Article | Open | Published:

Global-scale control of extensional tectonics on CO2 earth degassing

Nature Communicationsvolume 9, Article number: 4608 (2018) | Download Citation

Abstract

Earth degassing of CO2-rich fluids has been proven to contribute significantly to the global carbon budget. The presence of ubiquitous outgassing reveals some degree of permeability of the crust that often coincides with seismically active zones. In this study, we took advantage of the most recent global geological datasets to better understand earth degassing and how it correlates with tectonic regimes. Here we use an ad hoc point pattern analysis to show that there is a spatial correlation between CO2 discharges and the presence of active fault systems, in particular with those characterized by a normal slip type. Seismic data demonstrate the existence of a positive spatial correlation between gas discharges and extensional tectonic regimes and confirms that such processes would play a key role in creating pathways for the rising gases at micro- and macro-scales, increasing the rock permeability and connecting the deep crust to the earth surface.

Introduction

Carbon dioxide is one of the most abundant natural gases in the world. It has played and still plays a crucial role in controlling temperatures on the earth surface via the greenhouse effect. During the Eocene, for instance, a postcollisional prograde regional metamorphism is thought to have released enough CO2 to trigger a greenhouse global warming during this epoch1. Present-day natural CO2 degassing is continuously updated with direct measurements and global extrapolations. The measured CO2 emissions originate from volcanic or nonvolcanic sources. In the last decades the number of investigated nonvolcanic carbon-rich discharges has risen exponentially; results from these studies emphasize the important contribution to the earth gas budget.

To our knowledge, tectonic degassing has been quantified with a fairly good level of detail (albeit with some assumptions and extrapolations) for three regions in the world: the Himalayas2 (~7.5×105 km2 emitting ~40 Mt yr−1 of CO2), central Italy3 (~0.4×105 km2 emitting ~10 Mt yr−1 of CO2) and the Eastern Ethiopian rift4 (~1.7×105 km2 emitting ~70 Mt yr−1 of CO2, subsequently questioned and rescaled to ~20 Mt yr−1 by Hunt et al.5). On the basis of a worldwide census of continental rift lengths, Brune et al.6 have calculated a present-day CO2 flux of ~40 Mt yr−1 emitted from 20,000 km long active rifts. All these studies provided invaluable perspectives into the present and past tectonic degassing and have important implications for modeling the global carbon cycle.

Regional CO2 earth degassing can be estimated by the identification of CO2-rich waters. In fact, rising CO2 can be sequestrated for a certain amount of time (i.e. residence time) by shallow aquifers, channelized towards the atmosphere through CO2-rich springs. This process allows identifying extended areas of CO2 outgassing. Chiodini et al.3,7 have demonstrated that a carbon balance based on the isotopic composition of total dissolved inorganic carbon in aquifers can be a suitable tool for discriminating CO2 among biological, carbonate dissolution and deep sources. The application of this methodology to the regional aquifers in central Italy, hosted by Mesozoic carbonate-evaporite formations, allowed identifying a deep CO2 flux of ~10 Mt yr−1. The origin of this CO2 discharging in central Italy is still debated: Marini and Chiodini8 and Chiodini et al.3 proposed a mix of mantle and a crustal-derived components; Minissale9 favored a mantle-derived CO2 origin; Italiano et al.10 and De Paola et al.11 suggested that mechanical faulting energy may represent an additional source able to produce CO2. The further comparison between the mapped earth degassing and seismicity in central Italy3 revealed an important correlation between gas discharges and normal faults in the Tyrrhenian hinterland. The authors argued that, in this area, deep CO2-rich fluids ascend through the interconnected network of extensional fractures and normal faults and generate the earth degassing observed at the surface. On the contrary, the triggering effect of the deep degassing on the seismogenesis likely exists in the bordering Adriatic foreland, where thrusts and low-angle normal faults may create traps in which CO2 accumulates and gives rise to over-pressurized reservoirs that trigger earthquakes12 and a reduced earth degassing at the surface. The concordance between CO2 discharge, seismic activity, and major faults has also been shown at a regional scale in other geodynamic contexts4,5. Fault systems and associated fracturing play a fundamental role in CO2 propagation by creating pathways extending from the deep crust to the earth surface5,13,14.

The first census of the main tectonic degassing areas in the world was obtained 40 years ago by Barnes et al.15 and Irwin and Barnes16. Since then, the available global geological datasets and the methods of data processing have significantly improved. In this paper we update and re-examine the distribution of the main gas discharges in the world in relation to earthquakes and active faults. We observe that extensional tectonic facilitates the opening of pathways for deep rising CO2-rich fluids, unlike the compressional tectonic that may hinder the transport of fluids (Fig. 1). Studying the origin of this gas is beyond the scope of this paper that does not take into account the chemical and isotopic composition of the gas.

Fig. 1
Fig. 1

Earth degassing and tectonic regimes. a Sketch of an extensional tectonic setting with the pathways of fluids rising through the fractures. b Compressional tectonic setting with overlapping structures that may inhibit the rise of deep fluids

Results

Carbon dioxide discharges correlated with tectonic regimes

CO2 discharges and major faults are clustered around the active continental margins (Fig. 2), with the former more concentrated in Central Eastern Europe and western United States and almost absent in cratonic areas (e.g. Australia, northern Asia). Major faults exhibit clustering along the main plate boundaries with marked hiatus between clusters which, in the majority of the cases, is also manifested in the same way by the CO2 discharges (e.g. western US coast and northern Italy). There are very few gas discharges far from the mapped major faults (e.g. northeastern North America, Pannonian basin) that could be due to lack of data on fractures and faults in those areas; hence, it does not exclude the existence of a system of fractures or paleo-faults. The gas discharges dataset also shows a likely degree of incompleteness, as suggested by the scarcity of degassing sites in the African Rifts. The calculated distances (in km) between each CO2 discharges and the nearest fault are <100 km for the majority of the sites (Supplementary Fig. 1). This value is of the same order of magnitude as the error in the digitization of the points suggesting a likely spatial correspondence between the two processes. Moreover, because fault systems are often characterized by a complex geometry of fractures and secondary faults that increase their lateral extension17, and CO2-rich aquifers may cover large areas, their proximity is plausible.

Fig. 2
Fig. 2

Earth degassing distribution and active faults. Distribution of carbon dioxide discharges (green dots) and active faults with (magenta lines) and without (turquoise lines) normal component

If we consider only the active faults with a normal component (magenta lines in Fig. 2), the above-described spatial correspondence with gas discharges is even more pronounced. Normal faults are spatially nearer to the gas discharges than transcurrent or thrust faults (Supplementary Fig. 1). We therefore applied the statistical test described in Methods to quantify and assess the correlation between these phenomena. We calculated a Spearman’s rank correlation coefficient ρ and p values of gas discharges vs. all the active faults and five faults subcategories (Fig. 3a, b) divided as follows: normal faults (NF), normal faults with strike-slip component or transtensive faults (NS), strike-slip faults (SS), thrust faults with strike-slip component or transpressive faults (TS), thrust faults (TF). The NS and TS categories represent mixed-mode faulting. The subcategories have been chosen following the earthquakes tectonic regimes described by Zoback18 and discussed below. The null hypothesis of zero correlation is predominantly rejected (>75% of the built 500 hexagonal grids) for hexagon resolutions of 4−6, the most representative of a regional degassing, but also for smaller (7) and bigger (2–4) hexagonal areas. Resolutions 8 and 9 are too small for providing statistically significant counts, given that they include only one gas discharge in the majority of the cases (>80%, Supplementary Fig. 2). These results would confirm the existence of a significant correlation between faults and gas discharges locations. In particular, normal and strike-slip faults show a better correlation compared to the thrust and transpressive faults. Thus we infer that, where an input of deep crustal or mantle-derived CO2-rich gas occurs, the emplacement of the outgassing is controlled at a global scale by regional normal/transcurrent faulting and its resulting increase of crust permeability19,20,21,22.

Fig. 3
Fig. 3

Correlation between gas discharges and tectonic regimes. Box plots of calculated p values and Spearman’s rank correlation coefficients between gas discharges and a, b faults lengths of different slip types and c, d different tectonic stress regimes. Upper and lower whiskers are maximum and minimum values. Horizontal gray stripe in (b, d) shows the 95% confidence interval (the null hypothesis of no correlation is rejected if p value < 0.05). Box colors denote the eight hexagonal grids used for the calculations, from the greatest (red, resolution 2) to the smallest (pink, resolution 9) hexagonal cell

Our results are in line with the possible link between continental rifts lengths and their associated mantle-derived CO2 degassing rates, recently proposed by Brune et al.7. In fact, the magnitude of the extensional faulting of the rifts would control the amount of CO2 released. Furthermore, deep mantle degassing in strike slip faults has been observed at important fault systems such as the San Andreas Fault System23 or the Norwest fault zone in Australia24.

The tectonic control on the fluid pathway has been extensively observed in volcanic areas at regional and local scales14,25,26,27,28, but its role at a continental scale is still poorly studied.

At the time of writing, the GEM-GAD was the only available dataset concerning faults and was focused on active faults for promoting seismic hazard modeling. Hence, we are not able to determine here the role of nonactive faults that are not currently mapped at a global scale. Nonactive faults may still operate as fluid pathways in regions where there are no (or moderate) active tectonic structures.

In light of the direct link existing between extensional faults and gas discharges, we further tested the robustness of our hypothesis by investigating more in detail the correlation with earthquakes. The instrumentally recorded seismicity allows to assess the focal mechanisms of earthquakes and hence the different tectonic regimes, or style of faulting, of recent active faults18 (see faults classification used above). For this analysis, we used data from the Global CMT catalog29,30 (http://www.globalcmt.org/) which includes more than 48,000 earthquakes with the relative source parameters. The moment tensors are crucial for identifying the tectonic style regime of each earthquake. As observed by Zoback18, thrust and strike-slip regimes (TF, SS, and TS) prevail in intraplate regions (with mainly horizontal stress fields). Normal faulting regimes (NF and NS) occur mainly in topographically high areas. Both tectonic regimes and magnitudes are quite uniform at a regional scale and hence define tectonic style provinces as detailed in Zoback18. We applied the statistical analysis discussed in Methods to the gas discharges and the different tectonic regimes, defined on the basis of earthquake moment tensors, in order to understand if there is a correspondence between degassing and tectonic regimes (Fig. 3c, d). We have first removed noncrustal earthquakes (hypocentral depth > 70 km). The null hypothesis is consistently rejected only for the NF earthquakes, positively correlated at different hexagonal resolutions (2–8). A minor correlation is confirmed for transcurrent faults (NS and SS) for large hexagonal areas (resolution 2, red boxes in Fig. 3c, d). This result would finally confirm that extensional tectonic regimes (NF) can develop a permeable network of faults and fractures through which gases rise to the surface. Deep fault systems that penetrate the lower crust may facilitate the transfer of CO2-rich gases from greater depths, upper-mantle or deep-crust4,5 (reference therein). The encountered positive correlation between gas discharge and extensional displacements is therefore not surprising. It has been suggested that high fluid pressure at depth can play a major role in triggering earthquakes12,22,31,32,33,34; therefore, we argue that the positive correlation may generate also a feedback mechanism: extensional faulting facilitates the rising of deep fluids, which in turn may enhance the seismic activity.

On the contrary, thrust faulting results from compressional forces that may not significantly increase the permeability of the crust35, here supported by the null hypothesis and negative correlation with CO2 degassing features. We also stress that a separate correlation test on faults and earthquakes is mandatory. Mapped active faults may not have shown recent (M > 5) seismicity in the last decades and, vice versa, the faults that have produced recent recorded seismicity may have not been mapped yet.

A global catalog of small earthquakes (M < 5) with a high degree of completeness is not available and, hence, they are not included in this work. But large datasets of small earthquakes at a regional scale are more easily accessible and can be representative of the local tectonic regimes36. As a matter of fact, Chiodini et al.3 have demonstrated a spatial correlation between earth degassing and normal faults in the Tyrrhenian hinterland of central Italy. They argued that the triggering effect of the deep degassing on the seismogenesis likely exists in the bordering Adriatic foreland, where thrusts and low-angle normal faults may create traps in which CO2 accumulates and gives rise to over-pressurized reservoirs that trigger earthquakes. The presence of these mechanisms of gas accumulation implies a reduced earth degassing in the Adriatic foreland compared to the Tyrrhenian hinterland. In light of the magnitude lower threshold of the CMT dataset and the spatial resolutions of the hexagonal grids used here, such distinction is surely not identifiable at a global scale.

Aquifers distribution and earth degassing probabilities

Aquifers have allowed identifying most of the tectonic degassing regions worldwide shown here3,15,16,37, because they can trap huge amounts of rising CO2-rich fluids over wide areas, bypassing the need to measure diffuse degassing at a small scale in numerous sites (e.g. with an accumulation chamber38,39,40,41) and interpolating the results with interpolation algorithms (i.e. kriging or conditional sequential gaussian simulations42). The latter method is extremely time consuming in exploring large areas but it is mandatory in regions with modest or no aquifers (e.g. Ethiopian rift4,5). Here we took advantage of a recent estimation of the spatial distribution and volumes of modern groundwaters made by Gleeson et al.43 in order to understand where aquifers cannot be used to study wide degassing regions. The map shown in Supplementary Fig. 3 displays the depth of the groundwater divided into five categories, as it was extracted and pooled at the land surface, and the gas discharges. The 0–0.1 m category highlights very well the arid regions that range from the western Sahara desert to the eastern Taklimakan desert and shows a marked absence of gas discharges. These arid regions may represent a threshold for our ability to observe degassing areas via carbon-rich aquifers in eastern Turkey, eastern Himalaya, surrounding Mongolia and, even if less constrained, in northern Africa and southern Australia. These evidences raise questions on the extent of earth degassing. Is the absence of gas discharges in arid regions of the world due to the absence of aquifers that help to localize them, or is it a real existing distribution of earth degassing? Below we will try to answer this question by estimating the probability of occurrence of gas discharges in these arid regions and in the rest of the globe.

We combined normal and transtensive active faults and NF earthquakes spatial distributions (those which have rejected the null hypothesis in Fig. 3) to provide a first-order probability map of having an extensional tectonics process on Earth. In light of the positive spatial correlation between gas discharges and tectonic that we have demonstrated above, we hypothesize that higher probabilities of having extensional tectonic processes would fairly correspond to higher probabilities of having a related gas discharge. We first computed the kernel density estimates44,45 (Fig. 4a, b) of faults and earthquakes, that is represented by a 128 × 128 matrix containing the expected number of normal faults and NF earthquakes per unit area. We then normalized the two matrices by dividing by their respective integrals, that are the expected global total number of normal faults and NF earthquakes, in order to obtain two probability density matrices P(F) and P(E) respectively. We then combined these probabilities as P(F) + P(E) − P(F) × P(E) to obtain P(F or E), that is the probability to observe normal faults or NF earthquakes in different areas of the globe (Fig. 4c). The use of the logical operator or means that faults and seismicity can or cannot occur in the same place and therefore are not mutually exclusive. In fact, as mentioned above, gas discharges may occur in faulted regions with no recent seismicity or in areas with recent seismicity where active faults have not been mapped yet.

Fig. 4
Fig. 4

Probability of extensional tectonic and earth degassing. Estimated kernel densities for extensional faults (a) and earthquakes (b) used to obtain the probability of occurrence of tectonic gas discharges (c). Green dots are the existing gas discharges listed in this work

The result is shown in Fig. 4c. Higher probability of having extensional tectonic processes and, hence, correlated tectonic gas discharges are found in North America, Central America, Cordillera Blanca (Perú), central Europe, East African Rift and eastern Himalaya, and correspond well to the higher density of reported gas discharges (green dots). With the exception of Melanesia, there are no wide areas with noticeable high probabilities and scarcity of mapped gas discharges, suggesting a certain degree of completeness of the gas dataset here re-processed or, if not complete, at least representative of the current global tectonic degassing. Concerning the arid region discussed above, there is no evidence of a high probability of gas discharges occurrence. We therefore argue that there may be no relevant tectonic degassing that has not been studied yet. Instead, further studies on the tectonic degassing along the Ethiopian rift, central America, southern Central Asia (e.g. Kyrgyzstan and Tajikistan), western East Asia (i.e. eastern Himalaya) and Melanesia (poorly constrained) are strongly recommended based on the existing contrast between high probabilities and low density of mapped degassing sources. It should be underlined that the intensity of the degassing process is not determined for each gas discharge reported here, and one single point could be representative of an intense degassing process operating over a wide region. But we believe that the extension of the degassing area or aquifer to which each point belongs cannot be clearly observable at a global scale and that is adequately represented by the dimension of the symbols in the figures. Accordingly, the gas discharges density can be considered a good indicator of the intensity of degassing process or of the lack of data in some regions.

For completeness, the same procedure has been also applied for compressional tectonic regimes. The result (Supplementary Fig. 4) shows lower spatial correspondence between the main degassing regions and the areas with high probability of compressional tectonic, further corroborating our findings above discussed.

Influence of volcanism on tectonic degassing

In the discussion above, not much has been said about the origin of the gas. In fact, as already mentioned, any attempt to identify the source of the discharged gas would primarily require the knowledge of its isotopic and chemical composition4,7,21. Numerous studies have already investigated the origin of the gas in several regions and creating a database with such measurements, despite challenging, would be possible. But for a quick investigation on the magmatic origin of the gas discharges here reported, we can tentatively use a list of Holocene active volcanoes46 considering that a volcanic edifice can be an indicator of magmatic processes occurring nearby and leading to CO2 degassing5. The dataset includes 1444 volcanoes formed during Holocene, among which ~400 have erupted in the last century. Therefore, for each emission point we have calculated the minimum distance (in kilometers) from a volcano. The resulting map in Fig. 5 clearly shows that three tectonic degassing regions in the world (roughly corresponding to the Cordillera Blanca in Perú, Pannonian basin in Central Eastern Europe and eastern Himalaya) are separated by long distances (>400 km) from Holocene volcanoes suggesting a nonmagmatic origin of their gas discharges. As a matter of fact, the origin of the gas released from these three regions has been widely documented in previous works as described below.

Fig. 5
Fig. 5

Volcanic influence on earth degassing. World map of Holocene volcanoes (purple triangles) and gas discharged (circle) colored in function of the distance from the closest holocene volcano

The Cordillera Blanca is a massif in the Peruvian flat slab segment (a distinct type of low-angle subduction47) characterized by an absence of active continental arc magmatism and a millions years old undertaking extensional regime48. The helium isotopic data from the thermal springs issuing from this region provided direct evidence for circulation of mantle-derived fluids in an amagmatic flat-slab setting49. The more southern Pampean flat-slab segment of the Central Andes displays a similar scenario of the Cordillera Blanca, but with minor current extensional tectonics50 and known degassing activity15.

The Himalayas are characterized by diffuse gas emissions51 and hot springs52,53 with high δ13C values of the CO2 gas phase suggesting a deep metamorphic decarbonation and a subsequent release of CO2-rich gas2,54. An increase of diffuse CO2 emissions has been observed after the 2015 earthquake in Nepal55.

The Pannonian Basin is a Miocene back-arc basin characterized by several past extensional events and a high geothermal gradient56 (references therein). The numerous gas reservoirs scattered over the basin have been intensively studied57,58,59 and provided convincing evidence for a significant component of mantle-derived carbon21.

All of the above features are indicative for a nonmagmatic origin of these three degassing regions that have been recognized here only on the basis of the distance from Holocene volcanoes.

In this work, we have complemented and re-analyzed the census of carbon dioxide discharges of Barnes et al.15 and Irwin and Barnes16 and provided new information on tectonic degassing and its mechanisms and the factors that control its distribution on Earth. Although a correlation between tectonic degassing and earthquakes has been already proposed and qualitatively observed, we have provided further evidence for such correlation and described more in detail the crucial role of the extensional regimes in facilitating gas migration. We found out that more efforts should be dedicated to better constrain the tectonic degassing in central America, southern Central and western East Asia. Finally, we argue that future estimations would not change significantly the magnitude of the global degassing that has been hypothesized in the last decade (hundreds of megatons per year of CO2).

Methods

World datasets used

A large part of the gas data reported in this work was available in papers only in the form of plots and maps with no numerical table as reference. Hence, we have used an open source software60 for automatically digitizing the images and extracting geographic coordinates of points. We estimated the error of the imported coordinates by digitizing known coordinates from a world map. The error of ~0.1° longitude and ~0.4° latitude would correspond to distances ranging from 44.8 to 45.4 km, depending on the latitude. We consider such error not relevant for our analysis at a global scale, but we do not recommend the use of such data for studies at smaller scales. Most of the carbon dioxide discharges have been digitized from Barnes et al.15 and Irwin and Barnes16 and correspond to water springs with dissolved CO2 or HCO3 > 1 g l−1 and with a pH < 8.3. We integrated the complementary gas discharges coordinates in Italy available in Googas61 and MAGA62 databases that are defined as nonvolcanic and high flux emissions. Other gas discharges have been imported for Portugal63, Tibet53 and Cameroon64. All the gas discharges coordinates used in this work and their references are summarized in Supplementary Data 1.

The world active faults dataset was obtained from the Global Earthquake Model Foundation’s Global Active Faults project (GEM-GAF), freely downloadable at https://github.com/cossatot/gem-global-active-faults. The dataset consists of GIS files containing fault traces and small amounts of relevant attributes or metadata (fault geometry, kinematics, slip rate, etc.). However, given the absence of data in Melanesia and southern East Asia, we digitized and added the main fault systems described in Abers and McCaffrey65 and Darman and Sidi66 respectively. Gas discharges (green circles) and active faults (magenta and turquoise lines) are shown in Fig. 2.

Seismic data were obtained from the Global CMT Catalog (http://www.globalcmt.org/), a collection of seismic moment tensors of great to moderate magnitude earthquakes (M ≥ 5.5) occurred worldwide since 1976 to present29,30.

A list of 1443 volcanoes with eruptions during the Holocene period (~11,700 years ago) has been obtained from the database of the Global Volcanism Program46.

Spatial analysis of world datasets

In order to assess the correlation among these different spatial datasets, we applied a point pattern analysis. In this context, a common type of analysis that can be performed is quadrat counting. Quadrat analysis consists of dividing a study area into equal sized subareas called quadrats and using probability analysis to determine and correlate the actual frequency of points within each quadrat. However, dividing a world map into large quadrats of equal longitude and latitude intervals would generate areas of unequal dimensions and geometries. Therefore, a grid that can divide the whole globe into areas of similar extension is needed. Researchers in numerous fields67 have consistently concluded that hexagons are the optimal choice for discrete gridding at a global scale. To achieve this, we used a package for the R programming language called “dggridR”68,69 that allows dividing the entire globe into hexagons of equivalent extension, and posteriorly count the data points in each area for performing ulterior statistical analysis. The extension of the hexagons can been chosen among 21 levels (called “resolution”, see Supplementary Table 1), ranging from millions of square kilometers (level 0) to hundreds of square meters (level 20). As for quadrat analysis, the selection of the extension of the quadrats/hexagons can significantly influence the outcome of a statistical analysis. For our analysis we selected a resolution ranging from 2 to 9 corresponding to areas of ~5,700,000 to ~2600 km2, and average radius of ~1300 to ~28 km (Supplementary Table 1). However, we consider the hexagons with resolutions 4−6 (~630,000 to ~70,000 km2, and average radius of ~450 to ~150 km) of the same order of magnitude of the extensions of the different degassing regions and faults systems in the world (e.g. Chiodini et al.3 for central Italy) and hence the most representative for such analysis. We have then discarded the hexagons without gas discharges. A typical example of global hexagonal grids is shown in Supplementary Fig. 5. The grid can be shifted by changing longitude and latitude of the starting point from which it is built (by default 58.3° and 11.25°). Hence, we have randomly changed these values from −10° to 10° around the default starting point in order to obtain 500 grids; in fact after a shift of 20° the grid simply repeats. Such randomization is proposed also for quadrat subdivision70. For each grid we have counted the number of gas discharges, earthquakes (of different magnitudes and tectonic regimes) and lengths of major faults within each hexagon. This procedure allows avoiding the possible bias due to the selection of one single position of the grid. As example, in Supplementary Fig. 6 we show a scatterplot between gas discharges counts and earthquakes counts obtained by counting the points within the hexagons of a grid of resolution 2 (among 500 randomized grids). Given the non-normality of the distributions of count data (gas discharges and earthquakes have a negative binomial distribution, see Supplementary Fig. 2) and the presence of continuous variables (lengths of faults), a Spearman’s Rank correlation coefficient ρ has been preferred for calculating the correlation between gas discharges counts and the counts of earthquakes and lengths of active faults for each of the 500 different grids generated for each resolution in the 2−9 interval. Then we tested a null hypothesis that states that each value of ρ is significantly (95% confidence interval) equal to zero, and hence, no correlation exists. We calculated a p value for each correlation test and set a predefined threshold value to 0.05 for rejecting the null hypothesis. If the null hypothesis is rejected (p value < 0.05), the alternative hypothesis is, instead, accepted and states that ρ is significantly different than zero and hence a correlation may exist. Calculated ρ and p values are shown in the box and whiskers diagram in Fig. 3.

Data availability

The authors declare that the data supporting the findings of this study are available within the supplementary information files.

Additional information

Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

References

  1. 1.

    Kerrick, D. M. & Caldeira, K. Metamorphic CO2 degassing from orogenic belts. Chem. Geol. 145, 213–232 (1998).

  2. 2.

    Becker, J. A., Bickle, M. J., Galy, A. & Holland, T. J. B. Himalayan metamorphic CO2 fluxes: quantitative constraints from hydrothermal springs. Earth Planet. Sci. Lett. 265, 616–629 (2008).

  3. 3.

    Chiodini, G. et al. Carbon dioxide Earth degassing and seismogenesis in central and southern Italy. Geophys. Res. Lett. 31, 2–5 (2004).

  4. 4.

    Lee, H. et al. Massive and prolonged deep carbon emissions associated with continental rifting. Nat. Geosci. 9, 145 (2016).

  5. 5.

    Hunt, J. A., Zafu, A., Mather, T. A., Pyle, D. M. & Barry, P. H. Spatially variable CO2 degassing in the main Ethiopian rift: implications for magma storage, volatile transport, and rift-related emissions. Geochem. Geophys. Geosyst. 18, 3714–3737 (2017).

  6. 6.

    Brune, S., Williams, S. & Müller, D. Potential links between continental rifting, CO2 degassing and climate change through time. Nat. Geosci. 10, 941–947 (2017).

  7. 7.

    Chiodini, G., Frondini, F., Cardellini, C., Parello, F. & Peruzzi, L. Rate of diffuse carbon dioxide Earth degassing estimated from carbon balance of regional aquifers: the case of central Apennine, Italy. J. Geophys. Res. Solid Earth 105, 8423–8434 (2000).

  8. 8.

    Marini, L. & Chiodini, G. The role of CO2 in the carbonate–evaporite geothermal systems of Tuscany and Latium, Italy. Acta Volcanol. 5, 95–104 (1994).

  9. 9.

    Minissale, A. Origin, transport and discharge of CO2 in central Italy. Earth-Sci. Rev. 66, 89–141 (2004).

  10. 10.

    Italiano, F., Martinelli, G. & Plescia, P. CO2 degassing over seismic areas: the role of mechanochemical production at the study case of central apennines. Pure Appl. Geophys. 165, 75–94 (2008).

  11. 11.

    De Paola, N. et al. The geochemical signature caused by earthquake propagation in carbonate-hosted faults. Earth Planet. Sci. Lett. 310, 225–232 (2011).

  12. 12.

    Miller, S. A. et al. Aftershocks driven by a high-pressure CO2 source at depth. Nature 427, 724–727 (2004).

  13. 13.

    Faulkner, D. R. et al. A review of recent developments concerning the structure, mechanics and fluid flow properties of fault zones. J. Struct. Geol. 32, 1557–1575 (2010).

  14. 14.

    Muirhead, J. D. et al. Evolution of upper crustal faulting assisted by magmatic volatile release during early-stage continental rift development in the East African Rift. Geosphere 12, 1670–1700 (2016).

  15. 15.

    Barnes, I., Irwin, P. W. & White, D. E. Global Distribution of Carbon Dioxide Discharges, and Major Zones of Seismicity. Water Resour. Invest. WRI 78-39 (U.S. Geol. Surv., Washington, DC, 1978).

  16. 16.

    Irwin, W. P. & Barnes, I. Tectonic relations of carbon dioxide discharges and earthquakes. J. Geophys. Res. 85, 3115 (1980).

  17. 17.

    Cox, S. J. D. & Scholz, C. H. Rupture initiation in shear fracture of rocks: an experimental study. J. Geophys. Res. 93, 3307–3320 (1988).

  18. 18.

    Zoback, M. L. First and second order patterns of tectonic stress: the World Stress Map Project. J. Geophys. Res. 97, 703–11728 (1992).

  19. 19.

    Knipe, R. J. Faulting processes and fault seal. Norw. Petrol. Soc. Spec. Publ. 1, 325–342 (1992).

  20. 20.

    Caine, J. S., Evans, J. P. & Forster, C. B. Fault zone architecture and permeability structure. Geology 24, 1025–1028 (1996).

  21. 21.

    Sherwood Lollar, B., Ballentine, C. J. & Onions, R. K. The fate of mantle-derived carbon in a continental sedimentary basin: integration of relationships and stable isotope signatures. Geochim. Cosmochim. Acta 61, 2295–2307 (1997).

  22. 22.

    Reyners, M., Eberhart-Phillips, D. & Stuart, G. The role of fluids in lower-crustal earthquakes near continental rifts. Nature 446, 1075–1079 (2007).

  23. 23.

    Kennedy, B. M. et al. Mantle fluids in the San Andreas Fault System, California. Science 278, 1278–1281 (1997).

  24. 24.

    Ring, U. et al. Recent mantle degassing recorded by carbonic spring deposits along sinistral strike-slip faults, south-central Australia. Earth Planet. Sci. Lett. 454, 304–318 (2016).

  25. 25.

    Giammanco, S., Gurrieri, S. & Valenza, M. Soil CO2 degassing along tectonic structures of Mount Etna (Sicily): the Pernicana fault. Appl. Geochem. 12, 429–436 (1997).

  26. 26.

    Werner, C. & Cardellini, C. Comparison of carbon dioxide emissions with fluid upflow, chemistry, and geologic structures at the Rotorua geothermal system, New Zealand. J. Volcanol. Geotherm. Res. 35, 221–238 (2006).

  27. 27.

    Mazot, A., Rouwet, D., Taran, Y., Inguaggiato, S. & Varley, N. CO2 and He degassing at El Chichon volcano, Chiapas, Mexico: gas flux, origin and relationship with local and regional tectonics. Bull. Volcanol. 73, 423–441 (2011).

  28. 28.

    Mazot, A. et al. CO2 discharges from the bottom of volcanic Lake Rotomahana, New Zealand. Geochem. Geophys. Geosyst. 15, 577–588 (2014).

  29. 29.

    Dziewonski, A. M., Chou, T. A. & Woodhouse, J. H. Determination of earthquake source parameters from waveform data for studies of global and regional seismicity. J. Geophys. Res. 86, 2825–2852 (1981).

  30. 30.

    Ekström, G., Nettles, M. & Dziewonski, A. M. The global CMT project 2004−2010: centroid-moment tensors for 13,017 earthquakes. Phys. Earth Planet. Inter. 200, 1–9 (2012).

  31. 31.

    Rice, J. R. Fault stress states, pore pressure distributions, and the weakness of the San Andreas fault. In Fault Mechanics and Transport Properties of Rocks (eds Evans, B. & Wong, T. F.) (Academic Press, New York, 1992).

  32. 32.

    Sibson, R. H. Implications of fault-valve behavior for rupture nucleation and recurrence. Tectonophys. 18, 1031–1042 (1992).

  33. 33.

    Sibson, R. H. Fluid involvement in normal faulting. J. Geodynam. 29, 469–499 (2000).

  34. 34.

    Cox, S. F. Faulting processes at high fluid pressure; an example of fault valve behavior from the Wattle Gully Fault, Victoria, Australia. J. Geophys. Res. 100, 12841–12475 (1995).

  35. 35.

    Faulkner, D. R. & Armitage, P. J. The effect of tectonic environment on permeability development around faults and in the brittle crust. Earth Planet. Sci. Lett. 375, 71–77 (2013).

  36. 36.

    Amelung, F. & King, G. Large-scale tectonic deformation inferred from small earthquakes. Nature 386, 702–705 (1997).

  37. 37.

    Chiodini, G., Frondini, F. & Ponziani, F. Deep structures and carbon dioxide degassing in central Italy. Geothermics 24, 81–94 (1995).

  38. 38.

    Chiodini, G., Frondini, F. & Raco, B. Diffuse emission of CO2 from the Fossa crater, Vulcano Island (Italy). Bull. Volcanol. 58, 41–50 (1996).

  39. 39.

    Chiodini, G., Cioni, R., Guidi, M., Raco, B. & Marini, L. Soil CO2 flux measurements in volcanic and geothermal areas. Appl. Geochem. 13, 543–552 (1998).

  40. 40.

    Evans, W. C. et al. High CO2 emissions through porous media: Transport mechanisms and implications for flux measurement and fractionation. Chem. Geol. 177, 15–29 (2001).

  41. 41.

    Welles, J. M., Demetriades-Shah, T. H. & McDermitt, D. K. Considerations for measuring ground CO2 effluxes with chambers. Chem. Geol. 177, 3–13 (2001).

  42. 42.

    Cardellini, C., Chiodini, G. & Frondini, F. Application of stochastic simulation to CO2 flux from soil: mapping and quantification of gas release. J. Geophys. Res. Solid Earth 108, 2425 (2003).

  43. 43.

    Gleeson, T., Befus, K. M., Jasechko, S., Luijendijk, E. & Cardenas, M. B. The global volume and distribution of modern groundwater. Nat. Geosci. 9, 161–164 (2016).

  44. 44.

    Sheather, S. J. & Jones, M. C. A reliable data-based bandwidth selection method for kernel density estimation. J. Roy. Stat. Soc. B 53, 683–690 (1991).

  45. 45.

    Baddeley, A., Rubak, E. & Turner, R. Spatial Point Patterns: Methodology and Applications with R. London. (Chapman and Hall/CRC Press, Boca Raton, 2015).

  46. 46.

    Global Volcanism Program. Volcanoes of the World, v. 4.6.6. (ed. Venzke, E.) (Smithsonian Institution, Washington, DC, 2013).

  47. 47.

    Peacock, S. M. Fluid processes in subduction zones. Science 248, 329–337 (1990).

  48. 48.

    Giovanni, M. K., Horton, B. K., Garzione, C. N., McNulty, B. & Grove, M. Extensional basin evolution in the Cordillera Blanca, Perú: stratigraphic and isotopic records of detachment faulting and orogenic collapse in the Andean hinterland. Tectonics 29, 1–21 (2010).

  49. 49.

    Newell, D. L., Jessup, M. J., Hilton, D. R., Shaw, C. A. & Hughes, C. A. Mantle-derived helium in hot springs of the Cordillera Blanca, Perú: implications for mantle-to-crust fluid transfer in a flat-slab subduction setting. Chem. Geol. 417, 200–209 (2015).

  50. 50.

    Ramos, V. A., Cristallini, E. O. & Pérez, D. J. The Pampean flat-slab of the Central Andes. J. South Am. Earth Sci. 15, 59–78 (2002).

  51. 51.

    Perrier, F. et al. A direct evidence for high carbon dioxide and radon-222 discharge in Central Nepal. Earth Planet. Sci. Lett. 278, 198–207 (2009).

  52. 52.

    Evans, M. J., Derry, L. A. & France-Lanord, C. Geothermal fluxes of alkalinity in the Narayani river system of central Nepal. Geochem. Geophys. Geosyst. 5, Q08011 (2004).

  53. 53.

    Girault, F. et al. Large-scale organization of carbon dioxide discharge in the Nepal Himalayas. Geophys. Res. Lett. 41, 6358–6366 (2014).

  54. 54.

    Evans, M. J., Derry, L. A. & France-Lanord, C. Degassing of metamorphic carbon dioxide from the Nepal Himalaya. Geochem. Geophys. Geosyst. 9, Q04021 (2008).

  55. 55.

    Girault, F. et al. Persistent CO2 emissions and hydrothermal unrest following the 2015 earthquake in Nepal. Nat. Commun. 9, 2956 (2018).

  56. 56.

    Matenco, L. & Radivojevi, D. On the formation and evolution of the Pannonian Basin: constraints derived from the structure of the junction area between the Carpathians and Dinarides. Tectonics 31, 1–31 (2012).

  57. 57.

    Ballentine, C. J. & O’Nions, R. K. The nature of mantle neon contributions to Vienna Basin hydrocarbon reservoirs. Earth Planet. Sci. Lett. 113, 553–567 (1992).

  58. 58.

    Ballentine, C. J., O’Nions, R. K., Oxburgh, E. R., Horvath, F. & Deak, J. Rare gas constraints on hydrocarbon accumulation, crustal degassing, and groundwater flow in the Pannonian Basin. Earth Planet. Sci. Lett. 105, 229–246 (1991).

  59. 59.

    Sherwood Lollar, B., O’Nions, R. K. & Ballentine, C. J. Helium and neon isotope systematics in carbon dioxide-rich and hydrocarbon-rich gas reservoirs. Geochim. Cosmochim. Acta 58, 5279–5290 (1994).

  60. 60.

    Rohatgi A. WebPlotDigitizer 4.0, https://automeris.io/WebPlotDigitizer/ (2017).

  61. 61.

    Chiodini, G., Valenza, M., Cardellini, C. & Frigeri, A. A new web-based catalog of Earth degassing sites in Italy. Eos Trans. AGU 89, 341 (2008).

  62. 62.

    Cardellini, C. et al. The development of a new database of gas emissions: MAGA, a collaborative web environment for collecting data. American Geophysical Union, Fall Meeting 2013, San Francisco, USA, abstract id. V31B-2708 (2013).

  63. 63.

    Marques, J. M. & Carreira, P. M. Questions and answers ascribed to chaves CO2-rich thermal waters conceptual model (N Portugal): a review. Procedia Earth Planet. Sci. 17, 654–657 (2017).

  64. 64.

    Tanyileke, G. Z., Kusakabe, M. & Evans, W. C. Chemical and isotopic characteristics of fluids along the Cameroon volcanic line, Cameroon. J. Afr. Earth Sci. 22, 433–441 (1996).

  65. 65.

    Abers, G. & McCaffrey, R. Active deformation in the New Guinea fold-and-thrust belt: seismological evidence for strike-slip faulting and basement-involved thrusting. J. Geophys. Res. 93, 13332–13354 (1988).

  66. 66.

    Darman, H. & Sidi, H. An Outline of the Geology of Indonesia. (Indonesian Geologists Association publication, Jakarta, 2000).

  67. 67.

    Sahr, K. Hexagonal discrete global grid systems for geospatial computing. Arch. Photogr. Cartogr. Rem. Sens. 22, 363–376 (2011).

  68. 68.

    R Core Team. R: A Language and Environment for Statistical Computing (R Foundation for Statistical Computing, Vienna, Austria). http://www.R-project.org/ (2013).

  69. 69.

    Barnes, R. dggridR: Discrete Global Grids for R. R package version 0.1.12. https://github.com/r-barnes/dggridR/ (2017).

  70. 70.

    O’Sullivan, D. & Unwin, D. J. Geographic Information Analysis, 2nd edn (John Wiley & Sons, New York, 2010).

Download references

Acknowledgements

This work has been supported by the Deep Carbon Observatory (subcontract N. 10759-1254 “A first step toward the estimation of global tectonic carbon flux”, Principal Investigator: Carlo Cardellini). The authors wish to thank Tobias Fischer and an anonymous reviewer for their useful comments and suggestions upon reviewing the manuscript. Antonio Costa and Carlo Cardellini are also thanked for their valuable discussions that led to conceiving this manuscript.

Author information

Affiliations

  1. Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Bologna, via Creti, 12, 40128, Bologna, Italy

    • Giancarlo Tamburello
    • , Silvia Pondrelli
    • , Giovanni Chiodini
    •  & Dmitri Rouwet

Authors

  1. Search for Giancarlo Tamburello in:

  2. Search for Silvia Pondrelli in:

  3. Search for Giovanni Chiodini in:

  4. Search for Dmitri Rouwet in:

Contributions

G.T. conceived the idea for this manuscript and extracted the datasets and performed the statistical analysis. S.P. suggested to focus on the tectonic regimes and provided and processed the seismic data from GMT catalog. G.T. wrote the manuscript and S.P., G.C. and D.R. participated in the discussion and revised the text.

Competing interests

The authors declare no competing interests.

Corresponding author

Correspondence to Giancarlo Tamburello.

Electronic supplementary material

About this article

Publication history

Received

Accepted

Published

DOI

https://doi.org/10.1038/s41467-018-07087-z

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.