Abstract
NASA’s MESSENGER spacecraft has revealed geochemical diversity across Mercury’s volcanic crust. Near-infrared to ultraviolet spectra and images have provided evidence for the Fe2+-poor nature of silicate minerals, magnesium sulfide minerals in hollows and a darkening component attributed to graphite, but existing spectral data is insufficient to build a mineralogical map for the planet. Here we investigate the mineralogical variability of silicates in Mercury’s crust using crystallization experiments on magmas with compositions and under reducing conditions expected for Mercury. We find a common crystallization sequence consisting of olivine, plagioclase, pyroxenes and tridymite for all magmas tested. Depending on the cooling rate, we suggest that lavas on Mercury are either fully crystallized or made of a glassy matrix with phenocrysts. Combining the experimental results with geochemical mapping, we can identify several mineralogical provinces: the Northern Volcanic Plains and Smooth Plains, dominated by plagioclase, the High-Mg province, strongly dominated by forsterite, and the Intermediate Plains, comprised of forsterite, plagioclase and enstatite. This implies a temporal evolution of the mineralogy from the oldest lavas, dominated by mafic minerals, to the youngest lavas, dominated by plagioclase, consistent with progressive shallowing and decreasing degree of mantle melting over time.
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References
Binzel, R. P. & Xu, S. Chips off of asteroid 4 Vesta: evidence for the parent body of basaltic achondrite meteorites. Science 260, 186–191 (1993).
Mustard, J. et al. Olivine and pyroxene diversity in the crust of Mars. Science 307, 1594–1597 (2005).
Papike, J., Karner, J., Shearer, C. & Burger, P. Silicate mineralogy of martian meteorites. Geochim. Cosmochim. Acta 73, 7443–7485 (2009).
Smith, J. V. et al. Petrologic history of the Moon inferred from petrography, mineralogy and petrogenesis of Apollo 11 rocks. in Proc. Apollo 11 Lunar Sci. Conf. Vol. 1 (ed. Levinson, A. A.) 897–925 (Pergamon Press, 1970).
Ohtake, M. et al. The global distribution of pure anorthosite on the Moon. Nature 461, 236–240 (2009).
Bibring, J. P. et al. Global mineralogical and aqueous Mars history derived from OMEGA/Mars Express data. Science 312, 400–404 (2006).
Strom, R. G., Trask, N. J. & Guest, J. E. Tectonism and volcanism on Mercury. J. Geophys. Res. 80, 2478–2507 (1975).
Fassett, C. I., Kadish, S. J., Head, J. W., Solomon, S. C. & Strom, R. G. The global population of large craters on Mercury and comparison with the Moon. Geophys. Res. Lett. 38, L10202 (2011).
Denevi, B. W. et al. The evolution of Mercury’s crust: a global perspective from MESSENGER. Science 324, 613–618 (2009).
Head, J. W. et al. Volcanism on Mercury: evidence from the first MESSENGER flyby for extrusive and explosive activity and the volcanic origin of plains. Earth Planet. Sci. Lett. 285, 227–242 (2009).
Head, J. W. et al. Flood volcanism in the northern high latitudes of Mercury revealed by MESSENGER. Science 333, 1853–1856 (2011).
Marchi, S. et al. Global resurfacing of Mercury 4.0–4.1 billion years ago by heavy bombardment and volcanism. Nature 499, 59–61 (2013).
Charlier, B., Grove, T. L. & Zuber, M. T. Phase equilibria of ultramafic compositions on Mercury and the origin of the compositional dichotomy. Earth Planet. Sci. Lett. 363, 50–60 (2013).
Namur, O. et al. Melting processes and mantle sources of lavas on Mercury. Earth Planet. Sci. Lett. 439, 117–128 (2016).
Murchie, S. L. et al. Orbital multispectral mapping of Mercury with the MESSENGER Mercury Dual Imaging System: evidence for the origins of plains units and low-reflectance material. Icarus 254, 287–305 (2015).
Peplowski, P. N. et al. Remote sensing evidence for an ancient carbon-bearing crust on Mercury. Nat. Geosci. 9, 273–276 (2016).
Vilas, F. et al. Mineralogical indicators of Mercury’s hollows composition in MESSENGER color observations. Geophys. Res. Lett. 43, 1450–1456 (2016).
Neumann, G. A. et al. Bright and dark polar deposits on Mercury: evidence for surface volatiles. Science 339, 296–300 (2013).
Izenberg, N. R. et al. The low-iron, reduced surface of Mercury as seen in spectral reflectance by MESSENGER. Icarus 228, 364–374 (2014).
Nittler, L. R. et al. The major-element composition of Mercury’s surface from MESSENGER X-ray spectrometry. Science 333, 1847–1850 (2011).
Weider, S. Z. et al. Evidence for geochemical terranes on Mercury: global mapping of major elements with MESSENGER’s X-Ray Spectrometer. Earth Planet. Sci. Lett. 416, 109–120 (2015).
Peplowski, P. N. et al. Enhanced sodium abundance in Mercury’s north polar region revealed by the MESSENGER Gamma-ray spectrometer. Icarus 228, 86–95 (2014).
Peplowski, P. N. et al. Geochemical terranes of Mercury’s northern hemisphere as revealed by MESSENGER neutron measurements. Icarus 253, 346–363 (2015).
Nittler, L. R. et al. Global major-element maps of Mercury updated from four years of MESSENGER X-Ray observations. Proc. Lunar Planet. Sci. Conf. Vol. XLVII, 1237 (2016).
Namur, O., Charlier, B., Holtz, F., Cartier, C. & McCammon, C. Sulfur solubility in reduced mafic silicate melts: implications for the speciation and distribution of sulfur on Mercury. Earth Planet. Sci. Lett. 448, 102–114 (2016).
Vander Kaaden, K. E. & McCubbin, F. M. The origin of boninites on Mercury: an experimental study of the northern volcanic plains lavas. Geochim. Cosmochim. Acta 173, 246–263 (2016).
McCoy, T. J., Dickinson, T. L. & Lofgren, G. E. Partial melting of the Indarch (EH4) meteorite: a textural, chemical, and phase relations view of melting and melt migration. Meteorol. Planet. Sci. 34, 735–746 (1999).
Kerber, L. et al. Explosive volcanic eruptions on Mercury: eruption conditions, magma volatile content, and implications for interior volatile abundances. Earth Planet. Sci. Lett. 285, 263–271 (2009).
Goudge, T. A. et al. Global inventory and characterization of pyroclastic deposits on Mercury: new insights into pyroclastic activity from MESSENGER orbital data. J. Geophys. Res. 119, 635–658 (2014).
Thomas, R. J., Rothery, D. A., Conway, S. J. & Anand, M. Long-lived explosive volcanism on Mercury. Geophys. Res. Lett. 41, 6084–6092 (2014).
Byrne, P. K. et al. An assemblage of lava flow features on Mercury. J. Geophys. Res. 118, 1303–1322 (2013).
Hurwitz, D. M. et al. Investigating the origin of candidate lava channels on Mercury with MESSENGER data: theory and observations. J. Geophys. Res. 118, 471–486 (2013).
Sehlke, A. & Whittington, A. G. Rheology of lava flows on Mercury: an analog experimental study. J. Geophys. Res. 120, 1924–1955 (2015).
Vasavada, A. R., Paige, D. A. & Wood, S. E. Near-surface temperatures on Mercury and the Moon and the stability of polar ice deposits. Icarus 141, 179–193 (1999).
Grove, T. L. & Krawczynski, M. J. Lunar mare volcanism: where did the magmas come from? Elements 5, 29–34 (2009).
Walker, D., Kirkpatrick, R., Longhi, J. & Hays, J. Crystallization history of lunar picritic basalt sample 12002: phase-equilibria and cooling-rate studies. Geol. Soc. Am. Bull. 87, 646–656 (1976).
Chevrel, M. et al. Lava flow rheology: a comparison of morphological and petrological methods. Earth Planet. Sci. Lett. 384, 109–120 (2013).
Gregg, T. K. P. & Fink, J. H. Quantification of extraterrestrial lava flow effusion rates through laboratory simulation. J. Geophys. Res. 101, 16891–16900 (1996).
Philpotts, A. R. & Dickson, L. D. The formation of plagioclase chains during convective transfer in basaltic magma. Nature 406, 59–61 (2000).
Namur, O., Charlier, B., Toplis, M. J. & Vander Auwera, J. Prediction of plagioclase-melt equilibria in anhydrous silicate melts at 1-atm. Contrib. Mineral. Petrol. 163, 133–150 (2012).
Padovan, S., Wieczorek, M. A., Margot, J.-L., Tosi, N. & Solomon, S. C. Thickness of the crust of Mercury from geoid-to-topography ratios. Geophys. Res. Lett. 42, 1029–1038 (2015).
James, P. B., Zuber, M. T., Phillips, R. J. & Solomon, S. C. Support of long-wavelength topography on Mercury inferred from MESSENGER measurements of gravity and topography. J. Geophys. Res. 120, 287–310 (2015).
Pieters, C. M., Tompkins, S., Head, J. & Hess, P. Mineralogy of the mafic anomaly in the South Pole-Aitken Basin: implications for excavation of the lunar mantle. Geophys. Res. Lett. 24, 1903–1906 (1997).
Byrne, P. K. et al. Widespread effusive volcanism on Mercury likely ended by about 3.5 Ga. Geophys. Res. Lett. 43, 7408–7416 (2016).
Denevi, B. W. et al. The distribution and origin of smooth plains on Mercury. J. Geophys. Res. 118, 891–907 (2013).
Holzheid, A., Palme, H. & Chakraborty, S. The activities of NiO, CoO and FeO in silicate melts. Chem. Geol. 139, 21–38 (1997).
O’Neill, H. S. & Mavrogenes, J. A. The sulfide capacity and the sulfur content at sulfide saturation of silicate melts at 1400 °C and 1 bar. J. Petrol. 43, 1049–1087 (2002).
Ma, Z. Thermodynamic description for concentrated metallic solutions using interaction parameters. Metall. Mater. Trans. B 32, 87–103 (2001).
Wade, J. & Wood, B. J. Core formation and the oxidation state of the Earth. Earth Planet. Sci. Lett. 236, 78–95 (2005).
Corgne, A., Keshav, S., Wood, B. J., McDonough, W. F. & Fei, Y. Metal-silicate partitioning and constraints on core composition and oxygen fugacity during Earth accretion. Geochim. Cosmochim. Acta 72, 574–589 (2008).
Bouchard, D. & Bale, C. W. Simultaneous optimization of thermochemical data for liquid iron alloys containing C, N, Ti, Si, Mn, S, and P. Metall. Mater. Trans. B 26, 467–484 (1995).
Tuff, J., Wood, B. J. & Wade, J. The effect of Si on metal-silicate partitioning of siderophile elements and implications for the conditions of core formation. Geochim. Cosmochim. Acta 75, 673–690 (2011).
Cartier, C. et al. Experimental study of trace element partitioning between enstatite and melt in enstatite chondrites at low oxygen fugacities and 5 GPa. Geochim. Cosmochim. Acta 130, 167–187 (2014).
Robie, R. A. & Hemingway, B. S. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar pressure and at higher temperatures. USGS Bull. 2131, 1–461 (1995).
Huebner, J. S. in Research Techniques for High Pressure and High Temperature (ed. Ulmer, G. C.) 123–177 (Springer, 1971).
Myers, J. T. & Eugster, H. P. The system Fe–Si–O: oxygen buffer calibrations to 1,500 K. Contrib. Mineral. Petrol. 82, 75–90 (1983).
Grove, T. L., Kinzler, R. J. & Bryan, W. B. in Mantle Flow and Melt Generation at Mid-Ocean Ridges (eds Phipps Morgan, J., Blackman, D. & Sinton, J.) 281–310 (American Geophysical Union, 1992).
Acknowledgements
This research was carried out with financial support from a Marie Curie Intra-European Fellowship (SULFURONMERCURY-327046) to O.N. and the Belspo BRAIN-be program (BR/143/A2/COME-IN). O.N. also acknowledges support from the Belgian Fund for Scientific Research—FNRS for a position of Postdoctoral Researcher (Grant 1.B.341.16). B.C. is a Research Associate of the Belgian Fund for Scientific Research—FNRS. L. Nittler is thanked for providing the most recent XRS maps of Mercury. B. Mandler and V. Honour are thanked for careful editing of the manuscript.
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O.N. and B.C. designed the project. O.N. conducted the experiments and modelling. O.N. and B.C. interpreted the results and prepared the manuscript.
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Namur, O., Charlier, B. Silicate mineralogy at the surface of Mercury. Nature Geosci 10, 9–13 (2017). https://doi.org/10.1038/ngeo2860
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DOI: https://doi.org/10.1038/ngeo2860