Abstract
Controllable metal–insulator transitions (MIT), Rashba–Dresselhaus (RD) spin splitting, and Weyl semimetals are promising schemes for realizing processing devices. Complex oxides are a desirable materials platform for such devices, as they host delicate and tunable charge, spin, orbital, and lattice degrees of freedoms. Here, using firstprinciples calculations and symmetry analysis, we identify an electricfield tunable MIT, RD effect, and Weyl semimetal in a known, chargeordered, and polar relativistic oxide Ag_{2}BiO_{3} at room temperature. Remarkably, a centrosymmetric BiO_{6} octahedralbreathing distortion induces a sizable spontaneous ferroelectric polarization through Bi^{3+}/Bi^{5+} charge disproportionation, which stabilizes simultaneously the insulating phase. The continuous attenuation of the Bi^{3+}/Bi^{5+} disproportionation obtained by applying an external electric field reduces the band gap and RD spin splitting and drives the phase transition from a ferroelectric RD insulator to a paraelectric Dirac semimetal, through a topological Weyl semimetal intermediate state. These findings suggest that Ag_{2}BiO_{3} is a promising material for spinorbitonic applications.
Introduction
Crosscontrolling of order parameters by external stimuli in a singlephase material is of great interest in both fundamental research and technological applications^{1,2}. For instance, metaltoinsulator transitions (MIT) driven by the application of an electric field represent a viable way for designing energyefficient logic devices^{3,4,5}. Ferroelectric compounds, whose spontaneous electric polarization can be reversed by the application of an external electric field, are among the most promising materials to achieve this type of switch^{6}, owing to the many different driving forces enabling ferroelectric behavior, including cooperative interactions of lattice distortions, charge, spin, and orbital ordering^{7,8,9,10}. Among the different types of MIT observed in nature^{11} (Mott^{12}, Peierls^{13}, Slater^{14}, Lifshitz^{15}, Verwey^{16}, to name a few), the Peierls MIT, associated with a crystal lattice distortion, frequently exhibits a higher transition temperature (e.g., VO_{2}: T_{MIT} ~ 340 K;^{17} YNiO_{3}: T_{MIT} ~ 580 K^{18}). Although Peierlslike MITs are ubiquitous in oxides, the breathing mode involving cationoxygen bond length disproportionation usually does not couple with ferroelectric displacements^{17,19,20,21}.
Recent studies have shown that an external electric field could also be employed to switch the Rashba–Dresselhaus (RD) spin splitting in ferroelectric materials^{22,23,24}. The RD spin splitting is a consequence of lifting the spin degeneracy, typically occurring in materials with strong spin–orbit coupling (SOC) lacking inversion symmetry^{25,26,27}. The most interesting outcome of the RD effect is that an electron moving under an electric field (E) or a gradient of the crystal potential (E = −∇V) behaves as it experiences an effective magnetic field B_{eff} ∞ E × p/mc^{2}, where p, m, and c are momentum, mass, and speed of light, respectively, that couples to the spin of the electron^{28}. Owing to its promising applications in spinorbitronics devices such as the Datta–Das spin fieldeffect transistor^{29}, the RD effect has gained growing research attention^{24,28,30,31,32}. The tunability of the RD splitting by applying an external field is primary possible due to the dependence of B_{eff} on the crystal potential gradient, which is strongly affected by crystal structure distortions^{24,30,32,33}.
Additionally, Weyl semimetals are a topological phase whose low energy excitations are the massless chiral fermions^{34}. Weyl semimetals are the realization of Weyl fermions in condensed matter systems and exhibit many exotic properties^{35}. Since the Weyl semimetal typically only exists in crystals without either timereversal or inversion symmetry, but not both, it is also possible to activate a Weyl semimetal phase in a topologically trivial material by applying an external field. Although the magnetic field induced Weyl semimetal has been discovered in GdPtBi recently^{36}, the electric field promoted Weyl semimetal has not been reported yet.
Here, we explore the possibility of simultaneously controlling the MIT, RD spin splitting, and Weyl fermions in a singlephase ferroelectric oxide using an electric field by means of firstprinciples calculations and symmetry analysis. We demonstrate that this paradigm can be realized in the room temperature phase of the known Peierlslike semiconductor Ag_{2}BiO_{3}. We identify an atypical polar structural distortion that arises from the octahedralbreathing mode associated with Bi^{3+}/Bi^{5+} charge disproportion. This mechanism enables an unexpected route for tuning the MIT, RD spin splitting, and Weyl semimetallic state simultaneously by applying an external electric field. The modulation of the charge disproportion guides the transition from a polar insulating phase exhibiting RD spin splitting to a nonpolar spindegenerate Dirac semimetallic state. Remarkably, we find that across the MIT transition there exists an intermediate topological Weyl semimetallic state, manifested by a nondegenerate band crossing around the Fermi level and nontrivial surface states connecting Weyl nodes with opposite chirality.
Results
Ground state structural and electronic properties
At room temperature (and up to at least 380 K) Ag_{2}BiO_{3} crystallizes in a polar structure with Pnn2 (No. 34) space group^{37} (Fig. 1a). At 220 K the polar Pnn2 phase is converted to another polar monoclinic structure Pn (No. 7). There is no further observed phase transition down to 2 K^{37}. In the Pnn2 phase, each octahedra shares an edge (along [100]) and a corner (along [011] and [0\(\bar 1\)1] directions) with its adjacent octahedra, resulting in a checkerboardlike distribution of inequivalent Bi^{3+}/Bi^{5+} sites (nominal oxidation state) characterized by different Bi^{3+}/Bi^{5+}–O bond lengths of 2.34 and 2.13 Å, respectively^{37}. This chargeordered pattern is responsible for opening a band gap (0.7 eV^{38}), which has been observed in other Bi oxides^{39,40}, and for the onset of ferroelectric behavior, which is observed for the first time. Our density functional theory (DFT) calculations find that the fully relaxed lowtemperature Pn phase is nearly degenerate with the Pnn2 phase in energy, and correctly reproduce the bond length disproportionation, see Supplementary Tables 1 and 2 for a full structural characterization. We also find a direct band gap of 0.53 eV between the occupied Bi^{3+} and the unoccupied Bi^{5+} 6s orbitals hybridized with O2p states at the R point k = (1/2,1/2,1/2) (Fig. 1c). The slight underestimation of the band gap is due to inaccuracies in the semilocal functional within DFT. The accuracy of DFT in reproducing the crystal structures (lattice constants, volume, and Bi–O bond lengths), energy difference between ferroelectric and paraelectric phases, and band gaps is assessed with various functionals commonly used for ferroelectric oxides^{41,42} (Supplementary Table 1).
Since the R point preserves timereversal symmetry and the whole crystal lacks inversion symmetry, Kramers pairs (E^{↑} (k) = E^{↓} (−k)) are observed at the conduction band minimum and valence band maximum. Owing to the strong SOC of the Bi cation, both the lowest conduction band and the highest valence band split into two branches, forming inner and outer bands with opposite spin rotation patterns (Fig. 1e, f). The spin splitting (ΔE_{ RD }) is larger at the lowest conduction band and exhibits strong anisotropy, manifested by a larger ΔE_{ RD } in the R–T k_{ x } direction (6.4 meV) compared to that in the R–U k_{ y } direction (0.7 meV). Therefore, a combined Rashba and Dresselhaus spin splitting is expected, similar to the case of the formamidinium tin iodide perovskite FASnI_{3} and consistent with a C_{2v} symmetry, in which both Rashba and Dresselhaus spin splitting are symmetry allowed^{33}. The dispersion relation of the resulting electronic states is given, to linear order, by the coupling Hamiltonian H_{RD} = α_{R}(k_{ y }σ_{ x }−k_{ x }σ_{ y }) + α_{D}(−k_{ x }σ_{ x } + k_{ y }σ_{ y }), with \(\alpha _{\mathrm{R}} \sim 0.07\) eV Å and \(\alpha _{\mathrm{D}} \sim 0.17\) eV Å the fitted Rashba and Dresselhaus parameters. The predominant contribution of Dresselhaus character, i.e., α_{D} > α_{R}, is consistent with the calculated spin orientations showing also parallel components to the associated crystal momentum. The ground state band structure of the Pn phase is also insulating and exhibits very similar dispersion (Supplementary Figure 2), consistent with the structural similarity between the Pnn2 and Pn phases.
Symmetry analysis and lattice dynamics
By means of symmetry analysis based on representation theory^{43,44}, we find that Pnn2 is a subgroup of Pnna (Fig. 1b). Our DFT calculations show that the Pnna phase is only 5.3 meV per atom higher in energy than Pnn2, and can be considered as the parent phase of Pnn2. The super group of Pnna is Imma, which is 1,391 meV per f.u. higher in energy than Pnn2. The Imma polymorph is too high in energy to be achieved at elevated temperature. The main structure difference between the Pnna and Pnn2 phases is the splitting of the Bi Wyckoff positions in the lower symmetry phase Pnn2, which permits the Bi^{3+}/Bi^{5+} charge disproportionation (Fig. 1; Supplementary Table 2). From the point view of representation theory, Pnna is connected with the room temperature phase Pnn2 by a onedimensional order parameter \(\Gamma _{2^ {}}\) and with the lowtemperature phase Pn by a combination of the \(\Gamma _{2^ {}}\) and another onedimensional order parameter \(\Gamma _{3^ {}}\), i.e., \(\Gamma _{2^ {}} \oplus \Gamma _{3^ {}}\). This assessment is validated by the phonons dispersions of the Pnna phase (Fig. 2a), which exhibit two unstable phonon modes at Γ with imaginary frequencies ν = 392i cm^{−1} (\(\Gamma _{2^ {}}\)) and ν = 30i cm^{−1} (\(\Gamma _{3^ {}}\)). The condensation of the force constant eigenvector of \(\Gamma _{2^ {}}\) mode directly generates the room temperature phase Pnn2, whereas a simultaneous condensation of the \(\Gamma _{2^ {}}\) and \(\Gamma _{3^ {}}\) modes, i.e., \(\Gamma _{2^ {}} \oplus \Gamma _{3^ {}}\) establishes the Pn phase.
The main vibrational characteristic of the \(\Gamma _{2^ {}}\) mode is a Bi–O breathing distortion that causes the Bi^{3+}/Bi^{5+} disproportionation (Fig. 2b, c). Surprisingly, this mode is polar and is the primary order parameter for this paraelectric (Pnna) to ferroelectric (Pnn2) transition, which produces a spontaneous polarization (P_{z}) of 8.87 μC cm^{−2} (Fig. 3f). Considering that \(\Gamma _{2^ {}}\) is a onedimensional order parameter and the fact that the calculated polar displacement Q and ΔE/μ (where ΔE and μ are the energy differences between the paraelectric and ferroelectric states of the material and the dipole moment of ferroelectric phase, respectively) of Ag_{2}BiO_{3} are comparable with known ferroelectric materials (Supplementary Figure 3), Ag_{2}BiO_{3} should be electricfield tunable with moderate fields.
To the best of our knowledge, this is the first example of a polar octahedrabreathing mode. Typically, the breathing mode in perovskites with the cornersharing octahedra does not lift inversion symmetry^{19}. The reason for such an unusual behavior in Ag_{2}BiO_{3} is the coexistence of both cornersharing and edgesharing octahedra, which leads to a distorted octahedral framework with inversion centers on occupied Bi cation sites. The bonddisproportionation in combination with the lowcrystal symmetry enables an acentric octahedralbreathing mode. As a result, oxygen displacements along the c axis in the BiO_{6} octahedra are not completely compensated, as illustrated in Fig. 2c. Both Ag and Bi atoms have small polar distortions along the c axis as well. The polarity of the \(\Gamma _{2^ {}}\) mode and its connection with the Bi^{3+}/Bi^{5+} disproportionation is the crucial factor enabling the tunability of the electronic structure and spin properties of Ag_{2}BiO_{3}, as elaborated below.
Tunable MIT with RD and Weyl states
Unlike the ferroelectric Pnn2 phase, the nonpolar Pnna phase exhibits a semimetallic band structure without RD spin splitting (Fig. 1d). Nonetheless we find that the Pnna phase exhibits a Dirac point at the S point of the Brillouin zone, similar in nature to those defined in double Dirac semimetals^{45,46,47}. This feature is also independent of DFT functional (Supplementary Figure 6). The \(\Gamma _{2^ {}}\) mode breaks the mirror symmetry protecting the Dirac point and leads to the opening of a gap, as evidenced in Fig. 4a. This is due to the suppression of the charge disproportionation which produces halffilled Bi^{4+} 6s orbitals crossing the Fermi level (Fig. 1d). This means that the \(\Gamma _{2^ {}}\) order parameter simultaneously drives a ferroelectric and a metaltoinsulator transition (Fig. 3). The \(\Gamma _{2^ {}}\)driven paraelectrictoferroelectric transition is associated with a continuous increase of the spontaneous polarization and of the overall ferroelectric energy gain ΔE (Fig. 3d, f). The progressive increase of the amplitude of \(\Gamma _{2^ {}}\) is coupled with an enhanced charge disproportionation between the two inequivalent Bi sites, measured in terms of Bi–O bond length difference (Fig. 3b), valence Bader charges (Fig. 3c), and by a monotonous increase of the band gap (Fig. 3a). This type of MIT is common to other bismutathes^{19,48}. The degree of the ferroelectric distortion influences the RD splitting as well, owing to the coupling between the polar distortion and the potential gradient surrounding the Bi^{3+} and Bi^{5+} cations. This can be quantified by the RD spin splitting coefficient α_{RD} defined as \(2\Delta E_{{\mathrm{RD}}}{\mathrm{/}}\Delta k_{{\mathrm{RD}}}\). Figure 3e illustrates that α_{RD} decreases linearly with the amplitude of \(\Gamma _{2^ {}}\) until \(Q_{\Gamma _2^  }\) ≈ 0.25 Å. For \(Q_{\Gamma _2^  } < 0.25\) Å there is a band crossing between the valence and conduction RD bands (Fig. 3g), and then α_{RD} is illdefined.
Interestingly, our calculations reveal that during the ferroelectrictoparaelectric transition at \(Q_{\Gamma _2^  } = 0.22\) Å, there exists an intermediate phase that shows the typical hallmark of a Weyl semimetal state, similar to the Weyl semimetal recently found in HgPbO_{3}^{49}. Weyl semimetals are a class of quantum materials characterized by nonzero Fermi surface Chern numbers, which manifest as a linear band crossing around the Fermi level with nondegenerate spins in a system with either timereversal or inversion symmetry broken^{50}. In this intermediate phase of Ag_{2}BiO_{3}, the Weyl node is located near the R point with k = (0.4975,0.4725,0.4988), about 0.08 eV above the Fermi level (Fig. 4a, b). Symmetry considerations indicate that there are four pairs of Weyl nodes, whose coordinates are given in Supplementary Table 3. The four pairs of Weyl points are protected by a mirror operation, which is preserved through the entire transition from the insulatingferroelectric phase to the metallic centrosymmetric phase, i.e., always coexisting with the \(\Gamma _{2^ {}}\) mode. The Weyl nodes appear only at a specific interval of the \(\Gamma _{2^ {}}\) distortions as a result of balancing two competing interactions: (a) going towards the insulating phase the chemical bonding become progressively stronger (bonding/antibonding interactions increase) and destroys the Weyl nodes; (b) on the other side, approaching the metallic phase the broken inversion symmetry gradually fades away, which again results in the a disappearance of the Weyl nodes.
The presence of a Weyl node in the bulk phase is typically associated with topological nontrivial surface states, which connect two Weyl nodes with opposite chirality, and appear as broken Fermi arcs states. To inspect this feature, we have derived the (001) surface electron structure by the Green’s function based tightbinding method based on the maximally localized Wannier functions^{51,52,53,54,55}. The resulting Fermi arcs presented in Fig. 4b. Moreover, the calculation of the Berry curvature confirms the topological Weyl nature of this intermediate phase (Fig. 4c).
Discussion
We have established that two pairs of distinct properties, insulator/metal and RD/nonRD, through a Weyl semimetal state, are closely connected with the ferroelectric structure distortion in Ag_{2}BiO_{2}, indicating a potentially tunable MIT and spin splitting by applying an electric field. Since the energy difference between the semimetal paraelectric (Pnna) and insulatingferroelectric (Pnn2) phases is only 5.3 meV per atom and the polarization is relatively large (8.87 μC cm^{−2}), it is expected that the insulating phase could be suppressed (but not passed) by a relative small electric field (E) applied opposite to the direction of the spontaneous polarization (P) through the interaction P ⋅ E in the free energy. This is depicted in Fig. 3h based on a Landau–Ginzburg phenomenological model^{56}. If the frequency of the electric field pulse is carefully chosen, there should be an oscillation between the Pnn2 and Pnna phases. By increasing the strength of the electric field, the insulating phase of Ag_{2}BiO_{3} becomes more conducting, as shown by the density of states provided in Fig. 3a. Since the paraelectric phase is a poor metal, however, the free carriers will tend to screen the external electric field and therefore, the metallic phase is expected to survive only for a short time. This causes the socalled oscillating electroresistance effect (ER), which has potential applications in random access information storage^{57}. If the applied pulse electric field is strong enough, however, the Bi^{3+}/Bi^{5+} chargeorder can be melted and converted into a metallic phase, a phenomena called colossal ER, which has been observed in chargeordered insulators with strongly competing metallic phases, Pr_{0.7}Ca_{0.3}MnO_{3}, R_{0.5}Ca_{0.5}MnO_{3} (R = Nd, Gd, and Y)^{1,2}, and LuFe_{2}O_{4}^{6}.
We have demonstrated a controllable metal–insulator transition, Rashba–Dresselhaus spin splitting effect, and Weyl semimetallic state by applying an electric field in the experimentally available chargeordered oxide Ag_{2}BiO_{3} by means of firstprinciples calculations. The functionalized electricfield tunable MIT could make Ag_{2}BiO_{3} a suitable material for lower power memory applications compared to magnetic field controlled MITs. Moreover, the semiconducting nature of Ag_{2}BiO_{3} could allow for the injection of a reasonable number of carriers (if the Fermi level is properly tuned) without suppressing the ferroelectric instability, eventually resulting in electrically controllable spin polarized currents as a consequence of the Rashba–Dresselhaus effect^{58}. The higher stability of oxides in atmospheric conditions and the higher ferroelectric Curie temperature of Ag_{2}BiO_{3} over organic–inorganic metal halide perovskites and GeTe, the prototypical ferroelectric Rashba semiconductors^{22,33}, make this bismuthate more practical for realistic applications^{59}. Finally, the electricfield tunable Weyl semimetallic state proposed here will enable future studies on intertwined ferroelectric and topological phenomena.
Methods
Computational details
All the firstprinciples calculations were conducted by using the projectoraugmented wave pseudopotential methed^{60,61} as implemented in the Vienna ab intio Simulation Package (VASP)^{62,63}. PBEsol exchangecorrelation functional^{64} and the planewave basis set with energy cutoff of 520 eV were used. The MonkhorstPack kpoints grids of 10×10×6, was used to sample the Brillouin zones. All the crystal structures were fully relaxed until the Hellmann–Feynman foreces acting on each atom were less than 0.01 eV Å^{−1}. The phonon dispersion was calculated by using finite displacement method as implemented in the Phonopy code^{65}. Spin orbital coupling is included in all the electronic structures calculations. The symmetry analysis was conducted using the PSEUDO program provided by the Bilbao crystallographic server^{43,66}. The spontaneous ferroelectric polarization was calculated by using Born effective charges (Z^{*}) of the ferroelectric phase (Pnn2) and the structure distortion (u) of ferroelectric phase with respect to reference paraelectric phase (Pnna) as \(P_\alpha = \frac{e}{\Omega }\mathop {\sum}\nolimits_{k,\beta } Z_{k,\alpha \beta }^ \ast u_{k,\beta }\) where, Ω and e are the volume of unit cell and elementary charge, respectively. The spin texture of the lowest conduction band have been computed by plotting, for each momentum vector on the k_{ x }–k_{ y } plane, the expectation values of the Pauli σmatrices onto the Kohn–Sham wavefunctions, i.e., the vectorial quantity S_{ i }(n,k) = \(\langle \Psi _{n,k}\sigma _i\Psi _{n,k}\rangle\), with i = x,y,z and n referring to either the inner or the outer branch of the conduction bands. Represented as a vector, the kspace distribution of the S_{ i }(n,k) resulted in a combined Rashba and Dresselhaus spinpattern.
The surface state calculations have been performed using a Green’s function based tightbinding (TB) approach^{51}. The TB model Hamiltonian was constructed by means of maximally localized Wannier functions (MLWFs^{52,53}) obtained by the the Wannier90 code^{54} and constructed from Bi 5s and O 6p orbitals by employing VASP2WANNIER90^{55}. The TB parameters were obtained from the MLWFs overlap matrix. Finally, the berry curvatures based on the firstprinciples Bloch functions provided by VASP following the recipe described in ref. ^{67}. The topological charge of each Weyl point (WP) is defined by the integration of the Berry curvature over a closed surface enclosing that WP, and was computed by employing the Wilsonloop method^{68}.
Data and code availabity
All data are available from the corresponding authors upon reasonable request. All codes used in this work are either publicly available or available from the authors upon reasonable request.
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Acknowledgments
Work at the University of Vienna was sponsored by the FWF project INDOX (Grant No. I1490N19). Work at the Shenyang National Laboratory for Materials Science was supported by the National Science Fund for Distinguished Young Scholars (No. 51725103), by the National Natural Science Foundation of China (Grant Nos. 51671193 and 51474202), and by the Science Challenging Project No. TZ2016004. D.D.S. was supported by the German Research Foundation (DFG SFB 1170) and acknowledges the ERCStG336012ThomaleTOPOLECTRICS. J.M.R. was supported by the Army Research Office (W911NF1510017). All calculations were performed on the Vienna Scientific Cluster (VSC) and partially at the highperformance computational cluster in the Shenyang National University Science and Technology Park, as well as the National Supercomputing Center in Guangzhou (TH2 system).
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J.H. and C.F. conceived and coordinated the project. J.M.R. and J.H. performed symmetry analysis of the ferroelectric phase transition. J.H. conducted the DFT calculations. D.D.S. carried out Rashba/Dresselhaus analysis. R.L. and X.Q.C. analyzed and computed the topological properties (Weyl features) and Berry curvatures. All the authors contributed to discussions and writing of the manuscript.
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He, J., Di Sante, D., Li, R. et al. Tunable metalinsulator transition, Rashba effect and Weyl Fermions in a relativistic chargeordered ferroelectric oxide. Nat Commun 9, 492 (2018). https://doi.org/10.1038/s41467017028144
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