Abstract
Solidstate cooling is an energyefficient and scalable refrigeration technology that exploits the adiabatic variation of a crystalline order parameter under an external field (electric, magnetic, or mechanic). The mechanocaloric effect bears one of the greatest cooling potentials in terms of energy efficiency owing to its large available latent heat. Here we show that giant mechanocaloric effects occur in thin films of wellknown families of fastion conductors, namely Lirich (Li_{3}OCl) and typeI (AgI), an abundant class of materials that routinely are employed in electrochemistry cells. Our simulations reveal that at room temperature AgI undergoes an adiabatic temperature shift of 38 K under a biaxial stress of 1 GPa. Likewise, Li_{3}OCl displays a cooling capacity of 9 K under similar mechanical conditions although at a considerably higher temperature. We also show that ionic vacancies have a detrimental effect on the cooling performance of superionic thin films. Our findings should motivate experimental mechanocaloric searches in a wide variety of already known superionic materials.
Introduction
Conventional cooling methods based on gascompression cycles present a series of critical drawbacks including the use of environmental hazards and lack of scalability to micro sizes. Solidstate cooling represents an elegant solution to all these issues, with mechanocaloric (MC) effects possibly holding the greatest promise in terms of energy efficiency^{1}. Superelastic shapememory alloys (SMA) displaying firstorder martensitic transformations between a highT martensitic and a lowT austenitic phase (e.g., NiTi, CuAlNi, and CuZnSn alloys), are archetypal MC compounds^{2}. For example, a giant adiabatic temperature shift of 25.5 K has been measured in NiTi wires upon a small tensile stress of 0.65 GPa^{3}. Nevertheless, there are still several hurdles that need to be overcome in order to develop successful MC commercial applications. For instance, the firstorder nature of the martensitic transformation involves concomitant hysteresis losses, which is detrimental for cooling efficiency^{4}, and as the size of SMA shrinks towards the nanoscale the martensitic phase transformation may be suppressed due to overstabilisation of the highT distorted phase^{5}. Finding novel MC materials with sharp secondorder phase transitions occurring near room temperature and which persist down to the nanoscale, therefore, may advance the field of solidstate cooling.
Ferroelectric compounds (FE) like, for instance, BaTiO_{3} ^{6}, PbTiO_{3} ^{7}, and Ba_{1−x }Ca_{ x }Ti_{1−y }Zr_{ y }O_{3} solid solutions^{8} (generally exploited in sensing, information storage and energy applications), can be synthesised as nanosized materials and typically exhibit displacive secondorder phase transitions^{9}. However, current adiabatic temperature shifts, \(\left {\Delta T} \right\), estimated in most FE materials near room temperature are about one order of magnitude smaller than those achieved in SMA (made the exception of the ferrielectric compound (NH_{4})_{2}SO_{4} ^{10}), and the involved mechanical stresses appear to be unsuitably too large (\(\left \sigma \right \gg 1\) GPa). Consequently, the MC strengths reported so far for FE are rather poor in general, namely, \(\left {\Delta T} \right\)/\(\left \sigma \right\) < 1 K·GPa^{−1} (again, made the exception of (NH_{4})_{2}SO_{4} ^{10}). Recently, a giant MC effect has been predicted in fluoritestructured fastion conductors (FIC), typified by CaF_{2} and PbF_{2}, which is comparable in magnitude to the benchmark adiabatic temperature shifts measured in SMA^{11}. The MC effect disclosed in FIC may be understood in terms of stressdriven changes in ionic diffusivity, which in turn cause large variations in the entropy and dimensions of the material^{11}. The originating superionic transition is of secondorder type, in analogy to archetypal FE, and fluoritestructured FIC also can be synthesised as nanomaterials^{12}. Unfortunately, the superionic transition temperatures in fluoritestructured FIC are far above ambient conditions (i.e., T _{ s } = 1350 in CaF_{2} and 700 K in PbF_{2} ^{11, 13}), thus hindering the development of likely solidstate cooling applications.
Here we demonstrate giant MC effects in other predominant families of FIC, namely Lirich (Li_{3}OCl) and typeI (AgI) compounds (following Hull’s notation^{14}), some of them at room temperature. We use atomistic computer simulations based on force fields and density functional theory to estimate the isothermal entropy and adiabatic temperature shifts attained in FIC with biaxial stresses (σ _{ xx } = σ _{ yy } and σ _{ zz } = 0). (Biaxial stresses, either compressive, σ > 0, or tensile, σ < 0, are realisable in thin films^{15}; dynamic biaxial stresses leading to epitaxial strain changes of the order of 0.1–1% have been demonstrated in thin films by using ferroelectric substrates^{16, 17}, and larger dynamic changes can be envisaged by means of mechanical extensometer techniques applied on flexible polymeric substrates^{18} and of nanoidentation methods^{19}.) In AgI thin films, we find a roomtemperature adiabatic temperature shift of \(\left {\Delta T} \right\) = 38 K for a moderate compressive load of \(\left \sigma \right\) = 1 GPa. This result exceeds the corresponding values estimated in FE at T = 300 K (~1 K^{6}) and equals in magnitude the MC records set in SMA (~10 K^{3, 20}). Our findings in Li_{3}OCl thin films, namely \(\left {\Delta T} \right\) = 9 K for \(\left \sigma \right\) = 1 GPa at T = 1000 K, suggest that analogous Lirich FIC with lower superionic transition temperatures (e.g., Li_{10}GeP_{2}S_{12} ^{21}) should display giant MC effects as well. Therefore, we argue that solidstate cooling could benefit immensely from the intensive research already undertaken on solidstate electrochemical batteries^{22}.
Results
Effects of vacancies on the mechanocaloric performance of thin films
Vacancies are known to enhance significantly ionic transport and lower the superionic critical temperature in FIC^{23, 24}. This is explicitly shown in Fig. 1a, where we plot the F^{−} diffusion coefficient, D (see Methods section), calculated for unstrained CaF_{2} (typeII FIC^{14}) in the absence and presence of ionic vacancies as a function of temperature (note that D increases by >80% in the system containing vacancies). In Fig. 1b, we compare the critical superionic temperature obtained in perfect and defective thin films as a function of biaxial stress; in the c _{v} = 2.5% case, T _{ s } is reduced by ~300 K almost independently of σ. This outcome can be rationalised in terms of a steady lowering of the energy barrier and creation energy of Frenkel pair defects (see Fig. 1a), which is due to an increase of the space available to interstitial ions. Therefore, intuitively one might expect that by introducing ionic vacancies the mechanocaloric performance of FIC should be enhanced. We have found, however, that this is not actually the case in archetypal FIC CaF_{2} (see Supplementary Figs. 1 and 2).
In Fig. 2a, b, we show the isothermal entropy and adiabatic temperature changes, ΔS and ΔT (see Methods section), calculated in typeII FIC thin films with an arbitrary F^{−} vacancy concentration of 2.5%. Large values of 30 JK^{−1} kg^{−1} and −30 K are obtained respectively at the highest temperature and tensile stress (T = 1100 K and \(\left \sigma \right\) = 4 GPa), conditions at which the defective system is fully superionic. Upon comparison of the ΔT values obtained in perfect and defective CaF_{2} thin films at a fixed temperature of 1100 K (see Fig. 2c), however, we realise that the presence of anion vacancies does not produce any significant enhancement in MC performance (it is worth noticing that at the imposed conditions the perfect system remains in the normal state). Actually, the same applied maximum stress leads to \(\left {\Delta T} \right\) values two times larger in thin films without vacancies for a slightly higher temperature at which the perfect system becomes superionic^{11}. The main cause for this outcome is that the presence of ionic vacancies makes the superionic transition to be less abrupt, by smoothing the concomitant lattice strain associated to the prompt increase of ionic diffusivity (see Supplementary Methods and Supplementary Fig. 5). An analogous effect is observed also on the anion diffusion coefficient, which in the c _{v} = 2.5% case displays a steady, rather than a sudden, increase near the superionic transition point (see Fig. 1a). Therefore, we may conclude that despite ionic vacancies in general favor ionic conductivity their effects on the MC performance of FIC may be adverse.
Mechanocaloric effect in Lirich superionic thin films
We choose Li_{3}OCl as a representative member of the family of Lirich FIC^{25}. This compound adopts an antiperovskite phase characterised by Li, Cl, and O atoms placed at the octahedral vertices, octahedral centers, and center of a cubic unit cell, respectively (space group \(Fm\overline 3 m\), see Supplementary Figs. 1 and 3). We note that Li_{3}OCl has already been synthesised and characterised in thinfilm geometry^{26, 27}. The fundamental ionmigration mechanism in this material is related to the presence of vacancies: in the absence of points defects the diffusivity of Li^{+} ions is null below the corresponding melting point^{23, 24}. Meanwhile, the accompanying superionic temperature, T _{ s }, strongly depends on the concentration of ionic vacancies (see Supplementary Discussion and Supplementary Fig. 6). Here we analyse the c _{v} = 2.5% case, which according to our molecular dynamics simulations (see Methods section) renders a transition temperature of T _{ s } = 1000 K at σ = 0 conditions. In what follows, we focus on tensile stresses (σ < 0) as in Li_{3}OCl these favor ionic conductivity the most.
In Fig. 3a, b, we show the Li^{+} diffusion coefficient and inplane strain, \(\epsilon \) (see Methods section), calculated in Li_{3}OCl as a function of negative biaxial stress at a fixed temperature of 1000 K. Both quantities increase under applied tensile stress, and in the case of \(\epsilon \) the stressinduced enhancement is almost linear. As the ionic diffusivity in the thin film increases so does the isothermal entropy change (Fig. 3c), yielding a value of ΔS = 16 J·K^{−1} kg^{−1} at the maximum tensile stress σ _{max } = −1 GPa. The accompanying adiabatic temperature change is \(\left {\Delta T} \right\) = 9 K (Fig. 3d), which is about two times larger than the one calculated in CaF_{2} thin films considering identical (σ, T) conditions and vacancy concentration (see Fig. 2b). The main reason behind this difference is the larger isothermal entropy change found in Li_{3}OCl, which fundamentally is related to the way in which ions hop through favorable pathways within the corresponding structural frameworks.
The largest contribution to the entropy of the superionic transformation can be assumed to be due to the configurational degrees of freedom^{28}. Consequently, it is reasonable to expect finding comparable isothermal entropy changes to those attributed to Li_{3}OCl in other related Lirich FIC with transition temperatures close to ambient (e.g., Li_{10}GeP_{2}S_{12} ^{21}). Actually, larger \(\left {\Delta T} \right\) values may be anticipated in those cases as the cooling efficiency of crystals is enhanced at low temperatures (i.e., the corresponding heat capacity, C _{ σ }, is small and depends on temperature as ∝ T ^{3}, see Methods section).
Mechanocaloric effect in typeI superionic thin films
We select AgI as a representative member of the family of typeI FIC. At ambient conditions bulk AgI is found as a mixture of wurtzite (β, hexagonal P6_{3} mc) and zincblende (γ, cubic \(F\overline 4 3m\)) phases^{14}. As temperature is increased beyond T _{ s } ~ 400 K, bulk AgI transforms into a superionic phase (α) in which the I^{−} anions arrange in a cubic bcc lattice and the Ag^{+} cations are mobile. In practice, AgI thin films can be synthesised either in the β or γ phase depending on the employed preparation method^{29, 30}. For reasons that will become clear later on, we investigate here the cubic γ phase consisting of two interlaced monoatomic fcc sublattices with fourfold ionic coordination (see Supplementary Figs. 1 and 4). Our following analysis is restricted to compressive stresses (σ > 0) as we find the largest MC effect at such conditions.
In Figs. 4a and 5a, we show the Ag^{+} diffusion coefficient calculated in nondefective AgI thin films as a function of compressive biaxial stress at T = 300 and 400 K, respectively. It is appreciated that only at the highest analysed temperature and for stresses larger than 0.8 GPa the system becomes fully superionic (i.e., \(D \gg 0\)). Nevertheless, the isothermal entropy and adiabatic temperature changes estimated for the maximum stress σ _{max} = 1 GPa are giant in both cases (see panels c, d in Figs. 4 and 5). In particular, we obtain ΔS = 30 J·K^{−1} kg^{−1} and ΔT = 38 K at T = 300 K, and 35 J·K^{−1} kg^{−1} and 51 K at T = 400 K. We note that the inplane strains calculated in both cases are also considerably large; as compared to Li_{3}OCl thin films, for instance, those are about four times larger in absolute value (see Figs. 3b–5b). As T is increased beyond room temperature, the calculated entropy and temperature shifts become larger essentially due to the enhanced mobility of Ag^{+} cations (see Fig. 5a).
At room temperature, the MC performance of AgI thin films commences to be appreciable and to increase steadily for stresses larger than σ _{ c } = 0.2 GPa (see Fig. 4c, d). This finding signals the triggering of a structural phase transformation at around σ _{ c } different from the superionic transition, which occurs at higher temperatures. The continuous variation of the inplane strain and cation diffusion coefficient as driven by compressive stress indicate that this phase transition is of secondorder type. To get microscopic insight into such a structural transformation, we analyse the coordination number, radial pair distribution function, mean squared displacement, and density distribution of I^{−} and Ag^{+} ions under different temperature and stress conditions (see Methods section and Supplementary Figs. 7–9).
Our simulation results reveal the existence of a σinduced diffusionless orderdisorder phase transition involving sizeable displacements of the ionic equilibrium positions with respect to the original zincblende structure. Specifically, both II and AgAg coordination numbers amount to 12 in average similarly to what is found in the two monoatomic fcc lattices of reference. However, a precise determination of neighbouring atomic shells from the corresponding radial pair distribution functions, g(r), is not possible for distances larger than few angstroms at biaxial stresses higher than σ _{ c } (see Fig. 6). Furthermore, at room temperature and σ _{ c } < σ conditions the asymptotic behavior of the ionic pair distribution functions, namely, g(r) ≈ 1, is reached very rapidly with the radial distance (r ~ 10 Å, see Fig. 6a, b); this outcome evidences lack of solid translational invariance, in analogy to what is observed in glassy systems. We assuredly identify these features, and others shown in the Supplementary Figs. 7–9 (e.g., ionic mean squared displacement and density distribution plots), with the presence of atomic disorder in the I^{−} and Ag^{+} sublattices at σ _{ c } < σ conditions. It is worth noticing that, as we have explicitly checked, neither the hexagonal wurtzite nor the cubic rocksalt structures found in bulk AgI at ambient and highpressure conditions^{14} transform to a disordered phase when applying biaxial compressive stresses of ~1 GPa to them at room temperature (see Supplementary Fig. 10).
Discussion
The giant roomtemperature MC effect revealed in AgI thin films, which is originated by a σinduced diffusionless orderdisorder phase transition, appears to be very promising in terms of maximum adiabatic temperature shift and mechanocaloric strength, \(\left {\Delta T} \right\)/\(\left \sigma \right\). In Table 1, we compare the cooling properties of this FIC with those of other wellestablished MC compounds that have been reported at ambient and near ambient conditions. First, we note that the adiabatic temperature shift estimated in AgI (\(\left {\Delta T} \right\) = 38 K) is equivalent in magnitude to the MC benchmarks obtained in archetypal shapememory alloys like, for instance, NiTi (e.g., \(\left {\Delta T} \right\) = 25.5 K^{3}). As compared to ferroelectric materials, the estimated ΔT is several times larger in absolute value. In terms of mechanocaloric strength, AgI also shows great promise as it follows closely to shapememory alloys (\(\left {\Delta T} \right{\rm{/}}\left \sigma \right\sim 10\) K GPa^{−1} ^{20}) and outperforms perovskite oxide materials (e.g., BaTiO_{3} with \(\left {\Delta T} \right{\rm{/}}\left \sigma \right\sim 1\) K GPa^{−1} ^{6}).
Our findings should stimulate the development of new cooling devices based on FIC whose energy efficiency as compared to magnetocaloric and electrocaloric materials is very auspicious. In contrast to other mechanocaloric materials driven by firstorder transitions, mechanical hysteresis losses and scalability limitations towards nanosizes should be absent in FIC. Mechanical stresses other than biaxial (i.e., uniaxial and hydrostatic) also can be expected to produce similar mechanocaloric responses than reported here in FIC^{11}. In this context, the rich variety of superionic materials that have been already investigated with a focus on electrochemical applications grants solidstate cooling with vast new possibilities.
Methods
Classical molecular dynamics simulations
Molecular dynamics (N, P, T) simulations are performed with the LAMMPS code^{31}. The pressure and temperature in the system are kept fluctuating around a setpoint value by using thermostatting and barostatting techniques in which some dynamic variables are coupled to the particle velocities and simulation box dimensions. The interactions between atoms are modeled with rigidion BornMayerHuggins potentials. Large simulation boxes, typically containing 6,144 atoms, are used in which periodic boundary conditions along the three Cartesian directions are applied. Newton’s equations of motion are integrated using the customary Verlet’s algorithm with a timestep length of 10^{−3} ps. A particleparticle particlemesh kspace solver is used to compute longrange van der Waals and Coulomb interactions and forces beyond a cutoff distance of 12 Å at each time step.
We note that by using periodic boundary conditions in our calculations we avoid to explicitly simulate the substrate over which the thin film is grown in practice. Also, possible elastic relaxation effects and the interactions of the thin film with the vacuum at the top surface are totally neglected. Consequently, the simulations are performed very efficiently in terms of computational expense and the fundamental mechanocaloric effects occurring in FIC thin films can be singled out. Further details of our classical molecular dynamics simulations (e.g., interatomic potential models) can be found in the Supplementary Methods and Supplementary Tables 1 and 2.
Density functional theory calculations
Firstprinciples DFT calculations are performed to analyse the energy and structural properties of CaF_{2}, Li_{3}OCl, and AgI thin films at zero temperature (see Supplementary Figs. 2–4). We perform these calculations with the VASP code^{32} by following the generalized gradient approximation to the exchangecorrelation energy due to Perdew et al.^{33}. The projector augmentedwave method is used to represent the ionic cores^{34}, and the electronic states 2s3s3p4s of Ca, 2s2p of F, 1s2s of Li, 2s2p of O, 2s2p of Cl, 4d5s of Ag, and 5s5p of I, are considered as valence. Wave functions are represented in a planewave basis truncated at 650 eV. By using these parameters and dense kpoint grids for Brillouin zone integration, the resulting energies are converged to within 1 meV per formula unit. In the geometry relaxations, a tolerance of 0.01 eV·Å^{−1} is imposed in the atomic forces. We also perform ab initio molecular dynamics calculations in order to validate the reliability of the interatomic potential models employed in the classical molecular dynamics simulations. Details of these calculations can be found in the Supplementary Discussion.
Estimation of key quantities
The ionic diffusion coefficients are determined as:
where R _{ i }(t) is the position of the migrating ion labelled as i at time t, t _{0} an arbitrary time origin, and \(\left\langle \cdots \right\rangle \) denotes average over time and particles. Meanwhile, the mean squared displacement of each ionic species is defined as \(\left\langle {\Delta R_i^2(t)} \right\rangle \equiv \left\langle {{{\left {{R_i}\left( {t + {t_0}} \right)  {R_i}\left( {{t_0}} \right)} \right}^2}} \right\rangle \).
Owing to the cubic symmetry of the thin films considered in this study, strains \(\epsilon \) _{ xx } and \(\epsilon \) _{ yy } and stresses σ _{ xx } and σ _{ yy } are identical. Consequently, the accompanying isothermal entropy changes can be estimated with the formula:
where V _{0}(T) ≡ L _{ x,0}(T) · L _{ y,0}(T) · L _{ z,0}(T) is the Tdependent volume of the crystal at equilibrium (i.e., considering σ = 0 conditions), L _{ i } represents the length of the simulation box along the i Cartesian direction, and the mechanical strain components are defined as \({\epsilon _{ii}}(\sigma ,T) \equiv \frac{{{L_i}\left( {\sigma ,T} \right)  {L_{i,0}}(T)}}{{{L_{i,0}}(T)}}\). Regarding the adiabatic temperature shifts, those are calculated as:
where C _{ σ }(σ, T) is the heat capacity of the crystal calculated at fixed σ. In this study we assumed that C _{ σ }(σ, T) ≈ C _{ σ }(0, T). Further technical details on our calculations can be found in the Supplementary Methods.
Data availability
The data that support the findings of this study are available from the corresponding author (C.C.) upon reasonable request.
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Acknowledgements
This research was supported under the Australian Research Council’s Future Fellowship funding scheme (No. FT140100135). Computational resources and technical assistance were provided by the Australian Government and the Government of Western Australia through Magnus under the National Computational Merit Allocation Scheme and The Pawsey Supercomputing Centre. D.E. acknowledges financial support from Spanish government MINECO, the Spanish Agencia Estatal de Investigacion (AEI), and Fondo Europeo de Desarrollo Regional (FEDER) under Grants No. MAT201675586C41P and MAT201571070REDC.
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Affiliations
School of Materials Science and Engineering, UNSW Australia, Sydney, NSW, 2052, Australia
 Arun K. Sagotra
 & Claudio Cazorla
Integrated Materials Design Centre, UNSW Australia, Sydney, NSW, 2052, Australia
 Arun K. Sagotra
 & Claudio Cazorla
Departamento de Física Aplicada (ICMUV), Malta Consolider Team, Universitat de Valencia, 46100, Burjassot, Spain
 Daniel Errandonea
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Contributions
C.C. conceived the study and planned the research. C.C. and A.K.S. performed the theoretical calculations. Results were discussed by C.C., A.K.S. and D.E. The manuscript was written by C.C. and A.K.S. with substantial input from D.E.
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The authors declare no competing financial interests.
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Correspondence to Claudio Cazorla.
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Further reading

1.
Roomtemperature mechanocaloric effects in lithiumbased superionic materials
Nature Communications (2018)

2.
Giant barocaloric effects over a wide temperature range in superionic conductor AgI
Nature Communications (2017)
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