Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

# Rational design of spontaneous reactions for protecting porous lithium electrodes in lithium–sulfur batteries

## Abstract

A rechargeable lithium anode requires a porous structure for a high capacity, and a stable electrode/electrolyte interface against dendrite formation and polysulfide crossover when used in a lithium-sulfur battery. Here, we design two simple steps of spontaneous reactions for protecting porous lithium electrodes. First, a reaction between molten lithium and sulfur-impregnated carbon nanofiber forms a fibrous network with a lithium shell and a carbon core. Second, we coat the surface of this porous lithium electrode with a composite of lithium bismuth alloys and lithium fluoride through another spontaneous reaction between lithium and bismuth trifluoride, solvated with phosphorous pentasulfide, which also polymerizes with lithium sulfide residual in the electrode to form a solid electrolyte layer. This protected porous lithium electrode enables stable operation of a lithium-sulfur battery with a sulfur loading of 10.2 mg cm−2 at 6.0 mA cm−2 for 200 cycles.

## Introduction

The developments of electric vehicles and grid-scale energy storage have been relying heavily on lithium-ion batteries. Yet the low capacity of intercalation electrodes limits the further increase in the energy density of conventional lithium-ion batteries, which motivates our investigations of new materials1,2. There is also an ever-increasing interest in revisiting lithium (Li) anode, as Li has the lowest electrode potential (−3.04 V vs. SHE) and the highest capacity (3860 mAh g−1) among all anodes3. Pairing the Li anode with a high-capacity sulfur cathode, we may achieve an energy density of 500 Wh kg−1, doubling that of current Li-ion batteries. However, structural and chemical irreversibility encumbers its stable cycling. On the one hand, Li metal is reactive, continuously consuming electrolyte, electrolyte additives, and active materials. On the other hand, the volume change of Li is infinite, because of its hostless nature, so a solid electrolyte interphase (SEI) required for suppressing side reactions can be repeatedly breached, resulting in a vicious circle of anode degradation.

The infinite volume change of Li metal over cycling requires a porous scaffold to stabilize the electrode structure and to provide more reaction sites for Li plating/stripping. Typical freestanding scaffolds include layered reduced graphene oxide, porous nickel and copper foams4,5,6,7. Among them, porous carbonaceous scaffolds are attractive for their small pore size, low cost and light weight, but to load them with Li, the surface of the scaffolds needs to be highly lithiophilic. Even when we improve the lithiophilicity by decorating the carbon surfaces with materials like ZnO, Si, Ag, and Au, the molten Li necessitates a high temperature to lower its viscosity, which aggravates the unwanted reactions between Li and trace amounts of environmental impurities (e.g. N2 and O2) that in turn hinder the infusion8,9,10,11,12. In spite of the difficulty of fabrication, when the porous Li scaffold is employed in a Li–S full battery, a protective, ion-conductive surface layer is necessary to block the crossover of polysulfide intermediates. Inorganic solid electrolytes (e.g. Garnet-based) have been employed as the surface protective layer13. Though effective for the suppression of side reactions as well as dendrite propagation, the use of inorganic solid electrolyte suffers from the fragility, the high Li+ transport resistance, and the relatively low volumetric energy density14.

Moreover, inside the porous Li scaffold, liquid electrolyte is usually needed for wetting the Li surface. A robust artificial SEI for smoothing the Li deposits and suppressing the consumption of liquid electrolyte thus would be necessary. The SEI needs to satisfy requirements of high chemical stability, high uniformity, adequate elasticity and high Young’s and shear modulus15,16,17,18,19,20,21. Interfacial engineering is usually applied to achieve the above requirements by coating Li surface with mechanically stiff inorganic compounds (carbon, BN, SiO2, Al2O3, etc.); binary Li–X compounds (Li3N, Li2O, Li2S, LiF, Li4.4Sn, Li13In3); ternary Li–M–X compounds (Li3PO4 and Li3PS4)22,23,24,25,26,27,28,29,30,31. Among them, LiF is considered as one of the most promising choices for the suppression of side reactions and dendrite growth owing to its high stability and high mechanical strength (Young’s modulus: 65 GPa; shear modulus: 55 GPa)32,33,34,35. By treating the porous Li scaffold in the fluorine-rich gas atmosphere, the LiF-based artificial SEI could be formed across the electrode36,37. Such a vapor deposition method, however, might lead to safety concern during scaled-up production. Also, the issues, such as the loose binding between Li and LiF, and low ionic conductivity of LiF remain unsolved38. Spontaneous reactions at liquid/solid interface are arguably the most promising approach, recent examples of which include the use of InF3 as an electrolyte additive and CuF2 as the precursor for in-situ and ex-situ SEI formation, respectively39,40. However, neither work could generate a sufficiently robust and conductive layer that is also immune to the attack by polysulfides; InF3 is too low in solubility; and CuF2 produces Cu which is unstable towards polysulfides41.

With these considerations in mind, we design two steps of spontaneous reactions to achieve a porous Li electrode protected by functional composites. In the first step, we infuse molten Li into a sulfur/carbon nanofiber scaffold driven by the sparkling exothermic reaction between Li and the pre-impregnated sulfur to form a porous Li composite. In the next step, the porous Li composite reacts with a metal fluoride complex (BiF3–P2S5) to spontaneously form Li3Bi alloy and LiF that are tightly anchored to the Li surface. P2S5 also polymerizes with residual Li2S on the porous electrode to form an ion conductive amorphous Li2S–P2S5 solid electrolyte layer. The spontaneously achieved multiscale protection enables the stable operation of Li–S full batteries with a rather high sulfur loading (10.2 mg cm−2) at 6.0 mA cm−2 for over 200 cycles.

## Results

### Fabricating a porous Li electrode

The porous scaffold for Li we chose is a carbon nanofiber matrix (CNF) of a high specific surface area and a robust interwoven structure (Supplementary Fig. 1). Electrodeposition of Li led to a non-uniform distribution of Li, mostly at the separator side due to its high local Li+ concentration. Such an electrode could not achieve stable cycling (Supplementary Fig. 2). Alternatively, direct thermal infiltration of molten Li encountered the surface lithiophobicity issue, completely preventing the Li infusion12.

To tackle this issue, we applied the reactive wetting strategy to drive the Li infusion with a reaction between Li and sulfur. We chose sulfur out of a variety of materials after comparing their melting points and Gibbs free energies of complete lithiation reactions (Supplementary Fig. 3). The low melting point of sulfur and its high affinity with carbon allows for its effective filling into a porous scaffold at a low temperature. Besides, its highly exothermic reaction with Li can provide much heat to reduce the viscosity of molten Li and a chemical potential gradient that drives the wetting of Li on the carbon surface to overcome friction and surface tension (Fig. 1a)42. Therefore, we first impregnated the CNF with sulfur to form a composite called herein as S–CNF as shown in the scanning electron microscopy (SEM) image (Fig. 1b), which led to a uniform sulfur film on all carbon fiber surface. When we further infiltrated the as-prepared S–CNF scaffold with molten Li, we observed that Li rapidly reacted and wetted the carbon fiber scaffold as shown in Fig. 1c. The infusion of molten Li into a 50-μm-thick CNF scaffold finished within 120 s to form the Li–S/CNF composite. Even with a volume expansion of 70% in such a small duration, the interwoven structure of CNF well accommodated the infused Li (Supplementary Fig. 4). The void space was uniformly filled, as seen in the cross-sectional view (Fig. 1d). Interestingly, after the gravitational condensation, we can create a Li2S-rich surface and a Li-rich surface as shown in Supplementary Fig. 5a, b. This is because the Li2S with a higher density (1.66 g cm−3) has poor affinity with both carbon and Li, so it can gradually condense on the electrode’s bottom surface to form a dense layer as shown in Supplementary Fig. 5c, d. Differently, lithiated CNF can trap molten Li with its good lithiophilicity43,44. Therefore, on the Li-rich surface, we observe the carbon nanofiber was coated with a Li shell as shown in Supplementary Fig. 5e, f. The detailed gravimetric and volumetric fractions of these electrode components are shown in Supplementary Fig. 6 (calculation details can be found in Supplementary Fig. 7. Porosity could be estimated around 7.1 % for the Li/S–CNF electrode, which would be filled with the liquid electrolyte. The chosen initial sulfur loading was 2.5 mg cm−2, which guaranteed the uniform Li filling, and an adequate scaffold expansion ratio (Supplementary Figs. 7,  8 and Note 1).

### Protective coating with solubilized metal fluoride

Next, we need to build an artificial SEI inside the porous Li scaffold. In this step, we employed another spontaneous reaction between Li and BiF3. We chose BiF3 as its reaction with Li can create a composite coating of Li3Bi and LiF. The Young’s modulus of Li3Bi (22.20 GPa) is much higher than Li metal (1 GPa), which can suppress dendrite formation and strongly interconnect LiF on the Li surface45. In addition, Li3Bi is reported to possess a high concentration of interstitials, which may facilitate the Li+ transport within and through the artificial SEI38,46. Moreover, Li3Bi is electrochemically inert given its high delithiation voltage of ~1.1 V vs Li/Li+ (Supplementary Fig. 9 and Note 2). As a step further, we corroborate our postulation on the benefit of Li3Bi and LiF with first-principle density functional theory-based (DFT) calculations. The results show that Li adatom is weakly adsorbed on the substrate of Li3Bi, providing the lowest surface diffusion energy barriers for Li adatom (0.17 eV), followed by LiF (0.36 eV), and then Li metal (0.39 eV) (Fig. 2a, b, Supplementary Figs. 10 and 11). We thus expect that a surface composite layer of LiF and Li3Bi can result in facile Li plating and smooth Li deposits.

The benefits of this composite layer, however, should not dwarf the difficulty of reacting a compound of BiF3 with the Li/S–CNF composite uniformly, due to the high melting point of BiF3 (649 °C) and its insolubility in most solvents. Our strategy is solubilizing BiF3 with P2S5 as a complexing agent. P2S5 has been previously reported to complex with Li2S to form solid electrolyte precursor, because sulfide anions can initiate nucleophilic attack on the electrophilic phosphorous in P2S5, causing ionic polymerization27. Here we show that complexation occurs between BiF3 and P2S5. The lone pair electron of Bi can initiate nucleophilic attack toward P to form two possible products as shown in Fig. 2c. We measured 31P nuclear magnetic resonance spectroscopy (NMR) spectra of the supernatants of mixtures of 50 mM BiF3 with various amounts of P2S5 in DME (Fig. 2d) to verify our hypothesis. Comparing the NMR spectra, we can deduce that two peaks at 105.2 and 97.8 ppm represent the BiF3–P2S5 complex with one phosphorous reacted, which will take a higher portion in the soluble product when the molar ratio of BiF3: P2S5 decreases. And the peak at 83.1 ppm represents the complex with both phosphorous atoms reacted. This complex likely maintains the symmetrical adamantane-like cage structure, therefore showing the single peak in NMR. While BiF3 or P2S5 alone has intrinsically negligible solubility, for the solution with a BiF3: P2S5 ratio of 1:1, the solubility of Bi3+ is 570 ppm, as determined by the inductively coupled plasma optical emission spectrometry (ICP-OES)47. The as-prepared mixture will then be used to react with Li to form a composite artificial SEI comprising of LiF and Li3Bi (Fig. 2e). In spite of using ether-based solvent like DME, similar complexation and solvation behavior can also be attained in ester (e.g. ethyl propionate) and nitrile (e.g. acetonitrile) based solvents as shown in Supplementary Fig. 12.

We first applied this solution-based coating strategy to the planar Li foil. The reduction of BiF3 on the Li surface resulted in the formation of a uniform, conformal black layer around 5 µm in thickness as observed from the cross-sectional SEM images (Supplementary Fig. 13). This protected Li foil will be referred to herein as metal fluoride complex protected Li electrode (MFC-Li for short). The X-ray diffraction (XRD) results indicate the existence of Li3Bi and LiF phases (Supplementary Fig. 14), which can be further confirmed by the evolution of the X-ray photoelectron spectroscopy (XPS) spectra of Bi 4f and F 1 s after lithaition (Fig. 3a and Supplementary Fig. 15). No signals of BiF3 or Li metal can be found in XRD or XPS, confirming the complete reaction. We also analyzed quantitatively the composition of the coating along the depth direction via XPS spectroscopy by sputtering its surface by Ar gas for different durations. The results indicate a uniform distribution of LiF and Li3Bi alloy (Fig. 3b), with small contents of P and S (Fig. 3c), which is likely the residual P2S5 and the reaction products between Li and P2S5 (grey fitting line in Fig. 3a). The Li3Bi/LiF layer indeed provides a high ionic conductivity, estimated to be 6.9 × 10−4 S cm−1, with the layer thickness measured with cross-sectional SEM and time of flight-secondary ion mass spectroscopy (TOF-SIMS) and the resistance determined by the use of electrochemical impedance spectroscopy (EIS) (Supplementary Fig. 13 and Note 3). This value is much higher than that of defect-free LiF (~10−12 S cm−1)36.

The microscopic structure of the coating is shown in Fig. 3d. Although we could not ensure the integrity of the coating layer after stripping it off the sample for transmission electron microscopy (TEM) analysis, with the characterization we can confirm the uniform distribution of species (Fig. 3e, f). At a higher magnification, we can further identify the interconnected, nanometer-wide domains of LiF and Li3Bi (Supplementary Fig. 16). The abundant Li3Bi/LiF interfaces might accelerate the Li+ transport due to the space-charge effect, explaining the high ionic conductivity achieved36. One potential concern of the effectiveness of this layer is the possibility of Li plating on its top, which is however unlikely to happen owing to the relatively high electronic resistance as we observed in the earlier EIS test (Supplementary Fig. 13d). We confirmed the postulated plating location (beneath the protective coating) by employing this coated Li foil (MFC-Li) in a symmetric cell, at a moderate deposition current density (1.0 mA cm−2, 1.0 mAh cm−2) as shown in Supplementary Fig. 17a, b, we achieved stable cycling for 300 cycles. Over cycling, the electrode retained a rather thin layer of Li beneath the protective layer and a smooth surface morphology (Supplementary Figs. 18 and 19). However, at a higher rate (e.g. 2.5 mA cm−2, 1.0 mAh cm−2) the overpotential promoted to twice of its initial values after 300 cycles (Supplementary Fig. 20), indicating the necessity of the porous scaffold.

### A protected porous Li electrode

We then applied the coating strategy to the Li/S–CNF composite to form a metal fluoride complex coated Li/CNF composite electrode, referred to herein as MFC-Li/CNF, by soaking it in the BiF3–P2S5 mixture. In this step, due to the reaction between Li and solvated BiF3, there will be a spontaneous formation of Li3Bi and LiF composite, which functions as the artificial SEI on the Li-coated fibers. Meanwhile, P2S5 in the solution polymerized with the residual Li2S on the scaffold to form the solid electrolyte precursor. Upon subsequent annealing at 160 °C and mechanical pressing, a layer of light yellow solid electrolyte evolved to cover the Li scaffold surface (Fig. 4a, b), exhibiting a uniform surface morphology. No characteristic peak of this solid electrolyte can be seen in XRD likely due to its amorphous structure (Fig. 4c). From the Raman spectra for the reaction precursor, intermediates and reaction products, the species formed from the polymerization of P2S5 initiated by Li2S were identified (sample #2 in Fig. 4d), showing peaks at 218/476, and 248/437 cm−1, together with the peaks of $$P_2S_6^{{\mathrm{4 - }}}{\mathrm{,}}\;{\mathrm{P}}_2S_7^{{\mathrm{4 - }}}\;{\mathrm{and}}\;{\mathrm{PS}}_4^{{\mathrm{3 - }}}$$ from 380 to 420 cm−1 (Fig. 4d)48,49. Further sintering combines these unstable intermediates into a stable phase for the final product, showing a single peak representing Li3PS4 at 418 cm−150. The formation of Li3PS4 can be confirmed with the S 2p spectrum (Fig. 4e), which exhibits S 2p3/2 peaks at 159.6 and 161.2 eV corresponding to the P = S and P–S–Li moieties of Li3PS4 respectively. Besides, the P 2p spectrum at 132.4 eV also corresponds to the formation of Li3PS4 (Fig. 4f). Comparing these results with the S 2p and P 2p spectra of P2S5 (Fig. 4e, f), we can confirm the complete reaction between P2S5 and Li2S on the electrode surface51. The formation of the solid electrolyte layer can also be seen in the EIS profile and the polarization test. By applying the coating to a thick Li–S/CNF (240 µm) electrode, the low-frequency real part of the impedance (ReZ) decreased from 12 Ω (Supplementary Fig. 21a) to 9.0 Ω (Fig. 5a), indicating that the formation of a continuous solid electrolyte layer can indeed promote the ion transport. This value decreased to 6.0 Ω if the coating was applied to a thinner porous electrode (85 µm). In Supplementary Fig. 22, the polarization curves further reveal that, for the 85-µm-thick MFC-Li/CNF, because of the formation of a more continuous surface solid electrolyte layer, the transport of electron across the electrode surface can be well insulated, leading to an overall areal resistance of 14.9 Ω cm−2, markedly higher than that value of Li/S–CNF. The benefit of this layer of Li2S–P2S5 based solid electrolyte is to prevent the dissolved polysulfides from either corroding or passivating the porous Li electrode, and prevent dendrite penetration with its high stiffness, as we will see later in the battery tests.

### Battery performance

The capacity, reversibility and stability of the MFC-Li/CNF were further evaluated in the symmetric cell. We began with an 85 µm-thick MFC-Li/CNF electrode. By discharging the electrode at 0.5 mA cm−2 to the cut off voltage (−0.6 V) or cell shorting (Fig. 5b), we achieved an areal capacity of 13.2 mAh cm−2 (1517 mAh g−1 based on the overall electrode weight), with the utilized Li taking up 75.3% volume of the electrode. Similar levels of specific capacity (1352 mAh g−1) and volume fraction of utilized Li (68.3 %) were achieved for a thicker electrode (240 µm in thickness). We further show that at such a high areal discharge capacity (33.8 mAh cm−2), the counter electrode (also a MFC-Li/CNF) suffered from a loss of porosity, leading to the rise of impedances52. During charging, we observed that the impedance spectrum returned to its initial value, confirming the electrode’s capability to withstand large volume change (Fig. 5c). In comparison, symmetric cells with neither Li–S/CNF (240 µm in thickness, Supplementary Fig. 21b) nor planar Li electrodes could achieve such a high areal capacity due to the unregulated Li plating. Furthermore, we carried out the long-term cycling test to evaluate the stability of the Li/electrolyte interphase. The planar Li electrode could not be stably cycled at 1.0 mA cm−2 within 160 h and exhibited the high-overpotential, fluctuating voltage profiles at a higher current density (Fig. 5d, e). Such a phenomenon was ascribed to the significant heterogeneity on the Li/electrolyte interphase after cycling (Supplementary Fig. 18)53. Enlarging the electrode surface area and building robust SEI across Li and liquid electrolyte could smoothen the Li deposits. As a result, the symmetric cell with the MFC-Li/CNF electrode (85 µm) could be cycled for more than 400 times even at 5.0 mA cm−2 (Fig. 5f), and exhibited smaller overpotentials from 1.0 to 10 mA cm−2 (Fig. 5g).

For the Li–S full battery, we applied the 85-µm-thick MFC-Li/CNF anode to pair with a sulfur/carbon cloth cathode of a loading of 6.8 mgsulfur cm−2 as shown in Fig. 6a, b, d. At 23 °C, the discharge capacity achieved at a cathode current density of 4.0 mA cm−2 (anode current density 3.4 mA cm−2) was 4.14 mAh cm−2. If operated at 45 °C, this value could go up by 44% to 5.96 mAh cm−2 (Fig. 6a, b), owing to the enhancements in both ion mobility and reaction kinetics. For long-term cycling (200 cycles), the battery also presented stable performance at both 23 and 45 °C (Fig. 6d). At 1.0 mA cm−2 the battery achieved a specific capacity of 942 mAh g−1 after 200 cycles (112 days), with a capacity retention of 90.7% and practically utilizing more than 41% Li stored in the anode. At 4.0 mA cm−2, the achievable capacity was still as high as 662 mAh g−1 after 200 cycles. As comparisons, even with performance enhancement, neither MFC-Li nor Li/S–CNF could deliver similar performance due to a limited surface area or the lack of robust protective layer (Supplementary Figs. 23 and 24). Further, post-mortem structural/compositional characterizations were conducted for the cycled MFC-Li/CNF anode. There was either electrode-level deformation or structural change after high rate cycling (4.0 mA cm−2) as shown in Supplementary Fig. 25. From the XPS depth profiling, we can further observe that both the compositions of Li2S–P2S5 based solid electrolyte layer and Li3Bi/LiF-based artificial SEI retained stable.

## Discussion

In summary, we designed two steps of spontaneous reactions to achieve a porous Li electrode protected by functional composites, which delivered stable cycling performance at 45 °C with an areal capacity above 7.5 mAh cm−2 (4.0 mA cm−2) and 6.8 mAh cm−2 (6.0 mA cm−2) in a Li–S battery. Both steps of fabrication can be generalized to other structures or materials. In the first step, the sulfur impregnation can apply to other carbon-based porous frameworks to drive the infiltration of molten Li with the exothermic reaction. In the second step, the complexation strategy to solubilize metal fluoride is by no means limited to BiF3. SbF3 or InF3, can also complex with P2S5, which can then react with Li to form a composite coating comprising of LiF and Li-alloy (Supplementary Figs. 2729). It is evident that many parameters in the two steps can be tailored to optimize the anode structure for better performance. In addition, the BiF3-P2S5 precursor solution and the formed MFC-Li/CNF electrode are both stable in the dry air (Supplementary Fig. 30 and Note 5), which will facilitate cost-effective processing and battery assembly at a practical scale. Therefore, we believe that the facileness and the flexibility of our electrode design strategy holds a high promise in its application in practically rechargeable Li-based batteries.

## Methods

### Sample preparation

The CNF scaffold was prepared according to the reported method67. Briefly, polyacrylonitrile (PAN) fibers were firstly obtained from PAN in dimethylformamide (DMF) solution by electrospinning technique. Stabilization and subsequent carbonization of the electrospun PAN fibers were carried out in a high temperature furnace to form the CNF.

Sulfur was impregnated inside the CNF scaffold (13 mm in diameter) on a hot plate (155 °C). Due to the high affinity of sulfur/carbon, as soon as the CNF and molten sulfur droplet were attached, sulfur droplets could wet the CNF. The Li infusion, coating and heat treatment were all conducted inside the Ar-filled glove box, with O2 and H2O levels maintained below 1 ppm. When in contact with molten Li (200 °C), the sparking reaction soon occurred, which allowed the infusion of molten Li inside the CNF. After the reactive wetting process, by putting the composite on the heated flat stainless steel plate (200 °C) for 60 min, the gravitational setting of Li2S formed a Li2S-rich surface layer (Fig. 4c). Beside, excessive molten Li that attached on the carbon surface could be squeezed out of the Li/S–CNF composite. The areal weight of the CNF scaffold was 0.80 mg cm−2 and the areal sulfur loading before Li infusion was 2.5 mg cm−2. After Li infusion the areal weight increased to 5.5 mg cm−2 and thickness increased to 85 µm. With the thicker CNF scaffold (150 µm in thickness), sulfur loading was also tripled, after Li infusion, the areal weight increased to 14.7 mg cm−2, and thickness increased to 240 µm.

BiF3 (Sigma-Aldrich, anhydrous, ≥99.9%) together with P2S5 (Sigma-Aldrich) were dispersed in 1,2-dimethoxyethane (DME) (5 mL, Sigma-Aldrich) by vigorously stirring for 60 min. Prior to use, DME was dehydrated with 3 Å molecular sieves and BiF3 was heated at 120 °C under vacuum both for 48 h. Li foil (13 mm in diameter, 99.9%, Aldrich) was polished one side for coating, while the other side was coated with a removable, dense Kapton (polyimidie) film to prevent the reaction. The Li foil or the Li–S/CNF composite was put into the BiF3–P2S5 mixture (1:1 molar ratio, 50 mM BiF3 in 5 mL solvent) for 60 min. Afterwards, the coated Li or porous Li composite was rigorously rinsed with pure DME and was heated at 50 °C for 12 h to fully evaporate the solvent. After drying, there was an areal weight increase of 1.8 mg cm−2 on the Li foil. For the thinner Li/S–CNF composite (85 µm), the areal weight increase of 3.2 mg cm−2 (overall 8.7 mg cm−2) was attained after solution coating for 60 min. For the thicker Li/S–CNF composite (240 µm), the areal weight increase of 10.3 mg cm−2 (overall 25.0 mg cm−2) was attained. After the complete evaporation of solvent at 50 °C, all of the porous Li composites were compressed using a pellet die with a pressure of ~10 metric tons and heat treated at 160 °C to form the MFC-Li/CNF composite electrodes (13 mm in diameter).

### Battery assembly and testing

CR-2032 coin cell setup was employed for the battery assembly. The typical electrolyte composition is lithium bis(trifluoromethanesulphonyl)imide (LiTFSI, 1 M) in 1:1 v/v 1,3-dioxolane (DOL)/DME.

For assembling Li/Li symmetric cells, bare Li foil, MFC-Li or MFC-Li/CNF with the same diameter of 13 mm was used as the electrode. The two electrodes were saturated with overall 100 μL electrolyte and separated by two pieces of Celgard 2500 separators.

For assembling Li–S batteries, bare Li foil, MFC-Li or MFC-Li/CNF with the same diameter of 13 mm was used as the anode. Carbon cloth (12 mm diameter, ELAT®) was used as the cathode current collector and loaded with different amounts of sulfur (2.8, 6.8 or 10.2 mg cm−2). The two electrodes were filled with 100 μL electrolyte, and separated by two pieces of Celgard 2500 separators. The galvanostatic discharge and charge tests were conducted on a battery cycling system (Neware, CT-4008W) at a constant temperature (23 or 45 °C). Electrochemical impedance spectroscopy (EIS) from 100 kHz to 0.1 Hz with an alternating current amplitude of 5 mV was tested on a potentiostat (Princeton Applied Research, PARSTAT M2273) via the two-electrode setup.

### Characterization

JSM-6700F field emission SEM instruments were used for micrograph observation at an acceleration voltage of 5.0 kV. TEM images were taken on a high-resolution JEOL 2010F TEM using an accelerating voltage of 200 kV. The protective layer on the planar MFC-Li electrode can be stripped by sonification and dispersed in DME for preparation of the TEM samples.

NMR experiments were conducted with neat liquids on a Bruker Avance 400-MHz instrument at ambient temperature. 31P NMR spectra were recorded at 162 MHz. All signals were reported in δ unit with references to the external 85% H3PO4 for phosphorus chemical shifts. ICP-OES measurements were carried out using the ESCALAB250 version made in company THERMO in U.S.A.

The XRD pattern was analyzed with a Philips high-resolution X-ray diffraction system (model PW 1825) using a Cu Kα source operating at 40 kV with the scan rate of 0.025° s−1. To protect the highly reactive Li-related compound from the air, the XRD samples were loaded on a glass slide and covered with Kapton tape in the glove box before the measurements. XPS measurements were conducted on a Physical Electronics PHI5802 instrument using an X-rays magnesium anode (monochromatic Ka X-rays at 1253.6 eV) as the source. For the Raman study, modification of a regular single cell was made. The cathode end cap plate was cut with a hole and sealed with a quartz window. Raman spectra were collected using a spectrometer (Princeton Instruments, Spectrapro 2500i) with a wavelength of 514.5 nm and 50 mW laser power as the excitation source. The TOF‐SIMS test was conducted using TOF‐SIMS IV (ION‐TOF GmbH, Germany) with a 25 keV. The negative secondary ions were induced by the primary ion beam bombardment on the surface of Li electrodes. Depth profiles were obtained by sputtering ion beams of Cs+ (3 keV) on square areas of 150 × 150 µm2. The analysis area was 19 × 19 µm2. The UV-Vis spectra were collected by SEC2000 UV-visible spectrophotometer (ALS Co., Ltd.). An SCE-C thin layer quartz glass cell with an optical path length of 4.5 mm was used as the holder.

### Modeling

DFT based first-principles calculations were carried out using ABINIT code adopting the generalized gradient approximation (GGA) of Perdew-Burke-Ernzerhof (PBE) type68. The electron-ion interactions were taken into account by Projector-augmented-wave (PAW) potentials69. The energy cutoff and the thickness of vacuum layer were set to 24 Ha and 20 Å, respectively. The facets were chosen based on the TEM and XRD characterization ((111) facet for both Li3Bi and LiF) as shown in Supplementary Fig. 16. The spacing between k-point grids was all set to be <0.05 Å−1. The slab models contain four layers, with the bottom two layers fixed during structural optimization. The force convergence criteria for self-consistent-field cycles and structural relaxation were set to 4.0 × 10−5 and 6 × 10−4 Ha Bohr−1.

$$E_{{\mathrm{ads}}} = E_{{\mathrm{Li}}} + E_{{\mathrm{slab}}} - E_{{\mathrm{system}}}$$

where ELi, Eslab, and Esystem are the DFT energies of Li atom, slab and adsorption systems, respectively. To calculate the lithium diffusion barriers, the simplified string method was adopted70.

## Data availability

The data that support the plots within this paper and other finding of this study are available from the corresponding author upon reasonable request.

## References

1. 1.

Armand, M. & Tarascon, J. M. Building better batteries. Nature 451, 652–657 (2008).

2. 2.

Pang, Q., Liang, X., Kwok, C. Y. & Nazar, L. F. Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes. Nat. Energy 1, 16132 (2016).

3. 3.

Liu, B., Zhang, J.-G. & Xu, W. Advancing lithium metal batteries. Joule 2, 833–845 (2018).

4. 4.

Lin, D. et al. Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes. Nat. Nanotechnol. 11, 626 (2016).

5. 5.

Chi, S., Liu, Y., Song, W., Fan, L. & Zhang, Q. Prestoring lithium into stable 3D nickel foam host as dendrite‐free lithium metal anode. Adv. Funct. Mater. 27, 201700348 (2017).

6. 6.

Lu, L.-L. et al. Free-standing copper nanowire network current collector for improving lithium anode performance. Nano Lett. 16, 4431–4437 (2016).

7. 7.

Pu, J. et al. Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits. Nat. Commun. 10, 1896 (2019).

8. 8.

Liang, Z. et al. Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating. Proc. Natl Acad. Sci. USA 113, 2862–2867 (2016).

9. 9.

Liu, Y. et al. Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode. Nat. Commun. 7, 10992 (2016).

10. 10.

Yang, C. et al. Ultrafine silver nanoparticles for seeded lithium deposition toward stable lithium metal anode. Adv. Mater. 29, https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.201702714 (2017).

11. 11.

Zhang, R. et al. Coralloid carbon fiber-based composite lithium anode for robust lithium metal. Batter. Joule 2, 764–777 (2018).

12. 12.

Wang, J. et al. Fundamental Study on the wetting property of liquid lithium. Energy Storage Mater. 14, 345–350 (2018).

13. 13.

Xu, S. et al. All-in-one lithium-sulfur battery enabled by a porous-dense-porous garnet architecture. Energy Storage Mater. 15, 458–464 (2018).

14. 14.

Wang, B. et al. Atomic layer deposited lithium silicates as solid-state electrolytes for all-solid-state batteries. ACS Appl. Mater. Interfaces 9, 31786–31793 (2017).

15. 15.

Cheng, X. et al. A review of solid electrolyte interphases on lithium metal anode. Adv. Sci. 1500213, https://onlinelibrary.wiley.com/doi/full/10.1002/advs.201500213 (2015).

16. 16.

Ma, L., Kim, M. S. & Archer, L. A. Stable artificial solid electrolyte interphases for lithium batteries. Chem. Mater. 29, 4181–4189 (2017).

17. 17.

Tikekar, M. D., Archer, L. A. & Koch, D. L. Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions. Sci. Adv. 2, e1600320 (2016).

18. 18.

Khurana, R., Schaefer, J. L., Archer, L. A. & Coates, G. W. Suppression of lithium dendrite growth using cross-linked polyethylene/poly (ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries. J. Am. Chem. Soc. 136, 7395–7402 (2014).

19. 19.

Choudhury, S., Mangal, R., Agrawal, A. & Archer, L. A. A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles. Nat. Commun. 6, 10101 (2015).

20. 20.

Zhang, W. et al. Design principles of functional polymer separators for high‐energy, metal‐based batteries. Small 14, 1703001 (2018).

21. 21.

Li, N. et al. Suppressing dendritic lithium formation using porous media in lithium metal-based batteries. Nano Lett. 18, 2067–2073 (2018).

22. 22.

Ma, G. et al. A lithium anode protection guided highly-stable lithium–sulfur battery. Chem. Commun. 50, 14209–14212 (2014).

23. 23.

Cheng, X.-B. et al. Sulfurized solid electrolyte interphases with a rapid Li+ diffusion on dendrite-free Li metal anodes. Energy Storage Mater. 10, 199–205 (2017).

24. 24.

Zhang, Y. J. et al. An ex-situ nitridation route to synthesize Li 3 N-modified Li anodes for lithium secondary batteries. J. Power Sources 277, 304–311 (2015).

25. 25.

Wang, L. et al. Long lifespan lithium metal anodes enabled by Al2O3 sputter coating. Energy Storage Mater. 10, 16–23 (2018).

26. 26.

Kozen, A. C. et al. Next-generation lithium metal anode engineering via atomic layer deposition. ACS Nano 9, 5884–5892 (2015).

27. 27.

Kozen, A. C. et al. Stabilization of Lithium metal anodes by hybrid artificial solid electrolyte interphase. Chem. Mater. 29, 6298–6307 (2017).

28. 28.

Shim, J. et al. 2D boron nitride nanoflakes as a multifunctional additive in gel polymer electrolyte for safe, long cycle life and high rate lithium metal batteries. Energy Environ. Sci. 10, 1911–1916 (2017).

29. 29.

Pang, Q., Liang, X., Shyamsunder, A. & Nazar, L. F. An in vivo formed solid electrolyte surface layer enables stable plating of Li metal. Joule 1, 871–886 (2017).

30. 30.

Ma, L. et al. Atomic layer deposition for lithium‐based batteries. Adv. Mater. Interfaces 3, https://onlinelibrary.wiley.com/doi/full/10.1002/admi.201600564 (2016).

31. 31.

Liao, K. et al. Developing a “Water‐Defendable” and “Dendrite‐Free” lithium‐metal anode using a simple and promising GeCl4 pretreatment method. Adv. Mater. 1705711, https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201705711 (2018).

32. 32.

Zhang, X. et al. Columnar lithium metal anodes. Angew. Chem. 129, 14395–14399 (2017).

33. 33.

Lu, Y., Tu, Z. & Archer, L. A. Stable lithium electrodeposition in liquid and nanoporous solid electrolytes. Nat. Mater. 13, 961–969 (2014).

34. 34.

Choudhury, S. & Archer, L. A. Lithium fluoride additives for stable cycling of lithium batteries at high current densities. Adv. Electron. Mater. 2, 1500246 (2016).

35. 35.

Lang, J. et al. One-pot solution coating of high quality LiF layer to stabilize Li metal anode. Energy Storage Mater. 16, 85–90 (2019).

36. 36.

Lin, D. et al. A conformal lithium fluoride protection layer on three-dimensional lithium by non-hazardous gaseous reagent Freon. Nano Lett. 17, 3731–3737 (2017).

37. 37.

Zhao, J. et al. Surface fluorination of reactive battery anode materials for enhanced stability. J. Am. Chem. Soc. 139, 11550–11558 (2017).

38. 38.

Zhang, Q. et al. Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries. Nano Lett. 16, 2011–2016 (2016).

39. 39.

Pang, Q., Liang, X., Kochetkov, I. R., Hartmann, P. & Nazar, L. F. Stabilizing lithium plating by a biphasic surface layer formed in situ. Angew. Chem. Int. Ed. 57, 9795–9798 (2018).

40. 40.

Yan, C. et al. An armored mixed conductor interphase on a dendrite‐free lithium‐metal anode. Adv. Mater. 30, 1804461 (2018).

41. 41.

Sun, K. et al. Interaction of CuS and sulfur in Li-S battery system. J. Electrochem. Soc. 162, A2834–A2839 (2015).

42. 42.

Wang, M. F., Jin, M. J., Jin, X. J. & Zuo, S. G. Modeling of movement of liquid metal droplets driven by an electric field. Phys. Chem. Chem. Phys. 19, 18505–18513 (2017).

43. 43.

Shao, Y. et al. Drawing a soft interface: an effective interfacial modification strategy for garnet-type solid-state Li batteries. ACS Energy Lett. 3, 1212–1218 (2018).

44. 44.

Lang, J. et al. Surface graphited carbon scaffold enables simple and scalable fabrication of 3D composite lithium metal anode. J. Mater. Chem. A 5, 19168–19174 (2017).

45. 45.

Kalarasse, L., Bennecer, B. & Kalarasse, F. Elastic and electronic properties of the alkali pnictide compounds Li3Sb, Li3Bi, Li2NaSb and Li2NaBi. Comput. Mater. Sci. 50, 2880–2885 (2011).

46. 46.

Weppner, W. Trends in new materials for solid electrolytes and electrodes. Solid State Ion. 5, 3–8 (1981).

47. 47.

Lin, Z., Liu, Z., Fu, W., Dudney, N. J. & Liang, C. Phosphorous pentasulfide as a novel additive for high‐performance lithium‐sulfur batteries. Adv. Funct. Mater. 23, 1064–1069 (2013).

48. 48.

Lin, Z., Liu, Z., Fu, W., Dudney, N. J. & Liang, C. Lithium polysulfidophosphates: a family of lithium‐conducting sulfur‐rich compounds for lithium–sulfur batteries. Angew. Chem. 125, 7608–7611 (2013).

49. 49.

Busche, M. R. et al. In situ monitoring of fast Li-ion conductor Li7P3S11 crystallization inside a hot-press setup. Chem. Mater. 28, 6152–6165 (2016).

50. 50.

Ito, S., Nakakita, M., Aihara, Y., Uehara, T. & Machida, N. A synthesis of crystalline Li7P3S11 solid electrolyte from 1, 2-dimethoxyethane solvent. J. Power Sources 271, 342–345 (2014).

51. 51.

Wenzel, S. et al. Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte. Solid State Ion. 286, 24–33 (2016).

52. 52.

Wang, H., Lin, D., Liu, Y., Li, Y. & Cui, Y. Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF3 framework. Sci. Adv. 3, e1701301 (2017).

53. 53.

Cheng, Q. et al. Operando and three-dimensional visualization of anion depletion and lithium growth by stimulated Raman scattering microscopy. Nat. Commun. 9, 2942 (2018).

54. 54.

Jiao, S. et al. Behavior of lithium metal anodes under various capacity utilization and high current density in lithium metal batteries. Joule 2, 110–124 (2018).

55. 55.

Xiao, J. Understanding the lithium sulfur battery system at relevant scales. Adv. Energy Mater. 5, 1501102 (2015).

56. 56.

Liu, Y. et al. An ultrastrong double-layer nanodiamond interface for stable lithium metal anodes. Joule 2, 1595–1609 (2018).

57. 57.

Nanda, S., Gupta, A. & Manthiram, A. A lithium–sulfur cell based on reversible lithium deposition from a Li2S cathode host onto a hostless‐anode substrate. Adv. Energy Mater. 8, 1801556 (2018).

58. 58.

Cha, E. et al. 2D MoS 2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries. Nat. Nanotechnol. 13, 337–344 (2018).

59. 59.

Tang, W. et al. Lithium silicide surface enrichment: a solution to lithium metal battery. Adv. Mater. 30, 1801745 (2018).

60. 60.

Cai, W. et al. The dual‐play of 3D conductive scaffold embedded with Co, N codoped hollow polyhedra toward high‐performance Li–S Full cell. Adv. Energy Mater. 8, 1802561 (2018).

61. 61.

Chang, J. et al. Flexible and stable high-energy lithium-sulfur full batteries with only 100% oversized lithium. Nat. Commun. 9, 4480 (2018).

62. 62.

Chen, L. et al. Directly formed alucone on lithium metal for high-performance Li batteries and Li–S batteries with high sulfur mass loading. ACS Appl. Mater. Interfaces 10, 7043–7051 (2018).

63. 63.

Liu, S. et al. Superhierarchical cobalt‐embedded nitrogen‐doped porous carbon nanosheets as two‐in‐one hosts for high‐performance lithium–sulfur batteries. Adv. Mater. 30, 1706895 (2018).

64. 64.

Adams, B. D. et al. Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes. Nano Energy 40, 607–617 (2017).

65. 65.

Jozwiuk, A. et al. The critical role of lithium nitrate in the gas evolution of lithium–sulfur batteries. Energy Environ. Sci. 9, 2603–2608 (2016).

66. 66.

Qu, C. et al. LiNO3-free electrolyte for Li-S battery: a solvent of choice with low ksp of polysulfide and low dendrite of lithium. Nano Energy 39, 262–272 (2017).

67. 67.

Huang, J. et al. Electrospun graphitic carbon nanofibers with in-situ encapsulated Co–Ni nanoparticles as freestanding electrodes for Li–O2 batteries. Carbon N. Y. 100, 329–336 (2016).

68. 68.

Gonze, X. A brief introduction to the ABINIT software package. Z. f.ür. Krist. Mater. 220, 558–562 (2005).

69. 69.

Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B 50, 17953 (1994).

70. 70.

Weinan, E., Ren, W. & Vanden-Eijnden, E. Simplified and improved string method for computing the minimum energy paths in barrier-crossing events. J. Chem. Phys. 126, 164103 (2007).

## Acknowledgements

The work described in this paper was fully supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No. T23-601/17-R).

## Author information

Authors

### Contributions

T.S.Z. and Q.C. supervised the research; Y.X.R. conceived the experiments; Y.X.R. and H.R.J. designed the numerical simulations; Y.X.R., L.Z., H.R.J. and W.Q.R. analyzed the data; Y.X.R., Q.C. and T.S.Z. wrote the paper and all the authors discussed the paper.

### Corresponding authors

Correspondence to Q. Chen or T. S. Zhao.

## Ethics declarations

### Competing interests

The authors declare no competing interests.

Peer review information: Nature Communications thanks Chuan-Fu Lin, Mahdokht Shaibani and Rosy Sharma for their contribution to the peer review of this work. Peer reviewer reports are available.

Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

## Rights and permissions

Reprints and Permissions

Ren, Y.X., Zeng, L., Jiang, H.R. et al. Rational design of spontaneous reactions for protecting porous lithium electrodes in lithium–sulfur batteries. Nat Commun 10, 3249 (2019). https://doi.org/10.1038/s41467-019-11168-y

• Accepted:

• Published:

• ### Dense‐Stacking Porous Conjugated Polymer as Reactive‐Type Host for High‐Performance Lithium Sulfur Batteries

• Xiaowei Wang
• , Yangyuchen Yang
• , Chen Lai
• , Runlai Li
• , Haomin Xu
• , Darren H. S. Tan
• , Kun Zhang
• , Wei Yu
• , Oeystein Fjeldberg
• , Ming Lin
• , Wei Tang
• , Ying Shirley Meng
•  & Kian Ping Loh

Angewandte Chemie International Edition (2021)

• ### Deciphering interpenetrated interface of transition metal oxides/phosphates from atomic level for reliable Li/S electrocatalytic behavior

• Daorui Wang
• , Dan Luo
• , Yongguang Zhang
• , Yan Zhao
• , Guofu Zhou
• , Lingling Shui
• , Zhongwei Chen
•  & Xin Wang

Nano Energy (2021)

• ### Constructing Ultrafine Lithiophilic layer on MXene Paper by Sputtering for Stable and Flexible 3D Lithium Metal Anode

• Yi Qian
• , Chuanliang Wei
• , Yuan Tian
• , Baojuan Xi
• , Shenglin Xiong
• , Jinkui Feng
•  & Yitai Qian

Chemical Engineering Journal (2021)

• ### Functional-selected LiF-intercalated-graphene enabling ultra-stable lithium sulfur battery

• Haoliang Lu
• , Na Xu
• , Xuyan Ni
• , Jinqiu Zhou
• , Jie Liu
• , Zhenkang Wang
• , Tao Qian
•  & Chenglin Yan

Journal of Energy Chemistry (2021)

• ### Unlocking the dissolution mechanism of phosphorus anode for lithium-ion batteries

• Cheng Liu
• , Muyao Han
• , Yu Cao
• , Long Chen
• , Wencai Ren
• , Guangmin Zhou
• , Aibing Chen
•  & Jie Sun

Energy Storage Materials (2021)