What determines how grains such as sand pack together to fill a space? A thoroughgoing investigation of how geometry and friction interact in such systems is a step towards a more general understanding.
How should we arrange objects to pack them as tightly as possible, making best use of all the available space? Packing problems have long fascinated both physicists and mathematicians, but have proved surprisingly tough nuts to crack. Take the 'Kepler conjecture', for instance. It was in 1611 that Johannes Kepler first suggested that the densest packing of identical spheres is achieved by cubic (facecentred cubic) and hexagonal arrangements, with a packing fraction of 74%. Carl Friedrich Gauss produced the first partial proof of this in 1831. What might be a final proof was published only in 1998. It is a 'proof by exhaustion', reached using modern computing power to crunch wearisomely through an inordinate number of possible packing configurations — and its ultimate veracity is still being checked.
Sphere packings are extremely important, not only in condensedmatter physics^{1}, where they describe the favoured configurations adopted by crystals, but also in computer science and mathematics^{2}, where they pop up in problems related to group theory, number theory and errorcorrecting codes. On page 629 of this issue, Song, Wang and Makse^{3} take a significant stride towards a unified theory of a particular type of packing — not of the regular packings of the Kepler conjecture, but the random, amorphous packings that model the behaviour of everyday granular materials such as sand and nuts (Fig. 1).
When spherical grains are randomly thrown into a box and shaken, they form an amorphous arrangement with a packing fraction of 64%, significantly lower than the 74% of the densest possible crystalline packing. Remarkably, this final density — the signature of 'random close packing' — was found to occur however the samples were prepared: whether by throwing grains into a box, shaking them and allowing them to settle; depositing them randomly around a disordered 'seed cluster'; slowly compressing a looser arrangement; and so on.
If small regions of regular, crystalline packing are created first, a random close packing can then be continuously compacted until a denser, entirely crystalline structure is obtained^{4}. When looking at individual configurations, therefore, the density value 64% does not seem to have any special importance. Its relevance must instead be related to the statistical properties of an ensemble of packings produced by a given method. Is random close packing favoured for entropic reasons, such that there are just many more ways of jumbling grains up to form a random close packing than any other configuration? Is it a welldefined 'metastable' state that can persist for a considerable time? Or is it related to a hidden critical point, such that particularly large numbers of particles must be rearranged to change the density (a quality characterized by a large 'correlation length')? Many attempts have been made to achieve the statistical description of random close packings that such questions demand^{5,6,7,8,9}. These studies, supported by numerical simulations, revealed how important geometry, and in particular the network of particle contacts^{5}, was in determining the density and other structural features of the final packing.
Random loose packings are related to random close packings, but are even more elusive. They are obtained by letting spheres settle very gently^{10}; the loosest stable packings that have been achieved have a packing fraction of about 55%, and friction is known to determine their stability. Is there a consistent statistical theory that can account for both close and loose random packings? Are the close and loose packings special points, or do similar stable configurations with packing fractions between 55% and 64% exist? Do these packings have critical properties such as a large correlation length^{5,11}? What is the relative importance of geometry and friction?
Song et al.^{3} provide answers to some of these questions. They develop a consistent, although approximate, meanfield theory of 'jammed' amorphous packings. A meanfield approach works by modelling the average interaction between bodies, thus making it the same for all the bodies in the packing. It is usually the first step towards any more sophisticated computation. The authors start by deriving a relation between the unoccupied space in any locality and the local geometrical coordination, which is defined as the average number of contacts per particle. The meanfield assumption means that some of the niceties of particle correlations are neglected, but the result agrees well with experimental data^{12}. The derived relation indicates that the packing fraction, which is directly related to the free volume, is determined solely by the geometrical coordination.
The authors go on to show that not all geometrical contacts carry a nonzero force. As a consequence, they introduce a mechanical coordination number, defined as the average number of contacts carrying a nonzero force. On the basis of numerical simulations, they assume that this number is a universal function of the friction coefficient, and is independent of the way the sample is prepared.
The emerging picture is thus of mechanical coordination determined uniquely by friction, and geometrical coordination related to density. Considerations of general stability require that both coordination numbers are somewhere between 4 and 6 (the mechanical coordination number is by definition smaller than the geometrical coordination number). One then finds a collection of states satisfying these bounds, and draws a phase diagram by plotting two independent variables chosen from among the density, friction and the two coordination numbers of the states against each other. Song et al.^{3} choose density and mechanical coordination number. The final prediction is that if, for instance, friction is fixed (as it is in experiments), one can obtain packings with a whole range of densities (Fig. 2). The authors thus rationalize what is suggested by many experiments from the perspective of statistical mechanics.
An intriguing question immediately raised is how one might predict in which precise state a given preparation procedure will end. The authors follow a 20yearold suggestion^{13} in introducing a variable they term compactivity. Compactivity is akin to an inverse pressure, in that it decreases as density increases, and Song et al. produce some numerical evidence that, like thermodynamical pressure, it could be a 'state variable' that links different, seemingly independent, experimental control parameters.
Similar ideas have emerged in related contexts, such as the physics of glasses and problems of combinatorial optimization^{8,14}. In the latter example, researchers have tried to find a relationship between the behaviour of algorithms searching for solutions and the presence of transitions between different phases, and to identify state variables that could characterize these phases. Results so far have been contradictory, with some of them bringing into question the validity of this idea in situations beyond simple meanfield models^{15}. But the perspective offered by work such as this, and that of Song et al.^{3} — with its promise of transforming complex problems of nonequilibrium dynamics into much simpler statistical problems — is too fascinating to abandon, and the wait for new results will not be long.
References
 1
Torquato, S. Random Heterogeneous Materials: Microstructure and Macroscopic Properties (Springer, New York, 2006).
 2
Conway, J. H. & Sloane, N. J. A. Sphere Packings, Lattices and Groups (Springer, New York, 1999).
 3
Song, C., Wang, P. & Makse, H. A. Nature 453, 629–632 (2008).
 4
Torquato, S., Truskett, T. M. & Debenedetti, P. G. Phys. Rev. Lett. 84, 2064–2067 (2000).
 5
O'Hern, C. S., Silbert, L. E., Liu, A. J. & Nagel, S. R. Phys. Rev. E 68, 011306 (2003).
 6
Parisi, G. & Zamponi, F. J. Chem. Phys. 123, 144501 (2005).
 7
Parisi, G. & Zamponi, F. preprint at http://www.arxiv.org/abs/0802.2180 (2008).
 8
Krzakala, F. & Kurchan, J. Phys. Rev. E 76, 021122 (2007).
 9
Kamien, R. D. & Liu, A. J. Phys. Rev. Lett. 99, 155501 (2007).
 10
Onoda, G. Y. & Liniger, E. G. Phys. Rev. Lett. 64, 2727–2730 (1990).
 11
Dauchot, O., Marty, G. & Biroli, G. Phys. Rev. Lett. 95, 265701 (2005).
 12
Aste, T., Saadatfar, M. & Senden, T. J. J. Stat. Mech. P07010 (2006).
 13
Edwards, S. F. & Oakeshott, R. B. S. Physica A 157, 1080–1090 (1989).
 14
Altarelli, F., Monasson, R., Semerjian, G. & Zamponi, F. preprint at http://www.arxiv.org/abs/0802.1829 (2008).
 15
Kurchan, J. in Stealing the Gold: A Celebration of the Pioneering Physics of Sam Edwards (eds Goldbart, P. M., Goldenfeld, N. & Sherrington, D.) 375–390 (Oxford Univ. Press, 2004).
Author information
Affiliations
Rights and permissions
About this article
Cite this article
Zamponi, F. Packings close and loose. Nature 453, 606–607 (2008). https://doi.org/10.1038/453606a
Published:
Issue Date:
Further reading

Influence of the longrange forces in nonGaussian randompacking dynamics
Physics Letters A (2019)

Random loose packing of small particles with liquid cohesion
AIChE Journal (2019)

Viscoelastic granular dampers under lowamplitude vibration
Journal of Vibration and Control (2018)

Melt segregation from silicic crystal mushes: a critical appraisal of possible mechanisms and their microstructural record
Contributions to Mineralogy and Petrology (2018)

Orthopyroxene oikocrysts in the MG1 chromitite layer of the Bushveld Complex: implications for cumulate formation and recrystallisation
Contributions to Mineralogy and Petrology (2018)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.