Phase transitions in the incoherent lattice fluctuations in YBa 2Cu3O7-δ


The growing body of experimental evidence1,2,3,4,5,6,7 for the existence of complex textures of charges and spins in the high-temperature superconductors has drawn attention to the so-called ‘stripe-phase’ model8,9,10,11,12 as a possible basis for the mechanism of superconductivity in these materials. Such observations have until now been restricted to systems where the texture dynamics are slow or suppressed altogether, and do not include the important case of YBa2Cu 3O7-δ. It seems likely that the dynamic behaviour of stripes12,13, which has been suggested to undergo several phase transitions as a function of temperature12, should also be reflected in the lattice properties of the host materials, and this forms the motivation for our present experiments. Specifically, we use MeV helium ion channelling, an ultrafast real-space probe of atomic displacements (with sub-picometre resolution), to probe incoherent lattice fluctuations in YBa2Cu 3O7-δ as a function of temperature and oxygen doping. We detect lattice fluctuations that are larger than the expected thermal vibration component, and which show anomalies characteristic of the phase transitions anticipated for a dynamic stripe phase. Comparison of our lattice results with single-particle-tunnelling and photoemission data highlights the importance of spin–charge separation phenomena in the copper oxide superconductors.

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Figure 1: Temperature dependence of atomic displacements for YBa2Cu 3O7- x (x ≈ 0.05 and 0.065).
Figure 2: Temperature dependence of excess atomic displacement in YBa2Cu 3O7-x.
Figure 3: Oxygen-doping dependence of phase transition or crossover temperatures.


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We thank R. L. Greene for reading of the manuscript and suggestions. This work was supported by the National Science Foundation under the Materials Research Science and Engineering Center and Office of Naval Research at Maryland, by the state of Texas through the Texas Center for Superconductivity at the University of Houston, and the Department of Energy at Argonne.

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Correspondence to T. Venkatesan.

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