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The effect of gold loading and particle size on photocatalytic hydrogen production from ethanol over Au/TiO2 nanoparticles

Nature Chemistry volume 3, pages 489492 (2011) | Download Citation


Catalytic hydrogen production from renewables is a promising method for providing energy carriers in the near future. Photocatalysts capable of promoting this reaction are often composed of noble metal nanoparticles deposited on a semiconductor. The most promising semiconductor at present is TiO2. The successful design of these catalysts relies on a thorough understanding of the role of the noble metal particle size and the TiO2 polymorph. Here we demonstrate that Au particles in the size range 3–30 nm on TiO2 are very active in hydrogen production from ethanol. It was found that Au particles of similar size on anatase nanoparticles delivered a rate two orders of magnitude higher than that recorded for Au on rutile nanoparticles. Surprisingly, it was also found that Au particle size does not affect the photoreaction rate over the 3–12 nm range. The high hydrogen yield observed makes these catalysts promising materials for solar conversion.

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The authors would like to thank A. Goguet from Queen University of Belfast for discussions on gold particles. H.I. thanks Aberdeen City Council for a start-up grant to establish the Energy Futures Centre. The authors acknowledge the support of HEC Pakistan for the PhD scholarship to M.A.N. J.L. is grateful to grant CTQ2009-12520 (MICINN) and to ICREA Academia program (Generalitat de Catalunya), Spain.

Author information


  1. Energy Futures Research Centre, Department of Chemistry, University of Aberdeen, Aberdeen, AB24 3UE, UK

    • M. Murdoch
    • , M. A. Nadeem
    • , R. F. Howe
    •  & H. Idriss
  2. School of Engineering, Robert Gordon University, Aberdeen, AB10 1FR, UK

    • M. Murdoch
    • , M. A. Nadeem
    •  & H. Idriss
  3. Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand

    • G. I. N. Waterhouse
    • , M. A. Nadeem
    •  & J. B. Metson
  4. Chemical Engineering, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh, UK

    • M. A. Keane
  5. Institute of Energy Technologies and Centre for Research in Nanoengineering, Technical University of Catalonia, Barcelona, Spain

    • J. Llorca


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M.M. and M.A.N. conducted the photoreaction experiments, G.I.N.W. made the catalytic materials, J.L. produced the HRTEM and TEM images and provided the interpretation, H.I. conducted the XPS measurements, supervized M.M. and wrote the manuscript, J.B.M. supervised M.A.N., M.A.K. provided data interpretation for the photoreaction and R.H.F. provided data interpretation for the characterization of the materials.

Competing interests

The authors declare no competing financial interests.

Corresponding author

Correspondence to H. Idriss.

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