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Volcanic arcs fed by rapid pulsed fluid flow through subducting slabs

Abstract

At subduction zones, oceanic lithosphere that has interacted with sea water is returned to the mantle, heats up during descent and releases fluids by devolatilization of hydrous minerals. Models for the formation of magmas feeding volcanoes above subduction zones require largescale transport of these fluids into overlying mantle wedges1,2,3. Fluid flow also seems to be linked to seismicity in subducting slabs. However, the spatial and temporal scales of this fluid flow remain largely unknown, with suggested timescales ranging from tens to tens of thousands of years3,4,5. Here we use the Li–Ca–Sr isotope systems to consider fluid sources and quantitatively constrain the duration of subduction-zone fluid release at 70 km depth within subducting oceanic lithosphere, now exhumed in the Chinese Tianshan Mountains. Using lithium-diffusion modelling, we find that the wall-rock porosity adjacent to the flowpath of the fluids increased ten times above the background level. We show that fluids released by devolatilization travelled through the slab along major conduits in pulses with durations of about 200 years. Thus, although the overall slab dehydration process is continuous over millions of years and over a wide range of pressures and temperatures, we conclude that the fluids produced by dehydration in subducting slabs are mobilized in short-lived, channelized fluid-flow events.

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Figure 1: Outcrop photograph and apparent Rb/Sr-‘whole-rock isochron’ of an eclogite facies vein and its associated reaction halo in the Tianshan, China.
Figure 2: Calcium isotope ratios of the silicate rock fraction versus CaO concentration as a measure of the degree of Ca metasomatism.
Figure 3: Diffusion modelling of Li concentrations and δ7Li across the sampling profile perpendicular to the vein.

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References

  1. Schmidt, M. W. & Poli, S. Experimentally based water budgets for dehydrating slabs and consequences for arc magma generation. Earth Planet. Sci. Lett. 163, 361–379 (1998).

    Article  Google Scholar 

  2. Bebout, G. E. Metamorphic chemical geodynamics of subduction zones. Earth Planet. Sci. Lett. 260, 373–393 (2007).

    Article  Google Scholar 

  3. Turner, S., Evans, P. & Hawkesworth, C. Ultrafast source-to-surface movement of melt at island arcs from Ra-226-Th-230 systematics. Science 292, 1363–1366 (2001).

    Article  Google Scholar 

  4. Camacho, A. et al. Short-lived orogenic cycles and the eclogitization of cold crust by spasmodic hot fluids. Nature 435, 1191–1196 (2005).

    Article  Google Scholar 

  5. Penniston-Dorland, S. C., Sorensen, S. S., Ash, R. D. & Khadke, S. V. Lithium isotopes as a tracer of fluids in a subduction zone melange: Franciscan Complex, CA. Earth Planet. Sci. Lett. 292, 181–190 (2010).

    Article  Google Scholar 

  6. Zack, T. & John, T. An evaluation of reactive fluid flow and trace element mobility in subducting slabs. Chem. Geol. 239, 199–216 (2007).

    Article  Google Scholar 

  7. Putnis, A. & John, T. Replacement processes in the Earth’s Crust. Elements 6, 159–164 (2010).

    Article  Google Scholar 

  8. Scambelluri, M. & Philippot, P. Deep fluids in subduction zones. Lithos 55, 213–227 (2001).

    Article  Google Scholar 

  9. Hermann, J., Spandler, C., Hack, A. & Korsakov, A. V. Aqueous fluids and hydrous melts in high-pressure and ultra-high pressure rocks: Implications for element transfer in subduction zones. Lithos 92, 399–417 (2006).

    Article  Google Scholar 

  10. Ague, J. J. Extreme channelization of fluid and the problem of element mobility during barrovian metamorphism. Am. Mineral. 96, 333–352 (2011).

    Article  Google Scholar 

  11. Spandler, C. et al. Redistribution of trace elements during prograde metamorphism from lawsonite blueschist to eclogite facies; implications for deep subduction-zone processes. Contrib. Mineral. Petrol. 146, 205–222 (2003).

    Article  Google Scholar 

  12. Gao, J. & Klemd, R. Primary fluids entrapped at blueschist to eclogite transition; evidence from the Tianshan meta-subduction complex in northwestern China. Contrib. Mineral. Petrol. 142, 1–14 (2001).

    Article  Google Scholar 

  13. Gao, J., John, T., Klemd, R. & Xiong, X. Mobilisation of Ti–Nb–Ta during subduction: Insights from rutile precipitates in eclogite-facies segregations and veins (Tianshan, NW China). Geochim. Cosmochim. Acta 71, 4974–4996 (2007).

    Article  Google Scholar 

  14. Beinlich, A., Klemd, R., John, T. & Gao, J. Trace-element mobilization during Ca-metasomatism along a major fluid conduit: Eclogitization of blueschist as a consequence of fluid–rock interaction. Geochim. Cosmochim. Acta 74, 1892–1922 (2010).

    Article  Google Scholar 

  15. Glodny, J., Austrheim, H., Molina, J. F., Rusin, A. & Seward, D. Rb/Sr record of fluid–rock interaction in eclogites: The Marun-Keu complex, Polar Urals, Russia. Geochim. Cosmochim. Acta 67, 4353–4371 (2003).

    Article  Google Scholar 

  16. Klemd, R., John, T., Scherer, E. E., Rondenay, S. & Gao, J. Change in dip of subducting slabs at greater depths: Petrological and geochronological evidence from HP-UHP rocks (Tianshan, NW-China). Earth Planet. Sci. Lett. 310, 9–20 (2011).

    Article  Google Scholar 

  17. Klemd, R. et al. New age constraints on the metamorphic evolution of the high-pressure/low-temperature belt in the western Tianshan mountains, NW China. J. Geol. 113, 157–168 (2005).

    Article  Google Scholar 

  18. Veizer, J. Strontium isotopes in seawater through time. Annu. Rev. Earth Planet. Sci. 17, 141–167 (1989).

    Article  Google Scholar 

  19. Ranero, C. R., Phipps Morgan, J., McIntosh, K. & Reichert, C. Bending-related faulting and mantle serpentinization at the Middle American trench. Nature 425, 367–373 (2003).

    Article  Google Scholar 

  20. Amini, M. et al. Calcium Isotopes (δ44/40Ca) in MPI-DING reference glasses, USGS rock powders and various rocks: Evidence for Ca isotope fractionation in terrestrial silicates. Geostand. Geoanal. Res. 33, 231–247 (2009).

    Article  Google Scholar 

  21. Richter, F. M. et al. Kinetic isotopic fractionation during diffusion of ionic species in water. Geochim. Cosmochim. Acta 70, 277–289 (2006).

    Article  Google Scholar 

  22. Watson, E. B. & Baxter, E. F. Diffusion in solid-earth systems. Earth Planet. Sci. Lett. 253, 307–327 (2006).

    Article  Google Scholar 

  23. Teng, F-Z. et al. Diffusion-driven extreme lithium isotopic fractionation in country rocks of the Tin Mountain pegmatite. Earth Planet. Sci. Lett. 243, 701–710 (2006).

    Article  Google Scholar 

  24. Jamtveit, B., Austrheim, H. & Malthe-Sorensen, A. Accelerated hydration of the Earth’s deep crust induced by stress perturbations. Nature 408, 75–78 (2000).

    Article  Google Scholar 

  25. Norton, D. & Knapp, R. Transport phenomena in hydrothermal systems—Nature of porosity. Am. J. Sci. 277, 913–936 (1977).

    Article  Google Scholar 

  26. Baxter, E. F. & DePaolo, D. J. Field measurement of high temperature bulk reaction rates I: Theory and technique. Am. J. Sci. 302, 442–464 (2002).

    Article  Google Scholar 

  27. Skelton, A. Flux rates for water and carbon during greenschist facies metamorphism. Geology 39, 43–46 (2011).

    Article  Google Scholar 

  28. Ingebritsen, S. E. & Manning, C. E. Permeability of the continental crust: Dynamic variations inferred from seismicity and metamorphism. Geofluids 10, 193–205 (2010).

    Google Scholar 

  29. Oelkers, E. H. & Helgeson, H. C. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Aqueous tracer diffusion coefficients of ions to 1000 °C and 5 kb. Geochim. Cosmochim. Acta 52, 63–85 (1988).

    Article  Google Scholar 

  30. Marschall, H., Altherr, R. & Rüpke, L. Squeezing out the slab—modelling the release of Li, Be and B during progressive high-pressure metamorphism. Chem. Geol. 239, 323–335 (2007).

    Article  Google Scholar 

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Acknowledgements

We acknowledge discussions with and proofreading by K. Mezger and A. Putnis. We thank S. Penniston-Dorland and H. Marschall for their constructive criticisms. The Deutsche Forschungsgemeinschaft financially supported this research through grant JO 349/5-1. Samples of AOC were provided by the Ocean Drilling Program.

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Contributions

All authors participated in collecting the data and interpretation of the results; T.J. and N.G. took the lead in developing the final model. T.J. and R.K. focused on the fieldwork, N.G., T.J., R.H., G.E.B., H-M.S. and T.M. on geochemical methods and T.J., Y.Y.P. and R.D. on the Li chronometry.

Corresponding author

Correspondence to Nikolaus Gussone.

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The authors declare no competing financial interests.

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John, T., Gussone, N., Podladchikov, Y. et al. Volcanic arcs fed by rapid pulsed fluid flow through subducting slabs. Nature Geosci 5, 489–492 (2012). https://doi.org/10.1038/ngeo1482

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