Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Crystalline ice

Amorphous on the surface

Crystalline ice surfaces are found to exhibit an unusually large spread of vacancy formation energies, akin to an amorphous material. The finding has implications for the fundamental understanding of electrostatically frustrated surfaces and for the reactivity and catalytic properties of atmospheric ice.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Molecular representation of the crystalline surface of hexagonal ice, with a water molecule hovering above a vacancy defect.
Figure 2: Variation in vacancy formation energies of water molecules in the six bilayers closest to the surface of hexagonal ice1.

References

  1. Watkins, M. et al. Nature Mater. 10, 794–798 (2011).

    Article  CAS  Google Scholar 

  2. Petrenko, V. F. & Whitworth R. W. Physics of Ice (Oxford Univ. Press, 1999).

    Google Scholar 

  3. McDonald, S., Ojamäe, L. & Singer, S. J. J. Phys. Chem. A 102, 2824–2832 (1998).

    Article  CAS  Google Scholar 

  4. Buch, V., Groenzin, H., Li, I., Schultz, M. J. & Tosatti, E. Proc. Natl Acad. Sci. USA 105, 5969–5974 (2008).

    Article  CAS  Google Scholar 

  5. Molina, M. J., Tso, T-L., Molina, L. T. & Wang, F. C-Y. Science 238, 1253–1257 (1987).

    Article  CAS  Google Scholar 

  6. Ball, P. Life's Matrix: A Biography of Water (Univ. California Press, 2001).

    Google Scholar 

  7. Davy, J. G. & Somorjai, G. A. J. Chem. Phys. 35, 3624–3636 (1971).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lars Ojamäe.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ojamäe, L. Amorphous on the surface. Nature Mater 10, 725–726 (2011). https://doi.org/10.1038/nmat3129

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nmat3129

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing