Compound 5
tricarba[3]nickelocenophane
From: Main-chain metallopolymers at the static–dynamic boundary based on nickelocene
View in PubChem | 1H NMR | ESI MS | ESI MS | MDL Molfile | ChemDraw
Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.
The synthesis of 5 involved a modified literature procedure.29 The reaction of the ligand Li2[(C5H4)2(CH2)3] with NiCl2 was carried as described, but at 40 °C (vs. –78 °C in the original report), which resulted in the yield increasing from 17% to 44%.
