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Electrostatic self-assembly of macroscopic crystals using contact electrification

Nature Materials volume 2, pages 241–245 (2003)Cite this article

Abstract

Self-assembly1,2,3,4 of components larger than molecules into ordered arrays is an efficient way of preparing microstructured materials with interesting mechanical5,6 and optical7,8 properties. Although crystallization of identical particles9,10 or particles of different sizes11 or shapes12 can be readily achieved, the repertoire of methods to assemble binary lattices of particles of the same sizes but with different properties is very limited13,14. This paper describes electrostatic self-assembly15,16,17 of two types of macroscopic components of identical dimensions using interactions that are generated by contact electrification18,19,20. The systems we have examined comprise two kinds of objects (usually spheres) made of different polymeric materials that charge with opposite electrical polarities when agitated on flat, metallic surfaces. The interplay of repulsive interactions between like-charged objects and attractive interactions between unlike-charged ones results in the self-assembly of these objects into highly ordered, closed arrays. Remarkably, some of the assemblies that form are not electroneutral—that is, they possess a net charge. We suggest that the stability of these unusual structures can be explained by accounting for the interactions between electric dipoles that the particles in the aggregates induce in their neighbours.

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Figure 1: Electrostatic self-assembly (ESA) of polymeric spheres.
Figure 2: ESA of different numbers of Teflon and Nylon-6,6 spheres.
Figure 3: Pattern switching in an ensemble of 40 Teflon and 80 PP spheres agitated at ω = 9 Hz and A = 10 mm.
Figure 4: ESA of non-spherical, millimetre-sized objects assembled in a rotating glass cylinder of diameter ∼4 cm.

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References

  1. Philp, D. & Stoddart, J.F. Self-assembly in natural and unnatural systems. Angew. Chem. Int. Edn Engl. 35, 1155–1196 (1996).

    CAS  Google Scholar 

  2. Whitesides, G.M. & Grzybowski, B.A. Self-assembly at all scales. Science 295, 2418–2421 (2002).

    Article  CAS  Google Scholar 

  3. Fendler, J.H. Chemical self-assembly for electronic applications. Chem. Mater. 13, 3196–3210 (2001).

    Article  CAS  Google Scholar 

  4. Grzybowski, B.A., Stone, H.A. & Whitesides, G.M. Dynamic self-assembly of magnetized, millimetre-sized objects rotating at a liquid-air interface. Nature 405, 1033–1036 (2000).

    Article  CAS  Google Scholar 

  5. Ito, K., Sumaru, K. & Ise, N. Elastic properties of colloidal crystals. Phys. Rev. B 46, 3105–3107 (1992).

    Article  CAS  Google Scholar 

  6. Schope, H.J., Decker, T. & Palberg, T. Response of the elastic properties of colloidal crystals to phase transitions and morphological changes. J. Chem. Phys. 109, 10068–10074 (1998).

    Article  CAS  Google Scholar 

  7. Joannopoulos, J.D., Meade, R.D. & Winn, J.N. Photonic Crystals (Princeton Univ. Press, Princeton, New Jersey, 1995).

    Google Scholar 

  8. Reese, C.E., Baltusavich, M.E., Keim, J.P. & Asher, S.A. Development of an intelligent polymerized crystalline colloidal array colorimetric reagent. Anal. Chem. 73, 5038–5042 (2001).

    Article  CAS  Google Scholar 

  9. Xia, Y., Gates, B., Yin, Y.D. & Lu, Y. Monodispersed colloidal spheres: Old materials with new applications. Adv. Mater. 12, 693–713 (2000).

    Article  CAS  Google Scholar 

  10. Van Blaaderen, A., Ruel, R. & Wiltzius, P. Template-directed colloidal crystallization. Nature 385, 321–324 (1997).

    Article  CAS  Google Scholar 

  11. Kiely, C.J., Fink, J., Burst, M., Bethell, D. & Schiffrin, D.J. Spontaneous ordering of bimodal ensembles of nanoscopic gold clusters. Nature 396, 444–446 (1998).

    Article  CAS  Google Scholar 

  12. Adams, M., Dogic, Z., Keller, S.L. & Fraden, S. Entropically driven microphase transitions in mixtures of colloidal rods and spheres. Nature 393, 349–352 (1998).

    Article  CAS  Google Scholar 

  13. Bowden, N., Choi, I.S., Grzybowski, B.A. & Whitesides, G.M. Mesoscale self-assembly of hexagonal plates using lateral capillary forces: synthesis using the “capillary bond”. J. Am. Chem. Soc. 121, 5373–5391 (1999).

    Article  CAS  Google Scholar 

  14. Grzybowski, B.A., Bowden, N., Arias, F., Yang, H. & Whitesides, G.M. Modeling of menisci and capillary forces from millimeter to the micrometer size range. J. Phys. Chem. B 105, 404–412 (2001).

    Article  CAS  Google Scholar 

  15. Kumar, A. et al. Linear superclusters of colloidal gold particles by electrostatic assembly on DNA templates. Adv. Mater. 13, 341–344 (2001).

    Article  CAS  Google Scholar 

  16. Tien, J., Terfort, A. & Whitesides, G.M. Microfabrication through electrostatic self-assembly. Langmuir 13, 5349–5355 (1997).

    Article  CAS  Google Scholar 

  17. Caruso, F., Lichtenfeld, H., Giersig, M. & Mohwald, H. Electrostatic self-assembly of silica nanoparticle - Polyelectrolyte multilayers on polystyrene latex particles. A. J. Am. Chem. Soc. 120, 8523–8524 (1998).

    Article  CAS  Google Scholar 

  18. Horn, R.G., Smith, D.T. & Grabbe, A. Contact electrification of a surface and relation to acid-base interactions. Nature 366, 442–443 (1993).

    Article  CAS  Google Scholar 

  19. Horn, R.G. & Smith, D.T. Contact electrification and adhesion between dissimilar materials. Science 256, 362–364 (1992).

    Article  CAS  Google Scholar 

  20. Lowell, J. & Rose-Innes, A.C. Contact electrification. Adv. Phys. 29, 947–1023 (1980).

    Article  CAS  Google Scholar 

  21. Kirkpatrick, S., Gelatt, C.D. & Vecchi, M.P. Optimization by simulated annealing. Science 220, 671–680 (1983).

    Article  CAS  Google Scholar 

  22. Neirotti, J.P., Calvo, F., Freeman, D.L. & Doll, J.D. Phase changes in a 38-atom Lennard-Jones clusters. I. A parallel tempering study in the canonical ensemble. J. Chem. Phys. 112, 10340–10349 (2000).

    Article  CAS  Google Scholar 

  23. Jackson, J.D. Classical Electrodynamics 2nd edn 135–155 (Wiley, New York, 1975).

    Google Scholar 

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Acknowledgements

This work was supported by the Department of Energy (award 00ER45852). J.A.W. was supported by the Natural Sciences and Engineering Research Council of Canada. A.W. was supported by the Biophysics Training Grant. Y.B. was supported by the National Science Foundation. The authors would like to thank A. Epstein (The Ohio State University) for useful discussions.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, 02138, Massachusetts, USA

    Bartosz A. Grzybowski, Adam Winkleman, Jason A. Wiles, Yisroel Brumer & George M. Whitesides

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  1. Bartosz A. Grzybowski
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Correspondence to Bartosz A. Grzybowski or George M. Whitesides.

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Electrostatic Self-Assembly of Macroscopic Crystals Using Contact Electrification. (Supporting Information) (PDF 295 kb)

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Grzybowski, B., Winkleman, A., Wiles, J. et al. Electrostatic self-assembly of macroscopic crystals using contact electrification. Nature Mater 2, 241–245 (2003). https://doi.org/10.1038/nmat860

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