle θ. Taking the expression of the slip velocity given in Eq. (5), we find that the swimming velocity U is related to the parameter v_{0} through the relation U = v_{0}/K where \(K = 1/(2B_1/3) = 1/\left( {\frac{1}{6}  \frac{\pi }{{32}}} \right) \simeq 14.6\). The coefficient K can be understood as the proportionality coefficient between the amplitude of the slip velocity and the resulting swimming speed of the colloid. Finally, the expressions of the velocity field in the two situations where the particle is stuck and freely moving can be written explicitly as Legendre polynomials expansions (see Methods).
It is also interesting to compare this simplified slipvelocity profile, which is consistent with the results obtained from the above fitting procedure to the full experimental flow field, with estimated pole to equator changes in Pt surface reactivity as a function of θ. These reactivity variations can be related to the Ptcoating thickness (d) variations^{12} shown in Fig. 2 inset (d can be calculated by a simple geometric model: \(d = d_{{\mathrm{max}}}{\mathrm{cos}}(\pi  \theta )\) where d_{max} is 10 nm in our experiment, and π–θ gives the angle between the incident Pt “rays” during metal evaporation and the surface normal vector for the sphere). Using an exponential fit (reactivity = A + Be^{cd}; \(A = 1.12\, \times 10^{14} \pm 8 \times 10^{12}\,{\mathrm{s}}^{  1}\upmu {\mathrm{m}}^{  2}\), \(B =  1.184 \, \times 10^{14} \pm 9.67 \times 10^{12}\,{\mathrm{s}}^{  1}\upmu {\mathrm{m}}^{  2}\), \(C =  0.15236 \pm 0.0329\)) to the previously published experimental data for variations in surface reactivity as a function of Pt thickness from ref. ^{12}, it is consequently possible to arrive at predictions for the reactivity variation for the catalytically active hemisphere (Fig. 2). These predictions are for the variations in the overall decomposition rate of hydrogen peroxide per unit area under the experimental conditions at a given position on the Janus colloids active hemisphere. As discussed in refs. ^{13} and ^{17}, our previous findings suggest that some of the decomposition of hydrogen peroxide proceeds via a mechanism involving charged intermediates (protons and electrons), which leads to a flux of protons in the surrounding fluid. The rate of production of these charged species has not yet been determined.
We show the experimentally measured velocity fields for tracer particle motion in Fig. 1c, d) (see Supplementary Fig. 1 for zoomout versions). According to Faxen law, the tracers’ velocity will reflect both the fluid flow, and any other forces acting on the particles. The potential for the chemical gradient generated by the catalytic reaction to exert a phoretic force on the tracer clearly exists in the system under investigation. Consequently, to assess the magnitude of any phoretic contribution to tracer motion, a control experiment was performed to observe the motion of tracer particles in the vicinity of a stuck, symmetrically catalytically active colloid, fully covered in Pt. In this case, the symmetry of the catalytic reaction precludes the generation of flow fields, and the chemical gradient effect can be measured in isolation. Figure 3 displays a graph depicting the mean radially averaged velocity of the tracer particles as a function of radial distance from the symmetrical gradient only Pt colloid, both in water and in the presence of 10% w/v hydrogen peroxide fuel. It is clear that within error the tracer velocities are unchanged by the presence of the chemical gradient instigated by the addition of the hydrogen peroxide. Based on this evidence, the subsequent discussions considers the tracers’ velocity field to be equivalent to the fluid flow field.
It is apparent that the stuck particle (Fig. 1c) acts as a catalytic pump. Streamlines and velocity magnitudes indicate that the fluid is drawn in towards the equatorial region of the static PtPS particle and then pushed away from the Pt catalyst coated hemisphere. The pumping direction (away from Pt cap) is consistent with the direction of travel observed here, and reported previously^{24}. In regions of low velocity, such as in the fluid surrounding the inactive side of the PtPS particle, Brownian translations of the tracer particles influence the streamlines producing stochastic detail, whereas the catalytically induced velocity dominates elsewhere producing smooth streamlines. The flow field around the moving colloid is consistent with the stuck colloid (see Supplementary Note 1 and Supplementary Fig. 2) (Fig. 1d) exhibiting a tendency for fluid to be drawn in towards the equator of the particle. However, due to the overall translation of the fluid relative to the frame of reference, the movement towards the particle is less marked. The background relative fluid flow dominates the tracer particle Brownian motion, leading to smooth streamlines. The flow field retains the expected symmetry about the y = 0 line, which is a good indication that the transformation of tracer particle motion required to arrive at a fixed frame of reference, and averaging over multiple moving PtPS particles have been effective in capturing the essential details of the flow. The overall velocity magnitude variations are less striking compared with the stuck particle. However, a small area of reduced velocity at the pole of the Pt cap, and a larger area of low velocity around the PS cap are qualitatively apparent, together with an overall increased average velocity on the Pt side of the particle. Comparison with the theoretical predictions finds a good qualitative agreement between the structures of the flow field around the swimmer. In order to check quantitative agreement, and to observe more thoroughly the decay of the flow field far away from the surface of the colloid, we study different projections of the velocity field, namely u_{x} as a function of x around y = 0 and u_{y} as a function of y around x = 0 for the two situations (Fig. 4). To improve the statistics of the measurements, we average the velocity fields over stripes of width 2 μm around y = 0 and x = 0. These results are fitted with the components of the flow fields computed analytically with K = v_{0}/U (Eq. (5)) as a free parameter using a leastsquare method, for both the moving and stuck cases. We obtain \(K_{{\mathrm{stuck}}} = 11.6 \pm 0.7\) and \(K_{{\mathrm{moving}}} = 15.2 \pm 0.7\). These estimates are comparable to the theoretical prediction of \(K = 14.6\).
Influence of the solid wall
To the best of our knowledge, the generic solution for the flow field around a Janus colloid with a prescribed slip velocity v(θ) and near a wall with noslip has not been established analytically. Alternatively, Spagnolie and Lauga^{25} proposed to represent the flow field at position r around a squirmer as the superposition of the flow fields created by elementary singularities located at the centre of the colloid r_{0} (respectively, Stokeslet dipole, source dipole and Stokeslet quadrupole at order \({\cal{O}}({\mathbf{r}}  {\mathbf{r}}_0^{4})\) in the distance to centre of the colloid) whose relative strengths depend on the Legendre coefficients of the slip velocity B_{n}^{26}. More precisely, in units of U and in the case of a freely swimming colloid, they establish
where the quantities G_{D}, D and G_{Q} represent, respectively, the Stokeslet dipole, source dipole and Stokeslet quadrupole (evaluated at r − r_{0}), and the starred quantities their mirrorimage (evaluated at \({\mathbf{r}}  {\mathbf{r}}_0^ \ast\)) where \({\mathbf{r}}_0^ \ast\) is the symmetric of the centre of the colloid with respect to the wall. All of these functions depend on the orientation \({\hat{\mathbf{e}}}\) of the colloid. α, β and γ are dimensionless coefficients that depend on B_{1}, B_{2} and B_{3}^{26} (see Supplementary Note 2 and Supplementary Fig. 3). Note that the above expansion could in principle be extended, provided that the contributions of the mirrorimage of the higherorder modes are computed, although this is expected to be a cumbersome calculation beyond this order.
As opposed to the full solution of the Stokes equation in free space, which is valid at any point^{27,28}, this solution is a farfield expansion, so we expect it to be more accurate further away from the colloid. Using the simplified shape of v(θ) (Eq. (5)), we can compare these two calculated flow fields. As examples, we consider two projections of the flow field along the main axes of the colloid (\(u_x(x,y = 0)\) and \(u_y(x = 0,y)\)) (Fig. 5). As expected, the two solutions coincide far away from the surface of the colloid, and we observe that the singularities expansion of the flow field fails to describe faithfully the behaviour of u in the close vicinity of the colloid. The difference between the two fields far away from the tracer is within the noise of the data recorded. This comparison justifies the choice of the freespace solution. A farfield expansion that would account for the presence of the wall would only be useful to probe very fine differences, that cannot be reached within experimental precision.
Discussion
The very good quantitative agreement between the components of the velocity measured analytically and experimentally shows that the simple shape of the slip velocity (Eq. (5) and Fig. 1b) correctly captures the decay of the velocity field from the surface all the way to regions far from the PtPS particle, which is strongly in favour of the mechanism proposed in refs. ^{13,17}. The flow fields around a stuck or a moving swimmer for other candidate slip velocity profiles do not show a similarly good agreement in comparison (see Supplementary Note 4 and Supplementary Figs 4 and 5). A slip velocity that is foreaft symmetric with a peak at the equator and that vanishes at the poles, which corresponds to a source dipole, does not yield the right structure for the flow field (in particular, because the projection of u along y vanishes at x = z = 0). A profile of slip velocity that would be uniform on the Pt hemisphere and zero on the PS hemisphere will yield velocity profiles that are closer to the ones observed experimentally (even though there is no underlying theoretical mechanism to support this profile).
Our observations are consistent with a velocity profile that behaves as a pusher in the farfield limit, which can be a starting point for a description of the hydrodynamic interactions between many such selfphoretic active colloids^{29,30,31,32}. Indeed, using the usual definition of the squirmer parameter \(b = B_2/B_1\), we find from the data fit (inset of Fig. 1b) \(b \simeq  2.45 \, < \, 0\), which corresponds to a pusher. However, our experiments have provided a more complete picture with regards to the nearfield properties of the hydrodynamic interactions than a simplistic squirmer of pusher type, which can be used to build a more faithful representation of the hydrodynamic interactions. Therefore, our results will pave the way for a more comprehensive description of the selforganisation of such active colloids through hydrodynamic and phoretic interactions^{33,34}.
In conclusion, we have examined the hydrodynamic flow fields around a selfpropelled PtPS catalytic active colloid and found flow fields that are strongly asymmetric across the surface of the particle, with larger magnitude on the Ptcoated hemisphere. The experimental measurements show good agreement with the explicit solution of the Stokes equation with a simple slip velocity as a boundary condition, which is consistent with the conjectured current loops. Our results can be used to construct a comprehensive theoretical description of a suspension of such active colloids.
Methods
Experimental methods
Our experimental system consisted of a 4 cm × 1 cm × 0.1 cm glass cuvette filled with a very dilute suspension of a = 3.5 μm polystyrene Janus spheres in 10 wt% H_{2}O_{2} solution (no added electrolyte)^{12}. The Janus spheres are coated on one hemisphere with a thin evaporated layer of Pt metal with a maximum thickness of 10 nm. To the suspension we added 3 μL of a 1.0 wt% dispersion of green fluorescent polystyrene spheres (radius = 0.25 μm) to act as tracer particles. After vigorous shaking to fully disperse the tracer particles the cuvette was placed on the stage of a Nikon Eclipse LV100 microscope fitted with a Nikon 20 × 0.45 N.A. objective. Operating in fluorescence mode using the blue excitation band of a Nikon B2A filter cube the tracer particles at the top of the cuvette were brought into focus. The calculated depth of field for this optical arrangement is 3.1 μm, and the focal plane is manually positioned to capture the motion of the tracer colloids at a depth corresponding to the equatorial region of the Janus colloid. While some tracer particles that are nearer to the substrate will also be in focus, these rapidly move either out of focus and so do not contribute significantly to the flow field, or back towards the equatorial region. We recorded images (512 × 512 pixels) of the Janus spheres moving parallel to the glass surface and through the field of tracer particles using an Andor Neo camera at a frequency of 100 Hz.
We used the pattern matching functions of the LabView graphical programming language to obtain the center position of a Janus sphere and the angle of rotation of its Pt cap. Tracer particle and Janus sphere trajectories were smoothed to suppress Brownian noise. We then calculated the framebyframe vectors along the tracer particle trajectories relative to the position and angle of the Janus sphere. The vectors were then placed on a 0.5μm grid with the Janus sphere at the origin and an angle of rotation of 0°. Where multiple vectors occupied the same grid position an average vector was calculated. We used 1240 s of video data of 25 Janus spheres and 1260 s of video data of 21 Janus spheres to generate the average flow field around the translating and stuck Janus spheres, respectively. The streamlines depicted on the flow fields (Fig. 1) were generated using the streamplot function of the Python Matplotlib library.
Solution of the Stokes problem: stuck swimmer
The total flow field around a stuck Janus swimmer reads
where

u^{ph} is the phoretic contribution (whether electrophoretic or diffusiophoretic),

u^{mono} is the contribution from the force monopole that maintains the colloid steady in the laboratory reference of frame.
u^{ph} is the solution of the Stokes problem (Eq. (1) and (2) from the main text) with the boundary condition
where
where P_{n} are the Legendre polynomials. The contribution from the force monopole \({\mathbf{f}} =  f\hat e\) (f > 0) is
or, in dyadic notations,
Using the known expression of \({\mathbf{u}}^{{\mathrm{ph}}}\)^{27,28}, the total flow field then writes
with
The flow field at the surface of the colloid is
Imposing \(f\) such that the swimmer does not move, we find \(f = 4\pi \eta aB_1\), and
Solution of the Stokes problem: moving swimmer
Ignoring the contribution coming from the force monopole and solving the Stokes problem with the boundary condition
where \(U = \frac{2}{3}B_1\) is the swimming velocity of the colloid, we find
Fitting procedure
We start from the expression of the flow field in terms of the Legendre coefficients associated to the slip velocity (Eq. (15) for the case where the colloid is stuck and (17) for the case where it is freely moving). From the experimental data, we have actually four independent sets of data: \({\mathbf{u}}_{\mathrm{s}} \cdot {\hat{\mathbf{e}}}_r(r,\theta )\), \({\mathbf{u}}_{\mathrm{s}} \cdot {\hat{\mathbf{e}}}_\theta (r,\theta )\), \({\mathbf{u}}_{\mathrm{m}} \cdot {\hat{\mathbf{e}}}_r(r,\theta )\) and \({\mathbf{u}}_{\mathrm{m}} \cdot {\hat{\mathbf{e}}}_\theta (r,\theta )\). Projecting Eqs. (15) and (17) onto the unit vectors \({\hat{\mathbf{e}}}_r\) and \({\hat{\mathbf{e}}}_\theta\), we find the corresponding fit functions (we introduce for simplicity \(X \equiv a/r\)):
Each of these functions is used to fit the experimental data (for \((x,y) \in [  40\,\upmu {\mathrm{m}},40\,\upmu {\mathrm{m}}]^2\), with the constraint \(r \ge 3.5\,\upmu {\mathrm{m}}\)). The sums are truncated at order 5. Therefore there are five fit parameters \(B_1, \ldots ,B_5\). The values obtained from the fits (as well as the averages and standard deviations) are shown on the inset of Fig. 1a. We can then rebuild the slip velocity at the surface of the colloid, defined as
where
The reconstructed v(θ) is shown on the main plot of Fig. 1a.
Estimate of the coefficient K and of the error on this estimate
For each situation (moving colloid and stuck colloid), the experimental data consists in two sets of measurements \(\{ \tilde u_x(x_i)\} _i\) et \(\{ \tilde u_y(y_i)\} _i\). The objective is to fit each set of data, respectively, with the functions \(Ku_x(x_i,0,0) \equiv Kw_{x,i}\) and \(Ku_y(0,y_i,0) \equiv Kw_{y,i}\) (defined in Eq. (15) if the colloid is stuck or Eq. (17) if the colloid is moving) with a single parameter \(K\). This is done by a leastsquare method which yields
The error is estimated as
where n is the number of data points.
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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Acknowledgements
Both A.I.C. and S.J.E. thank the EPSRC for supporting this work via the Career Acceleration Fellowship (EP/J002402/1) granted to S.J.E. P.I. and R.G. would like to thank the hospitality of the MaxPlanckInstitute for the Physics of Complex Systems, where a part of this work was performed. We acknowledge support from the COST Action MP1305 Flowing Matter.
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A.I.C. and S.J.E. performed the experiments. P.I. and R.G. conducted the theoretical part of the work. All authors worked on data treatment, wrote the paper, discussed and interpreted the results.
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Campbell, A.I., Ebbens, S.J., Illien, P. et al. Experimental observation of flow fields around active Janus spheres. Nat Commun 10, 3952 (2019). https://doi.org/10.1038/s41467019118421
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DOI: https://doi.org/10.1038/s41467019118421
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