Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Glass and mineral corrosion

Dynamics and durability

The durability of glasses and minerals in water has traditionally been predicted using models that ignore the molecular details. Now the surface structure dynamics are shown to play an integral role in their aqueous corrosion.

This is a preview of subscription content, access via your institution

Relevant articles

Open Access articles citing this article.

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Solute fluxes from the dissolution of two forms of CaSiO3 in acidic solutions3.
Figure 2: Schematic of silicate glass aqueous dissolution.

References

  1. Casey, W. H. & Bunker, B. Mineral–Water Interface Geochemistry (eds Hochella, M. F. & White, A. F.) Ch. 10, 397–424 (Reviews in Mineralogy 23, Mineralogical Society of America, 1990).

    Book  Google Scholar 

  2. Cailleteau, C. et al. Nature Mater. 7, 978–983 (2008).

    Article  CAS  Google Scholar 

  3. Casey, W. H., Westrich, H. R., Banfield, J. R., Ferruzzi, G. & Arnold, G. W. Nature 366, 253–256 (1993).

    Article  CAS  Google Scholar 

  4. Bunker, B. C., Tallant, D. R., Headley, T. J., Turner, G. L. & Kirkpatrick, R. J. Phys. Chem. Glass. 29, 105–120 (1988).

    Google Scholar 

  5. Casey, W. H., Westrich, H. R., Arnold, G. W. & Banfield, J. F. Geochim. Cosmochim. Acta 53, 821–832 (1989).

    Article  CAS  Google Scholar 

  6. Boudart, M. J. Phys. Chem. 80, 2869–2870 (1976).

    Article  CAS  Google Scholar 

  7. Temkin, M. I. Int. Chem. Eng. 11, 709–717 (1971).

    Google Scholar 

  8. Casey, W. H. & Rustad, J. R. Annu. Rev. Earth Sci. 35, 21–46 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Casey, W. Dynamics and durability. Nature Mater 7, 930–932 (2008). https://doi.org/10.1038/nmat2326

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/nmat2326

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing