Compound 1
6,6',6''-((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(2-(adamantan-1-yl)-4-methylphenolate)uranium(III)
From: The role of uranium–arene bonding in H2O reduction catalysis
Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.
[((Ad,MeArO)3mes)U] (1) was prepared according to the literature procedures (La Pierre, H. S., Kameo, H., Halter, D. P., Heinemann, F. W. & Meyer, K. Coordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex. Angew. Chem. Int. Ed. 53, 7154–7157 (2014); Rosenzweig, M. W. et al. Uranium(IV) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond. Chem. Sci. 7, 5857–5866 (2016)).
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348274178
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