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Terrestrial nitrogen and noble gases in lunar soils

Abstract

The nitrogen in lunar soils is correlated to the surface and therefore clearly implanted from outside. The straightforward interpretation is that the nitrogen is implanted by the solar wind, but this explanation has difficulties accounting for both the abundance of nitrogen and a variation of the order of 30 per cent in the 15N/14N ratio. Here we propose that most of the nitrogen and some of the other volatile elements in lunar soils may actually have come from the Earth's atmosphere rather than the solar wind. We infer that this hypothesis is quantitatively reasonable if the escape of atmospheric gases, and implantation into lunar soil grains, occurred at a time when the Earth had essentially no geomagnetic field. Thus, evidence preserved in lunar soils might be useful in constraining when the geomagnetic field first appeared. This hypothesis could be tested by examination of lunar farside soils, which should lack the terrestrial component.

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Figure 1: Ion escape rates versus ionopause altitude for the present Earth's atmosphere without a global magnetic field.
Figure 2: Estimation of the fraction of the Earth wind (EW) that reaches the Moon.
Figure 3: D/H– 15 N/ 14 N mixing diagram.
Figure 4: Mixing diagrams.

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Acknowledgements

We thank B. Marty, D. Stevenson and K. Zahnle for suggestions and comments that improved the manuscript. We owe much to the work of K. Hashizume, V. Heber, and co-workers, which inspired us to undertake this work. This work is supported by the 21st Century Center of Excellence (21CoE) SELIS (Dynamics of Sun-Earth-Life Interactive System) Program of Japan. Author Contributions K.S. performed atmospheric escape estimation, and N.T. and H.S. ionospheric modelling.

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Correspondence to M. Ozima.

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Ozima, M., Seki, K., Terada, N. et al. Terrestrial nitrogen and noble gases in lunar soils. Nature 436, 655–659 (2005). https://doi.org/10.1038/nature03929

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