Chiral domain walls of Mn3Sn and their memory


Magnetic domain walls are topological solitons whose internal structure is set by competing energies which sculpt them. In common ferromagnets, domain walls are known to be of either Bloch or Néel types. Little is established in the case of Mn3Sn, a triangular antiferromagnet with a large room-temperature anomalous Hall effect, where domain nucleation is triggered by a well-defined threshold magnetic field. Here, we show that the domain walls of this system generate an additional contribution to the Hall conductivity tensor and a transverse magnetization. The former is an electric field lying in the same plane with the magnetic field and electric current and therefore a planar Hall effect. We demonstrate that in-plane rotation of spins inside the domain wall would explain both observations and the clockwise or anticlockwise chirality of the walls depends on the history of the field orientation and can be controlled.


A domain wall is the topological defect of a discrete symmetry. In ferromagnetic materials, these are narrow boundaries separating magnetic domains with different polarities. Their width and structure are set by the competition between the exchange energy and the magneto-crystalline anisotropy energy1. They are either of Bloch type, where the magnetization rotates in a plane parallel to the wall plane, or of Néel type, whose magnetization vector rotates in a plane perpendicular to the wall. Thanks to high-resolution scanning probes of local magnetization, they can be visualized2. Theoretical proposals for other more sophisticated spin textures have recently emerged3. In addition to their fundamental interest, the attention to domain walls is driven by the quest for new spintronic devices4. Much less is known about antiferromagnetic domain walls.

A large anomalous Hall effect (AHE) was recently discovered5,6,7 in the Mn3X (X = Sn,Ge) family of noncollinear antiferromagnets8,9,10,11. The discovery followed theoretical predictions12,13 and preceded the observation of a variety of other anomalous transverse responses by thermal and optical probes14,15,16,17,18,19,20. These materials constitute new platforms for antiferromagnetic spintronics21,22. The structure of domain walls have been a subject of theoretical23 and experimental studies24. Evidence and arguments for a nontrivial spin texture in domain walls are available, but no direct image of their magnetic structure, yet.

Here, we report on three distinct experimental observations leading us to identify the in-plane structure of the domain walls in Mn3Sn. The first observation is that in the narrow magnetic field window of multiple domains, there is a planar Hall effect (PHE), which consists in an electric field oriented parallel (and not perpendicular) to the applied magnetic field. The thermoelectric counterpart of this effect, namely a planar Nernst effect (PNE) was also detected. The second observation is the existence of a transverse magnetic response in the same narrow field window. Employing micron-size Hall sensors in close proximity with the sample25,26, we monitored the local magnetic field at the surface and found in the same field window a finite off-diagonal magnetization: a finite magnetization oriented perpendicular to the orientation of the applied magnetic field. We will argue below that a satisfactory explanation of both these observations is provided by a specific spin texture inside the domain walls. The third result is that the sign of the emergent electric field (set by the clockwise or anti-clockwise rotation of the spins inside walls) depends on the history of the magnetic field orientation. We will show that this is caused by residual minority domains promoting a specific chirality. This last observation constitutes a new case of memory formation in condensed matter recording a direction27.



Figure 1 shows an additional hitherto unreported component in the Hall and the Nernst responses of Mn3Sn, which we call PHE and PNE. The experimental configuration is sketched in Fig. 1a. Charge current was applied along the z-axis (J//z) and the magnetic field was oriented along the y-axis (H//y). Electric field was measured simultaneously along both x- and y-axes. Ex, which represents an electric field vector perpendicular the magnetic field and the charge current, is the Hall response. As seen in Fig. 1b, it displays a hysteretic jump as reported previously5,15,24. As the magnetic field is swept, three different regimes succeed each other24. In regime I, the system hosts one single domain. When the applied magnetic field (opposite to the magnetization of the dominant domain) exceeds a threshold, new domains nucleate and regime II starts. At sufficiently large magnetic field, the system becomes single-domain again (regime III). As seen in (Fig. 1c), in regime II, Ey, the component of the electric field parallel to the magnetic field, becomes finite. The result was reproduced in several other samples and was also detected when the applied magnetic field was along the x-axis, see Supplementary Fig. 2. In other words,in the presence of multiple domains, when J//z and H//y(//x), there is a nonvanishing Ey (Ex). This is a planar Hall effect, with an electric field, which is parallel and not perpendicular to the magnetic field. Note that this signal only emerges in the presence of domain walls. Its amplitude is comparable to the amplitude of the topological Hall effect (THE) (Fig. 1d) extracted by subtracting Hall and magnetization hysteresis loops24, see Supplementary Note 4. Interestingly, the THE is present in the same field interval as the PHE, but shows different signs for the two sweeping orientations.

Fig. 1

Room-temperature anomalous transverse response. a Experimental configuration for measuring Hall effect in sample #5 with square cross-section. Charge current is applied along the z-axis and the magnetic field along the y-axis. Two pairs of electrodes measure Ex and Ey. b Anomalous Hall resistivity (\(\rho _{xz}^{{\mathrm{AHE}}}\)), extracted from Ex. c Planar Hall resistivity (\(\rho _{yz}^{{\mathrm{PHE}}}\)), extracted from Ey. d Topological Hall resistivity (\(\rho _{xz}^{{\mathrm{THE}}}\)), extracted by subtracting magnetization and Hall hysteresis loops, see Supplementary Note 4. e Experimental configuration for measuring Nernst effect in sample #15 with rectangular cross-section. The temperature gradient is applied along the z-axis, the magnetic field is applied either along x-axis or y-axis. The electric field is always measured along the x-axis. f Anomalous Nernst effect (\(S_{xz}^{{\mathrm{ANE}}}\)) with the magnetic field along the y-axis, extracted from Ex. g Planar Nernst effect (\(S_{xz}^{{\mathrm{PNE}}}\)) measured with the magnetic field along x-axis, extracted from Ex. h Topological Nernst effect (\(S_{xz}^{{\mathrm{TNE}}}\)) extracted by subtracting magnetization and Nernst hysteresis loops, see Supplementary Note 4. The larger width of the hysteresis loop in the Nernst measurements is due to the larger aspect ratio of the sample (See Fig. 2b)

The experimental configuration for probing the Nernst response is shown in Fig. 1e. The thermal gradient is applied along the z-axis. When the magnetic field is oriented along the y-axis, there is a finite Ex. It represents the anomalous Nernst effect, which also displays a hysteretic jump (Fig. 1f), as reported previously14,15. In addition to this, however, when the magnetic field is along the x-axis, there is a finite Ex in regime II (Fig. 1g). This is the PNE. Like its Hall counterpart, it becomes nonzero in a narrow field window when there are multiple domains and its amplitude is comparable to the amplitude of the topological Nernst effect (TNE) (Fig. 1h) extracted by subtracting Nernst and magnetization hysteresis loops, see Supplementary Note 4.

We carried out an extensive set of temperature-dependent measurements, see Supplementary Fig. 4. In the whole temperature window of the triangular order in Mn3Sn (50 K < T < 300 K), the magnitude of PHE (PNE) remain a sizable fraction (≈0.3–0.4) of the total AHE (ANE) and there is no significant evolution with temperature. We will show below how the PHE, the PNE and their odd parity in field, are set by the internal structure of domain walls23 in this system.

Magnetization (bulk vs. surface; longitudinal vs. transverse)

Figure 2 presents the data magnetization obtained in two different ways. In addition to measuring bulk magnetization with a conventional vibrating sample magnetometer (VSM), we used two-dimensional electron gas (2DEG) Hall sensors, attached to one edge of the sample to monitor the local magnetic field at its surface (See method). By choosing the mutual orientation of the sensor and the applied magnetic field, we could extract both diagonal and off-diagonal magnetization at the surface of the sample.

Fig. 2

Bulk and surface magnetization. a Bulk magnetization (after subtracting the high-field slope) in a sample with an almost square cross-section (ly/lx = 1.08) for two field orientations. b Same in a sample where (ly/lx = 3.38). The hysteresis loop is wider when the field is oriented along the longer axis of the sample. c Bulk and surface magnetization in sample #13-3 for field along x. d Bulk and surface magnetization in sample #13-3 for field along y. In contrast to bulk magnetization, the hyteresis loop for surface magnetization is always narrow and does not depend on the aspect ratio. e Longitudinal surface magnetization coefficient μ0Mxx; f transverse surface magnetization coefficient μ0Myx in sample #13-2

As seen in Fig. 2a, b, the hysteresis loop of bulk magnetization depends on the aspect ratio ly/lx, where ly(lx) is the length of the sample along the y-axis (x-axis). When ly/lx ≈ 1 [inset (a)], bulk magnetization for the field along two orientations are almost coincident. But when ly/lx ≈ 3, the hysteresis loop is wider when the field is oriented along the longer axis, in agreement with that was reported previously15. As seen in the Fig. 2b, domain nucleation occurs at the same magnetic field for the two orientations, but the loop closes later when the field is oriented along the longer axis. A straightforward interpretation of this observation is that the new domain(s) occupy the whole sample more efficiently when the magnetic field is oriented along a shorter axis.

Additional insight is brought by surface magnetization data obtained with Hall sensors. As shown in Fig. 2c, d, no matter the sample’s aspect ratio, the hysteresis loop of surface magnetization is always narrow. The surface magnetization shows a sharp jump at the threshold field of bulk magnetization. We conclude that when the field is oriented along y- (x-)axis, the new domains nucleate at the xz(yz)-surface and immediately occupy the area (5 × 5 μm2) probed by a Hall sensor. The wide hysteresis loop of the bulk magnetization monitors the gradual enhancement produced by the smooth occupation of the center of the sample.

We used the Hall sensors to look for an off-diagonal magnetic response, namely a finite magnetic field perpendicular to the applied field. The mutual configuration of the sample, the magnetic field and the Hall sensors for quantifying longitudinal and transverse magnetization (TM) are shown in [inset (e)] and [inset (f)]. The obtained data at room temperature is shown in Fig. 2e, f. The transverse response is restricted to regime II and has symmetric and asymmetric components.

Chiral domain walls

A spin texture for domain walls (see Supplemental material in ref. 23), which would explain our results, is sketched in Fig. 3. One domain (oriented along θ = π) is located at the center and another domain with opposite polarity (θ = 0) at the periphery. [In the convention used here23, θ is the angle between the x-axis and a pair of parallel spins of the unit cell]. In the (more or less thick) wall separating these two domains, spins rotate smoothly and concomitantly in the xy plane. The texture along x-axis is such that at the center of the domain wall, the adopted configuration has an orientation perpendicular to the two domains. Figure 3b shows different versions of the same structure with a narrower wall. One can see that the two possible configurations are +π/2 and −π/2. This would correspond to an either clockwise or anticlockwise rotation of spins depending on the specific domain configuration at the center and the periphery. Note that domain walls of this type, with in-plane rotation of two possible signs, follow directly from the hierarchy of scales discussed in ref. 23, in which the Dzyaloshinskii–Moriya interaction is much stronger than an in-plane twofold anisotropy. The origin of the twofold anisotropy will be discussed in future work.

Fig. 3

Spin texture in a domain wall and the signals they generate. a Red and blue circles represent Mn atoms in adjacent planes. Arrows represent spins. A θ = π domain (at the center), a θ = 0 domain (at the periphery) and the wall separating them (in between). For the sake of illustration, the thickness of the wall is assumed to be only five unit cells. Along a radial direction, adjacent equivalent spins tilt by a constant angle. A zoom on the wall along x-axis shows that the domain wall can has a θ = ±π/2 spin configuration. b Domain walls can have either +π/2 or −π/2 configurations. This could correspond to a clockwise or an anticlockwise rotation of spins as one moves from the center toward the periphery. c The orientation of the spins at the center of domain wall would explain the finite planar Hall effect (PHE) and the transverse magnetization (TM). The sign of these signals (their odd parity or even parity with respect to magnetic field in a hysteresis loop from a θ = π domain to θ = 0 and back) depends on the chirality of the domain wall. The diagrams represent a field sweep (from one domain to another passing by a specific type of domain wall). In each case the four possible sequences are identified with a colored arrow. In the two plots sketched below each diagram, the same color is used to represent the expected curves for the PHE and TM response. The left-side diagram and plots refer to a case in which rotation keeps the same sense (either clockwise or anticlockwise). As a consequence, the peaks have opposite signs for opposite sweep orientations. The right-side diagram and plots refer to a case in which the orientation of spin remains the same (either +π/2 or −π/2), Therefore, the peaks have the same sign for both sweep orientations

We note that a study using Magneto-Optical Kerr Effect microscopy16 detected oppositely aligned domains in the multidomain regime at small magnetic fields. The domains were found to extend over tens of microns. However, the fine structure of the walls separating these domains23 could not be resolved in this study.

Such a texture would provide a natural explanation for the TM and the planar Hall effect observed in regime II. The in-plane tilt of spins (and the magnetic octupole28) would generate a magnetic field perpendicular to and electric field parallel to the orientation of the applied magnetic field. This is the origin of the TM and planar Hall effect. The angle-dependent study of the AHE24 has established that the orientation of the electric field associated with anomalous Hall effect is set by the orientation of spins (and not the crystal axes). Therefore, the π/2 spin configuration in the center of domain wall would naturally gives rise to an electric field perpendicular to those generated by the θ = 0 and θ = π domains.

In this picture, the sign of the signals reflects the chirality of the domain wall. Consider a hysteresis loop with the magnetic field swept from a θ = π single-domain to another θ = 0 single-domain regime and then back to the original θ = π single-domain (Fig. 3c). If during this sequence, for both sweeping orientations, the spin configuration inside the domain walls remains the same (either +π/2 or −π/2), then the PHE and the TM signals will be even (symmetric) in field. On the other hand, if what remains fixed is the sense of the rotation (clockwise or anticlockwise), then the signals will be odd (or asymmetric) in field, because the spin configuration inside the domain wall will be opposite during the two sweeps.

Domain walls have a memory

Keeping this in mind, let us turn our attention to another outcome of this study, a memory effect. The experimental protocol is defined in (Fig. 4a). We performed the measurement twice for identical configurations, but with different prior histories. The measurement consisted in sweeping the magnetic field oriented along x-axis from 0.5 to −0.5 T and back. This corresponds to switching domains from θ = 0 to θ = π configurations and back to the starting point. The measurement was preceded in the first case by a field rotation from +π/2 to 0 and in the second case, by a rotation from −π/2 to 0. As one can see in Fig. 4b, the results are strikingly different. In the first case the PHE signals are positive, in the second are negative. We note that this is a phenomenon belonging to the category dubbed memory of direction27. By subtracting the two sets of data or adding them, one can extract the symmetric (Fig. 4c) and the asymmetric (Fig. 4d) components of the PHE signal. The symmetric part is seven times larger than the asymmetrical part.

Fig. 4

Dependence of planar Hall effect and transverse magnetization on prior history. a The experimental protocol: measurements were performed in identical configurations but following different prior histories. In both cases, the applied magnetic field and the measured electric field were both along the x-axis and the magnetic field was swept from −x (that is θ = π) to +x. Before the measurement, however, in one case the magnetic field was rotated from −π/2 toward π, but in another from +π/2 toward π. b The planar Hall data for the two measurements. The prior history determines the sign of the observed signal. c The difference between the two data sets shown in (b) (the symmetric component). d The sum of the two data sets shown in (b) (the asymmetric response). e The experimental protocol for measuring transverse magnetization, similar to (a). f Transverse magnetization data for the two measurements. g The difference between the two measurements in (f) (the symmetric component). h The sum of the two measurements in (f) (the asymmetric component). The closed and open symbols refer to opposite field sweep orientations, marked by solid and dotted arrows shown in (b)

Note the small gap seen between the two sets of \(\rho _{xz}^{{\mathrm{PHE}}}\) data obtained with two different prior histories in Fig. 4b. It arises because we have assumed an identical offset for both sets of data. This offset is caused by an unavoidable misalignment between lateral contacts. The difference between the two sets of data obtained with different prior histories implies that history affects the offset too.

The TM displays also a similar memory (see the protocol defined in Fig. 4e and the data shown in Fig. 4f–h). One can see, however, that in this case, the main component is asymmetric, which is three times larger than the symmetric one.


Recalling that PHE is a bulk effect, we conclude that the orientation of the spins inside the walls is mainly set by the past history. On the other hand, in the case of TM at the surface, the spin orientation mainly depends on the sign of the magnetic field and the rotation orientation is less affected by the prior history. This raises an obvious question: where does the system stock the information regarding the previous orientation of the magnetic field?

A plausible answer to this question is provided by the scenario sketched above. When the magnetic field is oriented along θ = +π/2, at the end of a (−y ↔ +y) hysteretic loop, the sample is practically single-domain with π/2 spin configuration. In principle rotating from π/2 to 0 before the measurement would change the spin configuration of the whole sample from π/2 to 0. However, if residual domains remain stuck in the π/2 configuration, they will set the spin configuration of the domain walls along π/2. If this is the case, then one would expect to see a dependence of the memory effect on the strength of the prior magnetic field. The larger the magnetic field at which the (π/2 to 0) rotation takes place before the measurement, the smaller the fraction of the domains which had stayed in place and the smaller their role in setting the chirality.

As seen in Fig. 5, this is indeed the case. We measured PHE after cycling and rotating the magnetic field at B = 0.5, 1, and 2 T. One can see that the magnitude of the PHE and in its symmetric component steadily decreases. This implies that the symmetric component of the PHE set by the chirality of the wall is promoted by the presence of minority domains, whose population decrease with increasing magnetic field. The asymmetric component, on other hand, does not show significant evolution with magnetic field.

Fig. 5

Evolution of the PHE signal with the amplitude of the prior magnetic field. a Planar Hall effect measured after cycling and rotating the magnetic field at 0.5, 1, and 2T. b, c Asymmetrical and symmetrical components of planar Hall effect, extracted from (a). Inset in (c) shows the evolution of the magnitudes of the two components. The symmetric component steadily decreases with the increasing prior magnetic field, but the asymmetric component does not. The closed and open symbols refer to opposite field sweep orientations, marked by solid and dotted arrows shown in (a)

If domain walls with opposite chiralities were evenly distributed in the sample no PHE or TM signal would have been observed. This is not the case. The dominance of a symmetric and history-dependent component in the PHE signal implies that deep inside the sample, minority domains set the chirality of the domain wall. The dominance of the asymmetric and history-independent component in surface TM indicates that wall spin orientation at surface is principally set by the orientation of the magnetic field with only a minor role proposed by the minority domains. We note that the domain wall spin texture proposed here can also generate a topological Hall response as reported previously24, provided that we assume an additional off-plane tilt of spins residing inside the domain walls. Indeed, if the unit vector of magnetization has a finite z dependence (\(\frac{{\partial \vec n}}{{\partial z}} \ne 0\)), then combined with the finite \(\frac{{\partial \vec n}}{{\partial r}}\), it generates an axially oriented emergent magnetic field (Bθ ≠ 0 in cylindrical coordinates)29 and the skyrmionic number will be finite, producing real-space Berry curvature. Such an assumption would not alter the conclusions drawn above. Yet, it is not necessary for explaining the observations reported in the present study.

Heating the sample above TN = 420 K would presumably erase all history dependence. It would be interesting to compare field-cooled and zero-field-cooled behaviors across the transition temperature in future experiments combining a furnace and a magnet.

In summary we put under scrutiny a narrow field window in which there are multiple magnetic domains in Mn3Sn and found that in this regime, one can observe a planar Hall and planar Nernst effect as well as TM. These observations can be explained by a specific spin texture for domain walls where spins rotate in the pseudo-Kagomé plane. The choice of clockwise or anticlockwise rotation can be controlled by the prior magnetic history of the sample, providing a new platform for memory formation.


Sample preparation and transport measurements

Mn3Sn single crystals with a typical size in the range of centimeter were grown by the vertical Bridgman technique24. They were cut to desired dimensions by a wire saw. All transport experiments were performed in a commercial measurement system (Quantum Design PPMS), using the Horizontal Rotator Option. Hall resistivity was measured by a standard four-probe method using a current source and a DC-nanovoltmeter. Two Chromel- Constantan (type E) thermocouples were employed to measure the temperature difference in the case of Nernst measurements.


Bulk magnetization was measured using a VSM method. For surface magnetization measurements, we employed an array of Hall sensors based on high-mobility AlGaAs/GaAs heterostructure. The density of the 2DEG was n = 2.5 × 1011 cm−2 (300 K) and it was located 160 nm below the surface. The device was fabricated using electron beam lithography and 250 V argon ions to define the mesa. Supplementary Figure 1 shows an array of ten sensors each 5 × 5 μm2 square with a 100 μm interval between two neighboring sensors26. Attaching the device to the surface of the sample, the local magnetic field was determined by measuring the Hall resistivity of the sensor using an AC current source and a lock-in amplifier.

Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.


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This work was supported by the National Science Foundation of China (Grant nos. 51861135104 and 11574097), the National Key Research and Development Program of China (Grant no. 2016YFA0401704), the Fundamental Research Funds for the Central Universities (Grant no. 2019kfyXMBZ071) and by Agence Nationale de la Recherche (ANR-18-CE92-0020-01). Z.Z. was supported by the 1000 Youth Talents Plan. K.B. was supported by China High-end foreign expert program and Fonds-ESPCI-Paris. L.B. was supported by the US National Science Foundation Materials Theory program, Grant number DMR-1818533. X.L. acknowledges a PhD scholarship by the China Scholarship Council (CSC).

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Z.Z. and K.B. supervised the research project. X.L. prepared the samples. X.L. carried out the experiments with the help from C.C., L.X., H.Z. and B.F. A.C, U.G, and D.M. made the 2DEG Hall sensors used in the experiments. L.B. provided theoretical background. X.L, Z.Z. and K.B. wrote the paper, and all authors commented on the paper.

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Correspondence to Zengwei Zhu or Kamran Behnia.

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Li, X., Collignon, C., Xu, L. et al. Chiral domain walls of Mn3Sn and their memory. Nat Commun 10, 3021 (2019).

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