Abstract
New bis-acetylenic monomers; succin(m-ethynyl)dianilide and sebaco(m-ethynyl)dianilide were synthesized and polymerized by oxidative polycoupling to give high molecular weight semicrystalline polymers. These polymers were found to be highly light sensitive and turned blue on UV-irradiation to give transparent blue films with absorption maximum beyond 600 nm. The polymers were found to be rather stable on heating and thermal cross-linking via diacetylene groups took place only above 170°C.
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D. C. Chemla and J. Zyss, Ed., “Nonlinear Optical Properties of Organic Molecules and Crystals,” Academic Press, Inc., New York, N.Y., 1987.
H. Nakanishi, H. Matsuda, S. Okada, and M. Kato, Polym. Advanced Technol., 1, 75 (1990).
G. Burillo and T. Ogawa, Polym. Bull., 16, 257 (1986).
G. Wegner, Makromol. Chem., 134, 219 (1970).
S. Kuhling, H. Keul, and H. Hocker, Macromolecules, 23, 4192 (1990).
R.-C. Liang and A. Reiser, J. Polym. Sci., A, 25, 451 (1987).
M. F. Rubner, Macromolecules, 19, 2129 (1986).
E. Kwock, Teaster Baird, Jr., and T. Miller, Macromolecules, 26, 2935 (1993).
J. Perez, G. Burillo, M. Roa, C. Vazqez, and T. Ogawa, Polym. Bull., 27, 527 (1992).
M. Estrada, G. Burillo, and T. Ogawa, Polym. Andanced Technol., 3, 419 (1992).
R. Neyra, C. Chavarin, and T. Ogawa, Abstracts, “Memorias de Division de Polimeros,” 28th Congreso Mexicana de Quimica Puro y Aplicada, Nov. 1992, Puerto Vallanta, (Issued by Grupo de Polímeros, ICN-UNAM, Mexico, DF. 1992), p 60.
W. Austin, N. Bilow, W. Kelleghan, and K. S. Y. Lau, Org. Chem., 46, 2280 (1981).
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Fomine, S., Ogawa, T. Diacetylene-Containing Polymers III. Poly(m,m′-butadiynylenesuccindianilide) and Poly(m,m′-butadiynylene sebacodianilide): Novel Materials for Preparation of Transparent Polydiacetylene Containing Films. Polym J 26, 93–97 (1994). https://doi.org/10.1295/polymj.26.93
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DOI: https://doi.org/10.1295/polymj.26.93
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